Calcium intercalation into layered fluorinated sodium iron phosphate
Abstract
Here, the energy density and cost of battery systems could be improved by moving to alternative battery chemistries such as Ca-ion. However, in order to switch chemistries many problems need to be solved including the identification of cathode materials with high energy density, and electrolytes that can plate and strip calcium metal. Herein, the feasibility and cycling performance of Ca2+ intercalation into a desodiated layered Na2FePO4F host is described. This is the first demonstration of Ca2+ intercalation into a polyanionic framework, which implies that other polyanionic framework materials may be active for Ca2+ intercalation. Although substantial effort is still needed to identify a high energy density cathode material, this study and others demonstrate the feasibility of Ca2+ intercalation into multiple materials making it more probable that such a cathode material can be found.
- Authors:
-
[1];
[1]
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States); Nanotek Instruments, Dayton, OH (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Joint Center for Energy Storage Research (JCESR); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1401979
- Alternate Identifier(s):
- OSTI ID: 1549369
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 369; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Electrochemical Energy Storage; Multivalent-ion battery; Calcium-ion battery; Energy storage; Electrochemistry
Citation Formats
Lipson, Albert L., Kim, Soojeong, Pan, Baofei, Liao, Chen, Fister, Timothy T., and Ingram, Brian J. Calcium intercalation into layered fluorinated sodium iron phosphate. United States: N. p., 2017.
Web. doi:10.1016/j.jpowsour.2017.09.081.
Lipson, Albert L., Kim, Soojeong, Pan, Baofei, Liao, Chen, Fister, Timothy T., & Ingram, Brian J. Calcium intercalation into layered fluorinated sodium iron phosphate. United States. https://doi.org/10.1016/j.jpowsour.2017.09.081
Lipson, Albert L., Kim, Soojeong, Pan, Baofei, Liao, Chen, Fister, Timothy T., and Ingram, Brian J. Mon .
"Calcium intercalation into layered fluorinated sodium iron phosphate". United States. https://doi.org/10.1016/j.jpowsour.2017.09.081. https://www.osti.gov/servlets/purl/1401979.
@article{osti_1401979,
title = {Calcium intercalation into layered fluorinated sodium iron phosphate},
author = {Lipson, Albert L. and Kim, Soojeong and Pan, Baofei and Liao, Chen and Fister, Timothy T. and Ingram, Brian J.},
abstractNote = {Here, the energy density and cost of battery systems could be improved by moving to alternative battery chemistries such as Ca-ion. However, in order to switch chemistries many problems need to be solved including the identification of cathode materials with high energy density, and electrolytes that can plate and strip calcium metal. Herein, the feasibility and cycling performance of Ca2+ intercalation into a desodiated layered Na2FePO4F host is described. This is the first demonstration of Ca2+ intercalation into a polyanionic framework, which implies that other polyanionic framework materials may be active for Ca2+ intercalation. Although substantial effort is still needed to identify a high energy density cathode material, this study and others demonstrate the feasibility of Ca2+ intercalation into multiple materials making it more probable that such a cathode material can be found.},
doi = {10.1016/j.jpowsour.2017.09.081},
journal = {Journal of Power Sources},
number = C,
volume = 369,
place = {United States},
year = {Mon Oct 09 00:00:00 EDT 2017},
month = {Mon Oct 09 00:00:00 EDT 2017}
}
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Works referenced in this record:
The composition of the continental crust
journal, April 1995
- Hans Wedepohl, K.
- Geochimica et Cosmochimica Acta, Vol. 59, Issue 7
Fraction of the theoretical specific energy achieved on pack level for hypothetical battery chemistries
journal, December 2014
- Eroglu, Damla; Ha, Seungbum; Gallagher, Kevin G.
- Journal of Power Sources, Vol. 267
Rechargeable Ca-Ion Batteries: A New Energy Storage System
journal, December 2015
- Lipson, Albert L.; Pan, Baofei; Lapidus, Saul H.
- Chemistry of Materials, Vol. 27, Issue 24
Nickel hexacyanoferrate, a versatile intercalation host for divalent ions from nonaqueous electrolytes
journal, September 2016
- Lipson, Albert L.; Han, Sang-Don; Kim, Soojeong
- Journal of Power Sources, Vol. 325
Advancing towards a veritable calcium-ion battery: CaCo2O4 positive electrode material
journal, June 2016
- Cabello, Marta; Nacimiento, Francisco; González, José R.
- Electrochemistry Communications, Vol. 67
Assessing Si-based anodes for Ca-ion batteries: Electrochemical decalciation of CaSi2
journal, May 2016
- Ponrouch, A.; Tchitchekova, D.; Frontera, C.
