skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: An Ordered Ni 6 ‐Ring Superstructure Enables a Highly Stable Sodium Oxide Cathode

Authors:
 [1];  [2];  [3];  [2];  [4];  [2];  [5];  [2];  [4];  [4];  [1];  [4];  [2];  [2];  [1];  [2]; ORCiD logo [1]
  1. CAS Key Laboratory of Molecular Nanostructure and NanotechnologyCAS Research/Education Center for Excellence in Molecular SciencesBeijing National Laboratory for Molecular Sciences (BNLMS)Institute of ChemistryChinese Academy of Sciences (CAS) Beijing 100190 P. R. China, School of Chemical SciencesUniversity of Chinese Academy of Sciences Beijing 100049 P. R. China
  2. School of Advanced MaterialsPeking UniversityShenzhen Graduate School Shenzhen 518055 P. R. China
  3. CAS Key Laboratory of Molecular Nanostructure and NanotechnologyCAS Research/Education Center for Excellence in Molecular SciencesBeijing National Laboratory for Molecular Sciences (BNLMS)Institute of ChemistryChinese Academy of Sciences (CAS) Beijing 100190 P. R. China
  4. Beijing National Laboratory for Condensed Matter PhysicsInstitute of PhysicsCAS Beijing 100190 P. R. China
  5. School of Chemical SciencesUniversity of Chinese Academy of Sciences Beijing 100049 P. R. China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1560746
Grant/Contract Number:  
DE‐AC02‐05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 31 Journal Issue: 43; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Wang, Peng‐Fei, Weng, Mouyi, Xiao, Yao, Hu, Zongxiang, Li, Qinghao, Li, Meng, Wang, Yi‐Ding, Chen, Xin, Yang, Xinan, Wen, Yuren, Yin, Ya‐Xia, Yu, Xiqian, Xiao, Yinguo, Zheng, Jiaxin, Wan, Li‐Jun, Pan, Feng, and Guo, Yu‐Guo. An Ordered Ni 6 ‐Ring Superstructure Enables a Highly Stable Sodium Oxide Cathode. Germany: N. p., 2019. Web. doi:10.1002/adma.201903483.
Wang, Peng‐Fei, Weng, Mouyi, Xiao, Yao, Hu, Zongxiang, Li, Qinghao, Li, Meng, Wang, Yi‐Ding, Chen, Xin, Yang, Xinan, Wen, Yuren, Yin, Ya‐Xia, Yu, Xiqian, Xiao, Yinguo, Zheng, Jiaxin, Wan, Li‐Jun, Pan, Feng, & Guo, Yu‐Guo. An Ordered Ni 6 ‐Ring Superstructure Enables a Highly Stable Sodium Oxide Cathode. Germany. doi:10.1002/adma.201903483.
Wang, Peng‐Fei, Weng, Mouyi, Xiao, Yao, Hu, Zongxiang, Li, Qinghao, Li, Meng, Wang, Yi‐Ding, Chen, Xin, Yang, Xinan, Wen, Yuren, Yin, Ya‐Xia, Yu, Xiqian, Xiao, Yinguo, Zheng, Jiaxin, Wan, Li‐Jun, Pan, Feng, and Guo, Yu‐Guo. Sun . "An Ordered Ni 6 ‐Ring Superstructure Enables a Highly Stable Sodium Oxide Cathode". Germany. doi:10.1002/adma.201903483.
@article{osti_1560746,
title = {An Ordered Ni 6 ‐Ring Superstructure Enables a Highly Stable Sodium Oxide Cathode},
author = {Wang, Peng‐Fei and Weng, Mouyi and Xiao, Yao and Hu, Zongxiang and Li, Qinghao and Li, Meng and Wang, Yi‐Ding and Chen, Xin and Yang, Xinan and Wen, Yuren and Yin, Ya‐Xia and Yu, Xiqian and Xiao, Yinguo and Zheng, Jiaxin and Wan, Li‐Jun and Pan, Feng and Guo, Yu‐Guo},
abstractNote = {},
doi = {10.1002/adma.201903483},
journal = {Advanced Materials},
number = 43,
volume = 31,
place = {Germany},
year = {2019},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adma.201903483

Citation Metrics:
Cited by: 11 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Safety-Enhanced Polymer Electrolytes for Sodium Batteries: Recent Progress and Perspectives
journal, April 2019

  • Yang, Jinfeng; Zhang, Huanrui; Zhou, Qian
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 19
  • DOI: 10.1021/acsami.9b01239

Vacancy Ordering in O 3 -Type Layered Metal Oxide Sodium-Ion Battery Cathodes
journal, December 2015


Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials
journal, December 2013


Branching ratio in x-ray absorption spectroscopy
journal, August 1988


Review—Practical Issues and Future Perspective for Na-Ion Batteries
journal, January 2015

  • Kubota, Kei; Komaba, Shinichi
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0151514jes

Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010

  • Berthelot, R.; Carlier, D.; Delmas, C.
  • Nature Materials, Vol. 10, Issue 1
  • DOI: 10.1038/nmat2920

A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries
journal, January 2015

  • Han, Man Huon; Gonzalo, Elena; Singh, Gurpreet
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE03192J

Stacking-Sequence Changes and Na Ordering in Layered Intercalation Materials
journal, November 2016


Electrochemistry and Solid‐State Chemistry of NaMeO 2 (Me = 3d Transition Metals)
journal, June 2018

  • Kubota, Kei; Kumakura, Shinichi; Yoda, Yusuke
  • Advanced Energy Materials, Vol. 8, Issue 17
  • DOI: 10.1002/aenm.201703415

