Observation of a -type short-range antiferromagnetic order in layer spacing expanded FeS
Abstract
Here, we report neutron diffraction studies of FeS single crystals obtained from RbxFe2-yS2 single crystals via a hydrothermal method. While no $$\sqrt{5}$$×$$\sqrt{5}$$ iron vacancy order or block antiferromagnetic order typical of RbxFe2-yS2 is found in our samples, we observe C-type short-range antiferromagnetic order with moments pointed along the c axis hosted by a different phase of FeS with an expanded interlayer spacing. The Néel temperature for this magnetic order is determined to be 170 ± 4 K. Our finding of a variant FeS structure hosting this C-type antiferromagnetic order demonstrates that the known FeS phase synthesized in this method is in the vicinity of a magnetically ordered ground state, providing insights into understanding a variety of phenomena observed in FeS and the related FeSe1-xSx iron chalcogenide system.
- Authors:
-
[1];
[5];
[8];
- Sun Yat-Sen Univ., Guangzhou, Guangdong (China); Univ. of California, Berkeley, CA (United States)
- Rice Univ., Houston, TX (United States); Univ. of California, Berkeley, CA (United States)
- Brigham Young Univ., Provo, UT (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sun Yat-Sen Univ., Guangzhou, Guangdong (China)
- National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research; Univ. of Maryland, College Park, MD (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); NSF of Guangdong
- OSTI Identifier:
- 1632138
- Alternate Identifier(s):
- OSTI ID: 1603815; OSTI ID: 1657934
- Grant/Contract Number:
- AC02-05CH11231; 2018A030313055; AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Materials
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 3; Journal ID: ISSN 2475-9953
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Wang, Meng, Yi, Ming, Frandsen, Benjamin A., Yin, Junjie, Sun, Hualei, Xu, Zhijun, Cao, Huibo, Bourret-Courchesne, Edith, Lynn, Jeffrey W., and Birgeneau, Robert J. Observation of a C -type short-range antiferromagnetic order in layer spacing expanded FeS. United States: N. p., 2020.
Web. doi:10.1103/PhysRevMaterials.4.034802.
Wang, Meng, Yi, Ming, Frandsen, Benjamin A., Yin, Junjie, Sun, Hualei, Xu, Zhijun, Cao, Huibo, Bourret-Courchesne, Edith, Lynn, Jeffrey W., & Birgeneau, Robert J. Observation of a C -type short-range antiferromagnetic order in layer spacing expanded FeS. United States. https://doi.org/10.1103/PhysRevMaterials.4.034802
Wang, Meng, Yi, Ming, Frandsen, Benjamin A., Yin, Junjie, Sun, Hualei, Xu, Zhijun, Cao, Huibo, Bourret-Courchesne, Edith, Lynn, Jeffrey W., and Birgeneau, Robert J. Mon .
"Observation of a C -type short-range antiferromagnetic order in layer spacing expanded FeS". United States. https://doi.org/10.1103/PhysRevMaterials.4.034802. https://www.osti.gov/servlets/purl/1632138.
@article{osti_1632138,
title = {Observation of a C -type short-range antiferromagnetic order in layer spacing expanded FeS},
author = {Wang, Meng and Yi, Ming and Frandsen, Benjamin A. and Yin, Junjie and Sun, Hualei and Xu, Zhijun and Cao, Huibo and Bourret-Courchesne, Edith and Lynn, Jeffrey W. and Birgeneau, Robert J.},
abstractNote = {Here, we report neutron diffraction studies of FeS single crystals obtained from RbxFe2-yS2 single crystals via a hydrothermal method. While no $\sqrt{5}$×$\sqrt{5}$ iron vacancy order or block antiferromagnetic order typical of RbxFe2-yS2 is found in our samples, we observe C-type short-range antiferromagnetic order with moments pointed along the c axis hosted by a different phase of FeS with an expanded interlayer spacing. The Néel temperature for this magnetic order is determined to be 170 ± 4 K. Our finding of a variant FeS structure hosting this C-type antiferromagnetic order demonstrates that the known FeS phase synthesized in this method is in the vicinity of a magnetically ordered ground state, providing insights into understanding a variety of phenomena observed in FeS and the related FeSe1-xSx iron chalcogenide system.},
doi = {10.1103/PhysRevMaterials.4.034802},
journal = {Physical Review Materials},
number = 3,
volume = 4,
place = {United States},
year = {Mon Mar 09 00:00:00 EDT 2020},
month = {Mon Mar 09 00:00:00 EDT 2020}
}
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Works referenced in this record:
Suppression of electronic correlations by chemical pressure from FeSe to FeS
journal, September 2017
- Reiss, P.; Watson, M. D.; Kim, T. K.
- Physical Review B, Vol. 96, Issue 12
A model for the temperature dependence of the incoherent scattering from H2 and CH4 in zeolites
journal, January 1986
- Stockmeyer, R.
