Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalyst for the hydrogen evolution reaction
Abstract
Three of the fundamental catalytic limitations that have plagued the electrochemical production of hydrogen for decades still remain: low efficiency, short lifetime of catalysts and a lack of low-cost materials. Here, we address these three challenges by establishing and exploring an intimate functional link between the reactivity and stability of crystalline (CoS2 and MoS2) and amorphous (CoSx and MoSx) hydrogen evolution catalysts. We propose that Co2+ and Mo4+ centers promote the initial discharge of water (alkaline solutions) or hydronium ions (acid solutions). We establish that although CoSx materials are more active than MoSx they are also less stable, suggesting that the active sites are defects formed after dissolution of Co and Mo cations. Finally, by combining the higher activity of CoSx building blocks with the higher stability of MoSx units into a compact and robust CoMoSx structure, we are able to design a low-cost alternative to noble metal catalysts for efficient electrocatalytic production of hydrogen in both alkaline and acidic environments.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Univ. of Ljubljana (Slovenia)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1248731
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Materials
- Additional Journal Information:
- Journal Volume: 15; Journal Issue: 2; Journal ID: ISSN 1476-1122
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Staszak-Jirkovský, Jakub, Malliakas, Christos D., Lopes, Pietro P., Danilovic, Nemanja, Kota, Subrahmanyam S., Chang, Kee-Chul, Genorio, Bostjan, Strmcnik, Dusan, Stamenkovic, Vojislav R., Kanatzidis, Mercouri G., and Markovic, Nenad M. Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalyst for the hydrogen evolution reaction. United States: N. p., 2015.
Web. doi:10.1038/NMAT4481.
Staszak-Jirkovský, Jakub, Malliakas, Christos D., Lopes, Pietro P., Danilovic, Nemanja, Kota, Subrahmanyam S., Chang, Kee-Chul, Genorio, Bostjan, Strmcnik, Dusan, Stamenkovic, Vojislav R., Kanatzidis, Mercouri G., & Markovic, Nenad M. Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalyst for the hydrogen evolution reaction. United States. https://doi.org/10.1038/NMAT4481
Staszak-Jirkovský, Jakub, Malliakas, Christos D., Lopes, Pietro P., Danilovic, Nemanja, Kota, Subrahmanyam S., Chang, Kee-Chul, Genorio, Bostjan, Strmcnik, Dusan, Stamenkovic, Vojislav R., Kanatzidis, Mercouri G., and Markovic, Nenad M. Mon .
"Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalyst for the hydrogen evolution reaction". United States. https://doi.org/10.1038/NMAT4481. https://www.osti.gov/servlets/purl/1248731.
@article{osti_1248731,
title = {Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalyst for the hydrogen evolution reaction},
author = {Staszak-Jirkovský, Jakub and Malliakas, Christos D. and Lopes, Pietro P. and Danilovic, Nemanja and Kota, Subrahmanyam S. and Chang, Kee-Chul and Genorio, Bostjan and Strmcnik, Dusan and Stamenkovic, Vojislav R. and Kanatzidis, Mercouri G. and Markovic, Nenad M.},
abstractNote = {Three of the fundamental catalytic limitations that have plagued the electrochemical production of hydrogen for decades still remain: low efficiency, short lifetime of catalysts and a lack of low-cost materials. Here, we address these three challenges by establishing and exploring an intimate functional link between the reactivity and stability of crystalline (CoS2 and MoS2) and amorphous (CoSx and MoSx) hydrogen evolution catalysts. We propose that Co2+ and Mo4+ centers promote the initial discharge of water (alkaline solutions) or hydronium ions (acid solutions). We establish that although CoSx materials are more active than MoSx they are also less stable, suggesting that the active sites are defects formed after dissolution of Co and Mo cations. Finally, by combining the higher activity of CoSx building blocks with the higher stability of MoSx units into a compact and robust CoMoSx structure, we are able to design a low-cost alternative to noble metal catalysts for efficient electrocatalytic production of hydrogen in both alkaline and acidic environments.},
doi = {10.1038/NMAT4481},
journal = {Nature Materials},
number = 2,
volume = 15,
place = {United States},
year = {Mon Nov 30 00:00:00 EST 2015},
month = {Mon Nov 30 00:00:00 EST 2015}
}
Web of Science
Works referenced in this record:
Interfacing electrochemistry
journal, January 2013
- Markovic, Nenad M.
- Nature Materials, Vol. 12, Issue 2
Alternative energy technologies
journal, November 2001
- Dresselhaus, M. S.; Thomas, I. L.
- Nature, Vol. 414, Issue 6861
Hydrogen-storage materials for mobile applications
journal, November 2001
- Schlapbach, Louis; Züttel, Andreas
- Nature, Vol. 414, Issue 6861
Just a Dream—or Future Reality?
journal, April 2009
- Gasteiger, Hubert A.; Marković, Nenad M
- Science, Vol. 324, Issue 5923, p. 48-49
All-solid-state dye-sensitized solar cells with high efficiency
journal, May 2012
- Chung, In; Lee, Byunghong; He, Jiaqing
- Nature, Vol. 485, Issue 7399, p. 486-489
Renewable Hydrogen Production: Performance of an Alkaline Water Electrolyzer Working under Emulated Wind Conditions
journal, May 2007
- Gandía, Luis M.; Oroz, Raquel; Ursúa, Alfredo
- Energy & Fuels, Vol. 21, Issue 3
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces
journal, December 2011
- Subbaraman, R.; Tripkovic, D.; Strmcnik, D.
- Science, Vol. 334, Issue 6060
Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts
journal, May 2012
- Subbaraman, Ram; Tripkovic, Dusan; Chang, Kee-Chul
- Nature Materials, Vol. 11, Issue 6
Studies of the Hydrogen Evolution Reaction on Raney Nickel–Molybdenum Electrodes
journal, July 2004
- Birry, L.; Lasia, A.
- Journal of Applied Electrochemistry, Vol. 34, Issue 7
Kinetics of hydrogen evolution on nickel electrodes
journal, November 1990
- Lasia, A.; Rami, A.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 294, Issue 1-2
Hydrogen evolution reaction on Ni-Al electrodes
journal, February 1993
- Los, P.; Rami, A.; Lasia, A.
- Journal of Applied Electrochemistry, Vol. 23, Issue 2
Advances in electrocatalysis for hydrogen evolution in the light of the Brewer-Engel valence-bond theory☆
journal, January 1987
- Jaksic, M.
- International Journal of Hydrogen Energy, Vol. 12, Issue 11
Hydrogen evolution reaction on amorphous Ni–S–Co alloy in alkaline medium
journal, December 2003
- Han, Q.
- International Journal of Hydrogen Energy, Vol. 28, Issue 12
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
journal, October 2006
- Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob
- Nature Materials, Vol. 5, Issue 11, p. 909-913
Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts
journal, July 2007
- Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J.
- Science, Vol. 317, Issue 5834, p. 100-102
Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo3S13]2− clusters
journal, January 2014
- Kibsgaard, Jakob; Jaramillo, Thomas F.; Besenbacher, Flemming
- Nature Chemistry, Vol. 6, Issue 3
Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
journal, October 2012
- Kibsgaard, Jakob; Chen, Zhebo; Reinecke, Benjamin N.
