Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel
Abstract
The electrochemical properties of NaNi0.5Co0.5O2 and NaNi0.5Fe0.5O2 and their structural transitions as a function of Na extraction associated with redox reactions are investigated. Synthesized in the O3-type layered structure, both materials show reasonable electrochemical activities at room temperature, delivering approximately 0.5 Na per formula unit at C/10 discharge. More Na can be reversibly cycled in NaNi0.5Co0.5O2 at elevated temperature and/or in an extended voltage window, while NaNi0.5Fe0.5O2 shows significant capacity fading at a high voltage cutoff which is likely due to Fe4+ migration. In situ X-ray diffraction shows that the structural changes in the two materials upon desodiation are very different. NaNi0.5Co0.5O2 goes through many different two-phase reactions including three different O3-type and three different P3-type structures during cycling, producing a voltage profile with multiple plateau-like features. In contrast, NaNi0.5Fe0.5O2 has a smooth voltage profile and shows the typical O3–P3 phase transition without lattice distortion seen in other materials. Finally, this different structural evolution upon desodiation and re-sodiation can be explained by the electronic structure of the mixed transition metals and how it perturbs the ordering between Na ions differently.
- Authors:
-
[4]
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
- Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering; Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Science Foundation (NSF); Samsung Advanced Inst. of Technology (Korea, Republic of)
- OSTI Identifier:
- 1475004
- Grant/Contract Number:
- AC02-05CH11231; ACI-1053575
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 9; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Vassilaras, Plousia, Kwon, Deok-Hwang, Dacek, Stephen T., Shi, Tan, Seo, Dong-Hwa, Ceder, Gerbrand, and Kim, Jae Chul. Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel. United States: N. p., 2017.
Web. doi:10.1039/c6ta09220a.
Vassilaras, Plousia, Kwon, Deok-Hwang, Dacek, Stephen T., Shi, Tan, Seo, Dong-Hwa, Ceder, Gerbrand, & Kim, Jae Chul. Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel. United States. https://doi.org/10.1039/c6ta09220a
Vassilaras, Plousia, Kwon, Deok-Hwang, Dacek, Stephen T., Shi, Tan, Seo, Dong-Hwa, Ceder, Gerbrand, and Kim, Jae Chul. Mon .
"Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel". United States. https://doi.org/10.1039/c6ta09220a. https://www.osti.gov/servlets/purl/1475004.
@article{osti_1475004,
title = {Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel},
author = {Vassilaras, Plousia and Kwon, Deok-Hwang and Dacek, Stephen T. and Shi, Tan and Seo, Dong-Hwa and Ceder, Gerbrand and Kim, Jae Chul},
abstractNote = {The electrochemical properties of NaNi0.5Co0.5O2 and NaNi0.5Fe0.5O2 and their structural transitions as a function of Na extraction associated with redox reactions are investigated. Synthesized in the O3-type layered structure, both materials show reasonable electrochemical activities at room temperature, delivering approximately 0.5 Na per formula unit at C/10 discharge. More Na can be reversibly cycled in NaNi0.5Co0.5O2 at elevated temperature and/or in an extended voltage window, while NaNi0.5Fe0.5O2 shows significant capacity fading at a high voltage cutoff which is likely due to Fe4+ migration. In situ X-ray diffraction shows that the structural changes in the two materials upon desodiation are very different. NaNi0.5Co0.5O2 goes through many different two-phase reactions including three different O3-type and three different P3-type structures during cycling, producing a voltage profile with multiple plateau-like features. In contrast, NaNi0.5Fe0.5O2 has a smooth voltage profile and shows the typical O3–P3 phase transition without lattice distortion seen in other materials. Finally, this different structural evolution upon desodiation and re-sodiation can be explained by the electronic structure of the mixed transition metals and how it perturbs the ordering between Na ions differently.},
doi = {10.1039/c6ta09220a},
journal = {Journal of Materials Chemistry. A},
number = 9,
volume = 5,
place = {United States},
year = {Mon Jan 30 00:00:00 EST 2017},
month = {Mon Jan 30 00:00:00 EST 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 46 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Layered-to-Rock-Salt Transformation in Desodiated Na x CrO 2 ( x 0.4)
journal, February 2016
- Bo, Shou-Hang; Li, Xin; Toumar, Alexandra J.
- Chemistry of Materials, Vol. 28, Issue 5
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Electrochemical Na-Deintercalation from NaVO2
journal, January 2011
- Didier, C.; Guignard, M.; Denage, C.
