Endohedral fullerenes: Synthesis, isolation, mono- and bis -functionalization
Abstract
Here, in this paper, we present a short overview of the contribution of our research group to the discovery, functionalization and characterization of unprecedented endohedral fullerenes. We also report a comprehensive study of regioselective bis-1,3-dipolar cycloadditions to cluster endohedral fullerenes M3N@Ih-C80 (M = Lu, Y and Er) and the spectroscopic characterization of the new bis-adducts obtained.
- Authors:
-
- University of Texas at El Paso, El Paso, TX (United States). Department of Chemistry; Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Physical and Life Sciences
- University of Texas at El Paso, El Paso, TX (United States); Istituto Italiano di Tecnologia (Italy). Nano Carbon Materials Laboratory; University of Genova (Italy). Department of Chemistry and Industrial Chemistry
- Indiana-Purdue University at Fort Wayne, Fort Wayne, IN (United States). Department of Chemistry
- University of Texas at El Paso, El Paso, TX (United States). Department of Chemistry
- Publication Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1409946
- Report Number(s):
- LLNL-JRNL-720246
Journal ID: ISSN 0020-1693
- Grant/Contract Number:
- AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganica Chimica Acta
- Additional Journal Information:
- Journal Volume: 468; Journal Issue: C; Journal ID: ISSN 0020-1693
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Citation Formats
Cerón, Maira R., Maffeis, Viviana, Stevenson, Steven, and Echegoyen, Luis. Endohedral fullerenes: Synthesis, isolation, mono- and bis -functionalization. United States: N. p., 2017.
Web. doi:10.1016/j.ica.2017.03.040.
Cerón, Maira R., Maffeis, Viviana, Stevenson, Steven, & Echegoyen, Luis. Endohedral fullerenes: Synthesis, isolation, mono- and bis -functionalization. United States. https://doi.org/10.1016/j.ica.2017.03.040
Cerón, Maira R., Maffeis, Viviana, Stevenson, Steven, and Echegoyen, Luis. Wed .
"Endohedral fullerenes: Synthesis, isolation, mono- and bis -functionalization". United States. https://doi.org/10.1016/j.ica.2017.03.040. https://www.osti.gov/servlets/purl/1409946.
@article{osti_1409946,
title = {Endohedral fullerenes: Synthesis, isolation, mono- and bis -functionalization},
author = {Cerón, Maira R. and Maffeis, Viviana and Stevenson, Steven and Echegoyen, Luis},
abstractNote = {Here, in this paper, we present a short overview of the contribution of our research group to the discovery, functionalization and characterization of unprecedented endohedral fullerenes. We also report a comprehensive study of regioselective bis-1,3-dipolar cycloadditions to cluster endohedral fullerenes M3N@Ih-C80 (M = Lu, Y and Er) and the spectroscopic characterization of the new bis-adducts obtained.},
doi = {10.1016/j.ica.2017.03.040},
journal = {Inorganica Chimica Acta},
number = C,
volume = 468,
place = {United States},
year = {Wed Mar 29 00:00:00 EDT 2017},
month = {Wed Mar 29 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 23 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
C60: Buckminsterfullerene
journal, November 1985
- Kroto, H. W.; Heath, J. R.; O'Brien, S. C.
- Nature, Vol. 318, Issue 6042
Solid C60: a new form of carbon
journal, September 1990
- Krätschmer, W.; Lamb, Lowell D.; Fostiropoulos, K.
- Nature, Vol. 347, Issue 6291
Electrochemical detection of C606- and C706-: Enhanced stability of fullerides in solution
journal, May 1992
- Xie, Qingshan; Perez-Cordero, Eduardo; Echegoyen, Luis
- Journal of the American Chemical Society, Vol. 114, Issue 10
Electrochemically-reversible, single-electron oxidation of C60 and C70
journal, October 1993
- Xie, Qingshan; Arias, Francisco; Echegoyen, Luis
- Journal of the American Chemical Society, Vol. 115, Issue 21
Reversible Fullerene Electrochemistry: Correlation with the HOMO-LUMO Energy Difference for C60, C70, C76, C78, and C84
journal, July 1995
- Yang, Yifan; Arias, Francisco; Echegoyen, Luis
- Journal of the American Chemical Society, Vol. 117, Issue 29
Redox Characteristics of Covalent Derivatives of the Higher Fullerenes C 70 , C 76 , and C 78
journal, August 1998
- Boudon, Corinne; Gisselbrecht, Jean-Paul; Gross, Maurice
- Journal of the American Chemical Society, Vol. 120, Issue 31
Kinetic Effects in the Electrochemistry of Fullerene Derivatives at Very Negative Potentials
journal, July 1994
- Arias, Francisco; Xie, Qingshan; Echegoyen, Luis
- Journal of the American Chemical Society, Vol. 116, Issue 14
Methanofullerenes and Methanofulleroids Have Different Electrochemical Behavior at Negative Potentials
journal, February 1995
- Arias, Francisco; Echegoyen, Luis; Wilson, Stephen R.
