High-Entropy and Superstructure-Stabilized Layered Oxide Cathodes for Sodium-Ion Batteries
Abstract
Abstract Layered transition metal oxides are appealing cathodes for sodium‐ion batteries due to their overall advantages in energy density and cost. But their stabilities are usually compromised by the complicated phase transition and the oxygen redox, particularly when operating at high voltages, leading to poor structural stability and substantial capacity loss. Here an integrated strategy combing the high‐entropy design with the superlattice‐stabilization to extend the cycle life and enhance the rate capability of layered cathodes is reported. It is shown that the as‐prepared high‐entropy Na 2/3 Li 1/6 Fe 1/6 Co 1/6 Ni 1/6 Mn 1/3 O 2 cathode enables a superlattice structure with Li/transition metal ordering and delivers excellent electrochemical performance that is not affected by the presence of phase transition and oxygen redox. It achieves a high reversible capacity (171.2 mAh g −1 at 0.1 C), a high energy density (531 Wh kg −1 ), extended cycling stability (89.3% capacity retention at 1 C for 90 cycles and 63.7% capacity retention at 5 C after 300 cycles), and excellent fast‐charging capability (78 mAh g −1 at 10 C). This strategy would inspire more rational designs that can be leveraged to improve the reliability of layered cathodes for secondary‐ion batteries.
- Authors:
-
[3];
[1]
- Univ. of California, Irvine, CA (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Div.
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Southeast Univ., Nanjing (China)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1889148
- Alternate Identifier(s):
- OSTI ID: 1896836
- Report Number(s):
- BNL-223423-2022-JAAM
Journal ID: ISSN 1614-6832
- Grant/Contract Number:
- SC0012704; DMR-2011967; CHE-1338173; AC02-06CH11357; AC02-76SF00515; DE‐SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 41; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; high-entropy oxides; layered materials; sodium-ion cathodes; superlattice
Citation Formats
Yao, Libing, Zou, Peichao, Wang, Chunyang, Jiang, Jiahao, Ma, Lu, Tan, Sha, Beyer, Kevin A., Xu, Feng, Hu, Enyuan, and Xin, Huolin L. High-Entropy and Superstructure-Stabilized Layered Oxide Cathodes for Sodium-Ion Batteries. United States: N. p., 2022.
Web. doi:10.1002/aenm.202201989.
Yao, Libing, Zou, Peichao, Wang, Chunyang, Jiang, Jiahao, Ma, Lu, Tan, Sha, Beyer, Kevin A., Xu, Feng, Hu, Enyuan, & Xin, Huolin L. High-Entropy and Superstructure-Stabilized Layered Oxide Cathodes for Sodium-Ion Batteries. United States. https://doi.org/10.1002/aenm.202201989
Yao, Libing, Zou, Peichao, Wang, Chunyang, Jiang, Jiahao, Ma, Lu, Tan, Sha, Beyer, Kevin A., Xu, Feng, Hu, Enyuan, and Xin, Huolin L. Thu .
"High-Entropy and Superstructure-Stabilized Layered Oxide Cathodes for Sodium-Ion Batteries". United States. https://doi.org/10.1002/aenm.202201989. https://www.osti.gov/servlets/purl/1889148.
@article{osti_1889148,
title = {High-Entropy and Superstructure-Stabilized Layered Oxide Cathodes for Sodium-Ion Batteries},
author = {Yao, Libing and Zou, Peichao and Wang, Chunyang and Jiang, Jiahao and Ma, Lu and Tan, Sha and Beyer, Kevin A. and Xu, Feng and Hu, Enyuan and Xin, Huolin L.},
abstractNote = {Abstract Layered transition metal oxides are appealing cathodes for sodium‐ion batteries due to their overall advantages in energy density and cost. But their stabilities are usually compromised by the complicated phase transition and the oxygen redox, particularly when operating at high voltages, leading to poor structural stability and substantial capacity loss. Here an integrated strategy combing the high‐entropy design with the superlattice‐stabilization to extend the cycle life and enhance the rate capability of layered cathodes is reported. It is shown that the as‐prepared high‐entropy Na 2/3 Li 1/6 Fe 1/6 Co 1/6 Ni 1/6 Mn 1/3 O 2 cathode enables a superlattice structure with Li/transition metal ordering and delivers excellent electrochemical performance that is not affected by the presence of phase transition and oxygen redox. It achieves a high reversible capacity (171.2 mAh g −1 at 0.1 C), a high energy density (531 Wh kg −1 ), extended cycling stability (89.3% capacity retention at 1 C for 90 cycles and 63.7% capacity retention at 5 C after 300 cycles), and excellent fast‐charging capability (78 mAh g −1 at 10 C). This strategy would inspire more rational designs that can be leveraged to improve the reliability of layered cathodes for secondary‐ion batteries.},
doi = {10.1002/aenm.202201989},
journal = {Advanced Energy Materials},
number = 41,
volume = 12,
place = {United States},
year = {Thu Sep 08 00:00:00 EDT 2022},
month = {Thu Sep 08 00:00:00 EDT 2022}
}
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Works referenced in this record:
Entropy-stabilized oxides
journal, September 2015
- Rost, Christina M.; Sachet, Edward; Borman, Trent
- Nature Communications, Vol. 6, Issue 1
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013
- Sathiya, M.; Rousse, G.; Ramesha, K.
