Room-temperature in situ nuclear spin hyperpolarization from optically pumped nitrogen vacancy centres in diamond

King, Jonathan P.; Jeong, Keunhong; Vassiliou, Christophoros C.; Shin, Chang S.; Page, Ralph H.; Avalos, Claudia E.; Wang, Hai-Jing; Pines, Alexander

doi:10.1038/ncomms9965

Title: Room-temperature in situ nuclear spin hyperpolarization from optically pumped nitrogen vacancy centres in diamond

Abstract

Low detection sensitivity stemming from the weak polarization of nuclear spins is a primary limitation of magnetic resonance spectroscopy and imaging. Methods have been developed to enhance nuclear spin polarization but they typically require high magnetic fields, cryogenic temperatures or sample transfer between magnets. Here we report bulk, room-temperature hyperpolarization of 13C nuclear spins observed via high-field magnetic resonance. The technique harnesses the high optically induced spin polarization of diamond nitrogen vacancy centres at room temperature in combination with dynamic nuclear polarization. We observe bulk nuclear spin polarization of 6%, an enhancement of ~170,000 over thermal equilibrium. The signal of the hyperpolarized spins was detected in situ with a standard nuclear magnetic resonance probe without the need for sample shuttling or precise crystal orientation. In conclusion, hyperpolarization via optical pumping/dynamic nuclear polarization should function at arbitrary magnetic fields enabling orders of magnitude sensitivity enhancement for nuclear magnetic resonance of solids and liquids under ambient conditions.

Authors:

King, Jonathan P. ^[1]; Jeong, Keunhong ^[1]; Vassiliou, Christophoros C. ^[1]; Shin, Chang S. ^[1]; Page, Ralph H. ^[2]; Avalos, Claudia E. ^[1]; Wang, Hai-Jing ^[1]; Pines, Alexander ^[1]

Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States)

Publication Date:: Mon Dec 07 00:00:00 EST 2015

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1256043

Alternate Identifier(s):: OSTI ID: 1415948

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Nature Communications

Additional Journal Information:: Journal Volume: 6; Journal ID: ISSN 2041-1723

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS

Citation Formats


                    King, Jonathan P., Jeong, Keunhong, Vassiliou, Christophoros C., Shin, Chang S., Page, Ralph H., Avalos, Claudia E., Wang, Hai-Jing, and Pines, Alexander. Room-temperature in situ nuclear spin hyperpolarization from optically pumped nitrogen vacancy centres in diamond.  United States: N. p., 2015. 
Web.  doi:10.1038/ncomms9965.

Copy to clipboard


                    King, Jonathan P., Jeong, Keunhong, Vassiliou, Christophoros C., Shin, Chang S., Page, Ralph H., Avalos, Claudia E., Wang, Hai-Jing, & Pines, Alexander. Room-temperature in situ nuclear spin hyperpolarization from optically pumped nitrogen vacancy centres in diamond.  United States.  https://doi.org/10.1038/ncomms9965

Copy to clipboard


                    King, Jonathan P., Jeong, Keunhong, Vassiliou, Christophoros C., Shin, Chang S., Page, Ralph H., Avalos, Claudia E., Wang, Hai-Jing, and Pines, Alexander. Mon .  
"Room-temperature in situ nuclear spin hyperpolarization from optically pumped nitrogen vacancy centres in diamond".  United States.  https://doi.org/10.1038/ncomms9965.  https://www.osti.gov/servlets/purl/1256043.

Copy to clipboard


                    
@article{osti_1256043,

  title        = {Room-temperature in situ nuclear spin hyperpolarization from optically pumped nitrogen vacancy centres in diamond},

  author       = {King, Jonathan P. and Jeong, Keunhong and Vassiliou, Christophoros C. and Shin, Chang S. and Page, Ralph H. and Avalos, Claudia E. and Wang, Hai-Jing and Pines, Alexander},

  abstractNote = {Low detection sensitivity stemming from the weak polarization of nuclear spins is a primary limitation of magnetic resonance spectroscopy and imaging. Methods have been developed to enhance nuclear spin polarization but they typically require high magnetic fields, cryogenic temperatures or sample transfer between magnets. Here we report bulk, room-temperature hyperpolarization of 13C nuclear spins observed via high-field magnetic resonance. The technique harnesses the high optically induced spin polarization of diamond nitrogen vacancy centres at room temperature in combination with dynamic nuclear polarization. We observe bulk nuclear spin polarization of 6%, an enhancement of ~170,000 over thermal equilibrium. The signal of the hyperpolarized spins was detected in situ with a standard nuclear magnetic resonance probe without the need for sample shuttling or precise crystal orientation. In conclusion, hyperpolarization via optical pumping/dynamic nuclear polarization should function at arbitrary magnetic fields enabling orders of magnitude sensitivity enhancement for nuclear magnetic resonance of solids and liquids under ambient conditions.},

  doi          = {10.1038/ncomms9965},

  journal      = {Nature Communications},

  number       = ,

  volume       = 6,

  place        = {United States},

  year         = {Mon Dec 07 00:00:00 EST 2015},

  month        = {Mon Dec 07 00:00:00 EST 2015}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1038/ncomms9965

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 72 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

The nitrogen-vacancy colour centre in diamond
journal, July 2013

Doherty, Marcus W.; Manson, Neil B.; Delaney, Paul
Physics Reports, Vol. 528, Issue 1
DOI: 10.1016/j.physrep.2013.02.001

Enhancement of Solution NMR and MRI with Laser-Polarized Xenon
journal, March 1996

Navon, G.; Song, Y. -Q.; Room, T.
Science, Vol. 271, Issue 5257
DOI: 10.1126/science.271.5257.1848

High-field cross polarization NMR from laser-polarized xenon to surface nuclei
journal, March 1995

