Supramolecular and Hybrid Bonding Polymers
Abstract
Staudinger established a century ago the existence of covalent macromolecules, work that led to the development of transformative materials of great benefit to society and a “quantum leap” in our understanding of biological systems. Over the past few decades the concept of supramolecular polymers has emerged–chemical systems in which structural units bond strongly to each other non-covalently. Herein, we discuss how these dynamic systems actually exist in the natural world and can create soft materials with structures, properties, and functions beyond the ones we know in Staudinger polymers. We reflect here on the potential of novel systems in which covalent and supramolecular polymers are chemically integrated and describe them as hybrid bonding polymers. This paper describes the concept with recent examples from the Stupp laboratory, and discusses their potential functions as robotic materials that mimic living matter and structures that offer new ideas on how to recycle and reuse soft materials.
- Authors:
-
[1];
- Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Chicago, IL (United States). Dept. of Medicine
- Northwestern Univ., Evanston, IL (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Bio-Inspired Energy Science (CBES); Northwestern Univ., Evanston, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1767536
- Alternate Identifier(s):
- OSTI ID: 1602094; OSTI ID: 1822874
- Grant/Contract Number:
- SC0000989; FG02-00ER45810; DMR-1508731
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Israel Journal of Chemistry
- Additional Journal Information:
- Journal Volume: 60; Journal Issue: 1-2; Journal ID: ISSN 0021-2148
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (homogeneous); solar (photovoltaic); bio-inspired; charge transport; mesostructured materials; materials and chemistry by design; synthesis (novel materials); synthesis (self-assembly)
Citation Formats
Stupp, Samuel I., Clemons, Tristan D., Carrow, James K., Sai, Hiroaki, and Palmer, Liam C. Supramolecular and Hybrid Bonding Polymers. United States: N. p., 2020.
Web. doi:10.1002/ijch.202000005.
Stupp, Samuel I., Clemons, Tristan D., Carrow, James K., Sai, Hiroaki, & Palmer, Liam C. Supramolecular and Hybrid Bonding Polymers. United States. https://doi.org/10.1002/ijch.202000005
Stupp, Samuel I., Clemons, Tristan D., Carrow, James K., Sai, Hiroaki, and Palmer, Liam C. Fri .
"Supramolecular and Hybrid Bonding Polymers". United States. https://doi.org/10.1002/ijch.202000005. https://www.osti.gov/servlets/purl/1767536.
@article{osti_1767536,
title = {Supramolecular and Hybrid Bonding Polymers},
author = {Stupp, Samuel I. and Clemons, Tristan D. and Carrow, James K. and Sai, Hiroaki and Palmer, Liam C.},
abstractNote = {Staudinger established a century ago the existence of covalent macromolecules, work that led to the development of transformative materials of great benefit to society and a “quantum leap” in our understanding of biological systems. Over the past few decades the concept of supramolecular polymers has emerged–chemical systems in which structural units bond strongly to each other non-covalently. Herein, we discuss how these dynamic systems actually exist in the natural world and can create soft materials with structures, properties, and functions beyond the ones we know in Staudinger polymers. We reflect here on the potential of novel systems in which covalent and supramolecular polymers are chemically integrated and describe them as hybrid bonding polymers. This paper describes the concept with recent examples from the Stupp laboratory, and discusses their potential functions as robotic materials that mimic living matter and structures that offer new ideas on how to recycle and reuse soft materials.},
doi = {10.1002/ijch.202000005},
journal = {Israel Journal of Chemistry},
number = 1-2,
volume = 60,
place = {United States},
year = {Fri Feb 28 00:00:00 EST 2020},
month = {Fri Feb 28 00:00:00 EST 2020}
}
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