- Nature Materials, Vol. 11, Issue 11, p. 963-969
Earth-Abundant Metal Pyrites (FeS 2 , CoS 2 , NiS 2 , and Their Alloys) for Highly Efficient Hydrogen Evolution and Polysulfide Reduction Electrocatalysis
journal, September 2014
- Faber, Matthew S.; Lukowski, Mark A.; Ding, Qi
- The Journal of Physical Chemistry C, Vol. 118, Issue 37
High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS 2 ) Micro- and Nanostructures
journal, June 2014
- Faber, Matthew S.; Dziedzic, Rafal; Lukowski, Mark A.
- Journal of the American Chemical Society, Vol. 136, Issue 28
Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS 2 Nanosheets
journal, May 2013
- Lukowski, Mark A.; Daniel, Andrew S.; Meng, Fei
- Journal of the American Chemical Society, Vol. 135, Issue 28
Atomic-Scale Structure of Co–Mo–S Nanoclusters in Hydrotreating Catalysts
journal, January 2001
- Lauritsen, J. V.; Helveg, S.; Lægsgaard, E.
- Journal of Catalysis, Vol. 197, Issue 1
Location and coordination of promoter atoms in Co- and Ni-promoted MoS2-based hydrotreating catalysts
journal, July 2007
- Lauritsen, J.; Kibsgaard, J.; Olesen, G.
- Journal of Catalysis, Vol. 249, Issue 2
The role of Co–Mo–S type structures in hydrotreating catalysts
journal, April 2007
- Topsøe, Henrik
- Applied Catalysis A: General, Vol. 322
Comparative atomic-scale analysis of promotional effects by late 3d-transition metals in MoS2 hydrotreating catalysts
journal, June 2010
- Kibsgaard, Jakob; Tuxen, Anders; Knudsen, Kim G.
- Journal of Catalysis, Vol. 272, Issue 2
Porous Semiconducting Gels and Aerogels from Chalcogenide Clusters
journal, July 2007
- Bag, S.; Trikalitis, P. N.; Chupas, P. J.
- Science, Vol. 317, Issue 5837
Spongy chalcogels of non-platinum metals act as effective hydrodesulfurization catalysts
journal, May 2009
- Bag, Santanu; Gaudette, Amy F.; Bussell, Mark E.
- Nature Chemistry, Vol. 1, Issue 3
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
journal, April 2005
- Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob
- Journal of the American Chemical Society, Vol. 127, Issue 15
Ab Initio Study of the H2–H2S/MoS2 Gas–Solid Interface: The Nature of the Catalytically Active Sites
journal, January 2000
- Raybaud, P.; Hafner, J.; Kresse, G.
- Journal of Catalysis, Vol. 189, Issue 1
The Reaction Mechanism with Free Energy Barriers for Electrochemical Dihydrogen Evolution on MoS 2
journal, May 2015
- Huang, Yufeng; Nielsen, Robert J.; Goddard, William A.
- Journal of the American Chemical Society, Vol. 137, Issue 20
Formation of Sulfur Atomic Layers on Gold from Aqueous Solutions of Sulfide and Thiosulfate: Studies Using EC-STM, UHV-EC, and TLEC
journal, September 2003
- Lay, Marcus D.; Varazo, Kris; Stickney, John L.
- Langmuir, Vol. 19, Issue 20
The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum
journal, August 2009
- Strmcnik, D.; Kodama, K.; van der Vliet, D.
- Nature Chemistry, Vol. 1, Issue 6
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption
journal, February 2013
- Strmcnik, Dusan; Uchimura, Masanobu; Wang, Chao
- Nature Chemistry, Vol. 5, Issue 4
Surface science studies of model fuel cell electrocatalysts
journal, April 2002
- Markovic, N.
- Surface Science Reports, Vol. 45, Issue 4-6
Unconventional promoters of catalytic activity in electrocatalysis
journal, January 2012
- Tong, YuYe J.
- Chemical Society Reviews, Vol. 41, Issue 24
Effects of Li + , K + , and Ba 2+ Cations on the ORR at Model and High Surface Area Pt and Au Surfaces in Alkaline Solutions
journal, October 2011
- Strmcnik, D.; van der Vliet, D. F.; Chang, K. -C.
- The Journal of Physical Chemistry Letters, Vol. 2, Issue 21
Reduction of Oxygen on Dispersed Nanocrystalline CoS 2
journal, November 2012
- Jirkovský, Jakub S.; Björling, Alexander; Ahlberg, Elisabet
- The Journal of Physical Chemistry C, Vol. 116, Issue 46
Structure of Amorphous MoS3
journal, June 1995
- Weber, Th.; Muijsers, J. C.; Niemantsverdriet, J. W.
- The Journal of Physical Chemistry, Vol. 99, Issue 22
Ion-Exchangeable Cobalt Polysulfide Chalcogel
journal, February 2011
- Shafaei-Fallah, Maryam; He, Jiaqing; Rothenberger, Alexander
- Journal of the American Chemical Society, Vol. 133, Issue 5
One-Dimensional Molybdenum Thiochlorides and Their Use in High Surface Area MoS x Chalcogels
journal, August 2014
- Islam, Saiful M.; Subrahmanyam, Kota S.; Malliakas, Christos D.
- Chemistry of Materials, Vol. 26, Issue 17
Ion-Exchangeable Molybdenum Sulfide Porous Chalcogel: Gas Adsorption and Capture of Iodine and Mercury
journal, October 2015
- Subrahmanyam, Kota S.; Malliakas, Christos D.; Sarma, Debajit
- Journal of the American Chemical Society, Vol. 137, Issue 43
Turnover Rates in Heterogeneous Catalysis
journal, May 1995
- Boudart, M.
- Chemical Reviews, Vol. 95, Issue 3
Work function, electronegativity, and electrochemical behaviour of metals
journal, September 1972
- Trasatti, Sergio
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 1
Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH) 2 /Metal Catalysts
journal, November 2012
- Danilovic, N.; Subbaraman, Ram; Strmcnik, D.
- Angewandte Chemie International Edition, Vol. 51, Issue 50
Unique Activity of Platinum Adislands in the CO Electrooxidation Reaction
journal, November 2008
- Strmcnik, Dusan S.; Tripkovic, Dusan V.; van der Vliet, Dennis
- Journal of the American Chemical Society, Vol. 130, Issue 46
Activity–Stability Trends for the Oxygen Evolution Reaction on Monometallic Oxides in Acidic Environments
journal, July 2014
- Danilovic, Nemanja; Subbaraman, Ramachandran; Chang, Kee-Chul
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 14
Functional links between stability and reactivity of strontium ruthenate single crystals during oxygen evolution
journal, June 2014
- Chang, Seo Hyoung; Danilovic, Nemanja; Chang, Kee-Chul
- Nature Communications, Vol. 5, Issue 1
Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH) 2 /Metal Catalysts
journal, November 2012
- Danilovic, N.; Subbaraman, Ram; Strmcnik, D.
- Angewandte Chemie, Vol. 124, Issue 50
Porous Semiconducting Gels and Aerogels from Chalcogenide Clusters.
journal, October 2007
- Bag, Santanu; Trikalitis, Pantelis N.; Chupas, Peter J.
- ChemInform, Vol. 38, Issue 42
Advances in electrocatalysis for hydrogen evolution in the light of the Brewer-Engel valence-bond theory
journal, November 1986
- Jakšić, Milan M.