- Journal of the American Chemical Society, Vol. 117, Issue 4
Walk on the Sphere: Electrochemically Induced Isomerization of C 60 Bis-adducts by Migration of Di(alkoxycarbonyl)methano Bridges
journal, August 1998
- Kessinger, Roland; Gómez-López, Marcos; Boudon, Corinne
- Journal of the American Chemical Society, Vol. 120, Issue 33
Regioselective Synthesis oftrans-1 Fullerene Bis-Adducts Directed by a Crown Ether Tether: Alkali Metal Cation Modulated Redox Properties of Fullerene-Crown Ether Conjugates
journal, August 1998
- Bourgeois, Jean-Pascal; Echegoyen, Luis; Fibbioli, Monia
- Angewandte Chemie International Edition, Vol. 37, Issue 15
Electrochemistry of Fullerenes and Their Derivatives
journal, September 1998
- Echegoyen, Luis; Echegoyen, Lourdes E.
- Accounts of Chemical Research, Vol. 31, Issue 9, p. 593-601
First tether-directed regioselective bis-functionalisation of C70: effects of cation complexation on the redox properties of diastereoisomeric fullerene crown ether conjugates
journal, January 2000
- van Eis, Maurice J.; Seiler, Paul; Diederich, François
- Chemical Communications, Issue 19
Supramolecular Fullerene Chemistry: A Comprehensive Study of Cyclophane-Type Mono- and Bis-Crown Ether Conjugates of C70
journal, July 2002
- van Eis, Maurice J.; Seiler, Paul; Muslinkina, Liya A.
- Helvetica Chimica Acta, Vol. 85, Issue 7
Recent progress in the synthesis of regio-isomerically pure bis -adducts of empty and endohedral fullerenes: Fullerene bis -Adducts
journal, May 2016
- Cerón, Maira R.; Echegoyen, Luis
- Journal of Physical Organic Chemistry, Vol. 29, Issue 11
A new route for the selective synthesis of [6,6]-methanofullerenes. Electrosynthesis of C61HCMe3 and C61HCN
journal, January 1996
- Boulas, Pierre L.; Zuo, Yuhong; Echegoyen, Luis
- Chemical Communications, Issue 13
Chemistry of C84: Separation of Three Constitutional Isomers and Optical Resolution ofD2-C84 by Using the “Bingel-Retro-Bingel” Strategy
journal, June 1999
- Crassous, Jeanne; Rivera, José; Fender, Nicolette S.
- Angewandte Chemie International Edition, Vol. 38, Issue 11
Selective Electrolytic Removal of Bis(alkoxycarbonyl)methano Addends from C60 Bis-adducts and Electrochemical Stability of C70 Derivatives
journal, June 2000
- Kessinger, Roland; Fender, Nicolette S.; Echegoyen, Lourdes E.
- Chemistry - A European Journal, Vol. 6, Issue 12
Selective Electrochemical Retro-Cycloaddition Reaction of Pyrrolidinofullerenes
journal, November 2006
- Lukoyanova, Olena; Cardona, Claudia M.; Altable, Margarita
- Angewandte Chemie International Edition, Vol. 45, Issue 44
Preparation of Enantiomerically Pure C76 with a General Electrochemical Method for the Removal of Di(alkoxycarbonyl)methano Bridges from Methanofullerenes: The Retro-Bingel Reaction
journal, August 1998
- Kessinger, Roland; Crassous, Jeanne; Herrmann, Andreas
- Angewandte Chemie International Edition, Vol. 37, Issue 13-14
Lanthanum complexes of spheroidal carbon shells
journal, December 1985
- Heath, J. R.; O'Brien, S. C.; Zhang, Q.
- Journal of the American Chemical Society, Vol. 107, Issue 25
Fullerenes with metals inside
journal, October 1991
- Chai, Yan; Guo, Ting; Jin, Changming
- The Journal of Physical Chemistry, Vol. 95, Issue 20
Erratum: Small-bandgap endohedral metallofullerenes in high yield and purity
journal, December 1999
- Stevenson, S.; Rice, G.; Glass, T.