Gaede, H. C.; Song, Y. -Q.; Taylor, R. E.
Applied Magnetic Resonance, Vol. 8, Issue 3-4
DOI: 10.1007/BF03162652

An introduction to chemically induced dynamic nuclear polarization
journal, January 1995

Goez, Martin
Concepts in Magnetic Resonance, Vol. 7, Issue 1
DOI: 10.1002/cmr.1820070105

Optical polarization of nuclear ensembles in diamond
journal, March 2013

Fischer, Ran; Jarmola, Andrey; Kehayias, Pauli
Physical Review B, Vol. 87, Issue 12
DOI: 10.1103/PhysRevB.87.125207

NMR of hyperpolarised probes: NMR of hyperpolarised probes
journal, October 2012

Mulder, Willem J. M.; McMahon, Michael T.; Nicolay, Klaas
NMR in Biomedicine, Vol. 26, Issue 7
DOI: 10.1002/nbm.2873

Spin-exchange optical pumping of noble-gas nuclei
journal, April 1997

Walker, Thad G.; Happer, William
Reviews of Modern Physics, Vol. 69, Issue 2
DOI: 10.1103/RevModPhys.69.629

Transformation of Symmetrization Order to Nuclear-Spin Magnetization by Chemical Reaction and Nuclear Magnetic Resonance
journal, November 1986

Bowers, C. Russell; Weitekamp, Daniel P.
Physical Review Letters, Vol. 57, Issue 21
DOI: 10.1103/PhysRevLett.57.2645

Hybrid polarizing solids for pure hyperpolarized liquids through dissolution dynamic nuclear polarization
journal, September 2014

Gajan, D.; Bornet, A.; Vuichoud, B.
Proceedings of the National Academy of Sciences, Vol. 111, Issue 41
DOI: 10.1073/pnas.1407730111

High Frequency Dynamic Nuclear Polarization
journal, April 2013

Ni, Qing Zhe; Daviso, Eugenio; Can, Thach V.
Accounts of Chemical Research, Vol. 46, Issue 9
DOI: 10.1021/ar300348n

Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR
journal, August 2003

Ardenkjaer-Larsen, J. H.; Fridlund, B.; Gram, A.
Proceedings of the National Academy of Sciences, Vol. 100, Issue 18
DOI: 10.1073/pnas.1733835100

Proton‐enhanced NMR of dilute spins in solids
journal, July 1973

Pines, A.; Gibby, M. G.; Waugh, J. S.
The Journal of Chemical Physics, Vol. 59, Issue 2
DOI: 10.1063/1.1680061

Dynamic Nuclear Spin Polarization of Liquids and Gases in Contact with Nanostructured Diamond
journal, April 2014

Abrams, Daniel; Trusheim, Matthew E.; Englund, Dirk R.
Nano Letters, Vol. 14, Issue 5
DOI: 10.1021/nl500147b

Optically pumped nuclear magnetic resonance of semiconductors
journal, February 2008

Hayes, Sophia E.; Mui, Stacy; Ramaswamy, Kannan
The Journal of Chemical Physics, Vol. 128, Issue 5
DOI: 10.1063/1.2823131

Dynamic nuclear polarization at high magnetic fields in liquids
journal, July 2012

Griesinger, C.; Bennati, M.; Vieth, H. M.
Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 64
DOI: 10.1016/j.pnmrs.2011.10.002

Dynamic nuclear polarization of diamond. I. Solid state and thermal mixing effects
journal, September 1998

Reynhardt, Eduard C.; High, Grant L.
The Journal of Chemical Physics, Vol. 109, Issue 10
DOI: 10.1063/1.477009

Nuclear Polarization in ${He}^{3}$ Gas Induced by Optical Pumping and Dipolar Exchange
journal, October 1960

Bouchiat, M. A.; Carver, T. R.; Varnum, C. M.
Physical Review Letters, Vol. 5, Issue 8
DOI: 10.1103/PhysRevLett.5.373

Diamonds with a high density of nitrogen-vacancy centers for magnetometry applications
journal, September 2009

Acosta, V. M.; Bauch, E.; Ledbetter, M. P.
Physical Review B, Vol. 80, Issue 11
DOI: 10.1103/PhysRevB.80.115202

Nuclear hyperpolarization in solids and the prospects for nuclear spintronics
journal, February 2010

Reimer, Jeffrey A.
Solid State Nuclear Magnetic Resonance, Vol. 37, Issue 1-2
DOI: 10.1016/j.ssnmr.2010.04.001

Optical polarization of ${}^{13}C$ nuclei in diamond through nitrogen vacancy centers
journal, February 2010

King, Jonathan P.; Coles, Patrick J.; Reimer, Jeffrey A.
Physical Review B, Vol. 81, Issue 7
DOI: 10.1103/PhysRevB.81.073201

Room temperature hyperpolarization of nuclear spins in bulk
journal, May 2014

Tateishi, K.; Negoro, M.; Nishida, S.
Proceedings of the National Academy of Sciences, Vol. 111, Issue 21
DOI: 10.1073/pnas.1315778111

Sensitive magnetic control of ensemble nuclear spin hyperpolarization in diamond
journal, June 2013

Wang, Hai-Jing; Shin, Chang S.; Avalos, Claudia E.
Nature Communications, Vol. 4, Issue 1
DOI: 10.1038/ncomms2930

Local and bulk 13C hyperpolarization in nitrogen-vacancy-centred diamonds at variable fields and orientations
journal, September 2015

Álvarez, Gonzalo A.; Bretschneider, Christian O.; Fischer, Ran
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms9456

The Principles of Nuclear Magnetism
journal, December 1961

Abragam, A.; Hebel, L. C.
American Journal of Physics, Vol. 29, Issue 12
DOI: 10.1119/1.1937646

