Removal and recovery of ammonia from simulated wastewater using Ti3C2Tx MXene in flow electrode capacitive deionization

Mansoor, Naqsh E.; Diaz, Luis A.; Shuck, Christopher E.; Gogotsi, Yury; Lister, Tedd E.; Estrada, David

doi:10.1038/s41545-022-00164-3

Title: Removal and recovery of ammonia from simulated wastewater using Ti3C2Tx MXene in flow electrode capacitive deionization

Abstract

Abstract Flowing electrode capacitive deionization systems (FE-CDI) have recently garnered attention because of their ability to prevent cross contamination and operate in uninterrupted cycles ad infinitum. Typically, FE-CDI electrodes suffer from low conductivity, reducing deionization performance. Utilization of higher mass loadings to combat this leads to poor rheological properties. Herein, Ti ₃ C ₂ T _x MXene was introduced as 1 mg mL ⁻¹ slurry electrodes in an FE-CDI system for the removal and recovery of ammonia from simulated agricultural wastewater. The electrode performance was evaluated by operating the FE-CDI system with a feed solution of 500 mg L ⁻¹ NH ₄ Cl running in batch mode at a constant voltage of 1.20 and −1.20 V in charging and discharging modes, respectively. Despite the low loading, Ti ₃ C ₂ T _x flowing electrodes showed markedly improved performance, achieving 60% ion removal efficiency in a saturation time of 115 min with an adsorption capacity of 460 mg g ⁻¹ . To understand the high adsorption performance of the electrodes, physiochemical and structural analysis was done via a variety of characterization techniques such as SEM, TEM, XRD, DLS, and Raman spectroscopy. Cyclic voltammetry and galvanostatic charge/discharge profiles were obtained to evaluate the electrochemical properties ofmore »« less

Authors:

;

; Shuck, Christopher E.;

; Lister, Tedd E.;

Publication Date:: Tue Jul 05 00:00:00 EDT 2022

Research Org.:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE); USDOE Laboratory Directed Research and Development (LDRD) Program; Fulbright Fellowship Program; Boise State University; National Aeronautics and Space Administration (NASA); National Institutes of Health (NIH)

OSTI Identifier:: 1874833

Alternate Identifier(s):: OSTI ID: 1907950

Report Number(s):: INL/JOU-22-70569
Journal ID: ISSN 2059-7037; 26; PII: 164

Grant/Contract Number:: AC07-05ID14517; 80NSSC17M0029; NE0008677; P20GM103408; P20GM109095

Resource Type:: Published Article

Journal Name:: npj Clean Water

Additional Journal Information:: Journal Name: npj Clean Water Journal Volume: 5 Journal Issue: 1; Journal ID: ISSN 2059-7037

Publisher:: Nature Publishing Group

Country of Publication:: United Kingdom

Language:: English

Subject:: 36 MATERIALS SCIENCE; water; ammonia removal; electrodeionization; nanoscale materials; pollution remediation

Citation Formats


                    Mansoor, Naqsh E., Diaz, Luis A., Shuck, Christopher E., Gogotsi, Yury, Lister, Tedd E., and Estrada, David. Removal and recovery of ammonia from simulated wastewater using Ti3C2Tx MXene in flow electrode capacitive deionization.  United Kingdom: N. p., 2022. 
Web.  doi:10.1038/s41545-022-00164-3.

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                    Mansoor, Naqsh E., Diaz, Luis A., Shuck, Christopher E., Gogotsi, Yury, Lister, Tedd E., & Estrada, David. Removal and recovery of ammonia from simulated wastewater using Ti3C2Tx MXene in flow electrode capacitive deionization.  United Kingdom.  https://doi.org/10.1038/s41545-022-00164-3

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                    Mansoor, Naqsh E., Diaz, Luis A., Shuck, Christopher E., Gogotsi, Yury, Lister, Tedd E., and Estrada, David. Tue .  
"Removal and recovery of ammonia from simulated wastewater using Ti3C2Tx MXene in flow electrode capacitive deionization".  United Kingdom.  https://doi.org/10.1038/s41545-022-00164-3.