- Journal of Molecular Catalysis, Vol. 38, Issue 1-2
Photoelectrochemical Cells
journal, February 1980
- Nozik, A. J.
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 295, Issue 1414
Works referencing / citing this record:
Ternary Metal Phosphide with Triple-Layered Structure as a Low-Cost and Efficient Electrocatalyst for Bifunctional Water Splitting
journal, September 2016
- Yu, Jing; Li, Qianqian; Li, Yuan
- Advanced Functional Materials, Vol. 26, Issue 42
Homologous CoP/NiCoP Heterostructure on N‐Doped Carbon for Highly Efficient and pH‐Universal Hydrogen Evolution Electrocatalysis
journal, December 2018
- Boppella, Ramireddy; Tan, Jeiwan; Yang, Wooseok
- Advanced Functional Materials, Vol. 29, Issue 6
Ternary NiCo 2 P x Nanowires as pH-Universal Electrocatalysts for Highly Efficient Hydrogen Evolution Reaction
journal, December 2016
- Zhang, Rui; Wang, Xiangxue; Yu, Shujun
- Advanced Materials, Vol. 29, Issue 9
In Situ Transformation of MOFs into Layered Double Hydroxide Embedded Metal Sulfides for Improved Electrocatalytic and Supercapacitive Performance
journal, May 2017
- Yilmaz, Gamze; Yam, Kah Meng; Zhang, Chun
- Advanced Materials, Vol. 29, Issue 26
Regulating Water-Reduction Kinetics in Cobalt Phosphide for Enhancing HER Catalytic Activity in Alkaline Solution
journal, May 2017
- Xu, Kun; Ding, Hui; Zhang, Mengxing
- Advanced Materials, Vol. 29, Issue 28
Anion-Regulated Selective Generation of Cobalt Sites in Carbon: Toward Superior Bifunctional Electrocatalysis
journal, November 2017
- Wan, Gang; Yang, Ce; Zhao, Wanpeng
- Advanced Materials, Vol. 29, Issue 47
Atomic Vacancies Control of Pd-Based Catalysts for Enhanced Electrochemical Performance
journal, November 2017
- Zuo, Yunpeng; Rao, Dewei; Li, Shuo
- Advanced Materials, Vol. 30, Issue 1
Carbon-Based Photocathode Materials for Solar Hydrogen Production
journal, September 2018
- Bellani, Sebastiano; Antognazza, Maria Rosa; Bonaccorso, Francesco
- Advanced Materials, Vol. 31, Issue 9
Ultrafine Co Nanoparticles Encapsulated in Carbon-Nanotubes-Grafted Graphene Sheets as Advanced Electrocatalysts for the Hydrogen Evolution Reaction
journal, June 2018
- Chen, Ziliang; Wu, Renbing; Liu, Yang
- Advanced Materials, Vol. 30, Issue 30
Boosting Water Dissociation Kinetics on Pt–Ni Nanowires by N‐Induced Orbital Tuning
journal, February 2019
- Xie, Yufang; Cai, Jinyan; Wu, Yishang
- Advanced Materials, Vol. 31, Issue 16
Colloidal Synthesis of Mo-Ni Alloy Nanoparticles as Bifunctional Electrocatalysts for Efficient Overall Water Splitting
journal, May 2018
- Zhang, Taotao; Liu, Xiaowang; Cui, Xin
- Advanced Materials Interfaces, Vol. 5, Issue 13
Nickel Hydr(oxy)oxide Nanoparticles on Metallic MoS 2 Nanosheets: A Synergistic Electrocatalyst for Hydrogen Evolution Reaction
journal, December 2017
- Zhang, Xing; Liang, Yongye
- Advanced Science, Vol. 5, Issue 2
Stringing Bimetallic Metal–Organic Framework‐Derived Cobalt Phosphide Composite for High‐Efficiency Overall Water Splitting
journal, January 2020
- Chai, Lulu; Hu, Zhuoyi; Wang, Xian
- Advanced Science, Vol. 7, Issue 5
Mixed Metal Sulfides for Electrochemical Energy Storage and Conversion
journal, September 2017
- Yu, Xin Yao; David Lou, Xiong Wen
- Advanced Energy Materials, Vol. 8, Issue 3
Local Charge Distribution Engineered by Schottky Heterojunctions toward Urea Electrolysis
journal, August 2018
- Li, Caicai; Liu, Youwen; Zhuo, Zhiwen
- Advanced Energy Materials, Vol. 8, Issue 27
Trimetallic Sulfide Mesoporous Nanospheres as Superior Electrocatalysts for Rechargeable Zn-Air Batteries
journal, October 2018
- Yang, Haozhou; Wang, Bin; Li, Haoyi
- Advanced Energy Materials, Vol. 8, Issue 34
Construction of CoP/NiCoP Nanotadpoles Heterojunction Interface for Wide pH Hydrogen Evolution Electrocatalysis and Supercapacitor
journal, August 2019
- Lin, Yan; Sun, Kaian; Liu, Shoujie
- Advanced Energy Materials, Vol. 9, Issue 36
Layered Double Hydroxide Nanosheets with Multiple Vacancies Obtained by Dry Exfoliation as Highly Efficient Oxygen Evolution Electrocatalysts
journal, April 2017
- Wang, Yanyong; Zhang, Yiqiong; Liu, Zhijuan
- Angewandte Chemie, Vol. 129, Issue 21
Highly Tunable Heterojunctions from Multimetallic Sulfide Nanoparticles and Silver Nanowires
journal, April 2018
- Liu, Dongliang; Liu, Yong; Huang, Peng
- Angewandte Chemie, Vol. 130, Issue 19
Anodic Hydrazine Oxidation Assists Energy-Efficient Hydrogen Evolution over a Bifunctional Cobalt Perselenide Nanosheet Electrode
journal, May 2018
- Zhang, Jun-Ye; Wang, Hongming; Tian, Yifan
- Angewandte Chemie, Vol. 130, Issue 26
Nanosized Metal Phosphides Embedded in Nitrogen-Doped Porous Carbon Nanofibers for Enhanced Hydrogen Evolution at All pH Values
journal, January 2018
- Wang, Min-Qiang; Ye, Cui; Liu, Heng
- Angewandte Chemie International Edition, Vol. 57, Issue 7
Perovskite materials in energy storage and conversion: Perovskite materials in energy storage and conversion
journal, May 2016
- Zhu, Liang; Ran, Ran; Tadé, Moses
- Asia-Pacific Journal of Chemical Engineering, Vol. 11, Issue 3
Chemical Doped Ternary and Quaternary Transition‐Metal‐Based Electrocatalysts for Hydrogen Evolution Reaction
journal, September 2019
- Li, Jiayuan; Zhang, Mingkai; Zang, Hang
- ChemCatChem, Vol. 11, Issue 20
Synthesis of Ni−MoS x /g‐C 3 N 4 for Photocatalytic Hydrogen Evolution under Visible Light
journal, December 2019
- Wang, Bo; Li, Xia; Wu, Haining
- ChemCatChem, Vol. 12, Issue 3
Towards Versatile and Sustainable Hydrogen Production through Electrocatalytic Water Splitting: Electrolyte Engineering
journal, March 2017
- Shinagawa, Tatsuya; Takanabe, Kazuhiro
- ChemSusChem, Vol. 10, Issue 7
Strongly Coupled Molybdenum Carbide on Carbon Sheets as a Bifunctional Electrocatalyst for Overall Water Splitting
journal, August 2017
- Wang, Hao; Cao, Yingjie; Sun, Cheng
