Strain control of oxygen kinetics in the Ruddlesden-Popper oxide La1.85Sr0.15CuO4

Meyer, Tricia L.; Jacobs, Ryan; Lee, Dongkyu; Jiang, Lu; Freeland, John W.; Sohn, Changhee; Egami, Takeshi; Morgan, Dane; Lee, Ho Nyung

doi:10.1038/s41467-017-02568-z

Title: Strain control of oxygen kinetics in the Ruddlesden-Popper oxide La_1.85Sr_0.15CuO₄

Abstract

Oxygen defect control has long been considered an important route to functionalizing complex oxide films. However, the nature of oxygen defects in thin films is often not investigated beyond basic redox chemistry. One of the model examples for oxygen-defect studies is the layered Ruddlesden-Popper phase La2-xSrxCuO4-delta (LSCO), in which the superconducting transition temperature is highly sensitive to epitaxial strain. However, previous observations of strain-superconductivity coupling in LSCO thin films were mainly understood in terms of elastic contributions to mechanical buckling, with minimal consideration of kinetic or thermodynamic factors. Here, we report that the oxygen non-stoichiometry commonly reported for strained cuprates is mediated by the strain-modified surface exchange kinetics, rather than reduced thermodynamic oxygen formation energies. Remarkably, tensile-strained LSCO shows nearly an order of magnitude faster oxygen exchange rate than a compressively strained film, providing a strategy for developing high-performance energy materials.

Authors:

Meyer, Tricia L. ^[1]; Jacobs, Ryan ^[2];

^[1]; Jiang, Lu ^[3];

^[4];

^[1]; Egami, Takeshi ^[5];

^[2];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Univ. of Wisconsin, Madison, WI (United States). Dept. of Materials Science and Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy. Dept. of Materials Science and Engineering

Publication Date:: Mon Jan 08 00:00:00 EST 2018

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Argonne National Laboratory (ANL), Argonne, IL (United States); Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:: 1422606

Alternate Identifier(s):: OSTI ID: 1460837

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357; 1148011; OCI-1053575

Resource Type:: Accepted Manuscript

Journal Name:: Nature Communications

Additional Journal Information:: Journal Volume: 9; Journal ID: ISSN 2041-1723

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; electronic properties and materials; superconducting properties and materials; surfaces, interfaces and thin films

Citation Formats


                    Meyer, Tricia L., Jacobs, Ryan, Lee, Dongkyu, Jiang, Lu, Freeland, John W., Sohn, Changhee, Egami, Takeshi, Morgan, Dane, and Lee, Ho Nyung. Strain control of oxygen kinetics in the Ruddlesden-Popper oxide La1.85Sr0.15CuO4.  United States: N. p., 2018. 
Web.  doi:10.1038/s41467-017-02568-z.

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                    Meyer, Tricia L., Jacobs, Ryan, Lee, Dongkyu, Jiang, Lu, Freeland, John W., Sohn, Changhee, Egami, Takeshi, Morgan, Dane, & Lee, Ho Nyung. Strain control of oxygen kinetics in the Ruddlesden-Popper oxide La1.85Sr0.15CuO4.  United States.  https://doi.org/10.1038/s41467-017-02568-z

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                    Meyer, Tricia L., Jacobs, Ryan, Lee, Dongkyu, Jiang, Lu, Freeland, John W., Sohn, Changhee, Egami, Takeshi, Morgan, Dane, and Lee, Ho Nyung. Mon .  
"Strain control of oxygen kinetics in the Ruddlesden-Popper oxide La1.85Sr0.15CuO4".  United States.  https://doi.org/10.1038/s41467-017-02568-z.  https://www.osti.gov/servlets/purl/1422606.

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@article{osti_1422606,

  title        = {Strain control of oxygen kinetics in the Ruddlesden-Popper oxide La1.85Sr0.15CuO4},

  author       = {Meyer, Tricia L. and Jacobs, Ryan and Lee, Dongkyu and Jiang, Lu and Freeland, John W. and Sohn, Changhee and Egami, Takeshi and Morgan, Dane and Lee, Ho Nyung},

  abstractNote = {Oxygen defect control has long been considered an important route to functionalizing complex oxide films. However, the nature of oxygen defects in thin films is often not investigated beyond basic redox chemistry. One of the model examples for oxygen-defect studies is the layered Ruddlesden-Popper phase La2-xSrxCuO4-delta (LSCO), in which the superconducting transition temperature is highly sensitive to epitaxial strain. However, previous observations of strain-superconductivity coupling in LSCO thin films were mainly understood in terms of elastic contributions to mechanical buckling, with minimal consideration of kinetic or thermodynamic factors. Here, we report that the oxygen non-stoichiometry commonly reported for strained cuprates is mediated by the strain-modified surface exchange kinetics, rather than reduced thermodynamic oxygen formation energies. Remarkably, tensile-strained LSCO shows nearly an order of magnitude faster oxygen exchange rate than a compressively strained film, providing a strategy for developing high-performance energy materials.},