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@article{osti_1874833,

  title        = {Removal and recovery of ammonia from simulated wastewater using Ti3C2Tx MXene in flow electrode capacitive deionization},

  author       = {Mansoor, Naqsh E. and Diaz, Luis A. and Shuck, Christopher E. and Gogotsi, Yury and Lister, Tedd E. and Estrada, David},

  abstractNote = {Abstract Flowing electrode capacitive deionization systems (FE-CDI) have recently garnered attention because of their ability to prevent cross contamination and operate in uninterrupted cycles ad infinitum. Typically, FE-CDI electrodes suffer from low conductivity, reducing deionization performance. Utilization of higher mass loadings to combat this leads to poor rheological properties. Herein, Ti 3 C 2 T x MXene was introduced as 1 mg mL −1 slurry electrodes in an FE-CDI system for the removal and recovery of ammonia from simulated agricultural wastewater. The electrode performance was evaluated by operating the FE-CDI system with a feed solution of 500 mg L −1 NH 4 Cl running in batch mode at a constant voltage of 1.20 and −1.20 V in charging and discharging modes, respectively. Despite the low loading, Ti 3 C 2 T x flowing electrodes showed markedly improved performance, achieving 60% ion removal efficiency in a saturation time of 115 min with an adsorption capacity of 460 mg g −1 . To understand the high adsorption performance of the electrodes, physiochemical and structural analysis was done via a variety of characterization techniques such as SEM, TEM, XRD, DLS, and Raman spectroscopy. Cyclic voltammetry and galvanostatic charge/discharge profiles were obtained to evaluate the electrochemical properties of the electrodes. The system proved to be an energy-saving technology by exhibiting a charge efficiency of 58–70% while operating at an energy consumption of 0.45 kWh kg −1 . A 92% regeneration efficiency showed that the electrodes were stable and suitable for long term and scalable usage. The results demonstrate that MXenes have the potential to improve the FE-CDI process for energy-efficient removal and recovery of ammonia.},

  doi          = {10.1038/s41545-022-00164-3},

  journal      = {npj Clean Water},

  number       = 1,

  volume       = 5,

  place        = {United Kingdom},

  year         = {Tue Jul 05 00:00:00 EDT 2022},

  month        = {Tue Jul 05 00:00:00 EDT 2022}

}

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Title: Removal and recovery of ammonia from simulated wastewater using Ti3C2Tx MXene in flow electrode capacitive deionization

Abstract

Citation Formats

Flow-electrode capacitive deionization: A review and new perspectives journal, July 2021

There is plenty of space in the MXene layers: The confinement and fillings journal, September 2020

Adsorptive remediation of environmental pollutants using novel graphene-based nanomaterials journal, June 2013

The Rise of MXenes journal, July 2019

Consequences of the Clean Water Act and the Demand for Water Quality* journal, September 2018

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Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti 3 C 2 MXene journal, April 2021

Technology status and trends of industrial wastewater treatment: A patent analysis journal, February 2022

Hydration of NH 4 + in Water: Bifurcated Hydrogen Bonding Structures and Fast Rotational Dynamics journal, September 2020

Capacitive deionization (CDI) for desalination and water treatment — past, present and future (a review) journal, August 2008

Capacitive deionization for nutrient recovery from wastewater with disinfection capability journal, January 2018

Materials for electrochemical capacitors journal, November 2008

Capacitive deionization concept based on suspension electrodes without ion exchange membranes journal, June 2014

Various cell architectures of capacitive deionization: Recent advances and future trends journal, March 2019

Electrochemical capacitors: Technical challenges and prognosis for future markets journal, December 2012