- ChemSusChem, Vol. 10, Issue 18
Hydrogen Evolution Activity of Ruthenium Phosphides Encapsulated in Nitrogen- and Phosphorous-Codoped Hollow Carbon Nanospheres
journal, January 2018
- Chi, Jing-Qi; Gao, Wen-Kun; Lin, Jia-Hui
- ChemSusChem, Vol. 11, Issue 4
Efficient All‐2D Amorphous Cobalt Sulfide Nanosheets/Multilayered Molybdenum Disulfide Hybrid Heterojunction Catalyst for Electrochemical Hydrogen Evolution
journal, December 2019
- Li, Zhenbang; Liu, Pu; Yang, Guowei
- Global Challenges, Vol. 4, Issue 2
An Efficient Cobalt Phosphide Electrocatalyst Derived from Cobalt Phosphonate Complex for All‐pH Hydrogen Evolution Reaction and Overall Water Splitting in Alkaline Solution
journal, March 2019
- Wu, Jiadong; Wang, Depeng; Wan, Shuao
- Small, Vol. 16, Issue 15
Self‐Supportive Mesoporous Ni/Co/Fe Phosphosulfide Nanorods Derived from Novel Hydrothermal Electrodeposition as a Highly Efficient Electrocatalyst for Overall Water Splitting
journal, October 2019
- Yao, Mengqi; Hu, Haohui; Sun, Baolong
- Small, Vol. 15, Issue 50
A New Defect-Rich CoGa Layered Double Hydroxide as Efficient and Stable Oxygen Evolution Electrocatalyst
journal, September 2018
- Zhang, Jie; Dong, Chaoqun; Wang, Zhenbin
- Small Methods, Vol. 3, Issue 2
Polyoxometalate electrocatalysts based on earth-abundant metals for efficient water oxidation in acidic media
journal, October 2017
- Blasco-Ahicart, Marta; Soriano-López, Joaquín; Carbó, Jorge J.
- Nature Chemistry, Vol. 10, Issue 1
Promoting electrocatalytic CO2 reduction to formate via sulfur-boosting water activation on indium surfaces
journal, February 2019
- Ma, Wenchao; Xie, Shunji; Zhang, Xia-Guang
- Nature Communications, Vol. 10, Issue 1
Atomically engineering activation sites onto metallic 1T-MoS2 catalysts for enhanced electrochemical hydrogen evolution
journal, February 2019
- Huang, Yichao; Sun, Yuanhui; Zheng, Xueli
- Nature Communications, Vol. 10, Issue 1
Tuning orbital orientation endows molybdenum disulfide with exceptional alkaline hydrogen evolution capability
journal, March 2019
- Zang, Yipeng; Niu, Shuwen; Wu, Yishang
- Nature Communications, Vol. 10, Issue 1
Multi-site electrocatalysts for hydrogen evolution in neutral media by destabilization of water molecules
journal, December 2018
- Dinh, Cao-Thang; Jain, Ankit; de Arquer, F. Pelayo García
- Nature Energy, Vol. 4, Issue 2
Interlaced NiS 2 –MoS 2 nanoflake-nanowires as efficient hydrogen evolution electrocatalysts in basic solutions
journal, January 2016
- An, Tiance; Wang, Yang; Tang, Jing
- Journal of Materials Chemistry A, Vol. 4, Issue 35
Emerging two-dimensional nanomaterials for electrochemical hydrogen evolution
journal, January 2017
- Chen, Yunxu; Yang, Kena; Jiang, Bei
- Journal of Materials Chemistry A, Vol. 5, Issue 18
A 2D free-standing film-inspired electrocatalyst for highly efficient hydrogen production
journal, January 2017
- Gao, Jian; Cheng, Zhihua; Shao, Changxiang
- Journal of Materials Chemistry A, Vol. 5, Issue 24
Copper dopants improved the hydrogen evolution activity of earth-abundant cobalt pyrite catalysts by activating the electrocatalytically inert sulfur sites
journal, January 2017
- Zhang, Jingyan; Xiao, Baorui; Liu, Xiaoli
- Journal of Materials Chemistry A, Vol. 5, Issue 33
Hollow FeNi-based hybrid polyhedron derived from unique sulfur-modulating coordinated transition bimetal complexes for efficient oxygen evolution reactions
journal, January 2017
- Qiao, Hongyan; Yong, Jiaxi; Dai, Xiaoping
- J. Mater. Chem. A, Vol. 5, Issue 40
Non-covalent interactions in electrochemical reactions and implications in clean energy applications
journal, January 2018
- Huang, Botao; Muy, Sokseiha; Feng, Shuting
- Physical Chemistry Chemical Physics, Vol. 20, Issue 23
Recent advances in metal sulfides: from controlled fabrication to electrocatalytic, photocatalytic and photoelectrochemical water splitting and beyond
journal, January 2019
- Chandrasekaran, Sundaram; Yao, Lei; Deng, Libo
- Chemical Society Reviews, Vol. 48, Issue 15
Efficient alkaline hydrogen evolution electrocatalysis enabled by an amorphous Co–Mo–B film
journal, January 2018
- Sun, Zhaomei; Hao, Shuai; Ji, Xuqiang
- Dalton Transactions, Vol. 47, Issue 23
Enhancing the catalytic activity of the alkaline hydrogen evolution reaction by tuning the S/Se ratio in the Mo(S x Se 1−x ) 2 catalyst
journal, January 2018
- Bar-Ziv, Ronen; Meiron, Oren E.; Bar-Sadan, Maya
- Nanoscale, Vol. 10, Issue 34
Epitaxial growth of Ni(OH) 2 nanoclusters on MoS 2 nanosheets for enhanced alkaline hydrogen evolution reaction
journal, January 2018
- Zhao, Guoqiang; Lin, Yue; Rui, Kun
- Nanoscale, Vol. 10, Issue 40
Synthesis of dense MoS 2 nanosheet layers on hollow carbon spheres and their applications in supercapacitors and the electrochemical hydrogen evolution reaction
journal, January 2018
- Liu, Weiwei; Zhu, Menghua; Liu, Jinghua
- Inorganic Chemistry Frontiers, Vol. 5, Issue 9
Carbon nanotube-induced phase and stability engineering: a strained cobalt-doped WSe 2 /MWNT heterostructure for enhanced hydrogen evolution reaction
journal, January 2018
- Zhang, Guoyuan; Zheng, Xiaoli; Xu, Qun
- Journal of Materials Chemistry A, Vol. 6, Issue 11
A platinum oxide decorated amorphous cobalt oxide hydroxide nanosheet array towards alkaline hydrogen evolution
journal, January 2018
- Wang, Ziqiang; Ren, Xiang; Shi, Xifeng
- Journal of Materials Chemistry A, Vol. 6, Issue 9
Microwave-assisted synthesis of graphene-like cobalt sulfide freestanding sheets as an efficient bifunctional electrocatalyst for overall water splitting
journal, January 2018
- Souleymen, Rafai; Wang, Zhitao; Qiao, Chen
- Journal of Materials Chemistry A, Vol. 6, Issue 17
A metal-vacancy-solid-solution NiAlP nanowall array bifunctional electrocatalyst for exceptional all-pH overall water splitting