- Electrochemical and Solid-State Letters, Vol. 14, Issue 5
Microscopy and Spectroscopy of Lithium Nickel Oxide-Based Particles Used in High Power Lithium-Ion Cells
journal, January 2003
- Abraham, D. P.; Twesten, R. D.; Balasubramanian, M.
- Journal of The Electrochemical Society, Vol. 150, Issue 11
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
Novel LiCoO2 Cathode Material with Al2O3 Coating for a Li Ion Cell
journal, December 2000
- Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo
- Chemistry of Materials, Vol. 12, Issue 12, p. 3788-3791
Non-cooperative Jahn-Teller effect in LiNiO2: An EXAFS study
journal, April 1995
- Rougier, A.; Delmas, C.; Chadwick, A. V.
- Solid State Communications, Vol. 94, Issue 2
Lithium Batteries and Cathode Materials
journal, October 2004
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials
journal, January 2015
- Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P.
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Sodium deintercalation from sodium iron oxide
journal, June 1994
- Takeda, Yasuo; Nakahara, Kazuaki; Nishijima, Motoaki
- Materials Research Bulletin, Vol. 29, Issue 6
Effect of Cobalt Substitution on the Jahn-Teller Distortion of the NaNiO 2 Layered Oxide
journal, April 1994
- Delmas, C.; Saadoune, I.; Dordor, P.
- Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 244, Issue 1
Hybrid functionals based on a screened Coulomb potential
journal, May 2003
- Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias
- The Journal of Chemical Physics, Vol. 118, Issue 18
On the LixNi0.8Co0.2O2System
journal, February 1998
- Saadoune, I.; Delmas, C.
- Journal of Solid State Chemistry, Vol. 136, Issue 1
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials
journal, May 2016
- Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander
- Nature Chemistry, Vol. 8, Issue 7
Study on the Reversible Electrode Reaction of Na 1– x Ni 0.5 Mn 0.5 O 2 for a Rechargeable Sodium-Ion Battery
journal, May 2012
- Komaba, Shinichi; Yabuuchi, Naoaki; Nakayama, Tetsuri
- Inorganic Chemistry, Vol. 51, Issue 11
Electrochemical intercalation of sodium in NaxCoO2 bronzes
journal, August 1981
- Delmas, C.; Braconnier, J.; Fouassier, C.
- Solid State Ionics, Vol. 3-4
An overview of the Li(Ni,M)O2 systems: syntheses, structures and properties
journal, September 1999
- Delmas, C.; Ménétrier, M.; Croguennec, L.
- Electrochimica Acta, Vol. 45, Issue 1-2
Crystal Structures and Electrode Performance of Alpha-NaFeO2 for Rechargeable Sodium Batteries
journal, January 2012
- Yabuuchi, Naoaki; Yoshida, Hiroaki; Komaba, Shinichi
- Electrochemistry, Vol. 80, Issue 10
Synthesis, Computed Stability, and Crystal Structure of a New Family of Inorganic Compounds: Carbonophosphates
journal, November 2012
- Chen, Hailong; Hautier, Geoffroy; Ceder, Gerbrand
- Journal of the American Chemical Society, Vol. 134, Issue 48
In Situ X-Ray Absorption Studies of a High-Rate LiNi[sub 0.85]Co[sub 0.15]O[sub 2] Cathode Material
journal, January 2000
- Balasubramanian, M.; Sun, X.; Yang, X. Q.
- Journal of The Electrochemical Society, Vol. 147, Issue 8
Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials
journal, January 2011
- Ong, Shyue Ping; Chevrier, Vincent L.; Hautier, Geoffroy
- Energy & Environmental Science, Vol. 4, Issue 9
Battery materials for ultrafast charging and discharging
journal, March 2009
- Kang, Byoungwoo; Ceder, Gerbrand
- Nature, Vol. 458, Issue 7235, p. 190-193
Effect of iron on the electrochemical behaviour of lithium nickelate: from LiNiO2 to 2D-LiFeO2
journal, November 2000
- Delmas, C.
