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Title: NaCa 0.6 V 6 O 16 ·3H 2 O as an Ultra‐Stable Cathode for Zn‐Ion Batteries: The Roles of Pre‐Inserted Dual‐Cations and Structural Water in V 3 O 8 Layer

Authors:
 [1];  [1]; ORCiD logo [1]
  1. Department of Mechanical Engineering University of South Carolina Columbia SC 29201 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1559052
Grant/Contract Number:  
DE‐AR0000492
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 9 Journal Issue: 38; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zhu, Kaiyue, Wu, Tao, and Huang, Kevin. NaCa 0.6 V 6 O 16 ·3H 2 O as an Ultra‐Stable Cathode for Zn‐Ion Batteries: The Roles of Pre‐Inserted Dual‐Cations and Structural Water in V 3 O 8 Layer. Germany: N. p., 2019. Web. https://doi.org/10.1002/aenm.201901968.
Zhu, Kaiyue, Wu, Tao, & Huang, Kevin. NaCa 0.6 V 6 O 16 ·3H 2 O as an Ultra‐Stable Cathode for Zn‐Ion Batteries: The Roles of Pre‐Inserted Dual‐Cations and Structural Water in V 3 O 8 Layer. Germany. https://doi.org/10.1002/aenm.201901968
Zhu, Kaiyue, Wu, Tao, and Huang, Kevin. Wed . "NaCa 0.6 V 6 O 16 ·3H 2 O as an Ultra‐Stable Cathode for Zn‐Ion Batteries: The Roles of Pre‐Inserted Dual‐Cations and Structural Water in V 3 O 8 Layer". Germany. https://doi.org/10.1002/aenm.201901968.
@article{osti_1559052,
title = {NaCa 0.6 V 6 O 16 ·3H 2 O as an Ultra‐Stable Cathode for Zn‐Ion Batteries: The Roles of Pre‐Inserted Dual‐Cations and Structural Water in V 3 O 8 Layer},
author = {Zhu, Kaiyue and Wu, Tao and Huang, Kevin},
abstractNote = {},
doi = {10.1002/aenm.201901968},
journal = {Advanced Energy Materials},
number = 38,
volume = 9,
place = {Germany},
year = {2019},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/aenm.201901968

Citation Metrics:
Cited by: 24 works
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Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

K 2 V 6 O 16 ·2.7H 2 O nanorod cathode: an advanced intercalation system for high energy aqueous rechargeable Zn-ion batteries
journal, January 2018

  • Sambandam, Balaji; Soundharrajan, Vaiyapuri; Kim, Sungjin
  • Journal of Materials Chemistry A, Vol. 6, Issue 32
  • DOI: 10.1039/C8TA02018C

Hydrated Layered Vanadium Oxide as a Highly Reversible Cathode for Rechargeable Aqueous Zinc Batteries
journal, January 2019

  • Zhang, Ning; Jia, Ming; Dong, Yang
  • Advanced Functional Materials, Vol. 29, Issue 10
  • DOI: 10.1002/adfm.201807331

Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode
journal, February 2017


Projector augmented-wave method
journal, December 1994


Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Rechargeable Aqueous Zn–V 2 O 5 Battery with High Energy Density and Long Cycle Life
journal, May 2018


Cation-Deficient Spinel ZnMn 2 O 4 Cathode in Zn(CF 3 SO 3 ) 2 Electrolyte for Rechargeable Aqueous Zn-Ion Battery
journal, September 2016

  • Zhang, Ning; Cheng, Fangyi; Liu, Yongchang
  • Journal of the American Chemical Society, Vol. 138, Issue 39
  • DOI: 10.1021/jacs.6b05958

Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014

  • Augustyn, Veronica; Simon, Patrice; Dunn, Bruce
  • Energy & Environmental Science, Vol. 7, Issue 5
  • DOI: 10.1039/c3ee44164d

Electrochemical Zinc-Ion Intercalation Properties and Crystal Structures of ZnMo 6 S 8 and Zn 2 Mo 6 S 8 Chevrel Phases in Aqueous Electrolytes
journal, March 2016


Li + intercalated V 2 O 5 · n H 2 O with enlarged layer spacing and fast ion diffusion as an aqueous zinc-ion battery cathode
journal, January 2018

  • Yang, Yongqiang; Tang, Yan; Fang, Guozhao
  • Energy & Environmental Science, Vol. 11, Issue 11
  • DOI: 10.1039/C8EE01651H

Recent Advances in Zn-Ion Batteries
journal, August 2018

  • Song, Ming; Tan, Hua; Chao, Dongliang
  • Advanced Functional Materials, Vol. 28, Issue 41
  • DOI: 10.1002/adfm.201802564