- Physica B+C, Vol. 136, Issue 1-3
Critical exponents from field theory
journal, May 1980
- Le Guillou, J. C.; Zinn-Justin, J.
- Physical Review B, Vol. 21, Issue 9
Impact of Charge Ordering on Magnetic Correlations in Perovskite
journal, January 1997
- Bao, Wei; Axe, J. D.; Chen, C. H.
- Physical Review Letters, Vol. 78, Issue 3
Superconductivity in the PbO-type structure -FeSe
journal, September 2008
- Hsu, F. -C.; Luo, J. -Y.; Yeh, K. -W.
- Proceedings of the National Academy of Sciences, Vol. 105, Issue 38
Double-Q spin-density wave in iron arsenide superconductors
journal, January 2016
- Allred, J. M.; Taddei, K. M.; Bugaris, D. E.
- Nature Physics, Vol. 12, Issue 5
Mott localization in a pure stripe antiferromagnet
journal, September 2015
- Wang, Meng; Yi, Ming; Cao, Huibo
- Physical Review B, Vol. 92, Issue 12
Magnetic order in from neutron diffraction measurements
journal, September 2009
- Singh, Yogesh; Green, M. A.; Huang, Q.
- Physical Review B, Vol. 80, Issue 10
Two spatially separated phases in semiconducting
journal, September 2014
- Wang, Meng; Tian, Wei; Valdivia, P.
- Physical Review B, Vol. 90, Issue 12
Multiband superconductivity and large anisotropy in FeS crystals
journal, April 2016
- Lin, Hai; Li, Yufeng; Deng, Qiang
- Physical Review B, Vol. 93, Issue 14
Elucidating the magnetic and superconducting phases in the alkali metal intercalated iron chalcogenides
journal, February 2016
- Wang, Meng; Yi, Ming; Tian, Wei
- Physical Review B, Vol. 93, Issue 7
Coexistence of low-moment magnetism and superconductivity in tetragonal FeS and suppression of under pressure
journal, April 2016
- Holenstein, S.; Pachmayr, U.; Guguchia, Z.
- Physical Review B, Vol. 93, Issue 14
Suppression of orbital ordering by chemical pressure in
journal, September 2015
- Watson, M. D.; Kim, T. K.; Haghighirad, A. A.
- Physical Review B, Vol. 92, Issue 12
Neutron diffraction study of the magnetic and structural phase transitions in
journal, May 2009
- Wilson, Stephen D.; Yamani, Z.; Rotundu, C. R.
- Physical Review B, Vol. 79, Issue 18
Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor
journal, May 2011
- Chakoumakos, Bryan C.; Cao, Huibo; Ye, Feng
- Journal of Applied Crystallography, Vol. 44, Issue 3
Maximizing T c by tuning nematicity and magnetism in FeSe1−x S x superconductors
journal, October 2017
- Matsuura, K.; Mizukami, Y.; Arai, Y.
- Nature Communications, Vol. 8, Issue 1
A Novel Large Moment Antiferromagnetic Order in K 0.8 Fe 1.6 Se 2 Superconductor
journal, August 2011
- Bao, Wei; Huang, Qing-Zhen; Chen, Gen-Fu
- Chinese Physics Letters, Vol. 28, Issue 8
Emergence of the nematic electronic state in FeSe
journal, April 2015
- Watson, M. D.; Kim, T. K.; Haghighirad, A. A.
- Physical Review B, Vol. 91, Issue 15
Complex critical magnetic behaviour in three dimensions
journal, August 2007
- Köbler, U.; Hoser, A.; Mueller, R. M.
- Journal of Magnetism and Magnetic Materials, Vol. 315, Issue 1
Strong anisotropy in nearly ideal tetrahedral superconducting FeS single crystals
journal, March 2016
- Borg, Christopher K. H.; Zhou, Xiuquan; Eckberg, Christopher
- Physical Review B, Vol. 93, Issue 9
Orbital-driven nematicity in FeSe
journal, November 2014
- Baek, S-H.; Efremov, D. V.; Ok, J. M.
- Nature Materials, Vol. 14, Issue 2
Nematic Energy Scale and the Missing Electron Pocket in FeSe
journal, December 2019
- Yi, M.; Pfau, H.; Zhang, Y.
- Physical Review X, Vol. 9, Issue 4
Spin excitations and the Fermi surface of superconducting FeS
journal, March 2017
- Man, Haoran; Guo, Jiangang; Zhang, Rui
- npj Quantum Materials, Vol. 2, Issue 1
Lifting of xz / yz orbital degeneracy at the structural transition in detwinned FeSe
journal, September 2014
- Shimojima, T.; Suzuki, Y.; Sonobe, T.
