Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li 2/12Ni3/12Mn7/12]O2
Abstract
We have determined the electrochemical characteristics of the high voltage, high capacity Li-ion battery cathode material Li[Li 2/12Ni3/12Mn7/12]O2 prepared using three different synthesis routes: sol-gel, hydroxide co-precipitation, and carbonate co-precipitation. Each route leads to distinct morphologies and surface areas while maintaining the same crystal structures. X-ray photoelectron spectroscopy (XPS) measurements reveal differences in their surface chemistries upon cycling, which correlate with voltage fading. As expected, we observed the valence state of Mn on the surface to decrease upon lithiation, and this reduction is specifically correlated to discharging below 3.6V. Furthermore, the data shows a correlation of the formation of Li2CO3 with Mn oxidation state from the
- Authors:
-
- Univ. of California, San Diego, CA (United States). Dept. of NanoEngineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1286778
- Grant/Contract Number:
- AC05-00OR22725; AC02-05CH11231; 7056412
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 21; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; cathode; high energy density; Li-excess; Li-ion battery; Li-rich; surface; XPS
Citation Formats
Verde, Michael G., Liu, Haodong, Carroll, Kyler J., Baggetto, Loïc, Veith, Gabriel M., and Meng, Y. Shirley. Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li 2/12Ni3/12Mn7/12]O2. United States: N. p., 2014.
Web. doi:10.1021/am504701s.
Verde, Michael G., Liu, Haodong, Carroll, Kyler J., Baggetto, Loïc, Veith, Gabriel M., & Meng, Y. Shirley. Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li 2/12Ni3/12Mn7/12]O2. United States. https://doi.org/10.1021/am504701s
Verde, Michael G., Liu, Haodong, Carroll, Kyler J., Baggetto, Loïc, Veith, Gabriel M., and Meng, Y. Shirley. Thu .
"Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li 2/12Ni3/12Mn7/12]O2". United States. https://doi.org/10.1021/am504701s. https://www.osti.gov/servlets/purl/1286778.
@article{osti_1286778,
title = {Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li 2/12Ni3/12Mn7/12]O2},
author = {Verde, Michael G. and Liu, Haodong and Carroll, Kyler J. and Baggetto, Loïc and Veith, Gabriel M. and Meng, Y. Shirley},
abstractNote = {We have determined the electrochemical characteristics of the high voltage, high capacity Li-ion battery cathode material Li[Li 2/12Ni3/12Mn7/12]O2 prepared using three different synthesis routes: sol-gel, hydroxide co-precipitation, and carbonate co-precipitation. Each route leads to distinct morphologies and surface areas while maintaining the same crystal structures. X-ray photoelectron spectroscopy (XPS) measurements reveal differences in their surface chemistries upon cycling, which correlate with voltage fading. As expected, we observed the valence state of Mn on the surface to decrease upon lithiation, and this reduction is specifically correlated to discharging below 3.6V. Furthermore, the data shows a correlation of the formation of Li2CO3 with Mn oxidation state from the},
doi = {10.1021/am504701s},
journal = {ACS Applied Materials and Interfaces},
number = 21,
volume = 6,
place = {United States},
year = {Thu Oct 02 00:00:00 EDT 2014},
month = {Thu Oct 02 00:00:00 EDT 2014}
}
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