Evaluation of Multivalent Cation Insertion in Single- and Double-Layered Polymorphs of V 2 O 5
journal, July 2017

  • Parija, Abhishek; Prendergast, David; Banerjee, Sarbajit
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 28
  • DOI: 10.1021/acsami.7b05556

Mechanistic Insight into the Electrochemical Performance of Zn/VO 2 Batteries with an Aqueous ZnSO 4 Electrolyte
journal, April 2019

  • Li, Zhaolong; Ganapathy, Swapna; Xu, Yaolin
  • Advanced Energy Materials, Vol. 9, Issue 22
  • DOI: 10.1002/aenm.201900237

An Aqueous Zinc-Ion Battery Based on Copper Hexacyanoferrate
journal, December 2014


Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery
journal, December 2011

  • Xu, Chengjun; Li, Baohua; Du, Hongda
  • Angewandte Chemie International Edition, Vol. 51, Issue 4
  • DOI: 10.1002/anie.201106307

Long-life and deeply rechargeable aqueous Zn anodes enabled by a multifunctional brightener-inspired interphase
journal, January 2019

  • Zhao, Zhiming; Zhao, Jingwen; Hu, Zhenglin
  • Energy & Environmental Science, Vol. 12, Issue 6
  • DOI: 10.1039/C9EE00596J

Unraveling the role of structural water in bilayer V 2 O 5 during Zn 2+ -intercalation: insights from DFT calculations
journal, January 2019

  • Wu, Tao; Zhu, Kaiyue; Qin, Changyong
  • Journal of Materials Chemistry A, Vol. 7, Issue 10
  • DOI: 10.1039/C8TA12014E

Zinc-ion batteries: Materials, mechanisms, and applications
journal, January 2019


Zn/MnO 2 Battery Chemistry With H + and Zn 2+ Coinsertion
journal, July 2017

  • Sun, Wei; Wang, Fei; Hou, Singyuk
  • Journal of the American Chemical Society, Vol. 139, Issue 29
  • DOI: 10.1021/jacs.7b04471

Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers
journal, April 2018


Suppressed Activation Energy for Interfacial Charge Transfer of a Prussian Blue Analog Thin Film Electrode with Hydrated Ions (Li + , Na + , and Mg 2+ )
journal, May 2013

  • Mizuno, Yoshifumi; Okubo, Masashi; Hosono, Eiji
  • The Journal of Physical Chemistry C, Vol. 117, Issue 21
  • DOI: 10.1021/jp311616s

XPS and UPS study of Na deposition on thin film V2O5
journal, December 2005


Behavior of Molybdenum Nitrides as Materials for Electrochemical Capacitors
journal, January 1998

  • Liu, T. -C.
  • Journal of The Electrochemical Society, Vol. 145, Issue 6
  • DOI: 10.1149/1.1838571

A Brief Review on Multivalent Intercalation Batteries with Aqueous Electrolytes
journal, February 2016


High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance
journal, April 2013

  • Augustyn, Veronica; Come, Jérémy; Lowe, Michael A.
  • Nature Materials, Vol. 12, Issue 6
  • DOI: 10.1038/nmat3601

First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method
journal, January 1997

  • Anisimov, Vladimir I.; Aryasetiawan, F.; Lichtenstein, A. I.
  • Journal of Physics: Condensed Matter, Vol. 9, Issue 4, p. 767-808
  • DOI: 10.1088/0953-8984/9/4/002

Recent Progress of Rechargeable Batteries Using Mild Aqueous Electrolytes
journal, September 2018


Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities
journal, September 2017


Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Na 2 V 6 O 16 ·3H 2 O Barnesite Nanorod: An Open Door to Display a Stable and High Energy for Aqueous Rechargeable Zn-Ion Batteries as Cathodes
journal, March 2018


High power lithium ion battery materials by computational design
journal, July 2011


Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System
journal, September 2014

  • Zhang, Leyuan; Chen, Liang; Zhou, Xufeng
  • Advanced Energy Materials, Vol. 5, Issue 2
  • DOI: 10.1002/aenm.201400930

Opportunities and challenges for a sustainable energy future
journal, August 2012

  • Chu, Steven; Majumdar, Arun
  • Nature, Vol. 488, Issue 7411, p. 294-303
  • DOI: 10.1038/nature11475

H 2 V 3 O 8 Nanowire/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity
journal, March 2018

  • Pang, Qiang; Sun, Congli; Yu, Yanhao
  • Advanced Energy Materials, Vol. 8, Issue 19
  • DOI: 10.1002/aenm.201800144

Reversible aqueous zinc/manganese oxide energy storage from conversion reactions
journal, April 2016