- Solid State Ionics, Vol. 135, Issue 1-4
Ordered and Disordered Polymorphs of Na(Ni 2/3 Sb 1/3 )O 2 : Honeycomb-Ordered Cathodes for Na-Ion Batteries
journal, March 2015
- Ma, Jeffrey; Bo, Shou-Hang; Wu, Lijun
- Chemistry of Materials, Vol. 27, Issue 7
Oxidation state and chemical shift investigation in transition metal oxides by EELS
journal, May 2012
- Tan, Haiyan; Verbeeck, Jo; Abakumov, Artem
- Ultramicroscopy, Vol. 116
Direct visualization of the Jahn–Teller effect coupled to Na ordering in Na5/8MnO2
journal, May 2014
- Li, Xin; Ma, Xiaohua; Su, Dong
- Nature Materials, Vol. 13, Issue 6
Rechargeable Electrodes from Sodium Cobalt Bronzes
journal, January 1988
- Shacklette, L. W.
- Journal of The Electrochemical Society, Vol. 135, Issue 11
Erratum: “Hybrid functionals based on a screened Coulomb potential” [J. Chem. Phys. 118, 8207 (2003)]
journal, June 2006
- Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias
- The Journal of Chemical Physics, Vol. 124, Issue 21
A comparison of destabilization mechanisms of the layered NaxMO2 and LixMO2 compounds upon alkali de-intercalation
journal, January 2012
- Kim, Sangtae; Ma, Xiaohua; Ong, Shyue Ping
- Physical Chemistry Chemical Physics, Vol. 14, Issue 44
Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application
journal, January 2012
- Kim, Donghan; Lee, Eungje; Slater, Michael
- Electrochemistry Communications, Vol. 18
A bio-facilitated synthetic route for nano-structured complex electrode materials
journal, January 2016
- Moradi, Maryam; Kim, Jae Chul; Qi, Jifa
- Green Chemistry, Vol. 18, Issue 9
Spinel LiMn 2 O 4 Nanorods as Lithium Ion Battery Cathodes
journal, November 2008
- Kim, Do Kyung; Muralidharan, P.; Lee, Hyun-Wook
- Nano Letters, Vol. 8, Issue 11
O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries
journal, December 2014
- Li, Xin; Wu, Di; Zhou, Yong-Ning
- Electrochemistry Communications, Vol. 49
Lithium and sodium battery cathode materials: computational insights into voltage, diffusion and nanostructural properties
journal, January 2014
- Islam, M. Saiful; Fisher, Craig A. J.
- Chem. Soc. Rev., Vol. 43, Issue 1
A new class of high capacity cation-disordered oxides for rechargeable lithium batteries: Li–Ni–Ti–Mo oxides
journal, January 2015
- Lee, Jinhyuk; Seo, Dong-Hwa; Balasubramanian, Mahalingam
- Energy & Environmental Science, Vol. 8, Issue 11
Hybrid density functional calculations of redox potentials and formation energies of transition metal compounds
journal, August 2010
- Chevrier, V. L.; Ong, S. P.; Armiento, R.
- Physical Review B, Vol. 82, Issue 7
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
Electrochemical Properties of Monoclinic NaNiO 2
journal, November 2012
- Vassilaras, Plousia; Ma, Xiaohua; Li, Xin
- Journal of The Electrochemical Society, Vol. 160, Issue 2
High-Performance P2-Type Na 2/3 (Mn 1/2 Fe 1/4 Co 1/4 )O 2 Cathode Material with Superior Rate Capability for Na-Ion Batteries
journal, September 2015
- Liu, Lei; Li, Xin; Bo, Shou-Hang
- Advanced Energy Materials, Vol. 5, Issue 22
Combined First-Principle Calculations and Experimental Study on Multi-Component Olivine Cathode for Lithium Rechargeable Batteries
journal, October 2009
- Gwon, Hyeokjo; Seo, Dong-Hwa; Kim, Sung-Wook
- Advanced Functional Materials, Vol. 19, Issue 20
In situ XAFS analysis of the LixNi0.8Co0.2O2 cathode during cycling in lithium batteries
journal, July 2002
- Johnson, C. S.; Kropf, A. J.
- Electrochimica Acta, Vol. 47, Issue 19
Structure and Properties of Alkali Cobalt Double Oxides A 0.6 CoO 2 (A = Li, Na, and K)
journal, October 2009
- Pollet, Michaël; Blangero, Maxime; Doumerc, Jean-Pierre
- Inorganic Chemistry, Vol. 48, Issue 20
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Vacancy Ordering in -Type Layered Metal Oxide Sodium-Ion Battery Cathodes
journal, December 2015
- Toumar, Alexandra J.; Ong, Shyue Ping; Richards, William Davidson
- Physical Review Applied, Vol. 4, Issue 6
On the NaxNi0.6Co0.4O2System: Physical and Electrochemical Studies
journal, February 1996
- Saadoune, I.; Maazaz, A.; Ménétrier, M.