A Comprehensive Evaluation Model of Ammonia Pollution Trends in a Groundwater Source Area along a River in Residential Areas journal, July 2021

Water treatment and environmental remediation applications of two-dimensional metal carbides (MXenes) journal, November 2019

Textural characteristics, surface chemistry and oxidation of activated carbon journal, May 2010

Understanding the MXene Pseudocapacitance journal, February 2018

Lipid-Based Nanoparticles for Drug Delivery Systems book, January 2019

Capacitive deionization as an electrochemical means of saving energy and delivering clean water. Comparison to present desalination practices: Will it compete? journal, April 2010

The Electrochemical Flow Capacitor: A New Concept for Rapid Energy Storage and Recovery journal, May 2012

Operational water consumption and withdrawal factors for electricity generating technologies: a review of existing literature journal, December 2012

Raman spectroscopy on amorphous carbon films journal, July 1996

Carbon electrodes for capacitive technologies journal, January 2019

Timeline on the application of intercalation materials in Capacitive Deionization journal, April 2019

Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer journal, September 2006

X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes) journal, January 2016

Attractive forces in microporous carbon electrodes for capacitive deionization journal, February 2014

MXenes—A new class of 2D layered materials: Synthesis, properties, applications as supercapacitor electrode and beyond journal, March 2020

Rational Design of Titanium Carbide MXene Electrode Architectures for Hybrid Capacitive Deionization journal, August 2020

Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2 journal, August 2011

A protic salt-derived porous carbon for efficient capacitive deionization: Balance between porous structure and chemical composition journal, May 2017

Oxidation stability of Ti3C2Tx MXene nanosheets in solvents and composite films journal, February 2019

Influence of Feed-Electrode Concentration Differences in Flow-Electrode Systems for Capacitive Deionization journal, June 2018

Current perspectives of anoxic ammonia removal and blending of partial nitrifying and denitrifying bacteria for ammonia reduction in wastewater treatment journal, June 2021

Revisited insights into charge storage mechanisms in electrochemical capacitors with Li2SO4-based electrolyte journal, November 2019

Synthesis of Mo 4 VAlC 4 MAX Phase and Two-Dimensional Mo 4 VC 4 MXene with Five Atomic Layers of Transition Metals journal, December 2019

On the effective ionic radii for ammonium journal, August 2016

Scalable Synthesis of Ti 3 C 2 T x MXene journal, March 2020

Recovering ammonia from municipal wastewater by flow-electrode capacitive deionization journal, September 2018

Experimental and Theoretical Advances in MXene-Based Gas Sensors journal, January 2021

Role of acid mixtures etching on the surface chemistry and sodium ion storage in Ti 3 C 2 T x MXene journal, January 2020

All-MXene (2D titanium carbide) solid-state microsupercapacitors for on-chip energy storage journal, January 2016

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Approaches and processes for ammonia removal from side-streams of municipal effluent treatment plants journal, November 2018

Islanded ammonia power systems: Technology review & conceptual process design journal, October 2019

Dynamic Adsorption/Desorption Process Model for Capacitive Deionization journal, March 2009

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A review on ammonia, ammonia-hydrogen and ammonia-methane fuels journal, September 2021

Enhancement of charge efficiency for a capacitive deionization cell using carbon xerogel with modified potential of zero charge journal, February 2014

The world of two-dimensional carbides and nitrides (MXenes) journal, June 2021

Critical review of abatement of ammonia from wastewater journal, July 2018

Dispersions of Two-Dimensional Titanium Carbide MXene in Organic Solvents journal, February 2017

Enhancing understandability and performance of flow electrode capacitive deionisation by optimizing configurational and operational parameters: A review on recent progress journal, June 2020

Towards sustainable agriculture: Fossil-free ammonia journal, May 2017

Activated Carbon Spheres as a Flowable Electrode in Electrochemical Flow Capacitors journal, January 2014