journal, January 2018
- Cheng, Weiren; Zhang, Hui; Zhao, Xu
- Journal of Materials Chemistry A, Vol. 6, Issue 20
A general synthetic approach for hexagonal phase tungsten nitride composites and their application in the hydrogen evolution reaction
journal, January 2018
- Jin, Haiyan; Zhang, Hao; Chen, Jiayi
- Journal of Materials Chemistry A, Vol. 6, Issue 23
Stepwise synthesis of CoS 2 –C@CoS 2 yolk–shell nanocages with much enhanced electrocatalytic performances both in solar cells and hydrogen evolution reactions
journal, January 2018
- Niu, Yudi; Qian, Xing; Zhang, Jie
- Journal of Materials Chemistry A, Vol. 6, Issue 25
Highly active and stable electrocatalyst of Ni 2 P nanoparticles supported on 3D ordered macro-/mesoporous Co–N-doped carbon for acidic hydrogen evolution reaction
journal, January 2018
- Sun, Tingting; Dong, Jing; Huang, Yan
- Journal of Materials Chemistry A, Vol. 6, Issue 26
Synthesis, stabilization and applications of 2-dimensional 1T metallic MoS 2
journal, January 2018
- Shi, Shangli; Sun, Zhuxing; Hu, Yun Hang
- Journal of Materials Chemistry A, Vol. 6, Issue 47
Tailoring the geometric and electronic structure of tungsten oxide with manganese or vanadium doping toward highly efficient electrochemical and photoelectrochemical water splitting
journal, January 2019
- Chandrasekaran, Sundaram; Zhang, Peixin; Peng, Feng
- Journal of Materials Chemistry A, Vol. 7, Issue 11
Interfacial engineering of Ru–S–Sb/antimonene electrocatalysts for highly efficient electrolytic hydrogen generation in neutral electrolyte
journal, January 2019
- Li, Yan; Chen, Junxiang; Huang, Junheng
- Chemical Communications, Vol. 55, Issue 73
Synthesis and characterisation of [Cu 4 In(PPh 3 ) 3 SePh(μ-SePh) 3 (μ 3 -SePh) 3 ], and its application as a precursor of a sensitizer for a photocatalyst
journal, January 2019
- Mello, Melina de Azevedo; Rodrigues, Jéssica Fonseca; Salgueiro Soares, Thiago André
- New Journal of Chemistry, Vol. 43, Issue 35
The preparation of Ni/Mo-based ternary electrocatalysts by the self-propagating initiated nitridation reaction and their application for efficient hydrogen production
journal, January 2019
- Hou, Mengjie; Lan, Ruyue; Hu, Zhibiao
- Nanoscale, Vol. 11, Issue 36
Strategy to boost catalytic activity of polymeric carbon nitride: synergistic effect of controllable in situ surface engineering and morphology
journal, January 2019
- Li, Yuan-Yuan; Si, Yuan; Zhou, Bing-Xin
- Nanoscale, Vol. 11, Issue 35
Electrochemical fabrication of FeS x films with high catalytic activity for oxygen evolution
journal, January 2019
- Wang, Wenbin; Xu, Ruidong; Yu, Bohao
- RSC Advances, Vol. 9, Issue 55
MoC based Mott–Schottky electrocatalyst for boosting the hydrogen evolution reaction performance
journal, January 2020
- Ji, Xinyang; Wang, Kaixuan; Zhang, Yao
- Sustainable Energy & Fuels, Vol. 4, Issue 1
Metal–organic framework-derived hierarchical MoS 2 /CoS 2 nanotube arrays as pH-universal electrocatalysts for efficient hydrogen evolution
journal, January 2019
- Tang, Baoshan; Yu, Zhi Gen; Zhang, Yaoxin
- Journal of Materials Chemistry A, Vol. 7, Issue 21
Ternary metal sulfides for electrocatalytic energy conversion
journal, January 2019
- Fu, Gengtao; Lee, Jong-Min
- Journal of Materials Chemistry A, Vol. 7, Issue 16
Designing Pd/O co-doped MoS x for boosting the hydrogen evolution reaction
journal, January 2019
- Zhan, Yingxin; Zhou, Xuemei; Nie, Huagui
- Journal of Materials Chemistry A, Vol. 7, Issue 26
Activating and optimizing the activity of NiCoP nanosheets for electrocatalytic alkaline water splitting through the V doping effect enhanced by P vacancies
journal, January 2019
- Yan, Yaotian; Lin, Jinghuang; Cao, Jian
- Journal of Materials Chemistry A, Vol. 7, Issue 42
Carbon nanofibers@NiSe core/sheath nanostructures as efficient electrocatalysts for integrating highly selective methanol conversion and less-energy intensive hydrogen production
journal, January 2019
- Zhao, Bin; Liu, Jian-Wen; Yin, Ya-Ru
- Journal of Materials Chemistry A, Vol. 7, Issue 45
Enhanced hydrogen evolution reaction on hybrids of cobalt phosphide and molybdenum phosphide
journal, March 2017
- Fang, Si-Ling; Chou, Tsu-Chin; Samireddi, Satyanarayana
- Royal Society Open Science, Vol. 4, Issue 3
Porous Mn-Doped CoP 3 Nanowires as a Janus Electrocatalyst for Efficient Overall Water Splitting in Alkaline Solution
journal, January 2018
- Feng, Jiajia; Wang, Xiaodeng; Zhang, Dingke
- Journal of The Electrochemical Society, Vol. 165, Issue 16
Effect of gold underlayer on copper(I) oxide photocathode performance
journal, April 2017
- Lan, Tian; Mundt, Colton; Tran, Minh
- Journal of Materials Research, Vol. 32, Issue 9
Engineering Pyrite-Type Bimetallic Ni-Doped CoS2 Nanoneedle Arrays over a Wide Compositional Range for Enhanced Oxygen and Hydrogen Electrocatalysis with Flexible Property
journal, November 2017
- He, Guowei; Zhang, Wei; Deng, Yida
- Catalysts, Vol. 7, Issue 12
Modified Electrodeposited Cobalt Foam Coatings as Sensors for Detection of Free Chlorine in Water
journal, May 2019
- Vainoris, Modestas; Tsyntsaru, Natalia; Cesiulis, Henrikas
- Coatings, Vol. 9, Issue 5
Self-Supported Ni(P, O)x·MoOx Nanowire Array on Nickel Foam as an Efficient and Durable Electrocatalyst for Alkaline Hydrogen Evolution
journal, December 2017
- Hua, Wei; Liu, Huanyan; Wang, Jian-Gan
- Nanomaterials, Vol. 7, Issue 12
Effect of Ni Doping on the MoS2 Structure and Its Hydrogen Evolution Activity in Acid and Alkaline Electrolytes
journal, December 2019
- Mosconi, Dario; Till, Paul; Calvillo, Laura
- Surfaces, Vol. 2, Issue 4
Size Effects of Platinum Nanoparticles in the Photocatalytic Hydrogen Production Over 3D Mesoporous Networks of CdS and Pt Nanojunctions
journal, September 2016
- Vamvasakis, Ioannis; Liu, Bin; Armatas, Gerasimos S.