- Nature Materials, Vol. 12, Issue 9
Novel P2-type layered medium-entropy ceramics oxide as cathode material for sodium-ion batteries
journal, November 2021
- Yan, Shengxue; Luo, Shaohua; Yang, Liu
- Journal of Advanced Ceramics, Vol. 11, Issue 1
P3 Na 0.9 Ni 0.5 Mn 0.5 O 2 Cathode Material for Sodium Ion Batteries
journal, July 2019
- Risthaus, Tim; Chen, Lifang; Wang, Jun
- Chemistry of Materials, Vol. 31, Issue 15
Comprehensive Review of P2-Type Na 2/3 Ni 1/3 Mn 2/3 O 2 , a Potential Cathode for Practical Application of Na-Ion Batteries
journal, May 2019
- Zhang, Jiaolong; Wang, Wenhui; Wang, Wei
- ACS Applied Materials & Interfaces, Vol. 11, Issue 25
Evolution structurale et proprietes physiques des phases AXMO2 (A = Na, K; M = Cr, Mn, Co) (x ⩽ 1)
journal, June 1975
- Fouassier, Claude; Delmas, Claude; Hagenmuller, Paul
- Materials Research Bulletin, Vol. 10, Issue 6
Unified picture of anionic redox in Li/Na-ion batteries
journal, March 2019
- Ben Yahia, Mouna; Vergnet, Jean; Saubanère, Matthieu
- Nature Materials, Vol. 18, Issue 5
Uncommon Behavior of Li Doping Suppresses Oxygen Redox in P2‐Type Manganese‐Rich Sodium Cathodes
journal, October 2021
- Xiao, Biwei; Liu, Xiang; Chen, Xi
- Advanced Materials, Vol. 33, Issue 52
Rational design of layered oxide materials for sodium-ion batteries
journal, November 2020
- Zhao, Chenglong; Wang, Qidi; Yao, Zhenpeng
- Science, Vol. 370, Issue 6517
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials
journal, May 2016
- Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander
- Nature Chemistry, Vol. 8, Issue 7
Improving Energy Density and Structural Stability of Manganese Oxide Cathodes for Na-Ion Batteries by Structural Lithium Substitution
journal, December 2016
- de la Llave, Ezequiel; Talaie, Elahe; Levi, Elena
- Chemistry of Materials, Vol. 28, Issue 24
Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance
journal, November 2017
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Advanced Energy Materials, Vol. 8, Issue 8
High‐Entropy Layered Oxide Cathodes for Sodium‐Ion Batteries
journal, January 2020
- Zhao, Chenglong; Ding, Feixiang; Lu, Yaxiang
- Angewandte Chemie International Edition, Vol. 59, Issue 1
Advanced P2-Na 2/3 Ni 1/3 Mn 7/12 Fe 1/12 O 2 Cathode Material with Suppressed P2–O2 Phase Transition toward High-Performance Sodium-Ion Battery
journal, September 2018
- Yang, Qiong; Wang, Peng-Fei; Guo, Jin-Zhi
- ACS Applied Materials & Interfaces, Vol. 10, Issue 40
Revealing the anionic redox chemistry in O3-type layered oxide cathode for sodium-ion batteries
journal, June 2021
- Yu, Yang; Ning, De; Li, Qingyuan
- Energy Storage Materials, Vol. 38
Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes
journal, December 2019
- House, Robert A.; Maitra, Urmimala; Pérez-Osorio, Miguel A.