Thermally and Electrochemically Driven Topotactical Transformations in Sodium Layered Oxides Na x VO 2
journal, February 2016


Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials
journal, January 2015

  • Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P.
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0201514jes

Direct imaging of layered O3- and P2-Na x Fe 1/2 Mn 1/2 O 2 structures at the atomic scale
journal, January 2014

  • Lu, Xia; Wang, Yuesheng; Liu, Pin
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 40
  • DOI: 10.1039/C4CP02957G

Zigzag antiferromagnetic quantum ground state in monoclinic honeycomb lattice antimonates A 3 N i 2 Sb O 6 ( A = Li , Na )
journal, October 2015


Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance
journal, November 2017


High-performance sodium–organic battery by realizing four-sodium storage in disodium rhodizonate
journal, October 2017


P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries
journal, April 2015

  • Wang, Yuesheng; Xiao, Ruijuan; Hu, Yong-Sheng
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7954

Structural evolution and electrochemistry of monoclinic NaNiO2 upon the first cycling process
journal, July 2014


Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials
journal, January 2011

  • Ong, Shyue Ping; Chevrier, Vincent L.; Hautier, Geoffroy
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01782a

Electrochemical Shock in Ion-Intercalation Materials with Limited Solid-Solubility
journal, January 2013

  • Woodford, William H.; Chiang, Yet-Ming; Carter, W. Craig
  • Journal of The Electrochemical Society, Vol. 160, Issue 8
  • DOI: 10.1149/2.104308jes

Ordered and Disordered Polymorphs of Na(Ni 2/3 Sb 1/3 )O 2 : Honeycomb-Ordered Cathodes for Na-Ion Batteries
journal, March 2015

  • Ma, Jeffrey; Bo, Shou-Hang; Wu, Lijun
  • Chemistry of Materials, Vol. 27, Issue 7
  • DOI: 10.1021/cm504339y

Chemically Induced Crack Instability When Electrodes Fracture
journal, January 2012

  • Qi, Yue; Xu, Qingchuan; Van der Ven, Anton
  • Journal of The Electrochemical Society, Vol. 159, Issue 11
  • DOI: 10.1149/2.026211jes

Insight into the origin of lithium/nickel ions exchange in layered Li(NixMnyCoz)O2 cathode materials
journal, July 2018


Routes to High Energy Cathodes of Sodium-Ion Batteries
journal, December 2015

  • Fang, Chun; Huang, Yunhui; Zhang, Wuxing
  • Advanced Energy Materials, Vol. 6, Issue 5
  • DOI: 10.1002/aenm.201501727

Understanding the Air-Exposure Degradation Chemistry at a Nanoscale of Layered Oxide Cathodes for Sodium-Ion Batteries
journal, December 2018


Role of Superexchange Interaction on Tuning of Ni/Li Disordering in Layered Li(Ni x Mn y Co z )O 2
journal, November 2017


Inorganic Aromaticity of Mn 6 -Ring Cluster in Layered Li(Ni 0.5 Mn 0.5 )O 2
journal, February 2018

  • Hu, Zongxiang; Zheng, Jiaxin; Xin, Chao
  • The Journal of Physical Chemistry C, Vol. 122, Issue 8
  • DOI: 10.1021/acs.jpcc.7b10968

Air-Stable NaxTMO2 Cathodes for Sodium Storage
journal, May 2019


Designing Air-Stable O3-Type Cathode Materials by Combined Structure Modulation for Na-Ion Batteries
journal, June 2017

  • Yao, Hu-Rong; Wang, Peng-Fei; Gong, Yue
  • Journal of the American Chemical Society, Vol. 139, Issue 25
  • DOI: 10.1021/jacs.7b05176

Water sensitivity of layered P2/P3-Na x Ni 0.22 Co 0.11 Mn 0.66 O 2 cathode material
journal, January 2014

  • Buchholz, Daniel; Chagas, Luciana Gomes; Vaalma, Christoph
  • J. Mater. Chem. A, Vol. 2, Issue 33
  • DOI: 10.1039/C4TA02627F

Elucidating the origins of phase transformation hysteresis during electrochemical cycling of Li–Sb electrodes
journal, January 2015

  • Chang, Donghee; Huo, Hua; Johnston, Karen E.
  • Journal of Materials Chemistry A, Vol. 3, Issue 37
  • DOI: 10.1039/C5TA06183K

Oxygen 1 s x-ray-absorption edges of transition-metal oxides
journal, September 1989


Reviving lithium cobalt oxide-based lithium secondary batteries-toward a higher energy density
journal, January 2018

  • Wang, Longlong; Chen, Bingbing; Ma, Jun
  • Chemical Society Reviews, Vol. 47, Issue 17
  • DOI: 10.1039/C8CS00322J

Orbital degeneracy as a source of frustration in LiNiO 2
journal, July 2004


A Honeycomb-Layered Na 3 Ni 2 SbO 6 : A High-Rate and Cycle-Stable Cathode for Sodium-Ion Batteries
journal, July 2014


Structural classification and properties of the layered oxides
journal, January 1980


Direct Observation of an Anomalous Spinel-to-Layered Phase Transition Mediated by Crystal Water Intercalation
journal, October 2015

  • Kim, Sangryun; Nam, Kwan Woo; Lee, Soyeon
  • Angewandte Chemie International Edition, Vol. 54, Issue 50
  • DOI: 10.1002/anie.201505487

Solid solution studies of layered honeycomb-ordered phases O3–Na3M2SbO6 (M=Cu, Mg, Ni, Zn)
journal, May 2013


Research Development on Sodium-Ion Batteries
journal, October 2014

  • Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500192f