Vacancy‐Enabled O3 Phase Stabilization for Manganese‐Rich Layered Sodium Cathodes
Abstract
Abstract Manganese‐rich layered oxide materials hold great potential as low‐cost and high‐capacity cathodes for Na‐ion batteries. However, they usually form a P2 phase and suffer from fast capacity fade. In this work, an O3 phase sodium cathode has been developed out of a Li and Mn‐rich layered material by leveraging the creation of transition metal (TM) and oxygen vacancies and the electrochemical exchange of Na and Li. The Mn‐rich layered cathode material remains primarily O3 phase during sodiation/desodiation and can have a full sodiation capacity of ca. 220 mAh g −1 . It delivers ca. 160 mAh g −1 specific capacity between 2–3.8 V with >86 % retention over 250 cycles. The TM and oxygen vacancies pre‐formed in the sodiated material enables a reversible migration of TMs from the TM layer to the tetrahedral sites in the Na layer upon de‐sodiation and sodiation. The migration creates metastable states, leading to increased kinetic barrier that prohibits a complete O3‐P3 phase transition.
- Authors:
-
[1]
- Energy &, Environment Directorate Pacific Northwest National Laboratory Richland WA 99352 USA
- John A. Paulson School of Engineering and Applied Sciences Harvard University Cambridge MA 02138 USA
- Chemistry Division Brookhaven National Laboratory Upton NY 11973 USA
- Physical and Computational Sciences Directorate Pacific Northwest National Laboratory Richland WA 99352 USA
- Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32306 USA
- Department of Chemistry Virginia Tech Blacksburg VA 24061 USA
- Environmental Molecular Sciences Laboratory Pacific Northwest National Laboratory Richland WA 99352 USA
- Chemical Sciences and Engineering Division Argonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA, Materials Science and Engineering Stanford University Stanford CA 94305 USA
- Chemical Sciences and Engineering Division Argonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1786141
- Grant/Contract Number:
- 70247A; SC0012704; AC02-06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 133 Journal Issue: 15; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Xiao, Biwei, Wang, Yichao, Tan, Sha, Song, Miao, Li, Xiang, Zhang, Yuxin, Lin, Feng, Han, Kee Sung, Omenya, Fredrick, Amine, Khalil, Yang, Xiao‐Qing, Reed, David, Hu, Yanyan, Xu, Gui‐Liang, Hu, Enyuan, Li, Xin, and Li, Xiaolin. Vacancy‐Enabled O3 Phase Stabilization for Manganese‐Rich Layered Sodium Cathodes. Germany: N. p., 2021.
Web. doi:10.1002/ange.202016334.
Xiao, Biwei, Wang, Yichao, Tan, Sha, Song, Miao, Li, Xiang, Zhang, Yuxin, Lin, Feng, Han, Kee Sung, Omenya, Fredrick, Amine, Khalil, Yang, Xiao‐Qing, Reed, David, Hu, Yanyan, Xu, Gui‐Liang, Hu, Enyuan, Li, Xin, & Li, Xiaolin. Vacancy‐Enabled O3 Phase Stabilization for Manganese‐Rich Layered Sodium Cathodes. Germany. https://doi.org/10.1002/ange.202016334
Xiao, Biwei, Wang, Yichao, Tan, Sha, Song, Miao, Li, Xiang, Zhang, Yuxin, Lin, Feng, Han, Kee Sung, Omenya, Fredrick, Amine, Khalil, Yang, Xiao‐Qing, Reed, David, Hu, Yanyan, Xu, Gui‐Liang, Hu, Enyuan, Li, Xin, and Li, Xiaolin. Tue .
"Vacancy‐Enabled O3 Phase Stabilization for Manganese‐Rich Layered Sodium Cathodes". Germany. https://doi.org/10.1002/ange.202016334.
