Electrical resistance of single-crystal magnetite (Fe 3 O 4 ) under quasi-hydrostatic pressures up to 100 GPa
Abstract
We measured the pressure dependence of electrical resistance of single-crystal magnetite (Fe3O4) under quasi-hydrostatic conditions to 100 GPa using low-temperature, megabar diamond-anvil cell techniques in order to gain insight into the anomalous behavior of this material that has been reported over the years in different high-pressure experiments. The measurements under nearly hydrostatic pressure conditions allowed us to detect the clear Verwey transition and the high-pressure structural phase. Furthermore, the appearance of a metallic ground state after the suppression of the Verwey transition around 20 GPa and the concomitant enhancement of electrical resistance caused by the structural transformation to the high-pressure phase form reentrant semiconducting-metallic-semiconducting behavior, though the appearance of the metallic phase is highly sensitive to stress conditions and details of the measurement technique.
- Authors:
-
[2];
- Carnegie Inst. of Washington, Washington, DC (United States). Geophysical Lab.
- Univ. of North Florida, Jacksonville, FL (United States). Dept. of Physics
- Ecole Polytechnique Federale Lausanne (Switzlerland)
- Carnegie Inst. of Washington, Washington, DC (United States). Geophysical Lab.; Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Carnegie Inst. of Science, Washington, DC (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1364599
- Alternate Identifier(s):
- OSTI ID: 1246184
- Grant/Contract Number:
- NA0002006; SC-0001057; FG02-02ER45955; FG02-99ER45775; AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 119; Journal Issue: 13; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Muramatsu, Takaki, Gasparov, Lev V., Berger, Helmuth, Hemley, Russell J., and Struzhkin, Viktor V. Electrical resistance of single-crystal magnetite (Fe 3 O 4 ) under quasi-hydrostatic pressures up to 100 GPa. United States: N. p., 2016.
Web. doi:10.1063/1.4945388.
Muramatsu, Takaki, Gasparov, Lev V., Berger, Helmuth, Hemley, Russell J., & Struzhkin, Viktor V. Electrical resistance of single-crystal magnetite (Fe 3 O 4 ) under quasi-hydrostatic pressures up to 100 GPa. United States. https://doi.org/10.1063/1.4945388
Muramatsu, Takaki, Gasparov, Lev V., Berger, Helmuth, Hemley, Russell J., and Struzhkin, Viktor V. Thu .
"Electrical resistance of single-crystal magnetite (Fe 3 O 4 ) under quasi-hydrostatic pressures up to 100 GPa". United States. https://doi.org/10.1063/1.4945388. https://www.osti.gov/servlets/purl/1364599.
@article{osti_1364599,
title = {Electrical resistance of single-crystal magnetite (Fe 3 O 4 ) under quasi-hydrostatic pressures up to 100 GPa},
author = {Muramatsu, Takaki and Gasparov, Lev V. and Berger, Helmuth and Hemley, Russell J. and Struzhkin, Viktor V.},
abstractNote = {We measured the pressure dependence of electrical resistance of single-crystal magnetite (Fe3O4) under quasi-hydrostatic conditions to 100 GPa using low-temperature, megabar diamond-anvil cell techniques in order to gain insight into the anomalous behavior of this material that has been reported over the years in different high-pressure experiments. The measurements under nearly hydrostatic pressure conditions allowed us to detect the clear Verwey transition and the high-pressure structural phase. Furthermore, the appearance of a metallic ground state after the suppression of the Verwey transition around 20 GPa and the concomitant enhancement of electrical resistance caused by the structural transformation to the high-pressure phase form reentrant semiconducting-metallic-semiconducting behavior, though the appearance of the metallic phase is highly sensitive to stress conditions and details of the measurement technique.},
doi = {10.1063/1.4945388},
journal = {Journal of Applied Physics},
number = 13,
volume = 119,
place = {United States},
year = {Thu Apr 07 00:00:00 EDT 2016},
month = {Thu Apr 07 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 12 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Electronic Conduction of Magnetite (Fe3O4) and its Transition Point at Low Temperatures
journal, August 1939
- Verwey, E. J. W.