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journal, July 2021

There is plenty of space in the MXene layers: The confinement and fillings
journal, September 2020

Adsorptive remediation of environmental pollutants using novel graphene-based nanomaterials
journal, June 2013

The Rise of MXenes
journal, July 2019

Consequences of the Clean Water Act and the Demand for Water Quality*
journal, September 2018

Influence of operating conditions on the desalination performance of a symmetric pre-conditioned Ti3C2T -MXene membrane capacitive deionization system
journal, March 2020

Performance comparison and energy consumption analysis of capacitive deionization and membrane capacitive deionization processes
journal, September 2013

Characterization of MXenes at every step, from their precursors to single flakes and assembled films
journal, July 2021

Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti ₃ C ₂ MXene
journal, April 2021

Technology status and trends of industrial wastewater treatment: A patent analysis
journal, February 2022

Hydration of ${NH}_{4}^{+}$ in Water: Bifurcated Hydrogen Bonding Structures and Fast Rotational Dynamics
journal, September 2020

Capacitive deionization (CDI) for desalination and water treatment — past, present and future (a review)
journal, August 2008

Capacitive deionization for nutrient recovery from wastewater with disinfection capability
journal, January 2018

Materials for electrochemical capacitors
journal, November 2008

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journal, June 2014

Various cell architectures of capacitive deionization: Recent advances and future trends
journal, March 2019

Electrochemical capacitors: Technical challenges and prognosis for future markets
journal, December 2012

A Comprehensive Evaluation Model of Ammonia Pollution Trends in a Groundwater Source Area along a River in Residential Areas
journal, July 2021

Water treatment and environmental remediation applications of two-dimensional metal carbides (MXenes)
journal, November 2019

Textural characteristics, surface chemistry and oxidation of activated carbon
journal, May 2010

Understanding the MXene Pseudocapacitance
journal, February 2018

Lipid-Based Nanoparticles for Drug Delivery Systems
book, January 2019

Capacitive deionization as an electrochemical means of saving energy and delivering clean water. Comparison to present desalination practices: Will it compete?
journal, April 2010

The Electrochemical Flow Capacitor: A New Concept for Rapid Energy Storage and Recovery
journal, May 2012

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journal, December 2012

Raman spectroscopy on amorphous carbon films
journal, July 1996

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journal, January 2019

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journal, April 2019

Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
journal, September 2006

X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)
journal, January 2016

Attractive forces in microporous carbon electrodes for capacitive deionization
journal, February 2014

MXenes—A new class of 2D layered materials: Synthesis, properties, applications as supercapacitor electrode and beyond
journal, March 2020

Rational Design of Titanium Carbide MXene Electrode Architectures for Hybrid Capacitive Deionization
journal, August 2020

Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂
journal, August 2011

A protic salt-derived porous carbon for efficient capacitive deionization: Balance between porous structure and chemical composition
journal, May 2017

Oxidation stability of Ti3C2Tx MXene nanosheets in solvents and composite films
journal, February 2019

Influence of Feed-Electrode Concentration Differences in Flow-Electrode Systems for Capacitive Deionization
journal, June 2018

Current perspectives of anoxic ammonia removal and blending of partial nitrifying and denitrifying bacteria for ammonia reduction in wastewater treatment
journal, June 2021

Revisited insights into charge storage mechanisms in electrochemical capacitors with Li2SO4-based electrolyte
journal, November 2019

Synthesis of Mo 4 VAlC 4 MAX Phase and Two-Dimensional Mo 4 VC 4 MXene with Five Atomic Layers of Transition Metals
journal, December 2019

On the effective ionic radii for ammonium
journal, August 2016

Scalable Synthesis of Ti ₃ C ₂ T _x MXene
journal, March 2020

Recovering ammonia from municipal wastewater by flow-electrode capacitive deionization
journal, September 2018

Experimental and Theoretical Advances in MXene-Based Gas Sensors
journal, January 2021