- Nature, Vol. 402, Issue 6764
The Large Nd3N@C2n (40≤n≤49) Cluster Fullerene Family: Preferential Templating of a C88 Cage by a Trimetallic Nitride Cluster
journal, December 2007
- Melin, Frederic; Chaur, Manuel N.; Engmann, Sarah
- Angewandte Chemie International Edition, Vol. 46, Issue 47
New M3N@C2n Endohedral Metallofullerene Families (M=Nd, Pr, Ce;n=40–53): Expanding the Preferential Templating of the C88 Cage and Approaching the C96 Cage
journal, May 2008
- Chaur, Manuel N.; Melin, Frederic; Elliott, Bevan
- Chemistry - A European Journal, Vol. 14, Issue 15
Lanthanum Nitride Endohedral Fullerenes La 3 N@C 2 n (43≤ n ≤55): Preferential Formation of La 3 N@C 96
journal, September 2008
- Chaur, Manuel N.; Melin, Frederic; Ashby, Jarryd
- Chemistry - A European Journal, Vol. 14, Issue 27
Synthesis, Photochemistry, and Electrochemistry of Single-Wall Carbon Nanotubes with Pendent Pyridyl Groups and of Their Metal Complexes with Zinc Porphyrin. Comparison with Pyridyl-Bearing Fullerenes
journal, May 2006
- Alvaro, Mercedes; Atienzar, Pedro; de la Cruz, Pilar
- Journal of the American Chemical Society, Vol. 128, Issue 20
Electronic Structure and Redox Properties of Metal Nitride Endohedral Fullerenes M 3 N@C 2 n (M=Sc, Y, La, and Gd; 2 n =80, 84, 88, 92, 96)
journal, September 2009
- Valencia, Ramón; Rodríguez-Fortea, Antonio; Clotet, Anna
- Chemistry - A European Journal, Vol. 15, Issue 41
Different Extraction Behaviors between Divalent and Trivalent Endohedral Metallofullerenes
journal, March 2004
- Lian, Yongfu; Shi, Zujin; Zhou, Xihuang
- Chemistry of Materials, Vol. 16, Issue 9
Structural and electronic properties of endohedral metallofullerenes
journal, April 2012
- Akasaka, Takeshi; Lu, Xing
- The Chemical Record, Vol. 12, Issue 2
Selective Extraction and Purification of Endohedral Metallofullerene from Carbon Soot
journal, November 2006
- Tsuchiya, Takahiro; Wakahara, Takatsugu; Lian, Yongfu
- The Journal of Physical Chemistry B, Vol. 110, Issue 45
Partial separation of fullerenes by gradient sublimation
journal, September 1993
- Yeretzian, Chahan; Wiley, John B.; Holczer, Karoly
- The Journal of Physical Chemistry, Vol. 97, Issue 39
Improved Production and Separation Processes for Gadolinium Metallofullerenes
journal, May 2008
- Raebiger, James W.; Bolskar, Robert D.
- The Journal of Physical Chemistry C, Vol. 112, Issue 17
Purification of Trimetallic Nitride Templated Endohedral Metallofullerenes by a Chemical Reaction of Congeners with Eutectic 9-Methylanthracene
journal, June 2008
- Angeli, Clairette D.; Cai, Ting; Duchamp, James C.
- Chemistry of Materials, Vol. 20, Issue 15
Rapid Removal of D 5 h Isomer Using the “Stir and Filter Approach” and Isolation of Large Quantities of Isomerically Pure Sc 3 N@C 80 Metallic Nitride Fullerenes
journal, May 2007
- Stevenson, Steven; Mackey, Mary A.; Coumbe, Curtis E.
- Journal of the American Chemical Society, Vol. 129, Issue 19
Nonchromatographic “Stir and Filter Approach” (SAFA) for Isolating Sc 3 N@C 80 Metallofullerenes
journal, July 2006
- Stevenson, Steven; Harich, Kim; Yu, Hua
- Journal of the American Chemical Society, Vol. 128, Issue 27
Selective Complexation and Reactivity of Metallic Nitride and Oxometallic Fullerenes with Lewis Acids and Use as an Effective Purification Method
journal, November 2009
- Stevenson, Steven; Mackey, Mary A.; Pickens, Jane E.
- Inorganic Chemistry, Vol. 48, Issue 24
A reinvestigation of the electrochemical behavior of Sc3N@C80
journal, March 2008
- Plonska-Brzezinska, Marta E.; Athans, Andreas J.; Paige Phillips, J.
- Journal of Electroanalytical Chemistry, Vol. 614, Issue 1-2
A Simple Isomeric Separation of D 5 h and I h Sc 3 N@C 80 by Selective Chemical Oxidation
journal, August 2005
- Elliott, Bevan; Yu, Lei; Echegoyen, Luis
- Journal of the American Chemical Society, Vol. 127, Issue 31
An Efficient Method to Separate Sc 3 N@C 80 I h and D 5 h Isomers and Sc 3 N@C 78 by Selective Oxidation with Acetylferrocenium [Fe(COCH 3 C 5 H 4 )Cp] +
journal, April 2013
- Cerón, Maira R.; Li, Fang-Fang; Echegoyen, Luis
- Chemistry - A European Journal, Vol. 19, Issue 23
The stability of the fullerenes Cn, with n = 24, 28, 32, 36, 50, 60 and 70
journal, October 1987
- Kroto, H. W.
