Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

Manson, Jamie L.; Schlueter, John A.; Garrett, Kerry E.; Goddard, Paul A.; Lancaster, Tom; Möller, Johannes S.; Blundell, Stephen J.; Steele, Andrew J.; Franke, Isabel; Pratt, Francis L.; Singleton, John; Bendix, Jesper; Lapidus, Saul H.; Uhlarz, Marc; Ayala-Valenzuela, Oscar; McDonald, Ross David; Gurak, Mary; Baines, Christopher

doi:10.1039/C6CC05873F

Title: Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4-x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system

Abstract

We present that these title compounds are bimetallic MOFs containing [Cu(pyz)₂]²⁺ square lattices linked by MF₆^n-octahedra. In each, only the Cu²⁺ spins exhibit long-range magnetic order below 3.5 K (M = V⁴⁺) and 2.6 K (M = Ga³⁺). The V⁴⁺ spins remain disordered down to 0.5 K.

Authors:

Manson, Jamie L. ^[1]; Schlueter, John A. ^[2]; Garrett, Kerry E. ^[1]; Goddard, Paul A. ^[3]; Lancaster, Tom ^[4]; Möller, Johannes S. ^[5]; Blundell, Stephen J. ^[5]; Steele, Andrew J. ^[5]; Franke, Isabel ^[5]; Pratt, Francis L. ^[6];

^[7]; Bendix, Jesper ^[8]; Lapidus, Saul H. ^[2]; Uhlarz, Marc ^[9]; Ayala-Valenzuela, Oscar ^[7];

^[7]; Gurak, Mary ^[7]; Baines, Christopher ^[10]

Eastern Washington University, Cheney, WA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
University of Warwick, Coventry (United Kingdom)
Durham University (United Kingdom)
University of Oxford (United Kingdom)
STFC Rutherford Appleton Laboratory, Oxfordshire (United Kingdom)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
University of Copenhagen (Denmark)
Hochfeld-Magnetlabor Dresden (HLD-EMFL), Helmholtz-Zentrum Dresden Rossendorf (Germany)
Paul Scherrer Institut (Switzerland)

Publication Date:: Tue Sep 27 00:00:00 EDT 2016

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1415389

Report Number(s):: LA-UR-17-24407
Journal ID: ISSN 1359-7345; TRN: US1800790

Grant/Contract Number:: AC52-06NA25396

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 52; Journal Issue: 85; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; High Magnetic Field Science

Citation Formats


                    Manson, Jamie L., Schlueter, John A., Garrett, Kerry E., Goddard, Paul A., Lancaster, Tom, Möller, Johannes S., Blundell, Stephen J., Steele, Andrew J., Franke, Isabel, Pratt, Francis L., Singleton, John, Bendix, Jesper, Lapidus, Saul H., Uhlarz, Marc, Ayala-Valenzuela, Oscar, McDonald, Ross David, Gurak, Mary, and Baines, Christopher. Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system.  United States: N. p., 2016. 
Web.  doi:10.1039/C6CC05873F.

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                    Manson, Jamie L., Schlueter, John A., Garrett, Kerry E., Goddard, Paul A., Lancaster, Tom, Möller, Johannes S., Blundell, Stephen J., Steele, Andrew J., Franke, Isabel, Pratt, Francis L., Singleton, John, Bendix, Jesper, Lapidus, Saul H., Uhlarz, Marc, Ayala-Valenzuela, Oscar, McDonald, Ross David, Gurak, Mary, & Baines, Christopher. Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system.  United States.  https://doi.org/10.1039/C6CC05873F

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                    Manson, Jamie L., Schlueter, John A., Garrett, Kerry E., Goddard, Paul A., Lancaster, Tom, Möller, Johannes S., Blundell, Stephen J., Steele, Andrew J., Franke, Isabel, Pratt, Francis L., Singleton, John, Bendix, Jesper, Lapidus, Saul H., Uhlarz, Marc, Ayala-Valenzuela, Oscar, McDonald, Ross David, Gurak, Mary, and Baines, Christopher. Tue .  
"Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system".  United States.  https://doi.org/10.1039/C6CC05873F.  https://www.osti.gov/servlets/purl/1415389.

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@article{osti_1415389,

  title        = {Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system},

  author       = {Manson, Jamie L. and Schlueter, John A. and Garrett, Kerry E. and Goddard, Paul A. and Lancaster, Tom and Möller, Johannes S. and Blundell, Stephen J. and Steele, Andrew J. and Franke, Isabel and Pratt, Francis L. and Singleton, John and Bendix, Jesper and Lapidus, Saul H. and Uhlarz, Marc and Ayala-Valenzuela, Oscar and McDonald, Ross David and Gurak, Mary and Baines, Christopher},

  abstractNote = {We present that these title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n-octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.},

  doi          = {10.1039/C6CC05873F},

  journal      = {ChemComm},

  number       = 85,

  volume       = 52,

  place        = {United States},

  year         = {Tue Sep 27 00:00:00 EDT 2016},

  month        = {Tue Sep 27 00:00:00 EDT 2016}

}

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Works referenced in this record:

Dinuclear Complexes Containing Linear M–F–M [M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)] Bridges: Trends in Structures, Antiferromagnetic Superexchange Interactions, and Spectroscopic Properties
journal, October 2012

Reger, Daniel L.; Pascui, Andrea E.; Smith, Mark D.
Inorganic Chemistry, Vol. 51, Issue 21
DOI: 10.1021/ic301757g

Structural, Electronic, and Magnetic Properties of Quasi-1D Quantum Magnets [Ni(HF ₂ )(pyz) ₂ ]X (pyz = pyrazine; X = PF ₆ ^– , SbF ₆ ^– ) Exhibiting Ni-FHF-Ni and Ni-pyz-Ni Spin Interactions
journal, July 2011

Manson, Jamie L.; Lapidus, Saul H.; Stephens, Peter W.
Inorganic Chemistry, Vol. 50, Issue 13
DOI: 10.1021/ic102532h

Experimental and Theoretical Electron Density Analysis of Copper Pyrazine Nitrate Quasi-Low-Dimensional Quantum Magnets
journal, February 2016

Dos Santos, Leonardo H. R.; Lanza, Arianna; Barton, Alyssa M.
Journal of the American Chemical Society, Vol. 138, Issue 7
DOI: 10.1021/jacs.5b12817

Thermodynamics of the Spin- $1 / 2$ Antiferromagnetic Uniform Heisenberg Chain
journal, May 2000

Klümper, A.; Johnston, D. C.
Physical Review Letters, Vol. 84, Issue 20
DOI: 10.1103/PhysRevLett.84.4701

Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets
journal, August 2008

Goddard, P. A.; Singleton, J.; Sengupta, P.
New Journal of Physics, Vol. 10, Issue 8
DOI: 10.1088/1367-2630/10/8/083025

Magnetic properties of the quasi-two-dimensional $S = \frac{1}{2}$ Heisenberg antiferromagnet $[Cu {(pyz)}_{2} ({HF}_{2})] {PF}_{6}$
journal, February 2010

Čižmár, E.; Zvyagin, S. A.; Beyer, R.
Physical Review B, Vol. 81, Issue 6
DOI: 10.1103/PhysRevB.81.064422

Magnetic order in quasi-two-dimensional molecular magnets investigated with muon-spin relaxation
journal, August 2011

Steele, A. J.; Lancaster, T.; Blundell, S. J.
Physical Review B, Vol. 84, Issue 6
DOI: 10.1103/PhysRevB.84.064412

Strong H···F Hydrogen Bonds as Synthons in Polymeric Quantum Magnets: Structural, Magnetic, and Theoretical Characterization of [Cu(HF ₂ )(pyrazine) ₂ ]SbF ₆ , [Cu ₂ F(HF)(HF ₂ )(pyrazine) ₄ ](SbF ₆ ) ₂ , and [CuAg(H ₃ F ₄ )(pyrazine) ₅ ](SbF ₆ ) ₂
journal, May 2009

Manson, Jamie L.; Schlueter, John A.; Funk, Kylee A.
Journal of the American Chemical Society, Vol. 131, Issue 19
DOI: 10.1021/ja808761d

Two-Dimensional Heisenberg Antiferromagnets: Syntheses, X-ray Structures, and Magnetic Behavior of [Cu(pz) ₂ ](ClO ₄ ) ₂ , [Cu(pz) ₂ ](BF ₄ ) ₂ , and [Cu(pz) ₂ (NO ₃ )](PF ₆ )
journal, May 2007

Woodward, F. Matthew; Gibson, Pamela J.; Jameson, Geoffrey B.
Inorganic Chemistry, Vol. 46, Issue 10
DOI: 10.1021/ic0621392

Hydrothermal Synthesis of Vanadium Oxyfluoride Chains Incorporating Covalently Bound Copper Coordination Complexes
journal, October 2008

Mahenthirarajah, Thushitha; Li, Yang; Lightfoot, Philip
Inorganic Chemistry, Vol. 47, Issue 19
DOI: 10.1021/ic801106h

Muon-Fluorine Entangled States in Molecular Magnets
journal, December 2007

Lancaster, T.; Blundell, S. J.; Baker, P. J.
Physical Review Letters, Vol. 99, Issue 26
DOI: 10.1103/PhysRevLett.99.267601

Crystal Structure and Antiferromagnetic Ordering of Quasi-2D [Cu(HF2)(pyz)2]TaF6 (pyz=pyrazine)
journal, January 2010

Manson, J. L.; Schlueter, J. A.; McDonald, R. D.
Journal of Low Temperature Physics, Vol. 159, Issue 1-2
DOI: 10.1007/s10909-009-0079-5

Synthesis, structure of [H3dien]·(MF6)·H2O (M=Cr, Fe) and 57Fe Mössbauer study of [H3dien]·(FeF6)·H2O
journal, June 2007

