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Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes
Abstract
Abstract Ni‐rich layered oxides are the most promising cathodes for Li‐ion batteries, but chemo‐mechanical failures during cycling and large first‐cycle capacity loss hinder their applications in high‐energy batteries. Herein, by introducing spinel‐like mortise‐tenon structures into the layered phase of LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811), the adverse volume variations in cathode materials can be significantly suppressed. Meanwhile, these mortise‐tenon structures play the role of the expressway for fast lithium‐ion transport, which is substantiated by experiments and calculations. Moreover, the particles with mortise‐tenon structures usually terminate with the most stable (003) facet. The new cathode exhibits a discharge capacity of 215 mAh g −1 at 0.1 C with an initial Coulombic efficiency of 97.5%, and capacity retention of 82.2% after 1200 cycles at 1 C. This work offers a viable lattice engineering to address the stability and low initial Coulombic efficiency of the Ni‐rich layered oxides, and facilitates the implementation of Li‐ion batteries with high‐energy density and long durability.
- Authors:
-
[5];
[5];
[2]
- Peking Univ., Beijing (China); National Center for Nanoscience and Technology, Beijing (China). CAS Key Laboratory for Nanophotonic Materials and Devices
- Peking Univ., Beijing (China)
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- National Center for Nanoscience and Technology, Beijing (China). CAS Key Laboratory for Nanophotonic Materials and Devices
- Wuhan Univ. (China)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 2217540
- Alternate Identifier(s):
- OSTI ID: 1994587
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 35; Journal Issue: 32; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Ni-rich layered cathode; volume variations; mortise-tenon structure; fast lithiumion transport; initial Coulombic efficiency
Citation Formats
Tan, Xinghua, Chen, Zhefeng, Liu, Tongchao, Zhang, Yongxin, Zhang, Mingjian, Li, Shunning, Chu, Weiguo, Liu, Kang, Yang, Peihua, and Pan, Feng. Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes. United States: N. p., 2023.
Web. doi:10.1002/adma.202301096.
Tan, Xinghua, Chen, Zhefeng, Liu, Tongchao, Zhang, Yongxin, Zhang, Mingjian, Li, Shunning, Chu, Weiguo, Liu, Kang, Yang, Peihua, & Pan, Feng. Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes. United States. https://doi.org/10.1002/adma.202301096
Tan, Xinghua, Chen, Zhefeng, Liu, Tongchao, Zhang, Yongxin, Zhang, Mingjian, Li, Shunning, Chu, Weiguo, Liu, Kang, Yang, Peihua, and Pan, Feng. Fri .
"Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes". United States. https://doi.org/10.1002/adma.202301096.
@article{osti_2217540,
title = {Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes},
author = {Tan, Xinghua and Chen, Zhefeng and Liu, Tongchao and Zhang, Yongxin and Zhang, Mingjian and Li, Shunning and Chu, Weiguo and Liu, Kang and Yang, Peihua and Pan, Feng},
abstractNote = {Abstract Ni‐rich layered oxides are the most promising cathodes for Li‐ion batteries, but chemo‐mechanical failures during cycling and large first‐cycle capacity loss hinder their applications in high‐energy batteries. Herein, by introducing spinel‐like mortise‐tenon structures into the layered phase of LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811), the adverse volume variations in cathode materials can be significantly suppressed. Meanwhile, these mortise‐tenon structures play the role of the expressway for fast lithium‐ion transport, which is substantiated by experiments and calculations. Moreover, the particles with mortise‐tenon structures usually terminate with the most stable (003) facet. The new cathode exhibits a discharge capacity of 215 mAh g −1 at 0.1 C with an initial Coulombic efficiency of 97.5%, and capacity retention of 82.2% after 1200 cycles at 1 C. This work offers a viable lattice engineering to address the stability and low initial Coulombic efficiency of the Ni‐rich layered oxides, and facilitates the implementation of Li‐ion batteries with high‐energy density and long durability.},
doi = {10.1002/adma.202301096},
journal = {Advanced Materials},
number = 32,
volume = 35,
place = {United States},
year = {Fri Jun 30 00:00:00 EDT 2023},
month = {Fri Jun 30 00:00:00 EDT 2023}
}
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