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Title: Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 - x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system

Abstract

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

Authors:
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)
OSTI Identifier:
1393492
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 52; Journal Issue: 85; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; complexes; heisenberg antiferromagnets; magnetic-properties; pyrazine ligands

Citation Formats

Manson, Jamie L., Schlueter, John A., Garrett, Kerry E., Goddard, Paul A., Lancaster, Tom, Möller, Johannes S., Blundell, Stephen J., Steele, Andrew J., Franke, Isabel, Pratt, Francis L., Singleton, John, Bendix, Jesper, Lapidus, Saul H., Uhlarz, Marc, Ayala-Valenzuela, Oscar, McDonald, Ross D., Gurak, Mary, and Baines, Christopher. Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 - x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system. United States: N. p., 2016. Web. doi:10.1039/c6cc05873f.
Manson, Jamie L., Schlueter, John A., Garrett, Kerry E., Goddard, Paul A., Lancaster, Tom, Möller, Johannes S., Blundell, Stephen J., Steele, Andrew J., Franke, Isabel, Pratt, Francis L., Singleton, John, Bendix, Jesper, Lapidus, Saul H., Uhlarz, Marc, Ayala-Valenzuela, Oscar, McDonald, Ross D., Gurak, Mary, & Baines, Christopher. Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 - x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system. United States. doi:10.1039/c6cc05873f.
Manson, Jamie L., Schlueter, John A., Garrett, Kerry E., Goddard, Paul A., Lancaster, Tom, Möller, Johannes S., Blundell, Stephen J., Steele, Andrew J., Franke, Isabel, Pratt, Francis L., Singleton, John, Bendix, Jesper, Lapidus, Saul H., Uhlarz, Marc, Ayala-Valenzuela, Oscar, McDonald, Ross D., Gurak, Mary, and Baines, Christopher. Fri . "Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 - x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system". United States. doi:10.1039/c6cc05873f.
@article{osti_1393492,
title = {Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 - x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system},
author = {Manson, Jamie L. and Schlueter, John A. and Garrett, Kerry E. and Goddard, Paul A. and Lancaster, Tom and Möller, Johannes S. and Blundell, Stephen J. and Steele, Andrew J. and Franke, Isabel and Pratt, Francis L. and Singleton, John and Bendix, Jesper and Lapidus, Saul H. and Uhlarz, Marc and Ayala-Valenzuela, Oscar and McDonald, Ross D. and Gurak, Mary and Baines, Christopher},
abstractNote = {The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.},
doi = {10.1039/c6cc05873f},
journal = {ChemComm},
issn = {1359-7345},
number = 85,
volume = 52,
place = {United States},
year = {2016},
month = {1}
}

Works referenced in this record:

Experimental and Theoretical Electron Density Analysis of Copper Pyrazine Nitrate Quasi-Low-Dimensional Quantum Magnets
journal, February 2016

  • Dos Santos, Leonardo H. R.; Lanza, Arianna; Barton, Alyssa M.
  • Journal of the American Chemical Society, Vol. 138, Issue 7
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Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets
journal, August 2008


Magnetic properties of the quasi-two-dimensional S = 1 2 Heisenberg antiferromagnet [ Cu ( pyz ) 2 ( HF 2 ) ] PF 6
journal, February 2010


Magnetic order in quasi-two-dimensional molecular magnets investigated with muon-spin relaxation
journal, August 2011


Hydrothermal Synthesis of Vanadium Oxyfluoride Chains Incorporating Covalently Bound Copper Coordination Complexes
journal, October 2008

  • Mahenthirarajah, Thushitha; Li, Yang; Lightfoot, Philip
  • Inorganic Chemistry, Vol. 47, Issue 19
  • DOI: 10.1021/ic801106h

Muon-Fluorine Entangled States in Molecular Magnets
journal, December 2007


Crystal Structure and Antiferromagnetic Ordering of Quasi-2D [Cu(HF2)(pyz)2]TaF6 (pyz=pyrazine)
journal, January 2010

  • Manson, J. L.; Schlueter, J. A.; McDonald, R. D.
  • Journal of Low Temperature Physics, Vol. 159, Issue 1-2
  • DOI: 10.1007/s10909-009-0079-5

Synthesis, structure of [H3dien]·(MF6)·H2O (M=Cr, Fe) and 57Fe Mössbauer study of [H3dien]·(FeF6)·H2O
journal, June 2007

  • Ben Ali, Amor; Trang Dang, Minh; Grenèche, Jean-Marc
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Dividing the Spoils: Role of Pyrazine Ligands and Perchlorate Counterions in the Magnetic Properties of Bis(pyrazine)diperchloratecopper(II), [Cu(pz) 2 ](ClO 4 ) 2
journal, October 2013

  • Vela, Sergi; Jornet-Somoza, Joaquim; Turnbull, Mark M.
  • Inorganic Chemistry, Vol. 52, Issue 22
  • DOI: 10.1021/ic400712s