- Electrochemistry Communications, Vol. 66
A High Capacity Calcium Primary Cell Based on the Ca-S System
journal, April 2013
- See, Kimberly A.; Gerbec, Jeffrey A.; Jun, Young-Si
- Advanced Energy Materials, Vol. 3, Issue 8
Materials Design Rules for Multivalent Ion Mobility in Intercalation Structures
journal, August 2015
- Rong, Ziqin; Malik, Rahul; Canepa, Pieremanuele
- Chemistry of Materials, Vol. 27, Issue 17
Theoretical investigation of Chevrel phase materials for cathodes accommodating Ca2+ ions
journal, February 2016
- Smeu, Manuel; Hossain, Md Sazzad; Wang, Zi
- Journal of Power Sources, Vol. 306
Recent advances in the research of polyanion-type cathode materials for Li-ion batteries
journal, January 2011
- Gong, Zhengliang; Yang, Yong
- Energy & Environmental Science, Vol. 4, Issue 9
A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries
journal, September 2007
- Ellis, B. L.; Makahnouk, W. R. M.; Makimura, Y.
- Nature Materials, Vol. 6, Issue 10
Nano-assembled Na2FePO4F/carbon nanotube multi-layered cathodes for Na-ion batteries
journal, July 2015
- Yan, Jianhua; Liu, Xingbo; Li, Bingyun
- Electrochemistry Communications, Vol. 56
Synthesis, characterisation and enhanced electrochemical performance of nanostructured Na 2 FePO 4 F for sodium batteries
journal, January 2015
- Law, Markas; Ramar, Vishwanathan; Balaya, Palani
- RSC Advances, Vol. 5, Issue 62
Carbothermal reduction synthesis of carbon coated Na2FePO4F for lithium ion batteries
journal, January 2016
- Cui, Dongming; Chen, Shasha; Han, Chang
- Journal of Power Sources, Vol. 301
Tavorite Lithium Iron Fluorophosphate Cathode Materials: Phase Transition and Electrochemistry of LiFePO[sub 4]F–Li[sub 2]FePO[sub 4]F
journal, January 2010
- Ramesh, T. N.; Lee, Kyu Tae; Ellis, B. L.
- Electrochemical and Solid-State Letters, Vol. 13, Issue 4
Ionothermal Synthesis of Sodium-Based Fluorophosphate Cathode Materials
journal, January 2009
- Recham, N.; Chotard, J-N.; Dupont, L.
- Journal of The Electrochemical Society, Vol. 156, Issue 12
Crystal Structure and Electrochemical Properties of A 2 MPO 4 F Fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni) †
journal, February 2010
- Ellis, Brian L.; Makahnouk, W. R. Michael; Rowan-Weetaluktuk, W. N.
- Chemistry of Materials, Vol. 22, Issue 3
Na-ion mobility in layered Na2FePO4F and olivine Na[Fe,Mn]PO4
journal, January 2013
- Tripathi, R.; Wood, S. M.; Islam, M. S.
- Energy & Environmental Science, Vol. 6, Issue 8
Building a Fast Lane for Mg Diffusion in α-MoO 3 by Fluorine Doping
journal, September 2016
- Wan, Liwen F.; Incorvati, Jared T.; Poeppelmeier, Kenneth R.
- Chemistry of Materials, Vol. 28, Issue 19
Current Collector Corrosion in Ca-Ion Batteries
journal, January 2015
- Lipson, Albert L.; Proffit, Danielle L.; Pan, Baofei
- Journal of The Electrochemical Society, Vol. 162, Issue 8
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
First-principles prediction of redox potentials in transition-metal compounds with
journal, December 2004
- Zhou, F.; Cococcioni, M.; Marianetti, C. A.
- Physical Review B, Vol. 70, Issue 23
Works referencing / citing this record:
The critical role of configurational flexibility in facilitating reversible reactive metal deposition from borohydride solutions
journal, January 2020
- Hahn, Nathan T.; Self, Julian; Seguin, Trevor J.
- Journal of Materials Chemistry A, Vol. 8, Issue 15
Discovery of Calcium-Metal Alloy Anodes for Reversible Ca-Ion Batteries
journal, January 2019
- Yao, Zhenpeng; Hegde, Vinay I.; Aspuru-Guzik, Alán
- Advanced Energy Materials, Vol. 9, Issue 9
Laboratory-Based X-ray Absorption Spectroscopy on a Working Pouch Cell Battery at Industrially-Relevant Charging Rates
journal, January 2019
- Jahrman, Evan P.; Pellerin, Lisa A.; Ditter, Alexander S.
- Journal of The Electrochemical Society, Vol. 166, Issue 12