- Physical Review B, Vol. 90, Issue 12
Pressure-induced magnetic order in FeSe: A muon spin rotation study
journal, May 2017
- Khasanov, Rustem; Guguchia, Zurab; Amato, Alex
- Physical Review B, Vol. 95, Issue 18
Crystal and magnetic structure of CaCo As studied by x-ray and neutron diffraction
journal, November 2013
- Quirinale, D. G.; Anand, V. K.; Kim, M. G.
- Physical Review B, Vol. 88, Issue 17
Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR
journal, January 2012
- Lynn, J. W.; Chen, Y.; Chang, S.
- Journal of Research of the National Institute of Standards and Technology, Vol. 117
Tetragonal-to-Orthorhombic Structural Phase Transition at 90 K in the Superconductor
journal, July 2009
- McQueen, T. M.; Williams, A. J.; Stephens, P. W.
- Physical Review Letters, Vol. 103, Issue 5
Iron displacements and magnetoelastic coupling in the antiferromagnetic spin-ladder compound BaFe Se
journal, November 2011
- Caron, J. M.; Neilson, J. R.; Miller, D. C.
- Physical Review B, Vol. 84, Issue 18
High-temperature superconductivity in iron pnictides and chalcogenides
journal, March 2016
- Si, Qimiao; Yu, Rong; Abrahams, Elihu
- Nature Reviews Materials, Vol. 1, Issue 4
What drives nematic order in iron-based superconductors?
journal, January 2014
- Fernandes, R. M.; Chubukov, A. V.; Schmalian, J.
- Nature Physics, Vol. 10, Issue 2
Structure and property correlations in FeS
journal, March 2017
- Kuhn, S. J.; Kidder, M. K.; Parker, D. S.
- Physica C: Superconductivity and its Applications, Vol. 534
Dome of magnetic order inside the nematic phase of sulfur-substituted FeSe under pressure
journal, July 2017
- Xiang, Li; Kaluarachchi, Udhara S.; Böhmer, Anna E.
- Physical Review B, Vol. 96, Issue 2
An Investigation on the Growth and Characterization of Thiourea Single Crystal Grown from Aqueous Solutions
journal, January 1970
- Begum, Sa; Hossain, M.; Podder, J.
- Journal of Bangladesh Academy of Sciences, Vol. 33, Issue 1
Anomalous correlation effects and unique phase diagram of electron-doped FeSe revealed by photoemission spectroscopy
journal, March 2016
- Wen, C. H. P.; Xu, H. C.; Chen, C.
- Nature Communications, Vol. 7, Issue 1
Dome-shaped magnetic order competing with high-temperature superconductivity at high pressures in FeSe
journal, July 2016
- Sun, J. P.; Matsuura, K.; Ye, G. Z.
- Nature Communications, Vol. 7, Issue 1
Universal magnetic and structural behaviors in the iron arsenides
journal, January 2010
- Wilson, Stephen D.; Rotundu, C. R.; Yamani, Z.
- Physical Review B, Vol. 81, Issue 1
Neutron studies of the iron-based family of high TC magnetic superconductors
journal, May 2009
- Lynn, Jeffrey W.; Dai, Pengcheng
- Physica C: Superconductivity, Vol. 469, Issue 9-12
Reconstruction of Band Structure Induced by Electronic Nematicity in an FeSe Superconductor
journal, December 2014
- Nakayama, K.; Miyata, Y.; Phan, G. N.
- Physical Review Letters, Vol. 113, Issue 23
Coexistence of superconductivity and magnetism in FeSe under pressure
journal, February 2012
- Bendele, M.; Ichsanow, A.; Pashkevich, Yu.
- Physical Review B, Vol. 85, Issue 6
Nematic quantum critical point without magnetism in FeSe 1− x S x superconductors
journal, July 2016
- Hosoi, Suguru; Matsuura, Kohei; Ishida, Kousuke
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 29
Strong cooperative coupling of pressure-induced magnetic order and nematicity in FeSe
journal, September 2016
- Kothapalli, K.; Böhmer, A. E.; Jayasekara, W. T.
- Nature Communications, Vol. 7, Issue 1
Critical exponents and equation of state of the three-dimensional Heisenberg universality class
journal, April 2002
- Campostrini, Massimo; Hasenbusch, Martin; Pelissetto, Andrea
- Physical Review B, Vol. 65, Issue 14
The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides
journal, October 2010
- Johnston, David C.
- Advances in Physics, Vol. 59, Issue 6
Pressure Induced Stripe-Order Antiferromagnetism and First-Order Phase Transition in Fese
journal, November 2016
- Wang, P. S.; Sun, S. S.; Cui, Y.
- Physical Review Letters, Vol. 117, Issue 23
Observation of Superconductivity in Tetragonal FeS
journal, August 2015
- Lai, Xiaofang; Zhang, Hui; Wang, Yingqi
- Journal of the American Chemical Society, Vol. 137, Issue 32