Xenon NMR Spectroscopy
journal, May 2007

Raftery, Daniel
ChemInform, Vol. 38, Issue 21
DOI: 10.1002/chin.200721210

The Principles of Nuclear Magnetism
journal, November 1961

Abragam, A.; Carr, H. Y.
Physics Today, Vol. 14, Issue 11
DOI: 10.1063/1.3057238

Optical polarization of nuclear ensembles in diamond
text, January 2012

Fischer, Ran; Jarmola, Andrey; Kehayias, Pauli
arXiv
DOI: 10.48550/arxiv.1202.1072

Bulk Nuclear Polarization Enhanced at Room-Temperature by Optical Pumping
text, January 2012

Fischer, Ran; Bretschneider, Christian O.; London, Paz
arXiv
DOI: 10.48550/arxiv.1211.5801

Dynamic nuclear polarization at high magnetic fields in liquids
journal, July 2012

Griesinger, C.; Bennati, M.; Vieth, H. M.
Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 64
DOI: 10.1016/j.pnmrs.2011.10.002

Parahydrogen induced polarization
journal, November 1997

Natterer, Johannes; Bargon, Joachim
Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 31, Issue 4
DOI: 10.1016/s0079-6565(97)00007-1

High Frequency Dynamic Nuclear Polarization
journal, April 2013

Ni, Qing Zhe; Daviso, Eugenio; Can, Thach V.
Accounts of Chemical Research, Vol. 46, Issue 9
DOI: 10.1021/ar300348n

Dynamic Nuclear Spin Polarization of Liquids and Gases in Contact with Nanostructured Diamond
journal, April 2014

Abrams, Daniel; Trusheim, Matthew E.; Englund, Dirk R.
Nano Letters, Vol. 14, Issue 5
DOI: 10.1021/nl500147b

Sensitive magnetic control of ensemble nuclear spin hyperpolarization in diamond
journal, June 2013

Wang, Hai-Jing; Shin, Chang S.; Avalos, Claudia E.
Nature Communications, Vol. 4, Issue 1
DOI: 10.1038/ncomms2930

Optically pumped nuclear magnetic resonance of semiconductors
journal, February 2008

Hayes, Sophia E.; Mui, Stacy; Ramaswamy, Kannan
The Journal of Chemical Physics, Vol. 128, Issue 5
DOI: 10.1063/1.2823131

Dynamic nuclear polarization of diamond. I. Solid state and thermal mixing effects
journal, September 1998

Reynhardt, Eduard C.; High, Grant L.
The Journal of Chemical Physics, Vol. 109, Issue 10
DOI: 10.1063/1.477009

Room temperature hyperpolarization of nuclear spins in bulk
journal, May 2014

Tateishi, K.; Negoro, M.; Nishida, S.
Proceedings of the National Academy of Sciences, Vol. 111, Issue 21
DOI: 10.1073/pnas.1315778111

Hybrid polarizing solids for pure hyperpolarized liquids through dissolution dynamic nuclear polarization
journal, September 2014

Gajan, D.; Bornet, A.; Vuichoud, B.
Proceedings of the National Academy of Sciences, Vol. 111, Issue 41
DOI: 10.1073/pnas.1407730111

Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR
journal, August 2003

Ardenkjaer-Larsen, J. H.; Fridlund, B.; Gram, A.
Proceedings of the National Academy of Sciences, Vol. 100, Issue 18
DOI: 10.1073/pnas.1733835100

Bulk Nuclear Polarization Enhanced at Room Temperature by Optical Pumping
journal, July 2013

Fischer, Ran; Bretschneider, Christian O.; London, Paz
Physical Review Letters, Vol. 111, Issue 5
DOI: 10.1103/physrevlett.111.057601

Enhancement of Solution NMR and MRI with Laser-Polarized Xenon
journal, March 1996

Navon, G.; Song, Y. -Q.; Room, T.
Science, Vol. 271, Issue 5257
DOI: 10.1126/science.271.5257.1848

Optical polarization of nuclear ensembles in diamond
text, January 2012

Fischer, Ran; Jarmola, Andrey; Kehayias, Pauli
arXiv
DOI: 10.48550/arxiv.1202.1072

Works referencing / citing this record:

Diamond Quantum Devices in Biology
journal, April 2016

Wu, Yuzhou; Jelezko, Fedor; Plenio, Martin B.
Angewandte Chemie International Edition, Vol. 55, Issue 23
DOI: 10.1002/anie.201506556

On The Potential of Dynamic Nuclear Polarization Enhanced Diamonds in Solid-State and Dissolution ¹³ C NMR Spectroscopy
journal, July 2016

Bretschneider, Christian O.; Akbey, Ümit; Aussenac, Fabien
ChemPhysChem, Vol. 17, Issue 17
DOI: 10.1002/cphc.201600301

A Perspective on Fluorescent Nanodiamond Bioimaging
journal, June 2019

Torelli, Marco D.; Nunn, Nicholas A.; Shenderova, Olga A.
Small, Vol. 15, Issue 48
DOI: 10.1002/smll.201902151

Towards clinically translatable in vivo nanodiagnostics
journal, May 2017

Park, Seung-min; Aalipour, Amin; Vermesh, Ophir
Nature Reviews Materials, Vol. 2, Issue 5
DOI: 10.1038/natrevmats.2017.14

Local and bulk 13C hyperpolarization in nitrogen-vacancy-centred diamonds at variable fields and orientations
journal, September 2015

Álvarez, Gonzalo A.; Bretschneider, Christian O.; Fischer, Ran
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms9456

Hyperpolarized nanodiamond with long spin-relaxation times
journal, October 2015

Rej, Ewa; Gaebel, Torsten; Boele, Thomas
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms9459

Quantum probe hyperpolarisation of molecular nuclear spins
journal, March 2018

Broadway, David A.; Tetienne, Jean-Philippe; Stacey, Alastair
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-03578-1

First principles calculation of spin-related quantities for point defect qubit research
journal, December 2018

