Synthesis, transport properties and electronic structure of p-type Cu1+xMn2–xInTe4(x = 0, 0.2, 0.3)

Hobbis, Dean; Shi, Wencong; Popescu, Adrian; Wei, Kaya; Baumbach, Ryan E.; Wang, Hsin; Woods, Lilia M.; Nolas, George S.

doi:10.1039/C9DT04069B

Title: Synthesis, transport properties and electronic structure of p-type Cu_1+xMn_2–xInTe₄(x = 0, 0.2, 0.3)

Journal Article · 28 January 2020 · Dalton Transactions

DOI: https://doi.org/10.1039/C9DT04069B · OSTI ID:1615196

Hobbis, Dean ^[1]; Shi, Wencong ^[1]; Popescu, Adrian ^[1]; Wei, Kaya ^[2]; Baumbach, Ryan E. ^[3]; Wang, Hsin ^[4];

^[1];

^[1]

Univ. of Florida, Tampa, FL (United States)
Univ. of Florida, Tampa, FL (United States); Florida State Univ., Tallahassee, FL (United States)
Florida State Univ., Tallahassee, FL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The synthesis, electronic structure and temperature dependent transport properties of polycrystalline Cu_1+xMn_2–xInTe₄ (x = 0, 0.2, 0.3) are reported for the first time. These quaternary chalcogenides were synthesized by direct reaction of the elements, followed by solid state annealing and hot press densification. The thermal conductivity is low for all specimens and intrinsic to the material system. Furthermore, the off-stoichiometry specimens illustrate the sensitivity of the transport properties to stoichiometry, with a greater than two-orders-of magnitude increase in carrier concentration with increased Cu content. First principles calculations of the electronic structure are also reported, and are in agreement with the experimental data. Here, this fundamental investigation shows the potential towards further optimization of the electrical properties that, in addition to the intrinsically low thermal conductivity, provides a basis for further research into the viability of this material system for potential energy-related applications.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1615196

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 7 Vol. 49; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Synthesis, transport properties and electronic structure of p-type Cu_1+xMn_2–xInTe₄(x = 0, 0.2, 0.3)