  doi          = {10.1038/s41467-017-02568-z},

  journal      = {Nature Communications},

  number       = ,

  volume       = 9,

  place        = {United States},

  year         = {Mon Jan 08 00:00:00 EST 2018},

  month        = {Mon Jan 08 00:00:00 EST 2018}

}

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Works referencing / citing this record:

Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
journal, March 2019

Yang, Gene; Jung, Wonsang; Ahn, Sung-Jin
Applied Sciences, Vol. 9, Issue 5
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Title: Strain control of oxygen kinetics in the Ruddlesden-Popper oxide La1.85Sr0.15CuO4

Abstract

Citation Formats

Strain effects on oxygen migration in perovskites journal, January 2015

Room-temperature ferroelectricity in strained SrTiO3 journal, August 2004

Generalized Gradient Approximation Made Simple journal, October 1996

Growth of homoepitaxial SrTiO3 thin films by molecular-beam epitaxy journal, April 2009

Doubling the critical temperature of La1.9Sr0.1CuO4 using epitaxial strain journal, July 1998

Thickness-dependent electronic structure of ultrathin SrRuO3 films studied by in situ photoemission spectroscopy journal, October 2005

Superconductivity at 40 K in the Oxygen-Defect Perovskites La2-xSrxCuO4-y journal, March 1987

Oxygen Point Defect Chemistry in Ruddlesden–Popper Oxides (La 1– x Sr x ) 2 MO 4±δ (M = Co, Ni, Cu) journal, May 2016

Bulk superconductivity at 36 K in La 1.8 Sr 0.2 CuO 4 journal, January 1987

Special points for Brillouin-zone integrations journal, June 1976

Metal-insulator transitions journal, October 1998

Silicon Device Scaling to the Sub-10-nm Regime journal, December 2004

Out-of-plane orbital characters of intrinsic and doped holes in La 2 − x Sr x CuO 4 journal, April 1992

High-temperature interface superconductivity between metallic and insulating copper oxides journal, October 2008

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Scaling of transition temperature and CuO2 plane buckling in a high-temperature superconductor journal, January 1999

From ultrasoft pseudopotentials to the projector augmented-wave method journal, January 1999

Symmetry-Driven Atomic Rearrangement at a Brownmillerite-Perovskite Interface journal, December 2015

Strain-controlled oxygen vacancy formation and ordering in CaMnO 3 journal, August 2013

Redox-Based Resistive Switching Memories - Nanoionic Mechanisms, Prospects, and Challenges journal, July 2009

Enhancing Perovskite Electrocatalysis through Strain Tuning of the Oxygen Deficiency journal, June 2016

Band-Structure Trend in Hole-Doped Cuprates and Correlation with T c max journal, July 2001

Strain-relaxation and critical thickness of epitaxial La 1.85 Sr 0.15 CuO 4 films journal, December 2015

La 2 − x Sr x CuO y epitaxial thin films ( x = 0 to 2): Structure, strain, and superconductivity journal, May 2000

A high-mobility electron gas at the LaAlO3/SrTiO3 heterointerface journal, January 2004

Correlation of T c with hole concentration in La 2 − x Sr x Cu O 4 − δ superconductors journal, September 1987

Special quasirandom structures journal, July 1990

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Estimation of effective ionic radii in highly defective perovskite-type oxides from experimental data journal, March 2001

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Intrinsic defects and conduction characteristics of Sc 2 O 3 in thermionic cathode systems journal, August 2012

Chemical Expansivity of Electrochemical Ceramics journal, September 2001

First-principles calculation of intrinsic defect formation volumes in silicon journal, November 2005

Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films journal, January 2016

Electronic states in La 2 − x Sr x CuO 4 + δ probed by soft-x-ray absorption journal, January 1991

Strong polarization enhancement in asymmetric three-component ferroelectric superlattices journal, January 2005

Epitaxial Strain and Superconductivity in L a 2 − x S r x C u O 4 Thin Films journal, August 2002

Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures journal, March 2003

Silicon Device Scaling to the Sub-10-nm Regime journal, March 2005

Metal-insulator transitions journal, June 1991

Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets journal, May 2021

Strain-controlled oxygen vacancy formation and ordering in CaMnO₃ text, January 2013