@article{osti_1786141,
title = {Vacancy‐Enabled O3 Phase Stabilization for Manganese‐Rich Layered Sodium Cathodes},
author = {Xiao, Biwei and Wang, Yichao and Tan, Sha and Song, Miao and Li, Xiang and Zhang, Yuxin and Lin, Feng and Han, Kee Sung and Omenya, Fredrick and Amine, Khalil and Yang, Xiao‐Qing and Reed, David and Hu, Yanyan and Xu, Gui‐Liang and Hu, Enyuan and Li, Xin and Li, Xiaolin},
abstractNote = {Abstract Manganese‐rich layered oxide materials hold great potential as low‐cost and high‐capacity cathodes for Na‐ion batteries. However, they usually form a P2 phase and suffer from fast capacity fade. In this work, an O3 phase sodium cathode has been developed out of a Li and Mn‐rich layered material by leveraging the creation of transition metal (TM) and oxygen vacancies and the electrochemical exchange of Na and Li. The Mn‐rich layered cathode material remains primarily O3 phase during sodiation/desodiation and can have a full sodiation capacity of ca. 220 mAh g −1 . It delivers ca. 160 mAh g −1 specific capacity between 2–3.8 V with >86 % retention over 250 cycles. The TM and oxygen vacancies pre‐formed in the sodiated material enables a reversible migration of TMs from the TM layer to the tetrahedral sites in the Na layer upon de‐sodiation and sodiation. The migration creates metastable states, leading to increased kinetic barrier that prohibits a complete O3‐P3 phase transition.},
doi = {10.1002/ange.202016334},
journal = {Angewandte Chemie},
number = 15,
volume = 133,
place = {Germany},
year = {Tue Apr 06 00:00:00 EDT 2021},
month = {Tue Apr 06 00:00:00 EDT 2021}
}
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Works referenced in this record:
Insights into the structural effects of layered cathode materials for high voltage sodium-ion batteries
journal, January 2017
- Xu, Gui-Liang; Amine, Rachid; Xu, Yue-Feng
- Energy & Environmental Science, Vol. 10, Issue 7
Layered-to-Rock-Salt Transformation in Desodiated Na x CrO 2 ( x 0.4)
journal, February 2016
- Bo, Shou-Hang; Li, Xin; Toumar, Alexandra J.
- Chemistry of Materials, Vol. 28, Issue 5
In Operando XRD and TXM Study on the Metastable Structure Change of NaNi 1/3 Fe 1/3 Mn 1/3 O 2 under Electrochemical Sodium-Ion Intercalation
journal, September 2016
- Xie, Yingying; Wang, Hong; Xu, Guiliang
- Advanced Energy Materials, Vol. 6, Issue 24
Reining in dissolved transition-metal ions
journal, July 2020
- Asl, Hooman Yaghoobnejad; Manthiram, Arumugam
- Science, Vol. 369, Issue 6500
Electrochemistry and Solid‐State Chemistry of NaMeO 2 (Me = 3d Transition Metals)
journal, June 2018
- Kubota, Kei; Kumakura, Shinichi; Yoda, Yusuke
- Advanced Energy Materials, Vol. 8, Issue 17
Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials
journal, January 2015
- Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P.
