Growth and characterization of BaZnGa

Jo, Na Hyun; Lin, Qisheng; Nguyen, Manh Cuong; Kaluarachchi, Udhara S.; Meier, William R.; Manni, Soham; Downing, Savannah S.; Böhmer, Anna E.; Kong, Tai; Sun, Yang; Taufour, Valentin; Wang, Cai-Zhuang; Ho, Kai-Ming; Bud’ko, Sergey L.; Canfield, Paul C.

doi:10.1080/14786435.2017.1380861

Title: Growth and characterization of BaZnGa

Abstract

In this paper, we report the growth, structure and characterization of BaZnGa, identifying it as the sole known ternary compound in the Ba–Zn–Ga system. Single crystals of BaZnGa can be grown out of excess Ba–Zn and adopt a tI36 structure type. There are three unique Ba sites and three M = Zn/Ga sites. Using DFT calculations we can argue that whereas one of these three M sites is probably solely occupied by Ga, the other two M sites, most likely, have mixed Zn/Ga occupancy. Finally, temperature-dependent resistivity and magnetization measurements suggest that BaZnGa is a poor metal with no electronic or magnetic phase transitions between 1.8 and 300 K.

Authors:

Jo, Na Hyun ^[1]; Lin, Qisheng ^[2];

^[1]; Kaluarachchi, Udhara S. ^[1]; Meier, William R. ^[1]; Manni, Soham ^[1]; Downing, Savannah S. ^[1]; Böhmer, Anna E. ^[1]; Kong, Tai ^[1];

^[1]; Taufour, Valentin ^[1]; Wang, Cai-Zhuang ^[1]; Ho, Kai-Ming ^[1];

^[1]; Canfield, Paul C. ^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy
Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Chemistry

Publication Date:: Fri Oct 20 00:00:00 EDT 2017

Research Org.:: Ames Lab. and Iowa State Univ., Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Gordon and Betty Moore Foundation (United States)

OSTI Identifier:: 1407485

Report Number(s):: IS-J-9477
Journal ID: ISSN 1478-6435; TRN: US1703278

Grant/Contract Number:: AC02-07CH11358; GBMF4411

Resource Type:: Accepted Manuscript

Journal Name:: Philosophical Magazine (2003, Print)

Additional Journal Information:: Journal Name: Philosophical Magazine (2003, Print); Journal Volume: 97; Journal Issue: 35; Journal ID: ISSN 1478-6435

Publisher:: Taylor & Francis

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; material discovery; crystal growth; crystal structure; density functional theory; physical properties

Citation Formats


                    Jo, Na Hyun, Lin, Qisheng, Nguyen, Manh Cuong, Kaluarachchi, Udhara S., Meier, William R., Manni, Soham, Downing, Savannah S., Böhmer, Anna E., Kong, Tai, Sun, Yang, Taufour, Valentin, Wang, Cai-Zhuang, Ho, Kai-Ming, Bud’ko, Sergey L., and Canfield, Paul C. Growth and characterization of BaZnGa.  United States: N. p., 2017. 
Web.  doi:10.1080/14786435.2017.1380861.

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                    Jo, Na Hyun, Lin, Qisheng, Nguyen, Manh Cuong, Kaluarachchi, Udhara S., Meier, William R., Manni, Soham, Downing, Savannah S., Böhmer, Anna E., Kong, Tai, Sun, Yang, Taufour, Valentin, Wang, Cai-Zhuang, Ho, Kai-Ming, Bud’ko, Sergey L., & Canfield, Paul C. Growth and characterization of BaZnGa.  United States.  https://doi.org/10.1080/14786435.2017.1380861

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                    Jo, Na Hyun, Lin, Qisheng, Nguyen, Manh Cuong, Kaluarachchi, Udhara S., Meier, William R., Manni, Soham, Downing, Savannah S., Böhmer, Anna E., Kong, Tai, Sun, Yang, Taufour, Valentin, Wang, Cai-Zhuang, Ho, Kai-Ming, Bud’ko, Sergey L., and Canfield, Paul C. Fri .  
"Growth and characterization of BaZnGa".  United States.  https://doi.org/10.1080/14786435.2017.1380861.  https://www.osti.gov/servlets/purl/1407485.