- Nature, Vol. 577, Issue 7791
Utilizing Oxygen Redox in Layered Cathode Materials from Multiscale Perspective
journal, March 2021
- Lee, Gi‐Hyeok; Lau, Vincent Wing‐hei; Yang, Wanli
- Advanced Energy Materials, Vol. 11, Issue 27
In Situ/Operando (Soft) X‐ray Spectroscopy Study of Beyond Lithium‐ion Batteries
journal, April 2021
- Yang, Feipeng; Feng, Xuefei; Liu, Y. ‐Sheng
- ENERGY & ENVIRONMENTAL MATERIALS, Vol. 4, Issue 2
Unveiling the Role of Co in Improving the High-Rate Capability and Cycling Performance of Layered Na 0.7 Mn 0.7 Ni 0.3– x Co x O 2 Cathode Materials for Sodium-Ion Batteries
journal, June 2016
- Li, Zheng-Yao; Zhang, Jicheng; Gao, Rui
- ACS Applied Materials & Interfaces, Vol. 8, Issue 24
Inherent inhibition of oxygen loss by regulating superstructural motifs in anionic redox cathodes
journal, October 2021
- Liu, Jiajie; Qi, Rui; Zuo, Changjian
- Nano Energy, Vol. 88
P2–Na x Co y Mn 1– y O 2 ( y = 0, 0.1) as Cathode Materials in Sodium-Ion Batteries—Effects of Doping and Morphology To Enhance Cycling Stability
journal, March 2016
- Bucher, Nicolas; Hartung, Steffen; Franklin, Joseph B.
- Chemistry of Materials, Vol. 28, Issue 7
A Superlattice‐Stabilized Layered Oxide Cathode for Sodium‐Ion Batteries
journal, April 2020
- Li, Qi; Xu, Sheng; Guo, Shaohua
- Advanced Materials, Vol. 32, Issue 23
New O2/P2-type Li-Excess Layered Manganese Oxides as Promising Multi-Functional Electrode Materials for Rechargeable Li/Na Batteries
journal, May 2014
- Yabuuchi, Naoaki; Hara, Ryo; Kajiyama, Masataka
- Advanced Energy Materials, Vol. 4, Issue 13
A novel P3-type Na 2/3 Mg 1/3 Mn 2/3 O 2 as high capacity sodium-ion cathode using reversible oxygen redox
journal, January 2019
- Song, Bohang; Hu, Enyuan; Liu, Jue
- Journal of Materials Chemistry A, Vol. 7, Issue 4
Oxygen Redox Chemistry in Rechargeable Li-Ion and Na-Ion Batteries
journal, February 2021
- Rahman, Muhammad Mominur; Lin, Feng
- Matter, Vol. 4, Issue 2
On the P2-Na x Co 1– y (Mn 2/3 Ni 1/3 ) y O 2 Cathode Materials for Sodium-Ion Batteries: Synthesis, Electrochemical Performance, and Redox Processes Occurring during the Electrochemical Cycling
journal, December 2017
- Doubaji, Siham; Ma, Lu; Asfaw, Habtom Desta
- ACS Applied Materials & Interfaces, Vol. 10, Issue 1
Unlocking the potential of P3 structure for practical Sodium-ion batteries by fabricating zero strain framework for Na+ intercalation
journal, May 2021
- Shi, Yuansheng; Zhang, Zhizhen; Jiang, Pengfeng
- Energy Storage Materials, Vol. 37
Identifying the Critical Role of Li Substitution in P2–Na x [Li y Ni z Mn 1– y – z ]O 2 (0 < x , y , z < 1) Intercalation Cathode Materials for High-Energy Na-Ion Batteries
journal, December 2013
- Xu, Jing; Lee, Dae Hoe; Clément, Raphaële J.
- Chemistry of Materials, Vol. 26, Issue 2
Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries
journal, April 2015
- Hwang, Jang-Yeon; Oh, Seung-Min; Myung, Seung-Taek
- Nature Communications, Vol. 6, Issue 1
A cost and resource analysis of sodium-ion batteries
journal, March 2018
- Vaalma, Christoph; Buchholz, Daniel; Weil, Marcel
- Nature Reviews Materials, Vol. 3, Issue 4
Whole‐Voltage‐Range Oxygen Redox in P2‐Layered Cathode Materials for Sodium‐Ion Batteries
journal, March 2021
- Li, Xun‐Lu; Wang, Tian; Yuan, Yifei
- Advanced Materials, Vol. 33, Issue 13
Structural classification and properties of the layered oxides
journal, January 1980
- Delmas, C.; Fouassier, C.; Hagenmuller, P.
- Physica B+C, Vol. 99, Issue 1-4
First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk
journal, September 2020
- House, Robert A.; Rees, Gregory J.; Pérez-Osorio, Miguel A.
- Nature Energy, Vol. 5, Issue 10