- Journal of Solid State Chemistry, Vol. 122, Issue 1
Electrochemical properties of NaNi1/3Co1/3Fe1/3O2 as a cathode material for Na-ion batteries
journal, January 2014
- Vassilaras, Plousia; Toumar, Alexandra J.; Ceder, Gerbrand
- Electrochemistry Communications, Vol. 38
Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries
journal, June 2013
- Masquelier, Christian; Croguennec, Laurence
- Chemical Reviews, Vol. 113, Issue 8
Insights into Diffusion Mechanisms in P2 Layered Oxide Materials by First-Principles Calculations
journal, September 2014
- Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand
- Chemistry of Materials, Vol. 26, Issue 18
Redox Potential Paradox in Na x MO 2 for Sodium-Ion Battery Cathodes
journal, February 2016
- Nanba, Yusuke; Iwao, Tatsumi; Boisse, Benoit Mortemard de
- Chemistry of Materials, Vol. 28, Issue 4
Electrochemical Properties of Monoclinic NaMnO2
journal, January 2011
- Ma, Xiaohua; Chen, Hailong; Ceder, Gerbrand
- Journal of The Electrochemical Society, Vol. 158, Issue 12
Comprehensive Investigation of the Na 3 V 2 (PO 4 ) 2 F 3 –NaV 2 (PO 4 ) 2 F 3 System by Operando High Resolution Synchrotron X-ray Diffraction
journal, April 2015
- Bianchini, M.; Fauth, F.; Brisset, N.
- Chemistry of Materials, Vol. 27, Issue 8
Strain Accommodation during Phase Transformations in Olivine-Based Cathodes as a Materials Selection Criterion for High-Power Rechargeable Batteries
journal, March 2007
- Meethong, N.; Huang, H. -Y. S.; Speakman, S. A.
- Advanced Functional Materials, Vol. 17, Issue 7
Li Conductivity in Li[sub x]MPO[sub 4] (M = Mn, Fe, Co, Ni) Olivine Materials
journal, January 2004
- Morgan, D.; Van der Ven, A.; Ceder, G.
- Electrochemical and Solid-State Letters, Vol. 7, Issue 2
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
journal, February 2006
- Kang, Kisuk; Shirley Meng, Ying; Breger, Julien
- Science, Vol. 311, Issue 5763, p. 977-980
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
The Spinel Phase of LiMn[sub 2]O[sub 4] as a Cathode in Secondary Lithium Cells
journal, January 1991
- Tarascon, J. M.
- Journal of The Electrochemical Society, Vol. 138, Issue 10
White lines and -band occupancy for the transition-metal oxides and lithium transition-metal oxides
journal, June 2004
- Graetz, Jason; Ahn, Channing C.; Ouyang, Hao
- Physical Review B, Vol. 69, Issue 23
Hydrothermal synthesis of high surface LiFePO4 powders as cathode for Li-ion cells
journal, September 2006
- Meligrana, G.; Gerbaldi, C.; Tuel, A.
- Journal of Power Sources, Vol. 160, Issue 1
Electrical Energy Storage and Intercalation Chemistry
journal, June 1976
- Whittingham, M. S.
- Science, Vol. 192, Issue 4244
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013
- Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
- APL Materials, Vol. 1, Issue 1
Lithium insertion into manganese spinels
journal, April 1983
- Thackeray, M. M.; David, W. I. F.; Bruce, P. G.
- Materials Research Bulletin, Vol. 18, Issue 4, p. 461-472
Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO[sub 2] Thin Films Grown by Pulsed Laser Deposition
journal, January 2007
- Xia, H.; Lu, L.; Meng, Y. S.
- Journal of The Electrochemical Society, Vol. 154, Issue 4
Identification of cathode materials for lithium batteries guided by first-principles calculations
journal, April 1998
- Ceder, G.; Chiang, Y. -M.; Sadoway, D. R.
- Nature, Vol. 392, Issue 6677
NaFe0.5Co0.5O2 as high energy and power positive electrode for Na-ion batteries
journal, September 2013
- Yoshida, Hiroaki; Yabuuchi, Naoaki; Komaba, Shinichi
- Electrochemistry Communications, Vol. 34
Iron-Substituted Nickel Oxyhydroxides and Hydroxides Obtained by Chimie Douce
journal, June 1993
- Demourgues-Guerlou, L.; Braconnier, J. J.; Delmas, C.