Ivády, Viktor; Abrikosov, Igor A.; Gali, Adam
npj Computational Materials, Vol. 4, Issue 1
DOI: 10.1038/s41524-018-0132-5

Phase-Encoded Hyperpolarized Nanodiamond for Magnetic Resonance Imaging
journal, April 2019

Waddington, David E. J.; Boele, Thomas; Rej, Ewa
Scientific Reports, Vol. 9, Issue 1
DOI: 10.1038/s41598-019-42373-w

Dynamics of frequency-swept nuclear spin optical pumping in powdered diamond at low magnetic fields
journal, January 2019

Zangara, Pablo R.; Dhomkar, Siddharth; Ajoy, Ashok
Proceedings of the National Academy of Sciences, Vol. 116, Issue 7
DOI: 10.1073/pnas.1811994116

Carbon-13 dynamic nuclear polarization in diamond via a microwave-free integrated cross effect
journal, August 2019

Henshaw, Jacob; Pagliero, Daniela; Zangara, Pablo R.
Proceedings of the National Academy of Sciences, Vol. 116, Issue 37
DOI: 10.1073/pnas.1908780116

The alternative splicing of SKU5-Similar3 in Arabidopsis
journal, August 2019

Zhou, Ke
Plant Signaling & Behavior, Vol. 14, Issue 10
DOI: 10.1080/15592324.2019.1651182

Investigation of room temperature multispin-assisted bulk diamond ¹³ C hyperpolarization at low magnetic fields
journal, July 2018

Wunderlich, Ralf; Kohlrautz, Jonas; Abel, Bernd
Journal of Physics: Condensed Matter, Vol. 30, Issue 30
DOI: 10.1088/1361-648x/aacc32

Influence of magnetic field alignment and defect concentration on nitrogen-vacancy polarization in diamond
journal, December 2015

Drake, M.; Scott, E.; Reimer, J. A.
New Journal of Physics, Vol. 18, Issue 1
DOI: 10.1088/1367-2630/18/1/013011

Optically induced dynamic nuclear spin polarisation in diamond
journal, January 2016

Scheuer, Jochen; Schwartz, Ilai; Chen, Qiong
New Journal of Physics, Vol. 18, Issue 1
DOI: 10.1088/1367-2630/18/1/013040

How to detect qubit-environment entanglement generated during qubit dephasing
journal, August 2019

Roszak, Katarzyna; Kwiatkowski, Damian; Cywiński, Łukasz
Physical Review A, Vol. 100, Issue 2
DOI: 10.1103/physreva.100.022318

Dynamically Polarizing Spin Register of N- $V$ Centers in Diamond Using Chopped Laser Pulses
journal, August 2019

Xu, Nanyang; Tian, Yu; Chen, Bing
Physical Review Applied, Vol. 12, Issue 2
DOI: 10.1103/physrevapplied.12.024055

Resonance-inclined optical nuclear spin polarization of liquids in diamond structures
journal, February 2016

Chen, Q.; Schwarz, I.; Jelezko, F.
Physical Review B, Vol. 93, Issue 6
DOI: 10.1103/physrevb.93.060408

All-optical hyperpolarization of electron and nuclear spins in diamond
journal, August 2017

Green, B. L.; Breeze, B. G.; Rees, G. J.
Physical Review B, Vol. 96, Issue 5
DOI: 10.1103/physrevb.96.054101

Robust techniques for polarization and detection of nuclear spin ensembles
journal, November 2017

Scheuer, Jochen; Schwartz, Ilai; Müller, Samuel
Physical Review B, Vol. 96, Issue 17
DOI: 10.1103/physrevb.96.174436

Optically induced cross relaxation via nitrogen-related defects for bulk diamond ${}^{13}C$ hyperpolarization
journal, December 2017

Wunderlich, Ralf; Kohlrautz, Jonas; Abel, Bernd
Physical Review B, Vol. 96, Issue 22
DOI: 10.1103/physrevb.96.220407

Multispin-assisted optical pumping of bulk ${}^{13}C$ nuclear spin polarization in diamond
journal, January 2018

Pagliero, Daniela; Rao, K. R. Koteswara; Zangara, Pablo R.
Physical Review B, Vol. 97, Issue 2
DOI: 10.1103/physrevb.97.024422

Quantum Bath Control with Nuclear Spin State Selectivity via Pulse-Adjusted Dynamical Decoupling
journal, November 2019

Lang, J. E.; Broadway, D. A.; White, G. A. L.
Physical Review Letters, Vol. 123, Issue 21
DOI: 10.1103/physrevlett.123.210401

Orientation-independent room temperature optical ¹³ C hyperpolarization in powdered diamond
journal, May 2018

Ajoy, Ashok; Liu, Kristina; Nazaryan, Raffi
Science Advances, Vol. 4, Issue 5
DOI: 10.1126/sciadv.aar5492

Robust optical polarization of nuclear spin baths using Hamiltonian engineering of nitrogen-vacancy center quantum dynamics
journal, August 2018

Schwartz, Ilai; Scheuer, Jochen; Tratzmiller, Benedikt
Science Advances, Vol. 4, Issue 8
DOI: 10.1126/sciadv.aat8978

Two-dimensional nuclear magnetic resonance spectroscopy with a microfluidic diamond quantum sensor
journal, July 2019

Smits, Janis; Damron, Joshua T.; Kehayias, Pauli
Science Advances, Vol. 5, Issue 7
DOI: 10.1126/sciadv.aaw7895

Electron-nuclear spin dynamics of Ga centers in GaAsN dilute nitride semiconductors probed by pump-probe spectroscopy
journal, March 2018

Sandoval-Santana, J. C.; Ibarra-Sierra, V. G.; Azaizia, S.
The European Physical Journal Plus, Vol. 133, Issue 3
DOI: 10.1140/epjp/i2018-11957-4

Ab initio theory of the nitrogen-vacancy center in diamond
journal, September 2019