- Advanced Functional Materials, Vol. 26, Issue 44
Room-Temperature Electrochemical Conversion of Metal-Organic Frameworks into Porous Amorphous Metal Sulfides with Tailored Composition and Hydrogen Evolution Activity
journal, February 2018
- He, Wenhui; Ifraemov, Raya; Raslin, Arik
- Advanced Functional Materials, Vol. 28, Issue 18
Covalent Phenanthroline Framework Derived FeS@Fe 3 C Composite Nanoparticles Embedding in N-S-Codoped Carbons as Highly Efficient Trifunctional Electrocatalysts
journal, October 2018
- Kong, Fantao; Fan, Xiaohong; Kong, Aiguo
- Advanced Functional Materials, Vol. 28, Issue 51
Phase-Transformation Engineering in Cobalt Diselenide Realizing Enhanced Catalytic Activity for Hydrogen Evolution in an Alkaline Medium
journal, June 2016
- Chen, Pengzuo; Xu, Kun; Tao, Shi
- Advanced Materials, Vol. 28, Issue 34
Coupling Sub-Nanometric Copper Clusters with Quasi-Amorphous Cobalt Sulfide Yields Efficient and Robust Electrocatalysts for Water Splitting Reaction
journal, January 2017
- Liu, Yipu; Li, Qiuju; Si, Rui
- Advanced Materials, Vol. 29, Issue 13
Water-Plasma-Enabled Exfoliation of Ultrathin Layered Double Hydroxide Nanosheets with Multivacancies for Water Oxidation
journal, June 2017
- Liu, Rong; Wang, Yanyong; Liu, Dongdong
- Advanced Materials, Vol. 29, Issue 30
Accelerated Hydrogen Evolution Kinetics on NiFe-Layered Double Hydroxide Electrocatalysts by Tailoring Water Dissociation Active Sites
journal, January 2018
- Chen, Guangbo; Wang, Tao; Zhang, Jian
- Advanced Materials, Vol. 30, Issue 10
Morphology‐Controlled Metal Sulfides and Phosphides for Electrochemical Water Splitting
journal, February 2019
- Joo, Jinwhan; Kim, Taekyung; Lee, Jaeyoung
- Advanced Materials, Vol. 31, Issue 14
Superb Alkaline Hydrogen Evolution and Simultaneous Electricity Generation by Pt-Decorated Ni 3 N Nanosheets
journal, September 2016
- Wang, Yuhang; Chen, Long; Yu, Xiaomin
- Advanced Energy Materials, Vol. 7, Issue 2
Doped-MoSe 2 Nanoflakes/3d Metal Oxide-Hydr(Oxy)Oxides Hybrid Catalysts for pH-Universal Electrochemical Hydrogen Evolution Reaction
journal, August 2018
- Najafi, Leyla; Bellani, Sebastiano; Oropesa-Nuñez, Reinier
- Advanced Energy Materials, Vol. 8, Issue 27
Atomically Dispersed Mo Supported on Metallic Co 9 S 8 Nanoflakes as an Advanced Noble‐Metal‐Free Bifunctional Water Splitting Catalyst Working in Universal pH Conditions
journal, December 2019
- Wang, Ligang; Duan, Xinxuan; Liu, Xijun
- Advanced Energy Materials, Vol. 10, Issue 4
Layered Double Hydroxide Nanosheets with Multiple Vacancies Obtained by Dry Exfoliation as Highly Efficient Oxygen Evolution Electrocatalysts
journal, April 2017
- Wang, Yanyong; Zhang, Yiqiong; Liu, Zhijuan
- Angewandte Chemie International Edition, Vol. 56, Issue 21
Highly Tunable Heterojunctions from Multimetallic Sulfide Nanoparticles and Silver Nanowires
journal, April 2018
- Liu, Dongliang; Liu, Yong; Huang, Peng
- Angewandte Chemie International Edition, Vol. 57, Issue 19
Exploring Active Sites in Multi-Heteroatom-Doped Co-Based Catalysts for Hydrogen Evolution Reactions
journal, July 2018
- Shahraei, Ali; Martinaiou, Ioanna; Creutz, K. Alexander
- Chemistry - A European Journal, Vol. 24, Issue 48
Earth‐Abundant Transition‐Metal‐Based Electrocatalysts for Water Electrolysis to Produce Renewable Hydrogen
journal, June 2018
- Li, Ailong; Sun, Yimeng; Yao, Tingting
- Chemistry – A European Journal, Vol. 24, Issue 69
Porous Core–Shell CuCo 2 S 4 Nanospheres as Anode Material for Enhanced Lithium‐Ion Batteries
journal, December 2018
- Zheng, Tian; Li, Guangda; Meng, Xiangeng
- Chemistry – A European Journal, Vol. 25, Issue 3
Facile and Large‐Scale Fabrication of Sub‐3 nm PtNi Nanoparticles Supported on Porous Carbon Sheet: A Bifunctional Material for the Hydrogen Evolution Reaction and Hydrogenation
journal, May 2019
- Li, Jifan; Liu, Lei; Ai, Yongjian
- Chemistry – A European Journal, Vol. 25, Issue 29
Boosting Alkaline Hydrogen Evolution Activity with Ni‐Doped MoS 2 /Reduced Graphene Oxide Hybrid Aerogel
journal, December 2018
- Lin, Chong; Gao, Zhengfei; Jin, Jian
- ChemSusChem
Edge-Terminated MoS 2 Nanoassembled Electrocatalyst via In Situ Hybridization with 3D Carbon Network
journal, August 2018
- Chung, Dong Young; Yoo, Ji Mun; Park, Subin
- Small, Vol. 14, Issue 36
Cation‐Modulated HER and OER Activities of Hierarchical VOOH Hollow Architectures for High‐Efficiency and Stable Overall Water Splitting
journal, September 2019
- Zhang, Jian; Cui, Renjie; Gao, Chencheng
- Small, Vol. 15, Issue 47
Synthesis of amorphous MoSx and MoSx/carbon nanotubes composite aerogels as effective hydrogen evolution reaction catalysts
journal, September 2018
- Gao, Qiuyue; Jin, Yani; Jin, Yiming
- Journal of Sol-Gel Science and Technology, Vol. 88, Issue 1
Defective MoS2 electrocatalyst for highly efficient hydrogen evolution through a simple ball-milling method
journal, September 2017
- Zhang, Li-Fang; Ke, Xiaoxing; Ou, Gang
- Science China Materials, Vol. 60, Issue 9
Energy and fuels from electrochemical interfaces
journal, December 2016
- Stamenkovic, Vojislav R.; Strmcnik, Dusan; Lopes, Pietro P.