- Journal of The Electrochemical Society, Vol. 162, Issue 14
β-NaMnO 2 : A High-Performance Cathode for Sodium-Ion Batteries
journal, November 2014
- Billaud, Juliette; Clément, Raphaële J.; Armstrong, A. Robert
- Journal of the American Chemical Society, Vol. 136, Issue 49
NaTiO 2 : a layered anode material for sodium-ion batteries
journal, January 2015
- Wu, Di; Li, Xin; Xu, Bo
- Energy & Environmental Science, Vol. 8, Issue 1
Reversible Flat to Rippling Phase Transition in Fe Containing Layered Battery Electrode Materials
journal, July 2018
- Chen, Xi; Hwang, Sooyeon; Chisnell, Robin
- Advanced Functional Materials, Vol. 28, Issue 39
Roles of Coherent Interfaces on Electrochemical Performance of Sodium Layered Oxide Cathodes
journal, June 2018
- Huang, Qun; Liu, Jiatu; Xu, Sheng
- Chemistry of Materials, Vol. 30, Issue 14
Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance
journal, November 2017
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Advanced Energy Materials, Vol. 8, Issue 8
Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries
journal, February 2018
- Xu, Gui-Liang; Amine, Rachid; Abouimrane, Ali
- Advanced Energy Materials, Vol. 8, Issue 14
A Layered P2- and O3-Type Composite as a High-Energy Cathode for Rechargeable Sodium-Ion Batteries
journal, April 2015
- Guo, Shaohua; Liu, Pan; Yu, Haijun
- Angewandte Chemie, Vol. 127, Issue 20
The Layered Oxides in Lithium and Sodium‐Ion Batteries: A Solid‐State Chemistry Approach
journal, July 2020
- Delmas, Claude; Carlier, Dany; Guignard, Marie
- Advanced Energy Materials, Vol. 11, Issue 2
On the dynamics of transition metal migration and its impact on the performance of layered oxides for sodium-ion batteries: NaFeO 2 as a case study
journal, January 2018
- Silván, Begoña; Gonzalo, Elena; Djuandhi, Lisa
- Journal of Materials Chemistry A, Vol. 6, Issue 31
Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes
journal, January 2020
- Eum, Donggun; Kim, Byunghoon; Kim, Sung Joo
- Nature Materials, Vol. 19, Issue 4
Size‐Mediated Recurring Spinel Sub‐nanodomains in Li‐ and Mn‐Rich Layered Cathode Materials
journal, June 2020
- Xiao, Biwei; Liu, Hanshuo; Chen, Ning
- Angewandte Chemie International Edition, Vol. 59, Issue 34
A Long Cycle‐Life High‐Voltage Spinel Lithium‐Ion Battery Electrode Achieved by Site‐Selective Doping
journal, April 2020
- Liang, Gemeng; Wu, Zhibin; Didier, Christophe
- Angewandte Chemie International Edition, Vol. 59, Issue 26
Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries
journal, April 2020
- Song, Junhua; Wang, Kuan; Zheng, Jianming
- ACS Energy Letters, Vol. 5, Issue 6
Highly stable Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 enabled by novel atomic layer deposited AlPO 4 coating
journal, April 2017
- Xiao, Biwei; Wang, Biqiong; Liu, Jian
- Nano Energy, Vol. 34
Recent developments on layered 3d-transtition metal oxide cathode materials for sodium-ion batteries
journal, June 2020
- Palaniyandy, Nithyadharseni
- Current Opinion in Electrochemistry, Vol. 21
Explore the Effects of Microstructural Defects on Voltage Fade of Li- and Mn-Rich Cathodes
journal, September 2016
- Hu, Enyuan; Lyu, Yingchun; Xin, Huolin L.
- Nano Letters, Vol. 16, Issue 10
High Capacity Li-Rich Positive Electrode Materials with Reduced First-Cycle Irreversible Capacity Loss
journal, January 2015
- Shunmugasundaram, Ramesh; Senthil Arumugam, Rajalakshmi; Dahn, J. R.
- Chemistry of Materials, Vol. 27, Issue 3
A novel P3-type Na 2/3 Mg 1/3 Mn 2/3 O 2 as high capacity sodium-ion cathode using reversible oxygen redox
journal, January 2019
- Song, Bohang; Hu, Enyuan; Liu, Jue
- Journal of Materials Chemistry A, Vol. 7, Issue 4
Hard Carbon as Sodium‐Ion Battery Anodes: Progress and Challenges
journal, November 2018
- Xiao, Biwei; Rojo, Teófilo; Li, Xiaolin
- ChemSusChem, Vol. 12, Issue 1
Direct Observation of Alternating Octahedral and Prismatic Sodium Layers in O3‐Type Transition Metal Oxides
journal, June 2020
- Kim, Jae Chul; Kwon, Deok‐Hwang; Yang, Julia H.
- Advanced Energy Materials, Vol. 10, Issue 31
Progress in High-Voltage Cathode Materials for Rechargeable Sodium-Ion Batteries
journal, September 2017
- You, Ya; Manthiram, Arumugam
- Advanced Energy Materials, Vol. 8, Issue 2
New Insights into the Performance Degradation of Fe-Based Layered Oxides in Sodium-Ion Batteries: Instability of Fe 3+ /Fe 4+ Redox in α-NaFeO 2
journal, September 2015
- Lee, Eungje; Brown, Dennis E.; Alp, Esen E.