Gali, Ádám
Nanophotonics, Vol. 8, Issue 11
DOI: 10.1515/nanoph-2019-0154

On The Potential of Dynamic Nuclear Polarization Enhanced Diamonds in Solid-State and Dissolution ¹³ C NMR Spectroscopy
journal, August 2016

Bretschneider, Christian O.; Akbey, Ümit; Aussenac, Fabien
ChemPhysChem, Vol. 17, Issue 17
DOI: 10.1002/cphc.201600877

Robust optical polarization of nuclear spin baths using Hamiltonian engineering of nitrogen-vacancy center quantum dynamics
text, January 2018

Schwartz, Ilai; Scheuer, Jochen; Tratzmiller, Benedikt
Universität Ulm
DOI: 10.18725/oparu-36761

Resonance-inclined optical nuclear spin polarization of liquids in diamond structures
text, January 2015

Chen, Qiong; Schwarz, Ilai; Jelezko, Fedor
arXiv
DOI: 10.48550/arxiv.1510.03256

All-optical hyperpolarization of electron and nuclear spins in diamond
text, January 2016

Green, Ben L.; Breeze, Ben G.; Rees, Gregory J.
arXiv
DOI: 10.48550/arxiv.1610.03823

Quantum probe hyperpolarisation of molecular nuclear spins
text, January 2017

Broadway, David A.; Tetienne, Jean-Philippe; Stacey, Alastair
arXiv
DOI: 10.48550/arxiv.1708.05906

Investigation of room temperature multispin-assisted bulk diamond 13C hyperpolarization at low magnetic fields
text, January 2018

Wunderlich, Ralf; Kohlrautz, Jonas; Abel, Bernd
arXiv
DOI: 10.48550/arxiv.1802.08319

Dynamically Polarizing Spin Register of NV Centers in Diamond using Chopped Laser Pulses
text, January 2018

Xu, Nanyang; Tian, Yu; Chen, Bing
arXiv
DOI: 10.48550/arxiv.1806.05881

Orientation independent room-temperature optical 13C hyperpolarization in powdered diamond
text, January 2018

Ajoy, A.; Liu, K.; Nazaryan, R.
arXiv
DOI: 10.48550/arxiv.1806.09812

How to detect qubit-environment entanglement generated during qubit dephasing
text, January 2018

Roszak, Katarzyna; Kwiatkowski, Damian; Cywiński, Łukasz
arXiv
DOI: 10.48550/arxiv.1810.09217

Two-dimensional nuclear magnetic resonance spectroscopy with a microfluidic diamond quantum sensor
text, January 2019

Smits, Janis; Damron, Joshua; Kehayias, Pauli
arXiv
DOI: 10.48550/arxiv.1901.02952

Quantum probe hyperpolarisation of molecular nuclear spins
journal, March 2018

Broadway, David A.; Tetienne, Jean-Philippe; Stacey, Alastair
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-03578-1

Qubit-environment negativity versus fidelity of conditional environmental states for a nitrogen-vacancy-center spin qubit interacting with a nuclear environment
journal, October 2020

Strzałka, Małgorzata; Kwiatkowski, Damian; Cywiński, Łukasz
Physical Review A, Vol. 102, Issue 4
DOI: 10.1103/physreva.102.042602

Robust optical polarization of nuclear spin baths using Hamiltonian engineering of nitrogen-vacancy center quantum dynamics
text, January 2018

Schwartz, Ilai; Scheuer, Jochen; Tratzmiller, Benedikt
Universität Ulm
DOI: 10.18725/oparu-36761

Phase-Encoded Hyperpolarized Nanodiamond for Magnetic Resonance Imaging
preprint, January 2017

Waddington, David E. J.; Boele, Thomas; Rej, Ewa
arXiv
DOI: 10.48550/arxiv.1709.01851

Two-dimensional nuclear magnetic resonance spectroscopy with a microfluidic diamond quantum sensor
text, January 2019

Smits, Janis; Damron, Joshua; Kehayias, Pauli
arXiv
DOI: 10.48550/arxiv.1901.02952

Similar Records in DOE PAGES and OSTI.GOV collections:

Orientation-independent room temperature optical ¹³C hyperpolarization in powdered diamond

Journal Article Ajoy, Ashok ; Liu, Kristina ; Nazaryan, Raffi ; ... - Science Advances

Dynamic nuclear polarization via contact with electronic spins has emerged as an attractive route to enhance the sensitivity of nuclear magnetic resonance beyond the traditional limits imposed by magnetic field strength and temperature. Among the various alternative implementations, the use of nitrogen vacancy (NV) centers in diamond—a paramagnetic point defect whose spin can be optically polarized at room temperature—has attracted widespread attention, but applications have been hampered by the need to align the NV axis with the external magnetic field. We overcome this hurdle through the combined use of continuous optical illumination and a microwave sweep over a broad frequencymore »« less
https://doi.org/10.1126/sciadv.aar5492

Full Text Available
An optimized microfabricated platform for the optical generation and detection of hyperpolarized ¹²⁹Xe

Journal Article Kennedy, Daniel J. ; Seltzer, Scott J. ; Jiménez-Martínez, Ricardo ; ... - Scientific Reports

Low thermal-equilibrium nuclear spin polarizations and the need for sophisticated instrumentation render conventional nuclear magnetic resonance (NMR) spectroscopy and imaging (MRI) incompatible with small-scale microfluidic devices. Hyperpolarized ¹²⁹Xe gas has found use in the study of many materials but has required very large and expensive instrumentation. Recently a microfabricated device with modest instrumentation demonstrated all-optical hyperpolarization and detection of ¹²⁹Xe gas. This device was limited by ¹²⁹Xe polarizations less than 1%, ¹²⁹Xe NMR signals smaller than 20 nT, and transport of hyperpolarized ¹²⁹Xe over millimeter lengths. Higher polarizations, versatile detection schemes, and flow of ¹²⁹Xe over larger distances are desirablemore »« less
Cited by 15
https://doi.org/10.1038/srep43994