Role of acid mixtures etching on the surface chemistry and sodium ion storage in Ti ₃ C ₂ T _x MXene
journal, January 2020

All-MXene (2D titanium carbide) solid-state microsupercapacitors for on-chip energy storage
journal, January 2016

Adsorbent materials for ammonium and ammonia removal: A review
journal, February 2021

Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO₂ (Anatase) Nanoparticles
journal, October 2007

2D Ti3C2Tz MXene Synthesized by Water-free Etching of Ti3AlC2 in Polar Organic Solvents
journal, March 2020

Size-Dependent Physical and Electrochemical Properties of Two-Dimensional MXene Flakes
journal, June 2018

Ammonia: Its Effects on Biological Systems, Metabolic Hormones, and Reproduction
journal, March 1984

Approaches and processes for ammonia removal from side-streams of municipal effluent treatment plants
journal, November 2018

Islanded ammonia power systems: Technology review & conceptual process design
journal, October 2019

Dynamic Adsorption/Desorption Process Model for Capacitive Deionization
journal, March 2009

Improving the feasibility and applicability of flow-electrode capacitive deionization (FCDI): Review of process optimization and energy efficiency
journal, April 2021

Carbon flow electrodes for continuous operation of capacitive deionization and capacitive mixing energy generation
journal, January 2014

MXenes for Non‐Lithium‐Ion (Na, K, Ca, Mg, and Al) Batteries and Supercapacitors
journal, June 2020

An Earth-system perspective of the global nitrogen cycle
journal, January 2008

Apparatus and Methods for Measurement and Interpretation of the Angular Variation of Light Scattering; Preliminary Results on Polystyrene Solutions
journal, December 1948

Review on the science and technology of water desalination by capacitive deionization
journal, October 2013

Sedimentation Coefficient and Fragility under Hydrodynamic Shear as Measures of Molecular Weight of the DNA of Phage T5
journal, November 1962

Electrochemical analysis of slurry electrodes for flow-electrode capacitive deionization
journal, December 2017

Free-standing Ti3C2Tx MXene film as binder-free electrode in capacitive deionization with an ultrahigh desalination capacity
journal, March 2020

Photo-electric capacitive deionization enabled by solar-driven nano-ionics on the edges of plasma-made vertical graphenes
journal, October 2021

Application of Capacitive Deionisation in water desalination: A review
journal, June 2014

Intercalation in Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes) toward Electrochemical Capacitor and Beyond
journal, July 2020

Improved Dynamic Light Scattering using an adaptive and statistically driven time resolved treatment of correlation data
journal, September 2019

(Invited) Capacitive Deionization of High-Salinity Water Using Ion-Exchange Membranes
journal, September 2017

Porous Cryo-Dried MXene for Efficient Capacitive Deionization
journal, April 2018

A review on ammonia, ammonia-hydrogen and ammonia-methane fuels
journal, September 2021

Enhancement of charge efficiency for a capacitive deionization cell using carbon xerogel with modified potential of zero charge
journal, February 2014

The world of two-dimensional carbides and nitrides (MXenes)
journal, June 2021

Critical review of abatement of ammonia from wastewater
journal, July 2018

Dispersions of Two-Dimensional Titanium Carbide MXene in Organic Solvents
journal, February 2017

Enhancing understandability and performance of flow electrode capacitive deionisation by optimizing configurational and operational parameters: A review on recent progress
journal, June 2020

Towards sustainable agriculture: Fossil-free ammonia
journal, May 2017

Activated Carbon Spheres as a Flowable Electrode in Electrochemical Flow Capacitors
journal, January 2014

Efficiency of capacitive deionization using carbon materials based electrodes for water desalination
journal, February 2020

Removal of ammonia by graphite oxide via its intercalation and reactive adsorption
journal, September 2007

Enhanced charge efficiency and reduced energy use in capacitive deionization by increasing the discharge voltage
journal, May 2015