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Title: Sodium Rich Vanadium Oxy‐Fluorophosphate – Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O – as Advanced Cathode for Sodium Ion Batteries

Abstract

Abstract Conventional sodium‐based layered oxide cathodes are extremely air sensitive and possess poor electrochemical performance along with safety concerns when operating at high voltage. The polyanion phosphate, Na 3 V 2 (PO 4 ) 3 stands out as an excellent candidate due to its high nominal voltage, ambient air stability, and long cycle life. The caveat is that Na 3 V 2 (PO 4 ) 3 can only exhibit reversible capacities in the range of 100 mAh g −1 , 20% below its theoretical capacity. Here, the synthesis and characterizations are reported for the first time of the sodium‐rich vanadium oxyfluorophosphate, Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O, a tailored derivative compound of Na 3 V 2 (PO 4 ) 3 , with extensive electrochemical and structural analyses. Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O delivers an initial reversible capacity of 117 mAh g −1 between 2.5 and 4.5 V under the 1C rate at room temperature, with 85% capacity retention after 900 cycles. The cycling stability is further improved when the material is cycled at 50 °C within 2.8–4.3 V for 100 cycles. When paired with a presodiated hard carbon,more » Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O cycled with a capacity retention of 85% after 500 cycles. Cosubstitution of the transition metal and fluorine in Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O as well as the sodium‐rich structure are the major factors behind the improvement of specific capacity and cycling stability, which paves the way for this cathode in sodium‐ion batteries.« less

Authors:
 [1];  [2];  [1];  [1];  [3];  [4];  [1];  [1];  [5];  [6];  [1]; ORCiD logo [1]
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  1. Electrification and Energy Infrastructures Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA
  2. Qatar Environment and Energy Research Institute Hamad Bin Khalifa University Qatar Foundation Doha 34110 Qatar
  3. Exponent, Inc. Natick MA 01760 USA
  4. Department of Physics &, Astronomy Hunter College of the City University of New York New York NY 10065 USA
  5. Electrification and Energy Infrastructures Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA, Exponent, Inc. Natick MA 01760 USA, Department of Physics &, Astronomy Hunter College of the City University of New York New York NY 10065 USA, Greenmat Cesam Research Unit University of Liège Department of Chemistry Liège 4000 Belgium, Departamento de Química Inorgánica Facultad de Químicas Universidad Complutense Madrid 28040 Spain
  6. Departamento de Química Inorgánica Facultad de Químicas Universidad Complutense Madrid 28040 Spain
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Electricity (OE); USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)
OSTI Identifier:
1974479
Alternate Identifier(s):
OSTI ID: 1975348; OSTI ID: 1983413
Grant/Contract Number:  
DE‐AC05‐00OR22725; AC05-00OR22725
Resource Type:
Published Article
Journal Name:
Advanced Science
Additional Journal Information:
Journal Name: Advanced Science Journal Volume: 10 Journal Issue: 22; Journal ID: ISSN 2198-3844
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English
Subject:
25 ENERGY STORAGE; energy storage; high-voltage cathode; in situ X-ray; sodium-ion battery; vanadium Oxy-fluorophosphate

Citation Formats

Essehli, Rachid, Yahia, Hamdi Ben, Amin, Ruhul, Li, Mengya, Morales, Daniel, Greenbaum, Steven G., Abouimrane, Ali, Parejiya, Anand, Mahmoud, Abdelfattah, Boulahya, Khalid, Dixit, Marm, and Belharouak, Ilias. Sodium Rich Vanadium Oxy‐Fluorophosphate – Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O – as Advanced Cathode for Sodium Ion Batteries. Germany: N. p., 2023. Web. doi:10.1002/advs.202301091.
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Essehli, Rachid, Yahia, Hamdi Ben, Amin, Ruhul, Li, Mengya, Morales, Daniel, Greenbaum, Steven G., Abouimrane, Ali, Parejiya, Anand, Mahmoud, Abdelfattah, Boulahya, Khalid, Dixit, Marm, & Belharouak, Ilias. Sodium Rich Vanadium Oxy‐Fluorophosphate – Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O – as Advanced Cathode for Sodium Ion Batteries. Germany. https://doi.org/10.1002/advs.202301091
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Essehli, Rachid, Yahia, Hamdi Ben, Amin, Ruhul, Li, Mengya, Morales, Daniel, Greenbaum, Steven G., Abouimrane, Ali, Parejiya, Anand, Mahmoud, Abdelfattah, Boulahya, Khalid, Dixit, Marm, and Belharouak, Ilias. Thu . "Sodium Rich Vanadium Oxy‐Fluorophosphate – Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O – as Advanced Cathode for Sodium Ion Batteries". Germany. https://doi.org/10.1002/advs.202301091.
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@article{osti_1974479,
title = {Sodium Rich Vanadium Oxy‐Fluorophosphate – Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O – as Advanced Cathode for Sodium Ion Batteries},
author = {Essehli, Rachid and Yahia, Hamdi Ben and Amin, Ruhul and Li, Mengya and Morales, Daniel and Greenbaum, Steven G. and Abouimrane, Ali and Parejiya, Anand and Mahmoud, Abdelfattah and Boulahya, Khalid and Dixit, Marm and Belharouak, Ilias},
abstractNote = {Abstract Conventional sodium‐based layered oxide cathodes are extremely air sensitive and possess poor electrochemical performance along with safety concerns when operating at high voltage. The polyanion phosphate, Na 3 V 2 (PO 4 ) 3 stands out as an excellent candidate due to its high nominal voltage, ambient air stability, and long cycle life. The caveat is that Na 3 V 2 (PO 4 ) 3 can only exhibit reversible capacities in the range of 100 mAh g −1 , 20% below its theoretical capacity. Here, the synthesis and characterizations are reported for the first time of the sodium‐rich vanadium oxyfluorophosphate, Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O, a tailored derivative compound of Na 3 V 2 (PO 4 ) 3 , with extensive electrochemical and structural analyses. Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O delivers an initial reversible capacity of 117 mAh g −1 between 2.5 and 4.5 V under the 1C rate at room temperature, with 85% capacity retention after 900 cycles. The cycling stability is further improved when the material is cycled at 50 °C within 2.8–4.3 V for 100 cycles. When paired with a presodiated hard carbon, Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O cycled with a capacity retention of 85% after 500 cycles. Cosubstitution of the transition metal and fluorine in Na 3.2 Ni 0.2 V 1.8 (PO 4 ) 2 F 2 O as well as the sodium‐rich structure are the major factors behind the improvement of specific capacity and cycling stability, which paves the way for this cathode in sodium‐ion batteries.},
doi = {10.1002/advs.202301091},
journal = {Advanced Science},
number = 22,
volume = 10,
place = {Germany},
year = {Thu May 18 00:00:00 EDT 2023},
month = {Thu May 18 00:00:00 EDT 2023}
}
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