Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel
Abstract
The electrochemical properties of NaNi0.5Co0.5O2 and NaNi0.5Fe0.5O2 and their structural transitions as a function of Na extraction associated with redox reactions are investigated. Synthesized in the O3-type layered structure, both materials show reasonable electrochemical activities at room temperature, delivering approximately 0.5 Na per formula unit at C/10 discharge. More Na can be reversibly cycled in NaNi0.5Co0.5O2 at elevated temperature and/or in an extended voltage window, while NaNi0.5Fe0.5O2 shows significant capacity fading at a high voltage cutoff which is likely due to Fe4+ migration. In situ X-ray diffraction shows that the structural changes in the two materials upon desodiation are very different. NaNi0.5Co0.5O2 goes through many different two-phase reactions including three different O3-type and three different P3-type structures during cycling, producing a voltage profile with multiple plateau-like features. In contrast, NaNi0.5Fe0.5O2 has a smooth voltage profile and shows the typical O3–P3 phase transition without lattice distortion seen in other materials. Finally, this different structural evolution upon desodiation and re-sodiation can be explained by the electronic structure of the mixed transition metals and how it perturbs the ordering between Na ions differently.
- Authors:
-
[4]
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
- Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering; Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Science Foundation (NSF); Samsung Advanced Inst. of Technology (Korea, Republic of)
- OSTI Identifier:
- 1475004
- Grant/Contract Number:
- AC02-05CH11231; ACI-1053575
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 9; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Vassilaras, Plousia, Kwon, Deok-Hwang, Dacek, Stephen T., Shi, Tan, Seo, Dong-Hwa, Ceder, Gerbrand, and Kim, Jae Chul. Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel. United States: N. p., 2017.
Web. doi:10.1039/c6ta09220a.
Vassilaras, Plousia, Kwon, Deok-Hwang, Dacek, Stephen T., Shi, Tan, Seo, Dong-Hwa, Ceder, Gerbrand, & Kim, Jae Chul. Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel. United States. https://doi.org/10.1039/c6ta09220a
Vassilaras, Plousia, Kwon, Deok-Hwang, Dacek, Stephen T., Shi, Tan, Seo, Dong-Hwa, Ceder, Gerbrand, and Kim, Jae Chul. Mon .
"Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel". United States. https://doi.org/10.1039/c6ta09220a. https://www.osti.gov/servlets/purl/1475004.
@article{osti_1475004,
title = {Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel},
author = {Vassilaras, Plousia and Kwon, Deok-Hwang and Dacek, Stephen T. and Shi, Tan and Seo, Dong-Hwa and Ceder, Gerbrand and Kim, Jae Chul},
abstractNote = {The electrochemical properties of NaNi0.5Co0.5O2 and NaNi0.5Fe0.5O2 and their structural transitions as a function of Na extraction associated with redox reactions are investigated. Synthesized in the O3-type layered structure, both materials show reasonable electrochemical activities at room temperature, delivering approximately 0.5 Na per formula unit at C/10 discharge. More Na can be reversibly cycled in NaNi0.5Co0.5O2 at elevated temperature and/or in an extended voltage window, while NaNi0.5Fe0.5O2 shows significant capacity fading at a high voltage cutoff which is likely due to Fe4+ migration. In situ X-ray diffraction shows that the structural changes in the two materials upon desodiation are very different. NaNi0.5Co0.5O2 goes through many different two-phase reactions including three different O3-type and three different P3-type structures during cycling, producing a voltage profile with multiple plateau-like features. In contrast, NaNi0.5Fe0.5O2 has a smooth voltage profile and shows the typical O3–P3 phase transition without lattice distortion seen in other materials. Finally, this different structural evolution upon desodiation and re-sodiation can be explained by the electronic structure of the mixed transition metals and how it perturbs the ordering between Na ions differently.},
doi = {10.1039/c6ta09220a},
journal = {Journal of Materials Chemistry. A},
number = 9,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}
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Ni-based cathode materials for Na-ion batteries
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- Zhao, Chenglong; Lu, Yaxiang; Chen, Liquan
- Nano Research, Vol. 12, Issue 9
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures
journal, January 2019
- Wang, Shenghan; Sun, Chenglin; Wang, Ning
- Journal of Materials Chemistry A, Vol. 7, Issue 17
Understanding intercalation compounds for sodium-ion batteries and beyond
journal, July 2019
- Kaufman, Jonas L.; Vinckevičiūtė, Julija; Krishna Kolli, Sanjeev
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2152