- Nature, Vol. 329, Issue 6139
Endohedral fullerenes: the importance of electronic, size and shape complementarity between the carbon cages and the corresponding encapsulated clusters: ENDOHEDRAL FULLERENES
journal, January 2014
- Cerón, Maira R.; Li, Fang-Fang; Echegoyen, Luis A.
- Journal of Physical Organic Chemistry, Vol. 27, Issue 4
Aromaticity as the driving force for the stability of non-IPR endohedral metallofullerene Bingel–Hirsch adducts
journal, January 2013
- Garcia-Borràs, Marc; Osuna, Sílvia; Swart, Marcel
- Chemical Communications, Vol. 49, Issue 78
Maximum Aromaticity as a Guiding Principle for the Most Suitable Hosting Cages in Endohedral Metallofullerenes
journal, July 2013
- Garcia-Borràs, Marc; Osuna, Sílvia; Swart, Marcel
- Angewandte Chemie International Edition, Vol. 52, Issue 35
Reactivity differences of Sc 3 N@C 2n (2n = 68 and 80). Synthesis of the first methanofullerene derivatives of Sc 3 N@D 5h -C 80
journal, January 2016
- Cerón, Maira R.; Izquierdo, Marta; Alegret, Núria
- Chemical Communications, Vol. 52, Issue 1
Isolation and Structural Characterization of the Endohedral Fullerene Sc3N@C78
journal, April 2001
- Olmstead, Marilyn M.; de Bettencourt-Dias, Ana; Duchamp, James C.
- Angewandte Chemie International Edition, Vol. 40, Issue 7
Bonding within the Endohedral Fullerenes Sc 3 N@C 78 and Sc 3 N@C 80 as Determined by Density Functional Calculations and Reexamination of the Crystal Structure of {Sc 3 N@C 78 }·Co(OEP)}·1.5(C 6 H 6 )·0.3(CHCl 3 )
journal, December 2002
- Campanera, Josep M.; Bo, Carles; Olmstead, Marilyn M.
- The Journal of Physical Chemistry A, Vol. 106, Issue 51
Sc3N@C68: Folded Pentalene Coordination in an Endohedral Fullerene that Does Not Obey the Isolated Pentagon Rule
journal, February 2003
- Olmstead, Marilyn M.; Lee, Hon Man; Duchamp, James C.
- Angewandte Chemie International Edition, Vol. 42, Issue 8
Structure and Enhanced Reactivity Rates of the D 5 h Sc 3 N@C 80 and Lu 3 N@C 80 Metallofullerene Isomers: The Importance of the Pyracylene Motif
journal, July 2006
- Cai, Ting; Xu, Liaosa; Anderson, Mark R.
- Journal of the American Chemical Society, Vol. 128, Issue 26
A single crystal X-ray diffraction study of a fully ordered cocrystal of pristine Sc3N@D3h(5)–C78
journal, July 2013
- Mercado, Brandon Q.; Chaur, Manuel N.; Echegoyen, Luis
- Polyhedron, Vol. 58
Recent progress in the chemistry of endohedral metallofullerenes
journal, January 2014
- Lu, Xing; Bao, Lipiao; Akasaka, Takeshi
- Chem. Commun., Vol. 50, Issue 94
Metal Sulfide in a C 82 Fullerene Cage: A New Form of Endohedral Clusterfullerenes
journal, April 2010
- Dunsch, Lothar; Yang, Shangfeng; Zhang, Lin
- Journal of the American Chemical Society, Vol. 132, Issue 15
Endohedral Clusterfullerenes: Future Perspectives
journal, January 2017
- Cai, Wenting; Murillo, Jesse; Echegoyen, Luis
- ECS Journal of Solid State Science and Technology, Vol. 6, Issue 6
Gd 3 N@C 2 n ( n = 40, 42, and 44): Remarkably Low HOMO−LUMO Gap and Unusual Electrochemical Reversibility of Gd 3 N@C 88
journal, November 2007
- Chaur, Manuel N.; Melin, Frederic; Elliott, Bevan
- Journal of the American Chemical Society, Vol. 129, Issue 47
Is the Isolated Pentagon Rule Merely a Suggestion for Endohedral Fullerenes? The Structure of a Second Egg-Shaped Endohedral Fullerene—Gd 3 N@ C s (39663)-C 82
journal, June 2008
- Mercado, Brandon Q.; Beavers, Christine M.; Olmstead, Marilyn M.
- Journal of the American Chemical Society, Vol. 130, Issue 25
Large Metal Ions in a Relatively Small Fullerene Cage: The Structure of Gd 3 N@ C 2 (22010)-C 78 Departs from the Isolated Pentagon Rule
journal, July 2009
- Beavers, Christine M.; Chaur, Manuel N.; Olmstead, Marilyn M.
