High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries
Abstract
Calcium-ion batteries (CIBs) are under investigation as next-generation energy storage devices due to their theoretically high operating potentials and lower costs tied to the high natural abundance of calcium. However, the development of CIBs has been limited by the lack of available positive electrode materials. In this study, for the first time, we report two functional polyanionic phosphate materials as high-voltage cathodes for CIBs at room temperature. NaV2(PO4)3 electrodes were found to reversibly intercalate 0.6 mol of Ca2+ (81 mA h g–1) near 3.2 V (vs Ca2+/Ca) with stable cycling performance at a current density of 3.5 mA g–1. The olivine framework material FePO4 reversibly intercalates 0.2 mol of Ca2+ (72 mA h g–1) near 2.9 V (vs Ca2+/Ca) at a current density of 7.5 mA g–1 in the first cycle. Structural, electronic, and compositional changes are consistent with reversible Ca2+ intercalation into these two materials.
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[1];
[3];
[2];
[4];
[1];
[1]
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Seoul National Univ. (Korea, Republic of)
- Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Illinois, Chicago, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Waterloo, ON (Canada)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1774597
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Energy Letters
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 10; Journal ID: ISSN 2380-8195
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; calcium; electrodes; physical and chemical processes; intercalation; materials; energy storage; calcium-ion; framework; multivalent
Citation Formats
Kim, Sanghyeon, Yin, Liang, Lee, Myeong Hwan, Parajuli, Prakash, Blanc, Lauren, Fister, Timothy T., Park, Haesun, Kwon, Bob Jin, Ingram, Brian J., Zapol, Peter, Klie, Robert F., Kang, Kisuk, Nazar, Linda F., Lapidus, Saul H., and Vaughey, John T. High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries. United States: N. p., 2020.
Web. doi:10.1021/acsenergylett.0c01663.
Kim, Sanghyeon, Yin, Liang, Lee, Myeong Hwan, Parajuli, Prakash, Blanc, Lauren, Fister, Timothy T., Park, Haesun, Kwon, Bob Jin, Ingram, Brian J., Zapol, Peter, Klie, Robert F., Kang, Kisuk, Nazar, Linda F., Lapidus, Saul H., & Vaughey, John T. High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries. United States. https://doi.org/10.1021/acsenergylett.0c01663
Kim, Sanghyeon, Yin, Liang, Lee, Myeong Hwan, Parajuli, Prakash, Blanc, Lauren, Fister, Timothy T., Park, Haesun, Kwon, Bob Jin, Ingram, Brian J., Zapol, Peter, Klie, Robert F., Kang, Kisuk, Nazar, Linda F., Lapidus, Saul H., and Vaughey, John T. Mon .
"High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries". United States. https://doi.org/10.1021/acsenergylett.0c01663. https://www.osti.gov/servlets/purl/1774597.
@article{osti_1774597,
title = {High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries},
author = {Kim, Sanghyeon and Yin, Liang and Lee, Myeong Hwan and Parajuli, Prakash and Blanc, Lauren and Fister, Timothy T. and Park, Haesun and Kwon, Bob Jin and Ingram, Brian J. and Zapol, Peter and Klie, Robert F. and Kang, Kisuk and Nazar, Linda F. and Lapidus, Saul H. and Vaughey, John T.},
abstractNote = {Calcium-ion batteries (CIBs) are under investigation as next-generation energy storage devices due to their theoretically high operating potentials and lower costs tied to the high natural abundance of calcium. However, the development of CIBs has been limited by the lack of available positive electrode materials. In this study, for the first time, we report two functional polyanionic phosphate materials as high-voltage cathodes for CIBs at room temperature. NaV2(PO4)3 electrodes were found to reversibly intercalate 0.6 mol of Ca2+ (81 mA h g–1) near 3.2 V (vs Ca2+/Ca) with stable cycling performance at a current density of 3.5 mA g–1. The olivine framework material FePO4 reversibly intercalates 0.2 mol of Ca2+ (72 mA h g–1) near 2.9 V (vs Ca2+/Ca) at a current density of 7.5 mA g–1 in the first cycle. Structural, electronic, and compositional changes are consistent with reversible Ca2+ intercalation into these two materials.},
doi = {10.1021/acsenergylett.0c01663},
journal = {ACS Energy Letters},
number = 10,
volume = 5,
place = {United States},
year = {Mon Sep 14 00:00:00 EDT 2020},
month = {Mon Sep 14 00:00:00 EDT 2020}
}
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