- Nature Materials, Vol. 16, Issue 1
Balancing activity, stability and conductivity of nanoporous core-shell iridium/iridium oxide oxygen evolution catalysts
journal, November 2017
- Kim, Yong-Tae; Lopes, Pietro Papa; Park, Shin-Ae
- Nature Communications, Vol. 8, Issue 1
Electron density modulation of NiCo2S4 nanowires by nitrogen incorporation for highly efficient hydrogen evolution catalysis
journal, April 2018
- Wu, Yishang; Liu, Xiaojing; Han, Dongdong
- Nature Communications, Vol. 9, Issue 1
Dual-template engineering of triple-layered nanoarray electrode of metal chalcogenides sandwiched with hydrogen-substituted graphdiyne
journal, August 2018
- Zhuo, Sifei; Shi, Yusuf; Liu, Lingmei
- Nature Communications, Vol. 9, Issue 1
Single platinum atoms embedded in nanoporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction
journal, April 2019
- Jiang, Kang; Liu, Boyang; Luo, Min
- Nature Communications, Vol. 10, Issue 1
Interface engineering of a CeO 2 –Cu 3 P nanoarray for efficient alkaline hydrogen evolution
journal, January 2018
- Wang, Zao; Du, Huitong; Liu, Zhiang
- Nanoscale, Vol. 10, Issue 5
Tuning electrochemical catalytic activity of defective 2D terrace MoSe 2 heterogeneous catalyst via cobalt doping
journal, January 2017
- Chen, Xiaoshuang; Qiu, Yunfeng; Liu, Guangbo
- Journal of Materials Chemistry A, Vol. 5, Issue 22
Boosting electrochemical water splitting via ternary NiMoCo hybrid nanowire arrays
journal, January 2019
- Hu, Kailong; Wu, Mingxing; Hinokuma, Satoshi
- Journal of Materials Chemistry A, Vol. 7, Issue 5
Nitrogen and phosphorous co-doped graphitic carbon encapsulated ultrafine OsP 2 nanoparticles: a pH universal highly durable catalyst for hydrogen evolution reaction
journal, January 2019
- Chakrabartty, Sukanta; Barman, Barun Kumar; Retna Raj, C.
- Chemical Communications, Vol. 55, Issue 30
The construction of self-supported thorny leaf-like nickel-cobalt bimetal phosphides as efficient bifunctional electrocatalysts for urea electrolysis
journal, January 2019
- Sha, Linna; Yin, Jinling; Ye, Ke
- Journal of Materials Chemistry A, Vol. 7, Issue 15
A CoMoO 4 –Co 2 Mo 3 O 8 heterostructure with valence-rich molybdenum for a high-performance hydrogen evolution reaction in alkaline solution
journal, January 2019
- Liu, Zheng; Zhan, Changhong; Peng, Linkai
- Journal of Materials Chemistry A, Vol. 7, Issue 28
A universal synthesis strategy to make metal nitride electrocatalysts for hydrogen evolution reaction
journal, January 2019
- Yu, Luo; Song, Shaowei; McElhenny, Brian
- Journal of Materials Chemistry A, Vol. 7, Issue 34
Niobium disulphide (NbS 2 )-based (heterogeneous) electrocatalysts for an efficient hydrogen evolution reaction
journal, January 2019
- Najafi, Leyla; Bellani, Sebastiano; Oropesa-Nuñez, Reinier
- Journal of Materials Chemistry A, Vol. 7, Issue 44
Nickel nanograins anchored on a carbon framework for an efficient hydrogen evolution electrocatalyst and a flexible electrode
journal, January 2020
- Zhang, Zhiwei; Deng, Linjie; Zhao, Zhe
- Journal of Materials Chemistry A, Vol. 8, Issue 6
Evaluating Hydrogen Evolution and Oxidation in Alkaline Media to Establish Baselines
journal, January 2018
- Alia, Shaun M.; Pivovar, Bryan S.
- Journal of The Electrochemical Society, Vol. 165, Issue 7
Metal-Organic Frameworks Derived Nanotube of Nickel-Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting
journal, August 2017
- Yan, Liting; Cao, Lei; Dai, Pengcheng
- Advanced Functional Materials, Vol. 27, Issue 40
Ultrathin Transition Metal Dichalcogenide/3d Metal Hydroxide Hybridized Nanosheets to Enhance Hydrogen Evolution Activity
journal, May 2018
- Zhu, Zhengju; Yin, Huajie; He, Chun-Ting
- Advanced Materials, Vol. 30, Issue 28
Defect‐Rich Heterogeneous MoS 2 /NiS 2 Nanosheets Electrocatalysts for Efficient Overall Water Splitting
journal, May 2019
- Lin, Jinghuang; Wang, Pengcheng; Wang, Haohan
- Advanced Science, Vol. 6, Issue 14
RuP 2 -Based Catalysts with Platinum-like Activity and Higher Durability for the Hydrogen Evolution Reaction at All pH Values
journal, August 2017
- Pu, Zonghua; Amiinu, Ibrahim Saana; Kou, Zongkui
- Angewandte Chemie, Vol. 129, Issue 38
RuP 2 -Based Catalysts with Platinum-like Activity and Higher Durability for the Hydrogen Evolution Reaction at All pH Values
journal, August 2017
- Pu, Zonghua; Amiinu, Ibrahim Saana; Kou, Zongkui
- Angewandte Chemie International Edition, Vol. 56, Issue 38
Anodic Hydrazine Oxidation Assists Energy-Efficient Hydrogen Evolution over a Bifunctional Cobalt Perselenide Nanosheet Electrode
journal, May 2018
- Zhang, Jun-Ye; Wang, Hongming; Tian, Yifan
- Angewandte Chemie International Edition, Vol. 57, Issue 26
Strongly Coupled Molybdenum Carbide on Carbon Sheets as a Bifunctional Electrocatalyst for Overall Water Splitting
journal, September 2017
- Wang, Hao; Cao, Yingjie; Sun, Cheng
- ChemSusChem, Vol. 10, Issue 18
Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics
journal, May 2017
- Zhang, Jian; Wang, Tao; Liu, Pan
- Nature Communications, Vol. 8, Issue 1
Morphology and surface chemistry engineering toward pH-universal catalysts for hydrogen evolution at high current density
journal, January 2019
- Luo, Yuting; Tang, Lei; Khan, Usman
- Nature Communications, Vol. 10, Issue 1
Ruthenium atomically dispersed in carbon outperforms platinum toward hydrogen evolution in alkaline media
journal, February 2019
- Lu, Bingzhang; Guo, Lin; Wu, Feng
- Nature Communications, Vol. 10, Issue 1
Single-atom cobalt array bound to distorted 1T MoS2 with ensemble effect for hydrogen evolution catalysis
journal, November 2019
- Qi, Kun; Cui, Xiaoqiang; Gu, Lin
- Nature Communications, Vol. 10, Issue 1
Efficient electrocatalytic hydrogen gas evolution by a cobalt–porphyrin-based crystalline polymer
journal, January 2018
- Wu, Yanyu; Veleta, José M.; Tang, Diya
- Dalton Transactions, Vol. 47, Issue 26
Rational Design of Nanoarray Architectures for Electrocatalytic Water Splitting
journal, January 2019
- Hou, Jungang; Wu, Yunzhen; Zhang, Bo
- Advanced Functional Materials, Vol. 29, Issue 20