Zn/V 2 O 5 Aqueous Hybrid-Ion Battery with High Voltage Platform and Long Cycle Life
journal, December 2017

  • Hu, Ping; Yan, Mengyu; Zhu, Ting
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 49
  • DOI: 10.1021/acsami.7b13110

A reduced graphene oxide/Co3O4 composite for supercapacitor electrode
journal, March 2013


High-capacity aqueous zinc batteries using sustainable quinone electrodes
journal, March 2018


Quantitative investigation on the effect of hydrogenation on the performance of MnO 2 /H-TiO 2 composite electrodes for supercapacitors
journal, January 2015

  • Cao, X. Y.; Xing, X.; Zhang, N.
  • Journal of Materials Chemistry A, Vol. 3, Issue 7
  • DOI: 10.1039/C4TA06138A

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965


Layered VS 2 Nanosheet-Based Aqueous Zn Ion Battery Cathode
journal, January 2017


Effect of the damping function in dispersion corrected density functional theory
journal, March 2011

  • Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars
  • Journal of Computational Chemistry, Vol. 32, Issue 7
  • DOI: 10.1002/jcc.21759

Mechanistic Insights of Zn 2+ Storage in Sodium Vanadates
journal, August 2018

  • Guo, Xun; Fang, Guozhao; Zhang, Wenyu
  • Advanced Energy Materials, Vol. 8, Issue 27
  • DOI: 10.1002/aenm.201801819

Highly Durable Na 2 V 6 O 16 ·1.63H 2 O Nanowire Cathode for Aqueous Zinc-Ion Battery
journal, February 2018


Aqueous batteries as grid scale energy storage solutions
journal, February 2017

  • Posada, Jorge Omar Gil; Rennie, Anthony J. R.; Villar, Sofia Perez
  • Renewable and Sustainable Energy Reviews, Vol. 68
  • DOI: 10.1016/j.rser.2016.02.024

Structural water engaged disordered vanadium oxide nanosheets for high capacity aqueous potassium-ion storage
journal, May 2017

  • Charles, Daniel Scott; Feygenson, Mikhail; Page, Katharine
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15520

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Present and Future Perspective on Electrode Materials for Rechargeable Zinc-Ion Batteries
journal, September 2018


High-Performance Aqueous Zinc-Ion Battery Based on Layered H 2 V 3 O 8 Nanowire Cathode
journal, November 2017


Electrochemical Energy Storage for Green Grid
journal, May 2011

  • Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
  • Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
  • DOI: 10.1021/cr100290v

Aqueous Rechargeable Li and Na Ion Batteries
journal, September 2014

  • Kim, Haegyeom; Hong, Jihyun; Park, Kyu-Young
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500232y

Recent Advances in Aqueous Zinc-Ion Batteries
journal, September 2018


Rechargeable Aqueous Zinc-Ion Battery Based on Porous Framework Zinc Pyrovanadate Intercalation Cathode
journal, December 2017


Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface
journal, January 2018

  • Kundu, Dipan; Hosseini Vajargah, Shahrzad; Wan, Liwen
  • Energy & Environmental Science, Vol. 11, Issue 4
  • DOI: 10.1039/C8EE00378E

Inhomogeneous Electron Gas
journal, November 1964


Layered Mg x V 2 O 5 · n H 2 O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries
journal, September 2018


Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles
journal, October 2007

  • Wang, John; Polleux, Julien; Lim, James
  • The Journal of Physical Chemistry C, Vol. 111, Issue 40, p. 14925-14931
  • DOI: 10.1021/jp074464w

Design and Tailoring of the Nanotubular Arrayed Architecture of Hydrous RuO 2 for Next Generation Supercapacitors
journal, December 2006

  • Hu, Chi-Chang; Chang, Kuo-Hsin; Lin, Ming-Champ
  • Nano Letters, Vol. 6, Issue 12
  • DOI: 10.1021/nl061576a

Highly Stable Aqueous Zinc-Ion Storage Using a Layered Calcium Vanadium Oxide Bronze Cathode
journal, February 2018

  • Xia, Chuan; Guo, Jing; Li, Peng
  • Angewandte Chemie International Edition, Vol. 57, Issue 15
  • DOI: 10.1002/anie.201713291

Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014


The role and utilization of pseudocapacitance for energy storage by supercapacitors
journal, May 1997


A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode
journal, August 2016


Water-Lubricated Intercalation in V 2 O 5 ·nH 2 O for High-Capacity and High-Rate Aqueous Rechargeable Zinc Batteries
journal, November 2017


Highly reversible zinc metal anode for aqueous batteries
journal, April 2018