Full Text Available
Floquet Prethermalization with Lifetime Exceeding 90 s in a Bulk Hyperpolarized Solid

Journal Article Beatrez, William ; Janes, Otto ; Akkiraju, Amala ; ... - Physical Review Letters

Here, we report the observation of long-lived Floquet prethermal states in a bulk solid composed of dipolar-coupled ¹³C nuclei in diamond at room temperature. For precessing nuclear spins prepared in an initial transverse state, we demonstrate pulsed spin-lock Floquet control that prevents their decay over multiple-minute-long periods. We observe Floquet prethermal lifetimesmore »« less
https://doi.org/10.1103/physrevlett.127.170603

Full Text Available
Spin Hyperpolarization in Modern Magnetic Resonance

Journal Article Eills, James ; Budker, Dmitry ; Cavagnero, Silvia ; ... - Chemical Reviews

Magnetic resonance techniques are successfully utilized in a broad range of scientific disciplines and in various practical applications, with medical magnetic resonance imaging being the most widely known example. Currently, both fundamental and applied magnetic resonance are enjoying a major boost owing to the rapidly developing field of spin hyperpolarization. Hyperpolarization techniques are able to enhance signal intensities in magnetic resonance by several orders of magnitude, and thus to largely overcome its major disadvantage of relatively low sensitivity. This provides new impetus for existing applications of magnetic resonance and opens the gates to exciting new possibilities. In this review, wemore »« less
https://doi.org/10.1021/acs.chemrev.2c00534
Specialized diamond materials for NMR applications

Patent Parker, Alfred ; King, Jonathan ; Vassiliou, Christophoros C. ; ...

Polarizable diamond materials and methods for obtaining nuclear magnetic resonance spectra of samples external to the diamond materials are described. The diamond materials can include 12C, 13C, substitutional nitrogen, and nitrogen vacancy defects in a crystalline lattice, wherein the substitutional nitrogen concentration is between 10 ppm and 200 ppm, the nitrogen vacancy concentration is between 10 ppb and 10 ppm, and the 13C concentration is greater than 1.1% and not more than 25%. Methods for obtaining nuclear magnetic resonance spectra can include optically pumping a diamond material to generate electron spin hyperpolarization in nitrogen vacancy centers, transferring the electron spinmore »« less
Full Text Available

Similar Records

Title: Room-temperature in situ nuclear spin hyperpolarization from optically pumped nitrogen vacancy centres in diamond

Abstract

Citation Formats

The nitrogen-vacancy colour centre in diamond journal, July 2013

Enhancement of Solution NMR and MRI with Laser-Polarized Xenon journal, March 1996

High-field cross polarization NMR from laser-polarized xenon to surface nuclei journal, March 1995

An introduction to chemically induced dynamic nuclear polarization journal, January 1995

Optical polarization of nuclear ensembles in diamond journal, March 2013

NMR of hyperpolarised probes: NMR of hyperpolarised probes journal, October 2012

Spin-exchange optical pumping of noble-gas nuclei journal, April 1997

Transformation of Symmetrization Order to Nuclear-Spin Magnetization by Chemical Reaction and Nuclear Magnetic Resonance journal, November 1986

Hybrid polarizing solids for pure hyperpolarized liquids through dissolution dynamic nuclear polarization journal, September 2014

High Frequency Dynamic Nuclear Polarization journal, April 2013

Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR journal, August 2003

Proton‐enhanced NMR of dilute spins in solids journal, July 1973

Dynamic Nuclear Spin Polarization of Liquids and Gases in Contact with Nanostructured Diamond journal, April 2014

Optically pumped nuclear magnetic resonance of semiconductors journal, February 2008

Dynamic nuclear polarization at high magnetic fields in liquids journal, July 2012

Dynamic nuclear polarization of diamond. I. Solid state and thermal mixing effects journal, September 1998

Nuclear Polarization in He 3 Gas Induced by Optical Pumping and Dipolar Exchange journal, October 1960

Diamonds with a high density of nitrogen-vacancy centers for magnetometry applications journal, September 2009

Nuclear hyperpolarization in solids and the prospects for nuclear spintronics journal, February 2010

Optical polarization of C 13 nuclei in diamond through nitrogen vacancy centers journal, February 2010

Room temperature hyperpolarization of nuclear spins in bulk journal, May 2014

Sensitive magnetic control of ensemble nuclear spin hyperpolarization in diamond journal, June 2013

Local and bulk 13C hyperpolarization in nitrogen-vacancy-centred diamonds at variable fields and orientations journal, September 2015

The Principles of Nuclear Magnetism journal, December 1961

Xenon NMR Spectroscopy journal, May 2007

The Principles of Nuclear Magnetism journal, November 1961

Optical polarization of nuclear ensembles in diamond text, January 2012

Bulk Nuclear Polarization Enhanced at Room-Temperature by Optical Pumping text, January 2012

Dynamic nuclear polarization at high magnetic fields in liquids journal, July 2012

Parahydrogen induced polarization journal, November 1997

High Frequency Dynamic Nuclear Polarization journal, April 2013

Dynamic Nuclear Spin Polarization of Liquids and Gases in Contact with Nanostructured Diamond journal, April 2014

Sensitive magnetic control of ensemble nuclear spin hyperpolarization in diamond journal, June 2013

Optically pumped nuclear magnetic resonance of semiconductors journal, February 2008

Dynamic nuclear polarization of diamond. I. Solid state and thermal mixing effects journal, September 1998

Room temperature hyperpolarization of nuclear spins in bulk journal, May 2014

Hybrid polarizing solids for pure hyperpolarized liquids through dissolution dynamic nuclear polarization journal, September 2014

Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR journal, August 2003

Bulk Nuclear Polarization Enhanced at Room Temperature by Optical Pumping journal, July 2013