- Journal of the American Chemical Society, Vol. 131, Issue 32
Relevance of Thermal Effects in the Formation of Endohedral Metallofullerenes: The Case of Gd 3 N@ C s (39663)-C 82 and Other Related Systems
journal, January 2013
- Mulet-Gas, Marc; Rodríguez-Fortea, Antonio; Echegoyen, Luis
- Inorganic Chemistry, Vol. 52, Issue 4
Isolation and Crystallographic Characterization of Gd 3 N@ D 2 (35)-C 88 through Non-Chromatographic Methods
journal, September 2015
- Stevenson, Steven; Arvola, Kristine D.; Fahim, Muska
- Inorganic Chemistry, Vol. 55, Issue 1
Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80
journal, January 2004
- Stevenson, Steven; Phillips, J. Paige; Reid, Jon E.
- Chemical Communications, Issue 24
Synthesis of a new endohedral fullerene family, Sc2S@C2n (n = 40–50) by the introduction of SO2
journal, January 2010
- Chen, Ning; Chaur, Manuel N.; Moore, Cheryl
- Chemical Communications, Vol. 46, Issue 26
The Shape of the Sc 2 (μ 2 -S) Unit Trapped in C 82 : Crystallographic, Computational, and Electrochemical Studies of the Isomers, Sc 2 (μ 2 -S)@ C s (6)-C 82 and Sc 2 (μ 2 -S)@ C 3 v (8)-C 82
journal, May 2011
- Mercado, Brandon Q.; Chen, Ning; Rodríguez-Fortea, Antonio
- Journal of the American Chemical Society, Vol. 133, Issue 17
La@C 72 Having a Non-IPR Carbon Cage
journal, November 2006
- Wakahara, Takatsugu; Nikawa, Hidefumi; Kikuchi, Takashi
- Journal of the American Chemical Society, Vol. 128, Issue 44
Disclosure of the Elusive C 2 v -C 72 Carbon Cage
journal, December 2010
- Ziegler, Karolin; Mueller, Andreas; Amsharov, Konstantin Yu.
- Journal of the American Chemical Society, Vol. 132, Issue 48
C 72 Cl 4 : A Pristine Fullerene with Favorable Pentagon-Adjacent Structure
journal, December 2010
- Tan, Yuan-Zhi; Zhou, Ting; Bao, Jian
- Journal of the American Chemical Society, Vol. 132, Issue 48
Chemical Understanding of a Non-IPR Metallofullerene: Stabilization of Encaged Metals on Fused-Pentagon Bonds in La 2 @C 72
journal, June 2008
- Lu, Xing; Nikawa, Hidefumi; Nakahodo, Tsukasa
- Journal of the American Chemical Society, Vol. 130, Issue 28
Sc 2 S@ C s (10528)-C 72 : A Dimetallic Sulfide Endohedral Fullerene with a Non Isolated Pentagon Rule Cage
journal, April 2012
- Chen, Ning; Beavers, Christine M.; Mulet-Gas, Marc
- Journal of the American Chemical Society, Vol. 134, Issue 18
Sc 2 S@C 2 (7892)–C 70 : a metallic sulfide cluster inside a non-IPR C 70 cage
journal, January 2013
- Chen, Ning; Mulet-Gas, Marc; Li, Yu-Yang
- Chem. Sci., Vol. 4, Issue 1
Which Do Endohedral Ti 2 C 80 Metallofullerenes Prefer Energetically: Ti 2 @C 80 or Ti 2 C 2 @C 78 ? A Theoretical Study
journal, November 2005
- Yumura, Takashi; Sato, Yuta; Suenaga, Kazutomo
- The Journal of Physical Chemistry B, Vol. 109, Issue 43
Ti2C80 is more likely a titanium carbide endohedral metallofullerene (Ti2C2)@C78
journal, January 2005
- Tan, Kai; Lu, Xin
- Chemical Communications, Issue 35
Direct imaging of intracage structure in titanium-carbide endohedral metallofullerene
journal, May 2006
- Sato, Yuta; Yumura, Takashi; Suenaga, Kazu
- Physical Review B, Vol. 73, Issue 19
Production, Isolation, and EELS Characterization of Ti 2 @C 84 Dititanium Metallofullerenes
journal, September 2002
- Cao, Baopeng; Suenaga, Kazutomo; Okazaki, Toshiya
- The Journal of Physical Chemistry B, Vol. 106, Issue 36
An endohedral titanium(iii) in a clusterfullerene: putting a non-group-III metal nitride into the C80-Ih fullerene cage
journal, January 2009
- Yang, Shangfeng; Chen, Chuanbao; Popov, Alexey A.
