Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel

Vassilaras, Plousia; Kwon, Deok-Hwang; Dacek, Stephen T.; Shi, Tan; Seo, Dong-Hwa; Ceder, Gerbrand; Kim, Jae Chul

doi:10.1039/c6ta09220a

Title: Electrochemical properties and structural evolution of O3-type layered sodium mixed transition metal oxides with trivalent nickel

Journal Article · 30 January 2017 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/c6ta09220a · OSTI ID:1475004

Vassilaras, Plousia ^[1]; Kwon, Deok-Hwang ^[2]; Dacek, Stephen T. ^[1]; Shi, Tan ^[2]; Seo, Dong-Hwa ^[2]; Ceder, Gerbrand ^[3];

^[4]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering; Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division

The electrochemical properties of NaNi_0.5Co_0.5O₂ and NaNi_0.5Fe_0.5O₂ and their structural transitions as a function of Na extraction associated with redox reactions are investigated. Synthesized in the O3-type layered structure, both materials show reasonable electrochemical activities at room temperature, delivering approximately 0.5 Na per formula unit at C/10 discharge. More Na can be reversibly cycled in NaNi_0.5Co_0.5O₂ at elevated temperature and/or in an extended voltage window, while NaNi_0.5Fe_0.5O₂ shows significant capacity fading at a high voltage cutoff which is likely due to Fe⁴⁺ migration. In situ X-ray diffraction shows that the structural changes in the two materials upon desodiation are very different. NaNi_0.5Co_0.5O₂ goes through many different two-phase reactions including three different O3-type and three different P3-type structures during cycling, producing a voltage profile with multiple plateau-like features. In contrast, NaNi_0.5Fe_0.5O₂ has a smooth voltage profile and shows the typical O3–P3 phase transition without lattice distortion seen in other materials. Finally, this different structural evolution upon desodiation and re-sodiation can be explained by the electronic structure of the mixed transition metals and how it perturbs the ordering between Na ions differently.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC); National Science Foundation (NSF); Samsung Advanced Inst. of Technology (Korea, Republic of)

Grant/Contract Number:: AC02-05CH11231; ACI-1053575

OSTI ID:: 1475004

Journal Information:: Journal of Materials Chemistry. A, Vol. 5, Issue 9; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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A Chemical Approach to Raise Cell Voltage and Suppress Phase Transition in O3 Sodium Layered Oxide Electrodes Sathiya, Mariyappan; Jacquet, Quentin; Doublet, Marie-Liesse Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702599	journal	January 2018
Electrochemistry and Solid‐State Chemistry of NaMeO ₂ (Me = 3d Transition Metals) Kubota, Kei; Kumakura, Shinichi; Yoda, Yusuke Advanced Energy Materials, Vol. 8, Issue 17 https://doi.org/10.1002/aenm.201703415	journal	June 2018
A First-Principles and Experimental Investigation of Nickel Solubility into the P2 Na _x CoO ₂ Sodium-Ion Cathode Bianchini, Matteo; Wang, Jingyang; Clément, Raphaële Advanced Energy Materials, Vol. 8, Issue 26 https://doi.org/10.1002/aenm.201801446	journal	August 2018
High‐Abundance and Low‐Cost Metal‐Based Cathode Materials for Sodium‐Ion Batteries: Problems, Progress, and Key Technologies Chen, Mingzhe; Liu, Qiannan; Wang, Shi‐Wen Advanced Energy Materials, Vol. 9, Issue 14 https://doi.org/10.1002/aenm.201803609	journal	February 2019
Suppressing Cation Migration and Reducing Particle Cracks in a Layered Fe‐Based Cathode for Advanced Sodium‐Ion Batteries Xu, Jialu; Han, Zhen; Jiang, Kezhu Small, Vol. 16, Issue 3 https://doi.org/10.1002/smll.201904388	journal	December 2019
O3‐Type Layered Ni‐Rich Oxide: A High‐Capacity and Superior‐Rate Cathode for Sodium‐Ion Batteries Yang, Jun; Tang, Manjing; Liu, Hao Small, Vol. 15, Issue 52 https://doi.org/10.1002/smll.201905311	journal	December 2019
In Situ Investigation of Layered Oxides with Mixed Structures for Sodium‐Ion Batteries Keller, Marlou; Eisenmann, Tobias; Meira, Debora Small Methods, Vol. 3, Issue 11 https://doi.org/10.1002/smtd.201900239	journal	May 2019
Ni-based cathode materials for Na-ion batteries Zhao, Chenglong; Lu, Yaxiang; Chen, Liquan Nano Research, Vol. 12, Issue 9 https://doi.org/10.1007/s12274-019-2451-3	journal	June 2019
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures Wang, Shenghan; Sun, Chenglin; Wang, Ning Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c8ta12441h	journal	January 2019
Understanding intercalation compounds for sodium-ion batteries and beyond Kaufman, Jonas L.; Vinckevičiūtė, Julija; Krishna Kolli, Sanjeev Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2152 https://doi.org/10.1098/rsta.2019.0020	journal	July 2019

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