Reversible (De)Intercalation of Hydrated Zn2+ in Mg2+ -Stabilized V2O5 Nanobelts with High Areal Capacity
Abstract
The rechargeable aqueous zinc ion battery (ZIB) is regarded as one of the most promising candidates for large-scale energy storage applications due to its low-cost and eco-friendly properties. However, the development of a suitable cathode operating with high areal capacity and uncovering the relevant reaction mechanisms remain challenging. Herein, the application of Mg0.26V2O5∙0.73H2O (MVO) nanobelts as a ZIB cathode is demonstrated. In situ FT-IR reveals the shift of OH stretching from 3350 cm-1 to 3200 cm-1, corresponding to the hydration shell of Zn2+, while in situ Raman suggests the interlayer charges creening effect, which would boost the intercalation of hydrated Zn2+. Density function theory reveals that the hydrated Zn2+ can lower the Coulombic repulsion at the electrode-electrolyte interface and circumvents the desolvation penalty of hydrated Zn2+ during the (de)intercalation process. Additionally, excellent structure stability and large interlayer spacing guarantee the highly reversible (de)intercalation of hydrated Zn2+. Therefore, the MVO nanobelts exhibit a high areal capacity of 2.12 mAh cm-2 at 0.05 A g-1, outstanding cycling stability of 2500 cycles at 10 A g-1 with a mass loading of 5 mg cm-2. Finally, it is believed that the use of hydrated intercalation charge carriers will boost further studies in other multivalentmore »
- Authors:
-
[3]
- Shanghai Univ. (China)
- Wuhan Univ. of Technology (China)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Department of Chemistry Institute of New Energy Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) Fudan University Shanghai 200433 P. R. China
- Shanghai Univ. (China); Wuhan Univ. of Technology (China)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE); National Natural Science Foundation of China (NSFC); Shanghai Pujiang Program; China Baowu Steel Group Corp. Ltd.; Science and Technology Commission of Shanghai Municipality
- OSTI Identifier:
- 1756573
- Alternate Identifier(s):
- OSTI ID: 1668101
- Grant/Contract Number:
- AC02-06CH11357; 51874196; 21905169; 51674164; 2019PJD015; U1860203; 19DZ2270200; CERC-CVC2; AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 41; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Mg0.26V2O5·0.73H2O; Zinc-ion battery; in-situ FT-IR spectrum; in-situ Raman spectrum; zinc intercalation/deintercalation
Citation Formats
Wang, Na, Sun, Congli, Liao, Xiaobing, Yuan, Yifei, Cheng, Hongwei, Sun, Qiangchao, Wang, Bingliang, Pan, Xuelei, Zhao, Kangning, Xu, Qian, Lu, Xionggang, and Lu, Jun. Reversible (De)Intercalation of Hydrated Zn2+ in Mg2+ -Stabilized V2O5 Nanobelts with High Areal Capacity. United States: N. p., 2020.
Web. doi:10.1002/aenm.202002293.
Wang, Na, Sun, Congli, Liao, Xiaobing, Yuan, Yifei, Cheng, Hongwei, Sun, Qiangchao, Wang, Bingliang, Pan, Xuelei, Zhao, Kangning, Xu, Qian, Lu, Xionggang, & Lu, Jun. Reversible (De)Intercalation of Hydrated Zn2+ in Mg2+ -Stabilized V2O5 Nanobelts with High Areal Capacity. United States. https://doi.org/10.1002/aenm.202002293
Wang, Na, Sun, Congli, Liao, Xiaobing, Yuan, Yifei, Cheng, Hongwei, Sun, Qiangchao, Wang, Bingliang, Pan, Xuelei, Zhao, Kangning, Xu, Qian, Lu, Xionggang, and Lu, Jun. Sun .
"Reversible (De)Intercalation of Hydrated Zn2+ in Mg2+ -Stabilized V2O5 Nanobelts with High Areal Capacity". United States. https://doi.org/10.1002/aenm.202002293. https://www.osti.gov/servlets/purl/1756573.
@article{osti_1756573,
title = {Reversible (De)Intercalation of Hydrated Zn2+ in Mg2+ -Stabilized V2O5 Nanobelts with High Areal Capacity},
author = {Wang, Na and Sun, Congli and Liao, Xiaobing and Yuan, Yifei and Cheng, Hongwei and Sun, Qiangchao and Wang, Bingliang and Pan, Xuelei and Zhao, Kangning and Xu, Qian and Lu, Xionggang and Lu, Jun},
abstractNote = {The rechargeable aqueous zinc ion battery (ZIB) is regarded as one of the most promising candidates for large-scale energy storage applications due to its low-cost and eco-friendly properties. However, the development of a suitable cathode operating with high areal capacity and uncovering the relevant reaction mechanisms remain challenging. Herein, the application of Mg0.26V2O5∙0.73H2O (MVO) nanobelts as a ZIB cathode is demonstrated. In situ FT-IR reveals the shift of OH stretching from 3350 cm-1 to 3200 cm-1, corresponding to the hydration shell of Zn2+, while in situ Raman suggests the interlayer charges creening effect, which would boost the intercalation of hydrated Zn2+. Density function theory reveals that the hydrated Zn2+ can lower the Coulombic repulsion at the electrode-electrolyte interface and circumvents the desolvation penalty of hydrated Zn2+ during the (de)intercalation process. Additionally, excellent structure stability and large interlayer spacing guarantee the highly reversible (de)intercalation of hydrated Zn2+. Therefore, the MVO nanobelts exhibit a high areal capacity of 2.12 mAh cm-2 at 0.05 A g-1, outstanding cycling stability of 2500 cycles at 10 A g-1 with a mass loading of 5 mg cm-2. Finally, it is believed that the use of hydrated intercalation charge carriers will boost further studies in other multivalent rechargeable batteries.},
doi = {10.1002/aenm.202002293},
journal = {Advanced Energy Materials},
number = 41,
volume = 10,
place = {United States},
year = {Sun Sep 27 00:00:00 EDT 2020},
month = {Sun Sep 27 00:00:00 EDT 2020}
}
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