- Chemical Communications, Issue 42
Ti2S@D3h(24109)-C78: a sulfide cluster metallofullerene containing only transition metals inside the cage
journal, January 2013
- Li, Fang-Fang; Chen, Ning; Mulet-Gas, Marc
- Chemical Science, Vol. 4, Issue 9
A Scandium Carbide Endohedral Metallofullerene: (Sc2C2)@C84
journal, January 2001
- Wang, Chun-Ru; Kai, Tsutomu; Tomiyama, Testuo
- Angewandte Chemie International Edition, Vol. 40, Issue 2
Clusters Encapsulated in Endohedral Metallofullerenes: How Strained Are They?
journal, March 2014
- Deng, Qingming; Popov, Alexey A.
- Journal of the American Chemical Society, Vol. 136, Issue 11
Molecular and electronic structures of endohedral fullerenes, Sc 2 C 2 @ C 3v -C 82 and Sc 2 @ C 3v -C 82 : Benchmark for SCC-DFTB and proposal of new inner cluster structures: Molecular and electronic structures of endohedral fullerenes
journal, January 2012
- Nishimoto, Yoshio; Wang, Zhi; Morokuma, Keiji
- physica status solidi (b), Vol. 249, Issue 2
A Bent Tb 2 C 2 Cluster Encaged in a C S (6)-C 82 Cage: Synthesis, Isolation and X-ray Crystallographic Study
journal, January 2014
- Liu, Fupin; Wei, Tao; Wang, Song
- Fullerenes, Nanotubes and Carbon Nanostructures, Vol. 22, Issue 1-3
Beyond the Butterfly: Sc 2 C 2 @ C 2 v (9)-C 86 , an Endohedral Fullerene Containing a Planar, Twisted Sc 2 C 2 Unit with Remarkable Crystalline Order in an Unprecedented Carbon Cage
journal, August 2015
- Chen, Chia-Hsiang; Ghiassi, Kamran B.; Cerón, Maira R.
- Journal of the American Chemical Society, Vol. 137, Issue 32
Zigzag Sc 2 C 2 Carbide Cluster inside a [88]Fullerene Cage with One Heptagon, Sc 2 C 2 @ C s (hept)-C 88 : A Kinetically Trapped Fullerene Formed by C 2 Insertion?
journal, September 2016
- Chen, Chia-Hsiang; Abella, Laura; Cerón, Maira R.
- Journal of the American Chemical Society, Vol. 138, Issue 39
Bottom-up formation of endohedral mono-metallofullerenes is directed by charge transfer
journal, December 2014
- Dunk, Paul W.; Mulet-Gas, Marc; Nakanishi, Yusuke
- Nature Communications, Vol. 5, Issue 1
The First Fulleropyrrolidine Derivative of Sc 3 N@C 80 : Pronounced Chemical Shift Differences of the Geminal Protons on the Pyrrolidine Ring
journal, June 2005
- Cardona, Claudia M.; Kitaygorodskiy, Alex; Ortiz, Angy
- The Journal of Organic Chemistry, Vol. 70, Issue 13
Trimetallic Nitride Endohedral Fullerenes: Experimental and Theoretical Evidence for the M 3 N 6+ @C 2 n 6− model
journal, February 2009
- Chaur, Manuel N.; Valencia, Ramón; Rodríguez‐Fortea, Antonio
- Angewandte Chemie International Edition, Vol. 48, Issue 8
Trimetallic Nitride Endohedral Metallofullerenes: Reactivity Dictated by the Encapsulated Metal Cluster
journal, July 2005
- Cardona, Claudia M.; Kitaygorodskiy, Alex; Echegoyen, Luis
- Journal of the American Chemical Society, Vol. 127, Issue 29
X-Ray crystallographic and EPR spectroscopic characterization of a pyrrolidine adduct of Y3N@C80
journal, January 2006
- Echegoyen, Luis; Chancellor, Christopher J.; Cardona, Claudia M.
- Chemical Communications, Issue 25
Influence of the Encapsulated Clusters on the Electrochemical Behaviour of Endohedral Fullerene Derivatives: Comparative Study of N-Tritylpyrrolidino Derivatives of Sc3N@Ih-C80 and Lu3N@Ih-C80
journal, February 2011
- Chen, Ning; Pinzón, Julio R.; Echegoyen, Luis
- ChemPhysChem, Vol. 12, Issue 8
Dancing on a Fullerene Surface: Isomerization of Y3N@(N-Ethylpyrrolidino-C80) from the 6,6 to the 5,6 Regioisomer
journal, December 2006
- Rodríguez-Fortea, Antonio; Campanera, Josep M.; Cardona, Claudia M.
