Title: Dimensional isotropy of 6H and 3C SiC under neutron irradiation

Abstract

This investigation experimentally determines the as-irradiated crystal axes dimensional change of the common polytypes of SiC considered for nuclear application. Single crystal α-SiC (6H), β-SiC (3C), CVD β-SiC, and single crystal Si have been neutron irradiated near 60 °C from 2 × 10²³ to 2 × 10²⁶ n/m² (E > 0.1 MeV), or about 0.02–20 dpa, in order to study the effect of irradiation on bulk swelling and strain along independent crystalline axes. Single crystal, powder diffractometry and density measurement have been carried out. For all neutron doses where the samples remained crystalline all SiC materials demonstrated equivalent swelling behavior. Moreover the 6H–SiC expanded isotropically. The magnitude of the swelling followed a ~0.77 power law against dose consistent with a microstructure evolution driven by single interstitial (carbon) mobility. Extraordinarily large ~7.8% volume expansion in SiC was observed prior to amorphization. Above ~0.9 × 10²⁵ n/m² (E > 0.1 MeV) all SiC materials became amorphous with an identical swelling: a 11.7% volume expansion, lowering the density to 2.84 g/cm³. As a result, the as-amorphized density was the same at the 2 × 10²⁵ and 2 × 10²⁶ n/m² (E > 0.1 MeV) dose levels.

Authors:

Snead, Lance L. ^[1]; Katoh, Yutai ^[2]; Koyanagi, Takaaki ^[2]; Terrani, Kurt A. ^[2]; Specht, Eliot D. ^[2]

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+ Show Author Affiliations

1. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:

Sat Jan 16 00:00:00 EST 2016

Research Org.:

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:

USDOE Office of Nuclear Energy (NE), Nuclear Fuel Cycle and Supply Chain; USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:

1235847

Alternate Identifier(s):

OSTI ID: 1359403

Grant/Contract Number:  

AC05-00OR22725; 4000140949

Resource Type:

Accepted Manuscript

Journal Name:

Journal of Nuclear Materials

Additional Journal Information:

Journal Volume: 471; Journal Issue: C; Journal ID: ISSN 0022-3115

Publisher:

Elsevier

Country of Publication:

United States

Language:

English

Subject:

36 MATERIALS SCIENCE