Enhancement of Solution NMR and MRI with Laser-Polarized Xenon journal, March 1996

Optical polarization of nuclear ensembles in diamond text, January 2012

Diamond Quantum Devices in Biology journal, April 2016

On The Potential of Dynamic Nuclear Polarization Enhanced Diamonds in Solid-State and Dissolution 13 C NMR Spectroscopy journal, July 2016

A Perspective on Fluorescent Nanodiamond Bioimaging journal, June 2019

Towards clinically translatable in vivo nanodiagnostics journal, May 2017

Local and bulk 13C hyperpolarization in nitrogen-vacancy-centred diamonds at variable fields and orientations journal, September 2015

Hyperpolarized nanodiamond with long spin-relaxation times journal, October 2015

Quantum probe hyperpolarisation of molecular nuclear spins journal, March 2018

First principles calculation of spin-related quantities for point defect qubit research journal, December 2018

Phase-Encoded Hyperpolarized Nanodiamond for Magnetic Resonance Imaging journal, April 2019

Dynamics of frequency-swept nuclear spin optical pumping in powdered diamond at low magnetic fields journal, January 2019

Carbon-13 dynamic nuclear polarization in diamond via a microwave-free integrated cross effect journal, August 2019

The alternative splicing of SKU5-Similar3 in Arabidopsis journal, August 2019

Investigation of room temperature multispin-assisted bulk diamond 13 C hyperpolarization at low magnetic fields journal, July 2018

Influence of magnetic field alignment and defect concentration on nitrogen-vacancy polarization in diamond journal, December 2015

Optically induced dynamic nuclear spin polarisation in diamond journal, January 2016

How to detect qubit-environment entanglement generated during qubit dephasing journal, August 2019

Dynamically Polarizing Spin Register of N- V Centers in Diamond Using Chopped Laser Pulses journal, August 2019

Resonance-inclined optical nuclear spin polarization of liquids in diamond structures journal, February 2016

All-optical hyperpolarization of electron and nuclear spins in diamond journal, August 2017

Robust techniques for polarization and detection of nuclear spin ensembles journal, November 2017

Optically induced cross relaxation via nitrogen-related defects for bulk diamond C 13 hyperpolarization journal, December 2017

Multispin-assisted optical pumping of bulk C 13 nuclear spin polarization in diamond journal, January 2018

Quantum Bath Control with Nuclear Spin State Selectivity via Pulse-Adjusted Dynamical Decoupling journal, November 2019

Orientation-independent room temperature optical 13 C hyperpolarization in powdered diamond journal, May 2018

Robust optical polarization of nuclear spin baths using Hamiltonian engineering of nitrogen-vacancy center quantum dynamics journal, August 2018

Two-dimensional nuclear magnetic resonance spectroscopy with a microfluidic diamond quantum sensor journal, July 2019

Electron-nuclear spin dynamics of Ga centers in GaAsN dilute nitride semiconductors probed by pump-probe spectroscopy journal, March 2018

Ab initio theory of the nitrogen-vacancy center in diamond journal, September 2019

On The Potential of Dynamic Nuclear Polarization Enhanced Diamonds in Solid-State and Dissolution 13 C NMR Spectroscopy journal, August 2016

Robust optical polarization of nuclear spin baths using Hamiltonian engineering of nitrogen-vacancy center quantum dynamics text, January 2018

Resonance-inclined optical nuclear spin polarization of liquids in diamond structures text, January 2015

All-optical hyperpolarization of electron and nuclear spins in diamond text, January 2016

Quantum probe hyperpolarisation of molecular nuclear spins text, January 2017

Investigation of room temperature multispin-assisted bulk diamond 13C hyperpolarization at low magnetic fields text, January 2018

Dynamically Polarizing Spin Register of NV Centers in Diamond using Chopped Laser Pulses text, January 2018

Orientation independent room-temperature optical 13C hyperpolarization in powdered diamond text, January 2018

The nitrogen-vacancy colour centre in diamond
journal, July 2013

Enhancement of Solution NMR and MRI with Laser-Polarized Xenon
journal, March 1996

High-field cross polarization NMR from laser-polarized xenon to surface nuclei
journal, March 1995

An introduction to chemically induced dynamic nuclear polarization
journal, January 1995

Optical polarization of nuclear ensembles in diamond
journal, March 2013

NMR of hyperpolarised probes: NMR of hyperpolarised probes
journal, October 2012

Spin-exchange optical pumping of noble-gas nuclei
journal, April 1997

Transformation of Symmetrization Order to Nuclear-Spin Magnetization by Chemical Reaction and Nuclear Magnetic Resonance
journal, November 1986

Hybrid polarizing solids for pure hyperpolarized liquids through dissolution dynamic nuclear polarization
journal, September 2014

High Frequency Dynamic Nuclear Polarization
journal, April 2013

Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR
journal, August 2003

Proton‐enhanced NMR of dilute spins in solids
journal, July 1973

Dynamic Nuclear Spin Polarization of Liquids and Gases in Contact with Nanostructured Diamond
journal, April 2014

Optically pumped nuclear magnetic resonance of semiconductors
journal, February 2008

Dynamic nuclear polarization at high magnetic fields in liquids
journal, July 2012

Dynamic nuclear polarization of diamond. I. Solid state and thermal mixing effects
journal, September 1998

Nuclear Polarization in ${He}^{3}$ Gas Induced by Optical Pumping and Dipolar Exchange
journal, October 1960

Diamonds with a high density of nitrogen-vacancy centers for magnetometry applications
journal, September 2009

Nuclear hyperpolarization in solids and the prospects for nuclear spintronics
journal, February 2010

Optical polarization of ${}^{13}C$ nuclei in diamond through nitrogen vacancy centers
journal, February 2010