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@article{osti_1407485,

  title        = {Growth and characterization of BaZnGa},

  author       = {Jo, Na Hyun and Lin, Qisheng and Nguyen, Manh Cuong and Kaluarachchi, Udhara S. and Meier, William R. and Manni, Soham and Downing, Savannah S. and Böhmer, Anna E. and Kong, Tai and Sun, Yang and Taufour, Valentin and Wang, Cai-Zhuang and Ho, Kai-Ming and Bud’ko, Sergey L. and Canfield, Paul C.},

  abstractNote = {In this paper, we report the growth, structure and characterization of BaZnGa, identifying it as the sole known ternary compound in the Ba–Zn–Ga system. Single crystals of BaZnGa can be grown out of excess Ba–Zn and adopt a tI36 structure type. There are three unique Ba sites and three M = Zn/Ga sites. Using DFT calculations we can argue that whereas one of these three M sites is probably solely occupied by Ga, the other two M sites, most likely, have mixed Zn/Ga occupancy. Finally, temperature-dependent resistivity and magnetization measurements suggest that BaZnGa is a poor metal with no electronic or magnetic phase transitions between 1.8 and 300 K.},

  doi          = {10.1080/14786435.2017.1380861},

  journal      = {Philosophical Magazine (2003, Print)},

  number       = 35,

  volume       = 97,

  place        = {United States},

  year         = {Fri Oct 20 00:00:00 EDT 2017},

  month        = {Fri Oct 20 00:00:00 EDT 2017}

}

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Similar Records

Title: Growth and characterization of BaZnGa

Abstract

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Solution growth of a binary icosahedral quasicrystal of Sc 12 Zn 88 journal, January 2010

Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples journal, December 2015

FeAs-Based Superconductivity: A Case Study of the Effects of Transition Metal Doping on BaFe 2 As 2 journal, August 2010

Projector augmented-wave method journal, December 1994

Magnetic properties of R Fe 2 Zn 20 and R Co 2 Zn 20 ( R = Y , Nd , Sm , Gd – Lu ) journal, September 2009

Growth of single crystals from metallic fluxes journal, June 1992

Nearly ferromagnetic Fermi-liquid behaviour in YFe2Zn20 and high-temperature ferromagnetism of GdFe2Zn20 journal, March 2007

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Special points for Brillouin-zone integrations journal, June 1976

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Giant magnetic anisotropy and tunnelling of the magnetization in Li2(Li1−xFex)N journal, February 2014

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Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples
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Projector augmented-wave method
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journal, September 2009

Growth of single crystals from metallic fluxes
journal, June 1992

Nearly ferromagnetic Fermi-liquid behaviour in YFe2Zn20 and high-temperature ferromagnetism of GdFe2Zn20
journal, March 2007

Dirac node arcs in PtSn4
journal, April 2016

Special points for Brillouin-zone integrations
journal, June 1976

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Giant magnetic anisotropy and tunnelling of the magnetization in Li2(Li1−xFex)N
journal, February 2014

Magnetic and transport properties of single-grain $R - M g - Z n$ icosahedral quasicrystals [ $R = Y,$ $(Y_{1 - x} {Gd}_{x}),$ $(Y_{1 - x} {Tb}_{x}),$ Tb, Dy, Ho, and Er]
journal, January 1999

Magnetic field effects on transport properties of PtSn $_{4}$
journal, January 2012

A family of binary magnetic icosahedral quasicrystals based on rare earths and cadmium
journal, June 2013

Six closely related YbT2Zn20 (T = Fe, Co, Ru, Rh, Os, Ir) heavy fermion compounds with large local moment degeneracy
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