- Chemistry of Materials, Vol. 27, Issue 19
Sodium‐Ion Batteries Paving the Way for Grid Energy Storage
journal, July 2020
- Hirsh, Hayley S.; Li, Yixuan; Tan, Darren H. S.
- Advanced Energy Materials, Vol. 10, Issue 32
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Suppressing the P2-O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium-Ion Batteries
journal, May 2016
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Angewandte Chemie International Edition, Vol. 55, Issue 26
P2-NaxVO2 system as electrodes for batteries and electron-correlated materials
journal, November 2012
- Guignard, Marie; Didier, Christophe; Darriet, Jacques
- Nature Materials, Vol. 12, Issue 1
Electrochemical Properties of Monoclinic NaMnO2
journal, January 2011
- Ma, Xiaohua; Chen, Hailong; Ceder, Gerbrand
- Journal of The Electrochemical Society, Vol. 158, Issue 12
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release
journal, July 2018
- Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian
- Nature Energy, Vol. 3, Issue 8
Understanding intercalation compounds for sodium-ion batteries and beyond
journal, July 2019
- Kaufman, Jonas L.; Vinckevičiūtė, Julija; Krishna Kolli, Sanjeev
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2152
Understanding the Origins of Higher Capacities at Faster Rates in Lithium-Excess Li x Ni 2–4 x /3 Sb x /3 O 2
journal, November 2016
- Twu, Nancy; Metzger, Michael; Balasubramanian, Mahalingam
- Chemistry of Materials, Vol. 29, Issue 6
Uncovering the roles of oxygen vacancies in cation migration in lithium excess layered oxides
journal, January 2014
- Qian, Danna; Xu, Bo; Chi, Miaofang
- Phys. Chem. Chem. Phys., Vol. 16, Issue 28
Recent advances and prospects of layered transition metal oxide cathodes for sodium-ion batteries
journal, September 2020
- Gao, Rui-Min; Zheng, Zi-Jian; Wang, Peng-Fei
- Energy Storage Materials, Vol. 30
The Role of Metal Site Vacancies in Promoting Li–Mn–Ni–O Layered Solid Solutions
journal, June 2013
- McCalla, E.; Rowe, A. W.; Camardese, J.
- Chemistry of Materials, Vol. 25, Issue 13
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
journal, February 2006
- Kang, Kisuk; Shirley Meng, Ying; Breger, Julien
- Science, Vol. 311, Issue 5763, p. 977-980
Electrochemical and Structural Study of the Layered, “Li-Excess” Lithium-Ion Battery Electrode Material Li[Li 1/9 Ni 1/3 Mn 5/9 ]O 2
journal, July 2009
- Jiang, Meng; Key, Baris; Meng, Ying S.
- Chemistry of Materials, Vol. 21, Issue 13
From Charge Storage Mechanism to Performance: A Roadmap toward High Specific Energy Sodium-Ion Batteries through Carbon Anode Optimization
journal, March 2018
- Saurel, Damien; Orayech, Brahim; Xiao, Biwei
- Advanced Energy Materials, Vol. 8, Issue 17
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007
- Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
- Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125
Adverse effects of interlayer-gliding in layered transition-metal oxides on electrochemical sodium-ion storage
journal, January 2019
- Sun, Yang; Guo, Shaohua; Zhou, Haoshen
- Energy & Environmental Science, Vol. 12, Issue 3
Ti-Substituted NaNi 0.5 Mn 0.5- x Ti x O 2 Cathodes with Reversible O3−P3 Phase Transition for High-Performance Sodium-Ion Batteries
journal, March 2017
- Wang, Peng-Fei; Yao, Hu-Rong; Liu, Xin-Yu
- Advanced Materials, Vol. 29, Issue 19
Understanding the Capacity Fading Mechanisms of O3‐Type Na[Ni 0.5 Mn 0.5 ]O 2 Cathode for Sodium‐Ion Batteries
journal, July 2020
- Yu, Tae‐Yeon; Ryu, Hoon‐Hee; Han, Geumjae
- Advanced Energy Materials, Vol. 10, Issue 37
Nanoscale Manipulation of Spinel Lithium Nickel Manganese Oxide Surface by Multisite Ti Occupation as High-Performance Cathode
journal, October 2017
- Xiao, Biwei; Liu, Hanshuo; Liu, Jian
- Advanced Materials, Vol. 29, Issue 47
Suppressing the P2-O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium-Ion Batteries
journal, May 2016
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Angewandte Chemie, Vol. 128, Issue 26
Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction
journal, March 1988
- Le Bail, A.; Duroy, H.; Fourquet, J. L.