Crystal structure and magnetic characterization of [C(NH2)3]3FeF6
journal, July 1987


Mixed valency and magnetism in cyanometallates and Prussian blue analogues
journal, September 2007

  • Herrera, J. M.; Bachschmidt, A.; Villain, F.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 366, Issue 1862
  • DOI: 10.1098/rsta.2007.2145

Hydrothermal chemistry of oligomeric vanadium oxyfluorides
journal, January 2007

  • Aldous, David W.; Stephens, Nicholas F.; Lightfoot, Philip
  • Dalton Transactions, Issue 22
  • DOI: 10.1039/b702146a

Two-dimensional S = 1 2 Heisenberg antiferromagnets: Synthesis, structure, and magnetic properties
journal, March 2002


[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2? and pyrazine ligands
journal, January 2006

  • Manson, Jamie L.; Conner, Marianne M.; Schlueter, John A.
  • Chemical Communications, Issue 47
  • DOI: 10.1039/b608791d

    Works referencing / citing this record:

    CCDC 1494075: Experimental Crystal Structure Determination: UXOZIS02 : catena-[bis(μ-fluoro)-bis(μ-pyrazine)-tetrafluoro-copper-gallium tetrahydrate]
    dataset, July 2016


    Continuous One-Step Synthesis of Porous M-XF 6 -Based Metal-Organic and Hydrogen-Bonded Frameworks
    journal, April 2017

    • Guillerm, Vincent; Garzón-Tovar, Luis; Yazdi, Amirali
    • Chemistry - A European Journal, Vol. 23, Issue 28
    • DOI: 10.1002/chem.201605507

    Crystal Structure and Antiferromagnetic Ordering of Quasi-2D [Cu(HF2)(pyz)2]TaF6 (pyz=pyrazine)
    journal, January 2010

    • Manson, J. L.; Schlueter, J. A.; McDonald, R. D.
    • Journal of Low Temperature Physics, Vol. 159, Issue 1-2
    • DOI: 10.1007/s10909-009-0079-5

    Crystal structure and magnetic characterization of [C(NH2)3]3FeF6
    journal, July 1987


    Synthesis, structure of [H3dien]·(MF6)·H2O (M=Cr, Fe) and 57Fe Mössbauer study of [H3dien]·(FeF6)·H2O
    journal, June 2007

    • Ben Ali, Amor; Trang Dang, Minh; Grenèche, Jean-Marc
    • Journal of Solid State Chemistry, Vol. 180, Issue 6
    • DOI: 10.1016/j.jssc.2007.03.030

    Dividing the Spoils: Role of Pyrazine Ligands and Perchlorate Counterions in the Magnetic Properties of Bis(pyrazine)diperchloratecopper(II), [Cu(pz) 2 ](ClO 4 ) 2
    journal, October 2013

    • Vela, Sergi; Jornet-Somoza, Joaquim; Turnbull, Mark M.
    • Inorganic Chemistry, Vol. 52, Issue 22
    • DOI: 10.1021/ic400712s

    Hydrothermal Synthesis of Vanadium Oxyfluoride Chains Incorporating Covalently Bound Copper Coordination Complexes
    journal, October 2008

    • Mahenthirarajah, Thushitha; Li, Yang; Lightfoot, Philip
    • Inorganic Chemistry, Vol. 47, Issue 19
    • DOI: 10.1021/ic801106h

    Experimental and Theoretical Electron Density Analysis of Copper Pyrazine Nitrate Quasi-Low-Dimensional Quantum Magnets
    journal, February 2016

    • Dos Santos, Leonardo H. R.; Lanza, Arianna; Barton, Alyssa M.
    • Journal of the American Chemical Society, Vol. 138, Issue 7
    • DOI: 10.1021/jacs.5b12817

    [Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2? and pyrazine ligands
    journal, January 2006

    • Manson, Jamie L.; Conner, Marianne M.; Schlueter, John A.
    • Chemical Communications, Issue 47
    • DOI: 10.1039/b608791d

    Hydrothermal chemistry of oligomeric vanadium oxyfluorides
    journal, January 2007

    • Aldous, David W.; Stephens, Nicholas F.; Lightfoot, Philip
    • Dalton Transactions, Issue 22
    • DOI: 10.1039/b702146a

    Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets
    journal, August 2008


    Mixed valency and magnetism in cyanometallates and Prussian blue analogues
    journal, September 2007

    • Herrera, J. M.; Bachschmidt, A.; Villain, F.
    • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 366, Issue 1862
    • DOI: 10.1098/rsta.2007.2145

    Continuous One-Step Synthesis of Porous M-XF 6 -Based Metal-Organic and Hydrogen-Bonded Frameworks
    journal, April 2017

    • Guillerm, Vincent; Garzón-Tovar, Luis; Yazdi, Amirali
    • Chemistry - A European Journal, Vol. 23, Issue 28
    • DOI: 10.1002/chem.201605507