- Journal of Solid State Chemistry, Vol. 104, Issue 2
Formation enthalpies by mixing GGA and GGA calculations
journal, July 2011
- Jain, Anubhav; Hautier, Geoffroy; Ong, Shyue Ping
- Physical Review B, Vol. 84, Issue 4
Role of Ligand-to-Metal Charge Transfer in O3-Type NaFeO 2 –NaNiO 2 Solid Solution for Enhanced Electrochemical Properties
journal, January 2014
- Wang, Xianfen; Liu, Guandong; Iwao, Tatsumi
- The Journal of Physical Chemistry C, Vol. 118, Issue 6
Investigation of the NaNi x Mn 1-x O 2 (0 ≤ x ≤ 1) System for Na-Ion Battery Cathode Materials
journal, December 2014
- Fielden, R.; Obrovac, M. N.
- Journal of The Electrochemical Society, Vol. 162, Issue 3
Analysis of Charged State Stability for Monoclinic LiMnBO 3 Cathode
journal, July 2014
- Kim, Jae Chul; Li, Xin; Moore, Charles J.
- Chemistry of Materials, Vol. 26, Issue 14
A high-throughput infrastructure for density functional theory calculations
journal, June 2011
- Jain, Anubhav; Hautier, Geoffroy; Moore, Charles J.
- Computational Materials Science, Vol. 50, Issue 8
Li2Fe(SO4)2 as a 3.83V positive electrode material
journal, July 2012
- Reynaud, Marine; Ati, Mohamed; Melot, Brent C.
- Electrochemistry Communications, Vol. 21
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012
- Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
- Nature Materials, Vol. 11, Issue 6
Theoretical capacity achieved in a LiMn 0.5 Fe 0.4 Mg 0.1 BO 3 cathode by using topological disorder
journal, January 2015
- Kim, Jae Chul; Seo, Dong-Hwa; Ceder, Gerbrand
- Energy & Environmental Science, Vol. 8, Issue 6
Electrochemical intercalation and deintercalation of NaxMnO2 bronzes
journal, May 1985
- Mendiboure, A.; Delmas, C.; Hagenmuller, P.
- Journal of Solid State Chemistry, Vol. 57, Issue 3
Oxidation energies of transition metal oxides within the framework
journal, May 2006
- Wang, Lei; Maxisch, Thomas; Ceder, Gerbrand
- Physical Review B, Vol. 73, Issue 19
The Effect of Antisite Disorder and Particle Size on Li Intercalation Kinetics in Monoclinic LiMnBO 3
journal, January 2015
- Kim, Jae Chul; Seo, Dong-Hwa; Chen, Hailong
- Advanced Energy Materials, Vol. 5, Issue 8
Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi 1 / 3 Mn 1 / 3 Co 1 / 3 O 2
journal, April 2012
- Sathiya, M.; Hemalatha, K.; Ramesha, K.
- Chemistry of Materials, Vol. 24, Issue 10
Synthesis and electrochemistry of new layered (1−x)LiVO2·xLi2TiO3 (0≤x≤0.6) electrode materials
journal, December 2007
- Zhang, Lianqi; Takada, Kazunori; Ohta, Narumi
- Journal of Power Sources, Vol. 174, Issue 2
Structural classification and properties of the layered oxides
journal, January 1980
- Delmas, C.; Fouassier, C.; Hagenmuller, P.
- Physica B+C, Vol. 99, Issue 1-4
Electronic Structure of Transition Metal Ions in Deintercalated and Reintercalated LiCo[sub 0.5]Ni[sub 0.5]O[sub 2]
journal, January 2000
- Montoro, L. A.; Abbate, M.; Rosolen, J. M.
- Journal of The Electrochemical Society, Vol. 147, Issue 5
LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980
- Mizushima, K.; Jones, P. C.; Wiseman, P. J.
- Materials Research Bulletin, Vol. 15, Issue 6
Jahn–Teller Assisted Na Diffusion for High Performance Na Ion Batteries
journal, September 2016
- Li, Xin; Wang, Yan; Wu, Di
- Chemistry of Materials, Vol. 28, Issue 18
Sulfate-Based Polyanionic Compounds for Li-Ion Batteries: Synthesis, Crystal Chemistry, and Electrochemistry Aspects
journal, September 2013
- Rousse, G.; Tarascon, J. M.
