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In Situ Ion‐Exchange Metathesis Induced Conformal LiF Surface Films on Cathode (NMC811) as a Cathode Electrolyte Interphase
Abstract
Abstract High‐capacity cathodes (LiNi 0.8 Mn 0.1 Co 0.1 O 2 , NMC811) are promising for vehicle electrification because of their high gravimetric energy density. However, their electrochemical performance still relies upon the stability of the cathode electrolyte interphase (CEI). A highly reactive cathode interface leads to parasitic side reactions with electrolytes, resulting in accelerated capacity fading. Well‐developed LiF and LiF‐like inorganic compounds are believed to be good CEI components for stabilizing such reactive electrode interfaces. However, it is challenging to form an optimal surface sub‐nanolayer of LiF on the cathode surfaces because of the complexity of the electrochemical reaction during battery cycling. Herein, the formation of a conformal LiF layer on the NMC811 electrode surface via an in situ ion‐exchange metathesis process is reported, demonstrating a promising electrochemical performance because of a LiF‐stabilized CEI. In situ generated LiF‐coated NMC811 electrodes exhibit ≈97% capacity retention up to 100 cycles at a 0.3 C rate with average coulombic efficiency of ≈99.9% and ≈80% capacity retention up to 200 cycles at a 1 C rate with average coulombic efficiency of >99.6%. This finding may pave the way for reengineering the CEI to enhance the electrochemical performances and cycling stability of the high‐capacitymore »
- Authors:
-
[1];
[1];
[2];
[1];
[1];
[1];
[1];
[3]
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1997741
- Alternate Identifier(s):
- OSTI ID: 1988693
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 33; Journal Issue: 44; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; conformal LiF; high energy density batteries; high-capacity cathodes; in situ ion-exchange metathesis; NMC811
Citation Formats
Thapaliya, Bishnu P., Wang, Tao, Borisevich, Albina Y., Meyer, Harry M., Sun, Xiao‐Guang, Paranthaman, Mariappan Parans, Bridges, Craig A., and Dai, Sheng. In Situ Ion‐Exchange Metathesis Induced Conformal LiF Surface Films on Cathode (NMC811) as a Cathode Electrolyte Interphase. United States: N. p., 2023.
Web. doi:10.1002/adfm.202302443.
Thapaliya, Bishnu P., Wang, Tao, Borisevich, Albina Y., Meyer, Harry M., Sun, Xiao‐Guang, Paranthaman, Mariappan Parans, Bridges, Craig A., & Dai, Sheng. In Situ Ion‐Exchange Metathesis Induced Conformal LiF Surface Films on Cathode (NMC811) as a Cathode Electrolyte Interphase. United States. https://doi.org/10.1002/adfm.202302443
Thapaliya, Bishnu P., Wang, Tao, Borisevich, Albina Y., Meyer, Harry M., Sun, Xiao‐Guang, Paranthaman, Mariappan Parans, Bridges, Craig A., and Dai, Sheng. Sat .
"In Situ Ion‐Exchange Metathesis Induced Conformal LiF Surface Films on Cathode (NMC811) as a Cathode Electrolyte Interphase". United States. https://doi.org/10.1002/adfm.202302443.
@article{osti_1997741,
title = {In Situ Ion‐Exchange Metathesis Induced Conformal LiF Surface Films on Cathode (NMC811) as a Cathode Electrolyte Interphase},
author = {Thapaliya, Bishnu P. and Wang, Tao and Borisevich, Albina Y. and Meyer, Harry M. and Sun, Xiao‐Guang and Paranthaman, Mariappan Parans and Bridges, Craig A. and Dai, Sheng},
abstractNote = {Abstract High‐capacity cathodes (LiNi 0.8 Mn 0.1 Co 0.1 O 2 , NMC811) are promising for vehicle electrification because of their high gravimetric energy density. However, their electrochemical performance still relies upon the stability of the cathode electrolyte interphase (CEI). A highly reactive cathode interface leads to parasitic side reactions with electrolytes, resulting in accelerated capacity fading. Well‐developed LiF and LiF‐like inorganic compounds are believed to be good CEI components for stabilizing such reactive electrode interfaces. However, it is challenging to form an optimal surface sub‐nanolayer of LiF on the cathode surfaces because of the complexity of the electrochemical reaction during battery cycling. Herein, the formation of a conformal LiF layer on the NMC811 electrode surface via an in situ ion‐exchange metathesis process is reported, demonstrating a promising electrochemical performance because of a LiF‐stabilized CEI. In situ generated LiF‐coated NMC811 electrodes exhibit ≈97% capacity retention up to 100 cycles at a 0.3 C rate with average coulombic efficiency of ≈99.9% and ≈80% capacity retention up to 200 cycles at a 1 C rate with average coulombic efficiency of >99.6%. This finding may pave the way for reengineering the CEI to enhance the electrochemical performances and cycling stability of the high‐capacity cathodes.},
doi = {10.1002/adfm.202302443},
journal = {Advanced Functional Materials},
number = 44,
volume = 33,
place = {United States},
year = {Sat Jul 08 00:00:00 EDT 2023},
month = {Sat Jul 08 00:00:00 EDT 2023}
}
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