- Nature, Vol. 144, Issue 3642
Short-Range Correlations in Magnetite above the Verwey Temperature
journal, March 2014
- Bosak, Alexey; Chernyshov, Dmitry; Hoesch, Moritz
- Physical Review X, Vol. 4, Issue 1
Hyperfine field and electronic structure of magnetite below the Verwey transition
journal, March 2015
- Řezníček, R.; Chlan, V.; Štěpánková, H.
- Physical Review B, Vol. 91, Issue 12
Effect of Pressure on the Metal-Nonmetal Transition and Conductivity of
journal, September 1968
- Samara, G. A.
- Physical Review Letters, Vol. 21, Issue 12
Charge order and three-site distortions in the Verwey structure of magnetite
journal, December 2011
- Senn, Mark S.; Wright, Jon P.; Attfield, J. Paul
- Nature, Vol. 481, Issue 7380
Charge localization in the Verwey structure of magnetite
journal, July 2015
- Senn, Mark S.; Wright, Jon P.; Cumby, James
- Physical Review B, Vol. 92, Issue 2
Analysis of charge and orbital order in Fe O by Fe resonant x-ray diffraction
journal, November 2013
- Tanaka, A.; Chang, C. F.; Buchholz, M.
- Physical Review B, Vol. 88, Issue 19
Electric field control of the Verwey transition and induced magnetoelectric effect in magnetite
journal, August 2012
- Wong, Jared J. I.; Swartz, Adrian G.; Zheng, Renjing
- Physical Review B, Vol. 86, Issue 6
Orbital degrees of freedom as origin of magnetoelectric coupling in magnetite
journal, February 2012
- Yamauchi, Kunihiko; Picozzi, Silvia
- Physical Review B, Vol. 85, Issue 8
Spin state of iron in Fe O magnetite and -Fe O
journal, April 2013
- Bengtson, Amelia; Morgan, Dane; Becker, Udo
- Physical Review B, Vol. 87, Issue 15
Anharmonicity due to Electron-Phonon Coupling in Magnetite
journal, May 2013
- Hoesch, Moritz; Piekarz, Przemysław; Bosak, Alexey
- Physical Review Letters, Vol. 110, Issue 20
Pressure-Induced Crystal Structure and Spin-State Transitions in Magnetite (Fe 3 O 4 )
journal, August 2012
- Ju, Sheng; Cai, Tian-Yi; Lu, Hai-Shuang
- Journal of the American Chemical Society, Vol. 134, Issue 33
Abnormal Elastic and Vibrational Behaviors of Magnetite at High Pressures
journal, September 2014
- Lin, Jung-Fu; Wu, Junjie; Zhu, Jie
- Scientific Reports, Vol. 4, Issue 1
Metallization of magnetite at high pressures
journal, March 2002
- Môri, Nobuo; Todo, Sakae; Takeshita, Nao
- Physica B: Condensed Matter, Vol. 312-313
Pressure-induced coordination crossover in magnetite, a high pressure Mössbauer study
journal, August 2004
- Pasternak, M. P.; Xu, W. M.; Rozenberg, G. Kh.
- Journal of Physics and Chemistry of Solids, Vol. 65, Issue 8-9
High-pressure study of through the Verwey transition
journal, November 1994
- Ramasesha, Sheela K.; Mohan, Murali; Singh, A. K.
- Physical Review B, Vol. 50, Issue 18
Origin of the Verwey Transition in Magnetite
journal, February 2006
- Rozenberg, G. Kh.; Pasternak, M. P.; Xu, W. M.
- Physical Review Letters, Vol. 96, Issue 4
Pressure Dependence of the Verwey Temperature of Fe 3- y O 4 Obtained by Magnetic Permeability Measurements
journal, December 1990
- Tamura, Syuzo
- Journal of the Physical Society of Japan, Vol. 59, Issue 12
Pressure Effects on Magnetic Susceptibility in Fe 3 O 4
journal, January 2007
- Hosoya, Teppei; Takahasi, Hiroki; Yamada, Daikichi
- Journal of the Physical Society of Japan, Vol. 76, Issue Suppl.A
Verwey transition in at high pressure: Quantum critical point at the onset of metallization
journal, September 2008
- Spałek, J.; Kozłowski, A.; Tarnawski, Z.