Room temperature hyperpolarization of nuclear spins in bulk
journal, May 2014

Sensitive magnetic control of ensemble nuclear spin hyperpolarization in diamond
journal, June 2013

Local and bulk 13C hyperpolarization in nitrogen-vacancy-centred diamonds at variable fields and orientations
journal, September 2015

The Principles of Nuclear Magnetism
journal, December 1961

Xenon NMR Spectroscopy
journal, May 2007

The Principles of Nuclear Magnetism
journal, November 1961

Optical polarization of nuclear ensembles in diamond
text, January 2012

Bulk Nuclear Polarization Enhanced at Room-Temperature by Optical Pumping
text, January 2012

Dynamic nuclear polarization at high magnetic fields in liquids
journal, July 2012

Parahydrogen induced polarization
journal, November 1997

High Frequency Dynamic Nuclear Polarization
journal, April 2013

Dynamic Nuclear Spin Polarization of Liquids and Gases in Contact with Nanostructured Diamond
journal, April 2014

Sensitive magnetic control of ensemble nuclear spin hyperpolarization in diamond
journal, June 2013

Optically pumped nuclear magnetic resonance of semiconductors
journal, February 2008

Dynamic nuclear polarization of diamond. I. Solid state and thermal mixing effects
journal, September 1998

Room temperature hyperpolarization of nuclear spins in bulk
journal, May 2014

Hybrid polarizing solids for pure hyperpolarized liquids through dissolution dynamic nuclear polarization
journal, September 2014

Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR
journal, August 2003

Bulk Nuclear Polarization Enhanced at Room Temperature by Optical Pumping
journal, July 2013

Enhancement of Solution NMR and MRI with Laser-Polarized Xenon
journal, March 1996

Optical polarization of nuclear ensembles in diamond
text, January 2012

Diamond Quantum Devices in Biology
journal, April 2016

On The Potential of Dynamic Nuclear Polarization Enhanced Diamonds in Solid-State and Dissolution ¹³ C NMR Spectroscopy
journal, July 2016

A Perspective on Fluorescent Nanodiamond Bioimaging
journal, June 2019

Towards clinically translatable in vivo nanodiagnostics
journal, May 2017

Local and bulk 13C hyperpolarization in nitrogen-vacancy-centred diamonds at variable fields and orientations
journal, September 2015

Hyperpolarized nanodiamond with long spin-relaxation times
journal, October 2015

Quantum probe hyperpolarisation of molecular nuclear spins
journal, March 2018

First principles calculation of spin-related quantities for point defect qubit research
journal, December 2018

Phase-Encoded Hyperpolarized Nanodiamond for Magnetic Resonance Imaging
journal, April 2019

Dynamics of frequency-swept nuclear spin optical pumping in powdered diamond at low magnetic fields
journal, January 2019

Carbon-13 dynamic nuclear polarization in diamond via a microwave-free integrated cross effect
journal, August 2019

The alternative splicing of SKU5-Similar3 in Arabidopsis
journal, August 2019

Investigation of room temperature multispin-assisted bulk diamond ¹³ C hyperpolarization at low magnetic fields
journal, July 2018

Influence of magnetic field alignment and defect concentration on nitrogen-vacancy polarization in diamond
journal, December 2015

Optically induced dynamic nuclear spin polarisation in diamond
journal, January 2016

How to detect qubit-environment entanglement generated during qubit dephasing
journal, August 2019

Dynamically Polarizing Spin Register of N- $V$ Centers in Diamond Using Chopped Laser Pulses
journal, August 2019

Resonance-inclined optical nuclear spin polarization of liquids in diamond structures
journal, February 2016

All-optical hyperpolarization of electron and nuclear spins in diamond
journal, August 2017

Robust techniques for polarization and detection of nuclear spin ensembles
journal, November 2017

Optically induced cross relaxation via nitrogen-related defects for bulk diamond ${}^{13}C$ hyperpolarization
journal, December 2017

Multispin-assisted optical pumping of bulk ${}^{13}C$ nuclear spin polarization in diamond
journal, January 2018

Quantum Bath Control with Nuclear Spin State Selectivity via Pulse-Adjusted Dynamical Decoupling
journal, November 2019

Orientation-independent room temperature optical ¹³ C hyperpolarization in powdered diamond
journal, May 2018

Robust optical polarization of nuclear spin baths using Hamiltonian engineering of nitrogen-vacancy center quantum dynamics
journal, August 2018

Two-dimensional nuclear magnetic resonance spectroscopy with a microfluidic diamond quantum sensor
journal, July 2019

Electron-nuclear spin dynamics of Ga centers in GaAsN dilute nitride semiconductors probed by pump-probe spectroscopy
journal, March 2018

Ab initio theory of the nitrogen-vacancy center in diamond
journal, September 2019

On The Potential of Dynamic Nuclear Polarization Enhanced Diamonds in Solid-State and Dissolution ¹³ C NMR Spectroscopy
journal, August 2016

Robust optical polarization of nuclear spin baths using Hamiltonian engineering of nitrogen-vacancy center quantum dynamics
text, January 2018

Resonance-inclined optical nuclear spin polarization of liquids in diamond structures
text, January 2015

All-optical hyperpolarization of electron and nuclear spins in diamond
text, January 2016

Quantum probe hyperpolarisation of molecular nuclear spins
text, January 2017

Investigation of room temperature multispin-assisted bulk diamond 13C hyperpolarization at low magnetic fields
text, January 2018

Dynamically Polarizing Spin Register of NV Centers in Diamond using Chopped Laser Pulses
text, January 2018

Orientation independent room-temperature optical 13C hyperpolarization in powdered diamond
text, January 2018

How to detect qubit-environment entanglement generated during qubit dephasing
text, January 2018

Two-dimensional nuclear magnetic resonance spectroscopy with a microfluidic diamond quantum sensor
text, January 2019

Quantum probe hyperpolarisation of molecular nuclear spins
journal, March 2018