- Materials Research Bulletin, Vol. 23, Issue 3
Origins of Bistability and Na Ion Mobility Difference in P2- and O3-Na 2/3 Fe 2/3 Mn 1/3 O 2 Cathode Polymorphs
journal, September 2016
- Katcho, Nebil A.; Carrasco, Javier; Saurel, Damien
- Advanced Energy Materials, Vol. 7, Issue 1
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012
- Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
- Nature Materials, Vol. 11, Issue 6
Super Charge Separation and High Voltage Phase in Na x MnO 2
journal, October 2018
- Chen, Xi; Wang, Yichao; Wiaderek, Kamila
- Advanced Functional Materials, Vol. 28, Issue 50
Layered Oxide Cathodes Promoted by Structure Modulation Technology for Sodium‐Ion Batteries
journal, April 2020
- Xiao, Yao; Abbasi, Nasir Mahmood; Zhu, Yan‐Fang
- Advanced Functional Materials, Vol. 30, Issue 30
Identifying the Critical Role of Li Substitution in P2–Na x [Li y Ni z Mn 1– y – z ]O 2 (0 < x , y , z < 1) Intercalation Cathode Materials for High-Energy Na-Ion Batteries
journal, December 2013
- Xu, Jing; Lee, Dae Hoe; Clément, Raphaële J.
- Chemistry of Materials, Vol. 26, Issue 2
A Long Cycle‐Life High‐Voltage Spinel Lithium‐Ion Battery Electrode Achieved by Site‐Selective Doping
journal, April 2020
- Liang, Gemeng; Wu, Zhibin; Didier, Christophe
- Angewandte Chemie, Vol. 132, Issue 26
Electrochemical Activity of Li in the Transition-Metal Sites of O3 Li[Li[sub (1−2x)/3]Mn[sub (2−x)/3]Ni[sub x]]O[sub 2]
journal, January 2004
- Grey, Clare P.; Yoon, Won-Sub; Reed, John
- Electrochemical and Solid-State Letters, Vol. 7, Issue 9
Atomic Structure of Li 2 MnO 3 after Partial Delithiation and Re-Lithiation
journal, June 2013
- Wang, Rui; He, Xiaoqing; He, Lunhua
- Advanced Energy Materials, Vol. 3, Issue 10
Size‐Mediated Recurring Spinel Sub‐nanodomains in Li‐ and Mn‐Rich Layered Cathode Materials
journal, June 2020
- Xiao, Biwei; Liu, Hanshuo; Chen, Ning
- Angewandte Chemie, Vol. 132, Issue 34
Highly Reversible Oxygen-Redox Chemistry at 4.1 V in Na 4/7− x [□ 1/7 Mn 6/7 ]O 2 (□: Mn Vacancy)
journal, April 2018
- Mortemard de Boisse, Benoit; Nishimura, Shin-ichi; Watanabe, Eriko
- Advanced Energy Materials, Vol. 8, Issue 20
Jahn–Teller Assisted Na Diffusion for High Performance Na Ion Batteries
journal, September 2016
- Li, Xin; Wang, Yan; Wu, Di
- Chemistry of Materials, Vol. 28, Issue 18
A Layered P2- and O3-Type Composite as a High-Energy Cathode for Rechargeable Sodium-Ion Batteries
journal, April 2015
- Guo, Shaohua; Liu, Pan; Yu, Haijun
- Angewandte Chemie International Edition, Vol. 54, Issue 20