Ben Ali, Amor; Trang Dang, Minh; Grenèche, Jean-Marc
Journal of Solid State Chemistry, Vol. 180, Issue 6
DOI: 10.1016/j.jssc.2007.03.030

Dividing the Spoils: Role of Pyrazine Ligands and Perchlorate Counterions in the Magnetic Properties of Bis(pyrazine)diperchloratecopper(II), [Cu(pz) ₂ ](ClO ₄ ) ₂
journal, October 2013

Vela, Sergi; Jornet-Somoza, Joaquim; Turnbull, Mark M.
Inorganic Chemistry, Vol. 52, Issue 22
DOI: 10.1021/ic400712s

Crystal structure and magnetic characterization of [C(NH2)3]3FeF6
journal, July 1987

Fourquet, J. L.; Plet, F.; Calage, Y.
Journal of Solid State Chemistry, Vol. 69, Issue 1
DOI: 10.1016/0022-4596(87)90012-0

Mixed valency and magnetism in cyanometallates and Prussian blue analogues
journal, September 2007

Herrera, J. M.; Bachschmidt, A.; Villain, F.
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 366, Issue 1862
DOI: 10.1098/rsta.2007.2145

Hydrothermal chemistry of oligomeric vanadium oxyfluorides
journal, January 2007

Aldous, David W.; Stephens, Nicholas F.; Lightfoot, Philip
Dalton Transactions, Issue 22
DOI: 10.1039/b702146a

Two-dimensional $S = \frac{1}{2}$ Heisenberg antiferromagnets: Synthesis, structure, and magnetic properties
journal, March 2002

Woodward, F. M.; Albrecht, A. S.; Wynn, C. M.
Physical Review B, Vol. 65, Issue 14
DOI: 10.1103/PhysRevB.65.144412

[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2? and pyrazine ligands
journal, January 2006

Manson, Jamie L.; Conner, Marianne M.; Schlueter, John A.
Chemical Communications, Issue 47
DOI: 10.1039/b608791d

Experimental and Theoretical Electron Density Analysis of Copper Pyrazine Nitrate Quasi-Low-Dimensional Quantum Magnets
text, January 2016

Blundell, Stephen J.; Lanza, Arianna; Williams, Robert C.
American Chemical Society
DOI: 10.7892/boris.78906

Magnetic properties of the quasi-two-dimensional S = 1/2 Heisenberg antiferromagnet [Cu(pyz)2(HF2)]PF6
text, January 2009

Cizmar, E.; Zvyagin, S. A.; Beyer, R.
arXiv
DOI: 10.48550/arxiv.0911.4402

Thermodynamics of the Spin-1/2 Antiferromagnetic Uniform Heisenberg Chain
text, January 2000

Klümper, A.; Johnston, D. C.
arXiv
DOI: 10.48550/arxiv.cond-mat/0002140

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DOI: 10.1002/chem.201605507

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New Journal of Chemistry, Vol. 43, Issue 17
DOI: 10.1039/c8nj04724c

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Title: Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

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Citation Formats

Dinuclear Complexes Containing Linear M–F–M [M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)] Bridges: Trends in Structures, Antiferromagnetic Superexchange Interactions, and Spectroscopic Properties journal, October 2012

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journal, January 2010

Synthesis, structure of [H3dien]·(MF6)·H2O (M=Cr, Fe) and 57Fe Mössbauer study of [H3dien]·(FeF6)·H2O
journal, June 2007

Dividing the Spoils: Role of Pyrazine Ligands and Perchlorate Counterions in the Magnetic Properties of Bis(pyrazine)diperchloratecopper(II), [Cu(pz) ₂ ](ClO ₄ ) ₂
journal, October 2013

Crystal structure and magnetic characterization of [C(NH2)3]3FeF6
journal, July 1987

Mixed valency and magnetism in cyanometallates and Prussian blue analogues
journal, September 2007

Hydrothermal chemistry of oligomeric vanadium oxyfluorides
journal, January 2007

Two-dimensional $S = \frac{1}{2}$ Heisenberg antiferromagnets: Synthesis, structure, and magnetic properties
journal, March 2002

[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2? and pyrazine ligands
journal, January 2006

Experimental and Theoretical Electron Density Analysis of Copper Pyrazine Nitrate Quasi-Low-Dimensional Quantum Magnets
text, January 2016

Magnetic properties of the quasi-two-dimensional S = 1/2 Heisenberg antiferromagnet [Cu(pyz)2(HF2)]PF6
text, January 2009

Thermodynamics of the Spin-1/2 Antiferromagnetic Uniform Heisenberg Chain
text, January 2000

Continuous One-Step Synthesis of Porous M-XF ₆ -Based Metal-Organic and Hydrogen-Bonded Frameworks
journal, April 2017

Vapor-assisted preparation of Mn/Fe/Co/Zn–Cu bimetallic metal–organic frameworks based on octahedron micron crystals (PCN-6′)
journal, January 2019