- Angewandte Chemie International Edition, Vol. 45, Issue 48
Prato Reaction of M 3 N@ I h -C 80 (M = Sc, Lu, Y, Gd) with Reversible Isomerization
journal, December 2012
- Aroua, Safwan; Yamakoshi, Yoko
- Journal of the American Chemical Society, Vol. 134, Issue 50
Size Effect of Encaged Clusters on the Exohedral Chemistry of Endohedral Fullerenes: A Case Study on the Pyrrolidino Reaction of Sc x Gd 3- x N@C 80 ( x = 0−3)
journal, May 2007
- Chen, Ning; Zhang, Er-Yun; Tan, Kai
- Organic Letters, Vol. 9, Issue 10
Retro-Cycloaddition Reaction of Pyrrolidinofullerenes
journal, January 2006
- Martín, Nazario; Altable, Margarita; Filippone, Salvatore
- Angewandte Chemie International Edition, Vol. 45, Issue 1
“Open Rather than Closed” Malonate Methano-Fullerene Derivatives. The Formation of Methanofulleroid Adducts of Y 3 N@C 80
journal, August 2007
- Lukoyanova, Olena; Cardona, Claudia M.; Rivera, José
- Journal of the American Chemical Society, Vol. 129, Issue 34
Bingel−Hirsch Reactions on Non-IPR Gd 3 N@C 2 n (2 n = 82 and 84)
journal, December 2010
- Alegret, Núria; Chaur, Manuel N.; Santos, Eva
- The Journal of Organic Chemistry, Vol. 75, Issue 23
Synthesis and Electrochemical Studies of Bingel-Hirsch Derivatives of M3N@Ih-C80 (M=Sc, Lu)
journal, March 2010
- Pinzón, Julio R.; Zuo, Tianming; Echegoyen, Luis
- Chemistry - A European Journal, Vol. 16, Issue 16
The Regioselectivity of Bingel-Hirsch Cycloadditions on Isolated Pentagon Rule Endohedral Metallofullerenes
journal, January 2016
- Garcia-Borràs, Marc; Cerón, Maira R.; Osuna, Sílvia
- Angewandte Chemie International Edition, Vol. 55, Issue 7
The influence of cage size on the reactivity of trimetallic nitride metallofullerenes: a mono- and bis-methanoadduct of Gd3N@C80 and a monoadduct of Gd3N@C84
journal, January 2008
- Chaur, Manuel N.; Melin, Frederic; Athans, Andreas J.
- Chemical Communications, Issue 23
Buckyball maracas: exploring the inside and outside properties of endohedral fullerenes: BUCKYBALL MARACAS: ENDOHEDRAL FULLERENES
journal, August 2012
- Rivera-Nazario, Danisha M.; Pinzón, Julio R.; Stevenson, Steven
- Journal of Physical Organic Chemistry, Vol. 26, Issue 2
Reactivity of Metallic Nitride Endohedral Metallofullerene Anions: Electrochemical Synthesis of a Lu 3 N@ I h -C 80 Derivative
journal, March 2011
- Li, Fang-Fang; Rodríguez-Fortea, Antonio; Poblet, Josep M.
- Journal of the American Chemical Society, Vol. 133, Issue 8
Electrosynthesis of a Sc 3 N@ I h -C 80 Methano Derivative from Trianionic Sc 3 N@ I h -C 80
journal, April 2012
- Li, Fang-Fang; Rodríguez-Fortea, Antonio; Peng, Ping
- Journal of the American Chemical Society, Vol. 134, Issue 17
Endohedral fullerenes for organic photovoltaic devices
journal, February 2009
- Ross, Russel B.; Cardona, Claudia M.; Guldi, Dirk M.
- Nature Materials, Vol. 8, Issue 3
Diphenylmethanofullerenes: New and Efficient Acceptors in Bulk-Heterojunction Solar Cells
journal, December 2005
- Riedel, I.; von Hauff, E.; Parisi, J.
- Advanced Functional Materials, Vol. 15, Issue 12
The Origin of the High Voltage in DPM12/P3HT Organic Solar Cells
journal, July 2010
- Sánchez-Díaz, Antonio; Izquierdo, Marta; Filippone, Salvatore
- Advanced Functional Materials, Vol. 20, Issue 16
Polymer solar cells based on diphenylmethanofullerenes with reduced sidechain length
journal, January 2011
- Bolink, Henk J.; Coronado, Eugenio; Forment-Aliaga, Alicia
- J. Mater. Chem., Vol. 21, Issue 5
Origin of the Open Circuit Voltage of Plastic Solar Cells
journal, October 2001
- Brabec, C. J.; Cravino, A.; Meissner, D.
- Advanced Functional Materials, Vol. 11, Issue 5
[5,6]-Open Methanofullerene Derivatives of I h -C 80
journal, September 2013
- Izquierdo, Marta; Cerón, Maira R.; Olmstead, Marilyn M.
- Angewandte Chemie International Edition, Vol. 52, Issue 45
Sc3N@C80-Ferrocene Electron-Donor/Acceptor Conjugates as Promising Materials for Photovoltaic Applications
journal, May 2008
- Pinzón, Julio R.; Plonska-Brzezinska, Marta E.; Cardona, Claudia M.