Secondary‐Component Incorporated Hollow MOFs and Derivatives for Catalytic and Energy‐Related Applications
journal, July 2018
- Yang, Haozhou; Wang, Xun
- Advanced Materials, Vol. 31, Issue 38
Ruthenium‐Based Single‐Atom Alloy with High Electrocatalytic Activity for Hydrogen Evolution
journal, April 2019
- Chen, Cui‐Hong; Wu, Deyao; Li, Zhe
- Advanced Energy Materials, Vol. 9, Issue 20
The Hydrogen Evolution Reaction in Alkaline Solution: From Theory, Single Crystal Models, to Practical Electrocatalysts
journal, May 2018
- Zheng, Yao; Jiao, Yan; Vasileff, Anthony
- Angewandte Chemie International Edition, Vol. 57, Issue 26
An Engineered Superhydrophilic/Superaerophobic Electrocatalyst Composed of the Supported CoMoS x Chalcogel for Overall Water Splitting
journal, January 2020
- Shan, Xinyao; Liu, Jian; Mu, Haoran
- Angewandte Chemie International Edition, Vol. 59, Issue 4
Recent Advances in Carbon-Based Bifunctional Oxygen Electrocatalysts for Zn−Air Batteries
journal, May 2018
- Fu, Gengtao; Tang, Yawen; Lee, Jong-Min
- ChemElectroChem, Vol. 5, Issue 11
Microstructural Engineering of Heterogeneous P−S−Co Interface for Oxygen and Hydrogen Evolution
journal, July 2019
- Yu, Xiaoguang; Li, Na; Wang, Wenquan
- ChemElectroChem, Vol. 6, Issue 14
Enhancement of visible-light-driven photocatalytic performance of BiOBr nanosheets by Co2+ doping
journal, July 2019
- Huang, Wenmao; Hua, Xin; Zhao, Yaping
- Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 16
Interfacing nickel nitride and nickel boosts both electrocatalytic hydrogen evolution and oxidation reactions
journal, October 2018
- Song, Fuzhan; Li, Wei; Yang, Jiaqi
- Nature Communications, Vol. 9, Issue 1
Co‐Modified MoS 2 Hybrids as Superior Bifunctional Electrocatalysts for Water Splitting Reactions: Integrating Multiple Active Components in One
journal, April 2019
- Zhao, Zhong‐Yin; Li, Fei‐Long; Shao, Qi
- Advanced Materials Interfaces
Nanosized Metal Phosphides Embedded in Nitrogen-Doped Porous Carbon Nanofibers for Enhanced Hydrogen Evolution at All pH Values
journal, January 2018
- Wang, Min-Qiang; Ye, Cui; Liu, Heng
- Angewandte Chemie, Vol. 130, Issue 7
Nickel Nanocrystal Assemblies as Efficient Electrocatalysts for Hydrogen Evolution from pH‐Neutral Aqueous Solution
journal, March 2019
- Abdullah, Muhammad Imran; Hameed, Asima; Zhang, Ning
- ChemElectroChem, Vol. 6, Issue 7
CoSe 2 /MoSe 2 Heterostructures with Enriched Water Adsorption/Dissociation Sites towards Enhanced Alkaline Hydrogen Evolution Reaction
journal, June 2018
- Zhao, Guoqiang; Li, Peng; Rui, Kun
- Chemistry - A European Journal, Vol. 24, Issue 43
Dinitrosyl iron complexes: From molecular electrocatalysts to electrodeposited‐film electrodes for hydrogen evolution reaction
journal, May 2019
- Lu, Shan; Chiang, Jin‐Cheng; Chiou, Tzung‐Wen
- Journal of the Chinese Chemical Society, Vol. 66, Issue 9
Reduced graphene oxide-supported CoP nanocrystals confined in porous nitrogen-doped carbon nanowire for highly enhanced lithium/sodium storage and hydrogen evolution reaction
journal, October 2019
- Zhao, Xiaojun; Luo, Dan; Wang, Yan
- Nano Research, Vol. 12, Issue 11
A Ni(OH) 2 –CoS 2 hybrid nanowire array: a superior non-noble-metal catalyst toward the hydrogen evolution reaction in alkaline media
journal, January 2017
- Chen, Lanlan; Zhang, Jiayu; Ren, Xiang
- Nanoscale, Vol. 9, Issue 43
Salt-templated synthesis of defect-rich MoN nanosheets for boosted hydrogen evolution reaction
journal, January 2017
- Xiong, Jie; Cai, Weiwei; Shi, Weijia
- Journal of Materials Chemistry A, Vol. 5, Issue 46
Metal–organic framework-derived integrated nanoarrays for overall water splitting
journal, January 2018
- Guan, Cao; Wu, Haijun; Ren, Weina
- Journal of Materials Chemistry A, Vol. 6, Issue 19
Construction of hierarchical yolk–shell nanospheres organized by ultrafine Janus subunits for efficient overall water splitting
journal, January 2020
- Zhang, Qi; Liu, Bingqiu; Ji, Yue
- Nanoscale, Vol. 12, Issue 4
Metal-Organic Precursor-Derived Mesoporous Carbon Spheres with Homogeneously Distributed Molybdenum Carbide/Nitride Nanoparticles for Efficient Hydrogen Evolution in Alkaline Media
journal, November 2018
- Li, Shuang; Cheng, Chong; Sagaltchik, Anton
- Advanced Functional Materials, Vol. 29, Issue 3
Support and Interface Effects in Water‐Splitting Electrocatalysts
journal, December 2018
- Zhang, Jian; Zhang, Qiuyu; Feng, Xinliang
- Advanced Materials, Vol. 31, Issue 31
High Activity Hydrogen Evolution Catalysis by Uniquely Designed Amorphous/Metal Interface of Core-shell Phosphosulfide/N-Doped CNTs
journal, January 2018
- Li, Dong Jun; Kang, Joonhee; Lee, Ho Jin
- Advanced Energy Materials, Vol. 8, Issue 13
Engineered MoSe 2 -Based Heterostructures for Efficient Electrochemical Hydrogen Evolution Reaction
journal, February 2018
- Najafi, Leyla; Bellani, Sebastiano; Oropesa-Nuñez, Reinier
- Advanced Energy Materials, Vol. 8, Issue 16
An Engineered Superhydrophilic/Superaerophobic Electrocatalyst Composed of the Supported CoMoS x Chalcogel for Overall Water Splitting
journal, December 2019
- Shan, Xinyao; Liu, Jian; Mu, Haoran
- Angewandte Chemie, Vol. 132, Issue 4
Stable Active Sites on Ni 12 P 5 Surfaces for the Hydrogen Evolution Reaction
journal, May 2019
- Hu, Jun; Chen, Wei; Zhao, Xin
- Energy Technology, Vol. 7, Issue 6
SnS 2 Nanosheets Coating on Nanohollow Cubic CoS 2 /C for Ultralong Life and High Rate Capability Half/Full Sodium-Ion Batteries
journal, August 2018
- Shi, Ludi; Li, Dongzhi; Yao, Pingping
- Small, Vol. 14, Issue 41
Facile synthesis of hierarchical porous manganese nickel cobalt sulfide nanotube arrays with enhanced electrochemical performance for ultrahigh energy density fiber-shaped asymmetric supercapacitors
journal, January 2018
- Wang, Xiaona; Zhang, Qichong; Sun, Juan
- Journal of Materials Chemistry A, Vol. 6, Issue 17
An organic ligand promoting the electrocatalytic activity of cobalt oxide for the hydrogen evolution reaction
journal, January 2019
- Chen, Chien-Hong; Chiou, Tzung-Wen; Chang, Han-Chun
- Sustainable Energy & Fuels, Vol. 3, Issue 9