Band-Structure Trend in Hole-Doped Cuprates and Correlation with Tc max text, January 2001

Strong polarization enhancement in asymmetric three-component ferroelectric superlattices journal, April 2005

Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films text, January 2016

Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes journal, March 2019

Title: Strain control of oxygen kinetics in the Ruddlesden-Popper oxide La_1.85Sr_0.15CuO₄

Strain effects on oxygen migration in perovskites
journal, January 2015

Room-temperature ferroelectricity in strained SrTiO₃
journal, August 2004

Generalized Gradient Approximation Made Simple
journal, October 1996

Growth of homoepitaxial SrTiO3 thin films by molecular-beam epitaxy
journal, April 2009

Doubling the critical temperature of La1.9Sr0.1CuO4 using epitaxial strain
journal, July 1998

Thickness-dependent electronic structure of ultrathin SrRuO3 films studied by in situ photoemission spectroscopy
journal, October 2005

Superconductivity at 40 K in the Oxygen-Defect Perovskites La2-xSrxCuO4-y
journal, March 1987

Oxygen Point Defect Chemistry in Ruddlesden–Popper Oxides (La _{1– x} Sr _x ) ₂ MO _4±δ (M = Co, Ni, Cu)
journal, May 2016

Bulk superconductivity at 36 K in ${La}_{1.8}$ ${Sr}_{0.2}$ ${CuO}_{4}$
journal, January 1987

Special points for Brillouin-zone integrations
journal, June 1976

Metal-insulator transitions
journal, October 1998

Silicon Device Scaling to the Sub-10-nm Regime
journal, December 2004

Out-of-plane orbital characters of intrinsic and doped holes in ${La}_{2 - x}$ ${Sr}_{x}$ ${CuO}_{4}$
journal, April 1992

High-temperature interface superconductivity between metallic and insulating copper oxides
journal, October 2008

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Scaling of transition temperature and CuO2 plane buckling in a high-temperature superconductor
journal, January 1999

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Symmetry-Driven Atomic Rearrangement at a Brownmillerite-Perovskite Interface
journal, December 2015

Strain-controlled oxygen vacancy formation and ordering in CaMnO $_{3}$
journal, August 2013

Redox-Based Resistive Switching Memories - Nanoionic Mechanisms, Prospects, and Challenges
journal, July 2009

Enhancing Perovskite Electrocatalysis through Strain Tuning of the Oxygen Deficiency
journal, June 2016

Band-Structure Trend in Hole-Doped Cuprates and Correlation with $T_{c \max}$
journal, July 2001

Strain-relaxation and critical thickness of epitaxial La _1.85 Sr _0.15 CuO ₄ films
journal, December 2015

${La}_{2 - x} {Sr}_{x} {CuO}_{y}$ epitaxial thin films $(x = 0$ to 2): Structure, strain, and superconductivity
journal, May 2000

A high-mobility electron gas at the LaAlO3/SrTiO3 heterointerface
journal, January 2004

Correlation of $T_{c}$ with hole concentration in ${La}_{2 - x} {Sr}_{x} Cu O_{4 - δ}$ superconductors
journal, September 1987

Special quasirandom structures
journal, July 1990

Electronic and ionic transport properties and other physical aspects of perovskites
journal, September 2004

Estimation of effective ionic radii in highly defective perovskite-type oxides from experimental data
journal, March 2001

Electron correlations in narrow energy bands
journal, November 1963

Intrinsic defects and conduction characteristics of Sc $_{2}$ O $_{3}$ in thermionic cathode systems
journal, August 2012

Chemical Expansivity of Electrochemical Ceramics
journal, September 2001

First-principles calculation of intrinsic defect formation volumes in silicon
journal, November 2005

Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films
journal, January 2016

Electronic states in ${La}_{2 - x}$ ${Sr}_{x}$ ${CuO}_{4 + δ}$ probed by soft-x-ray absorption
journal, January 1991

Strong polarization enhancement in asymmetric three-component ferroelectric superlattices
journal, January 2005

Epitaxial Strain and Superconductivity in ${L a}_{2 - x} {S r}_{x} {C u O}_{4}$ Thin Films
journal, August 2002

Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures
journal, March 2003

Silicon Device Scaling to the Sub-10-nm Regime
journal, March 2005

Metal-insulator transitions
journal, June 1991

Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021

Strain-controlled oxygen vacancy formation and ordering in CaMnO₃
text, January 2013

Band-Structure Trend in Hole-Doped Cuprates and Correlation with Tc max
text, January 2001

Strong polarization enhancement in asymmetric three-component ferroelectric superlattices
journal, April 2005

Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films
text, January 2016

Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
journal, March 2019