- Angewandte Chemie International Edition, Vol. 47, Issue 22
Complexation of Sc 3 N@C 80 Endohedral Fullerene with Cyclic Zn-Bisporphyrins: Solid State and Solution Studies
journal, May 2011
- Hernández-Eguía, Laura P.; Escudero-Adán, Eduardo C.; Pinzón, Julio R.
- The Journal of Organic Chemistry, Vol. 76, Issue 9
Syntheses and Structures of Phenyl-C 81 -Butyric Acid Methyl Esters (PCBMs) from M 3 N@C 80
journal, March 2009
- Shu, Chunying; Xu, Wei; Slebodnick, Carla
- Organic Letters, Vol. 11, Issue 8
Endohedral Metallofullerenes-Filled Fullerene Derivatives towards Multifunctional Reaction Center Mimics
journal, March 2012
- Rudolf, Marc; Wolfrum, Silke; Guldi, Dirk M.
- Chemistry - A European Journal, Vol. 18, Issue 17
Bis-1,3-dipolar Cycloadditions on Endohedral Fullerenes M 3 N@ I h -C 80 (M = Sc, Lu): Remarkable Endohedral-Cluster Regiochemical Control
journal, September 2015
- Cerón, Maira R.; Izquierdo, Marta; Garcia-Borràs, Marc
- Journal of the American Chemical Society, Vol. 137, Issue 36
Endohedral Metal-Induced Regioselective Formation of Bis-Prato Adduct of Y 3 N@ I h -C 80 and Gd 3 N@ I h -C 80
journal, December 2014
- Aroua, Safwan; Garcia-Borràs, Marc; Bölter, Marc Florian
- Journal of the American Chemical Society, Vol. 137, Issue 1
Small Molecule Organic Semiconductors on the Move: Promises for Future Solar Energy Technology
journal, February 2012
- Mishra, Amaresh; Bäuerle, Peter
- Angewandte Chemie International Edition, Vol. 51, Issue 9
Tethered Bisadducts of C 60 and C 70 with Addends on a Common Hexagonal Face and a 12-Membered Hole in the Fullerene Cage
journal, June 2015
- Cerón, Maira R.; Izquierdo, Marta; Aghabali, Amineh
- Journal of the American Chemical Society, Vol. 137, Issue 23
Tether-Directed Bisfunctionalization Reactions of C 60 and C 70
journal, April 2015
- Cerón, Maira R.; Izquierdo, Marta; Pi, Yunhong
- Chemistry - A European Journal, Vol. 21, Issue 21
Unexpected Isomerism in cis -2 Bis(pyrrolidino)[60]Fullerene Diastereomers
journal, October 2013
- Izquierdo, Marta; Cerón, Maira R.; Alegret, Núria
- Angewandte Chemie International Edition, Vol. 52, Issue 49
Chemical, Electrochemical, and Structural Properties of Endohedral Metallofullerenes
journal, September 2009
- Chaur, Manuel N.; Melin, Frederic; Ortiz, Angy L.
- Angewandte Chemie International Edition, Vol. 48, Issue 41
Effect of Water and Solvent Selection on the SAFA Purification Times for Metallic Nitride Fullerenes
journal, January 2014
- Stevenson, Steven; Rose, Coralie B.; Robson, Alyssa A.
- Fullerenes, Nanotubes and Carbon Nanostructures, Vol. 22, Issue 1-3
Works referencing / citing this record:
All‐Fullerene Electron Donor–Acceptor Conjugates
journal, March 2019
- Izquierdo, Marta; Platzer, Benedikt; Stasyuk, Anton J.
- Angewandte Chemie, Vol. 131, Issue 21
All‐Fullerene Electron Donor–Acceptor Conjugates
journal, May 2019
- Izquierdo, Marta; Platzer, Benedikt; Stasyuk, Anton J.
- Angewandte Chemie International Edition, Vol. 58, Issue 21
Understanding the Reactivity of Fullerenes Through the Activation Strain Model: Understanding the Reactivity of Fullerenes Through the Activation Strain Model
journal, March 2018
- Fernández, Israel
- European Journal of Organic Chemistry, Vol. 2018, Issue 12
Nitrogen centered inverse coordination complexes. A survey of molecular topologies
journal, October 2018
- Haiduc, Ionel
- Journal of Coordination Chemistry, Vol. 71, Issue 19
Far infrared spectroscopy and other spectral and thermal properties of [Li@C 60 ]PF 6
journal, June 2019
- Cataldo, Franco; García-Hernández, D. Aníbal; Manchado, Arturo
- Fullerenes, Nanotubes and Carbon Nanostructures, Vol. 27, Issue 9
Nitrogen centered inverse coordination complexes. A survey of molecular topologies
text, January 2018
- Haiduc, Ionel
- Taylor & Francis
Nitrogen centered inverse coordination complexes. A survey of molecular topologies
text, January 2018
- Haiduc, Ionel
- Taylor & Francis