Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices
Abstract
This Letter describes strong coupling between a plasmonic nanoparticle (NP) lattice cavity and Soret excitons in a metal–organic framework (MOF) film. In optical transmission measurements, we observed a lower polariton mode that can be spectrally tuned by infiltrating MOF pores with solvents of different refractive index. Using transient absorption spectroscopy, both the lower and upper polariton modes can be resolved, with an estimated Rabi splitting of ~300 meV, nearly twice that of other plasmonic cavity–organic emitter systems. The polariton modes decay more rapidly than that of the uncoupled exciton. Furthermore, this hybrid system highlights the advantages of open plasmonic cavities for tunable coupling and the use of transient absorption spectroscopy to identify polariton modes.
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[2];
[1];
[1]
- Northwestern University, Evanston, IL (United States)
- Northwestern University, Evanston, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Northwestern Univ., Evanston, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 2001268
- Grant/Contract Number:
- SC0004752; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 126; Journal Issue: 44; Related Information: https://pubs.acs.org/doi/10.1021/acs.jpcc.2c05464.; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; Excitons; Lattices; Metal organic frameworks; Polaritons; Quantum mechanics
Citation Formats
Sample, Alexander D., Guan, Jun, Hu, Jingtian, Freire-Fernández, Francisco, Park, Sang-Min, Schaller, Richard D., Schatz, George C., and Odom, Teri W. Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices. United States: N. p., 2022.
Web. doi:10.1021/acs.jpcc.2c05464.
Sample, Alexander D., Guan, Jun, Hu, Jingtian, Freire-Fernández, Francisco, Park, Sang-Min, Schaller, Richard D., Schatz, George C., & Odom, Teri W. Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices. United States. https://doi.org/10.1021/acs.jpcc.2c05464
Sample, Alexander D., Guan, Jun, Hu, Jingtian, Freire-Fernández, Francisco, Park, Sang-Min, Schaller, Richard D., Schatz, George C., and Odom, Teri W. Fri .
"Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices". United States. https://doi.org/10.1021/acs.jpcc.2c05464. https://www.osti.gov/servlets/purl/2001268.
@article{osti_2001268,
title = {Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices},
author = {Sample, Alexander D. and Guan, Jun and Hu, Jingtian and Freire-Fernández, Francisco and Park, Sang-Min and Schaller, Richard D. and Schatz, George C. and Odom, Teri W.},
abstractNote = {This Letter describes strong coupling between a plasmonic nanoparticle (NP) lattice cavity and Soret excitons in a metal–organic framework (MOF) film. In optical transmission measurements, we observed a lower polariton mode that can be spectrally tuned by infiltrating MOF pores with solvents of different refractive index. Using transient absorption spectroscopy, both the lower and upper polariton modes can be resolved, with an estimated Rabi splitting of ~300 meV, nearly twice that of other plasmonic cavity–organic emitter systems. The polariton modes decay more rapidly than that of the uncoupled exciton. Furthermore, this hybrid system highlights the advantages of open plasmonic cavities for tunable coupling and the use of transient absorption spectroscopy to identify polariton modes.},
doi = {10.1021/acs.jpcc.2c05464},
journal = {Journal of Physical Chemistry. C},
number = 44,
volume = 126,
place = {United States},
year = {Fri Oct 28 00:00:00 EDT 2022},
month = {Fri Oct 28 00:00:00 EDT 2022}
}
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