- Physical Review B, Vol. 78, Issue 10
Metallization of magnetite (Fe3O4) under high pressure
journal, June 2001
- Todo, S.; Takeshita, N.; Kanehara, T.
- Journal of Applied Physics, Vol. 89, Issue 11
Raman study of the Verwey transition in magnetite at high-pressure and low-temperature: Effect of Al doping
journal, August 2012
- Gasparov, L.; Shirshikova, Z.; Pekarek, T. M.
- Journal of Applied Physics, Vol. 112, Issue 4
Magnetite: Raman study of the high-pressure and low-temperature effects
journal, May 2005
- Gasparov, L. V.; Arenas, D.; Choi, K. -Y.
- Journal of Applied Physics, Vol. 97, Issue 10
Pressure dependence of the Verwey transition in magnetite: An infrared spectroscopic point of view
journal, October 2012
- Ebad-Allah, J.; Baldassarre, L.; Sing, M.
- Journal of Applied Physics, Vol. 112, Issue 7
Isothermal compression of magnetite to 320 KB
journal, March 1974
- Mao, Ho-Kwang; Takahashi, Taro; Bassett, William A.
- Journal of Geophysical Research, Vol. 79, Issue 8
The structure of the metallic high-pressure Fe 3 O 4 polymorph: experimental and theoretical study
journal, October 2003
- Dubrovinsky, L. S.; Dubrovinskaia, N. A.; McCammon, C.
- Journal of Physics: Condensed Matter, Vol. 15, Issue 45
Mössbauer and resistivity studies of the magnetic and electronic properties of the high-pressure phase of
journal, November 2004
- Xu, W. M.; Machavariani, G. Yu.; Rozenberg, G. Kh.
- Physical Review B, Vol. 70, Issue 17
Nature of the Verwey transition in magnetite ( ) to pressures of 16 GPa
journal, March 1996
- Rozenberg, Gregory Kh.; Hearne, Giovanni R.; Pasternak, Moshe P.
- Physical Review B, Vol. 53, Issue 10
Pressure effect on the anomalous electrical conductivity of magnetite
journal, May 1979
- Kakudate, Y.; Mori, N.; Kino, Y.
- Journal of Magnetism and Magnetic Materials, Vol. 12, Issue 1
Solidification of High-Pressure Medium Daphne 7373
journal, June 2007
- Yokogawa, Keiichi; Murata, Keizo; Yoshino, Harukazu
- Japanese Journal of Applied Physics, Vol. 46, Issue 6A
Pressure calibration of diamond anvil Raman gauge to 410 GPa
journal, March 2010
- Akahama, Yuichi; Kawamura, Haruki
- Journal of Physics: Conference Series, Vol. 215
Polaron physics and crossover transition in magnetite probed by pressure-dependent infrared spectroscopy
journal, December 2012
- Ebad-Allah, J.; Baldassarre, L.; Sing, M.
- Journal of Physics: Condensed Matter, Vol. 25, Issue 3
High-pressure resistivity technique for quasi-hydrostatic compression experiments
journal, June 2013
- Rotundu, C. R.; Ćuk, T.; Greene, R. L.
- Review of Scientific Instruments, Vol. 84, Issue 6
Works referencing / citing this record:
A Room‐Temperature Verwey‐type Transition in Iron Oxide, Fe 5 O 6
journal, January 2020
- Ovsyannikov, Sergey V.; Bykov, Maxim; Medvedev, Sergey A.
- Angewandte Chemie, Vol. 132, Issue 14
A Room‐Temperature Verwey‐type Transition in Iron Oxide, Fe 5 O 6
journal, January 2020
- Ovsyannikov, Sergey V.; Bykov, Maxim; Medvedev, Sergey A.
- Angewandte Chemie International Edition, Vol. 59, Issue 14