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Title: Calcium intercalation into layered fluorinated sodium iron phosphate

Abstract

Here, the energy density and cost of battery systems could be improved by moving to alternative battery chemistries such as Ca-ion. However, in order to switch chemistries many problems need to be solved including the identification of cathode materials with high energy density, and electrolytes that can plate and strip calcium metal. Herein, the feasibility and cycling performance of Ca2+ intercalation into a desodiated layered Na2FePO4F host is described. This is the first demonstration of Ca2+ intercalation into a polyanionic framework, which implies that other polyanionic framework materials may be active for Ca2+ intercalation. Although substantial effort is still needed to identify a high energy density cathode material, this study and others demonstrate the feasibility of Ca2+ intercalation into multiple materials making it more probable that such a cathode material can be found.

Authors:
 [1];  [1];  [2]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Argonne National Lab. (ANL), Lemont, IL (United States)
  2. Argonne National Lab. (ANL), Lemont, IL (United States); Nanotek Instruments, Dayton, OH (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Joint Center for Energy Storage Research (JCESR); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1401979
Alternate Identifier(s):
OSTI ID: 1549369
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Power Sources
Additional Journal Information:
Journal Volume: 369; Journal Issue: C; Journal ID: ISSN 0378-7753
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Electrochemical Energy Storage; Multivalent-ion battery; Calcium-ion battery; Energy storage; Electrochemistry

Citation Formats

Lipson, Albert L., Kim, Soojeong, Pan, Baofei, Liao, Chen, Fister, Timothy T., and Ingram, Brian J. Calcium intercalation into layered fluorinated sodium iron phosphate. United States: N. p., 2017. Web. doi:10.1016/j.jpowsour.2017.09.081.
Lipson, Albert L., Kim, Soojeong, Pan, Baofei, Liao, Chen, Fister, Timothy T., & Ingram, Brian J. Calcium intercalation into layered fluorinated sodium iron phosphate. United States. doi:https://doi.org/10.1016/j.jpowsour.2017.09.081
Lipson, Albert L., Kim, Soojeong, Pan, Baofei, Liao, Chen, Fister, Timothy T., and Ingram, Brian J. Mon . "Calcium intercalation into layered fluorinated sodium iron phosphate". United States. doi:https://doi.org/10.1016/j.jpowsour.2017.09.081. https://www.osti.gov/servlets/purl/1401979.
@article{osti_1401979,
title = {Calcium intercalation into layered fluorinated sodium iron phosphate},
author = {Lipson, Albert L. and Kim, Soojeong and Pan, Baofei and Liao, Chen and Fister, Timothy T. and Ingram, Brian J.},
abstractNote = {Here, the energy density and cost of battery systems could be improved by moving to alternative battery chemistries such as Ca-ion. However, in order to switch chemistries many problems need to be solved including the identification of cathode materials with high energy density, and electrolytes that can plate and strip calcium metal. Herein, the feasibility and cycling performance of Ca2+ intercalation into a desodiated layered Na2FePO4F host is described. This is the first demonstration of Ca2+ intercalation into a polyanionic framework, which implies that other polyanionic framework materials may be active for Ca2+ intercalation. Although substantial effort is still needed to identify a high energy density cathode material, this study and others demonstrate the feasibility of Ca2+ intercalation into multiple materials making it more probable that such a cathode material can be found.},
doi = {10.1016/j.jpowsour.2017.09.081},
journal = {Journal of Power Sources},
number = C,
volume = 369,
place = {United States},
year = {2017},
month = {10}
}

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