- Chemistry of Materials, Vol. 26, Issue 1
Etude par desintercalation electrochimique des systemes NaxCrO2 et NaxNiO2
journal, August 1982
- Braconnier, J. J.; Delmas, C.; Hagenmuller, P.
- Materials Research Bulletin, Vol. 17, Issue 8
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis
journal, February 2013
- Ong, Shyue Ping; Richards, William Davidson; Jain, Anubhav
- Computational Materials Science, Vol. 68
A Combined Computational/Experimental Study on LiNi 1/3 Co 1/3 Mn 1/3 O 2
journal, September 2003
- Hwang, B. J.; Tsai, Y. W.; Carlier, D.
- Chemistry of Materials, Vol. 15, Issue 19
Structure and Electrochemistry of Na x Fe x Ti 1-x O 2 (1.0 ≥ x ≥ 0.75) for Na-Ion Battery Positive Electrodes
journal, January 2014
- Thorne, J. S.; Chowdhury, S.; Dunlap, R. A.
- Journal of The Electrochemical Society, Vol. 161, Issue 12
Porous Electrode Materials for Lithium-Ion Batteries - How to Prepare Them and What Makes Them Special
journal, August 2012
- Vu, Anh; Qian, Yuqiang; Stein, Andreas
- Advanced Energy Materials, Vol. 2, Issue 9
Lithium Batteries and Cathode Materials
journal, December 2004
- Whittingham, M. Stanley
- ChemInform, Vol. 35, Issue 50
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020
- Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna
- Scientific Reports, Vol. 10, Issue 1
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries.
journal, May 2006
- Kang, Kisuk; Meng, Ying Shirley; Breger, Julien
- ChemInform, Vol. 37, Issue 20
Works referencing / citing this record:
Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance
journal, November 2017
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Advanced Energy Materials, Vol. 8, Issue 8
A Chemical Approach to Raise Cell Voltage and Suppress Phase Transition in O3 Sodium Layered Oxide Electrodes
journal, January 2018
- Sathiya, Mariyappan; Jacquet, Quentin; Doublet, Marie-Liesse
- Advanced Energy Materials, Vol. 8, Issue 11
Electrochemistry and Solid‐State Chemistry of NaMeO 2 (Me = 3d Transition Metals)
journal, June 2018
- Kubota, Kei; Kumakura, Shinichi; Yoda, Yusuke
- Advanced Energy Materials, Vol. 8, Issue 17
A First-Principles and Experimental Investigation of Nickel Solubility into the P2 Na x CoO 2 Sodium-Ion Cathode
journal, August 2018
- Bianchini, Matteo; Wang, Jingyang; Clément, Raphaële
- Advanced Energy Materials, Vol. 8, Issue 26
High‐Abundance and Low‐Cost Metal‐Based Cathode Materials for Sodium‐Ion Batteries: Problems, Progress, and Key Technologies
journal, February 2019
- Chen, Mingzhe; Liu, Qiannan; Wang, Shi‐Wen
- Advanced Energy Materials, Vol. 9, Issue 14
Suppressing Cation Migration and Reducing Particle Cracks in a Layered Fe‐Based Cathode for Advanced Sodium‐Ion Batteries
journal, December 2019
- Xu, Jialu; Han, Zhen; Jiang, Kezhu
- Small, Vol. 16, Issue 3
O3‐Type Layered Ni‐Rich Oxide: A High‐Capacity and Superior‐Rate Cathode for Sodium‐Ion Batteries
journal, December 2019
- Yang, Jun; Tang, Manjing; Liu, Hao
- Small, Vol. 15, Issue 52
In Situ Investigation of Layered Oxides with Mixed Structures for Sodium‐Ion Batteries
journal, May 2019
- Keller, Marlou; Eisenmann, Tobias; Meira, Debora
- Small Methods, Vol. 3, Issue 11
Ni-based cathode materials for Na-ion batteries
journal, June 2019
- Zhao, Chenglong; Lu, Yaxiang; Chen, Liquan
- Nano Research, Vol. 12, Issue 9
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures
journal, January 2019
- Wang, Shenghan; Sun, Chenglin; Wang, Ning
- Journal of Materials Chemistry A, Vol. 7, Issue 17
Understanding intercalation compounds for sodium-ion batteries and beyond
journal, July 2019
- Kaufman, Jonas L.; Vinckevičiūtė, Julija; Krishna Kolli, Sanjeev
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2152