P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries
Abstract
P2-Na0.67Ni0.33Mn0.67O2 represents a promising cathode for Na-ion batteries, but it suffers from severe structural degradation upon storing in a humid atmosphere and cycling at a high cutoff voltage. Here we propose an in situ construction to achieve simultaneous material synthesis and Mg/Sn cosubstitution of Na0.67Ni0.33Mn0.67O2 via one-pot solid-state sintering. Here, the materials exhibit superior structural reversibility and moisture insensitivity. In-operando XRD reveals an essential correlation between cycling stability and phase reversibility, whereas Mg substitution suppressed the P2–O2 phase transition by forming a new Z phase, and Mg/Sn cosubstitution enhanced the P2–Z transition reversibility benefiting from strong Sn–O bonds. DFT calculations disclosed high chemical tolerance to moisture, as the adsorption energy to H2O was lower than that of the pure Na0.67Ni0.33Mn0.67O2. A representative Na0.67Ni0.23Mg0.1Mn0.65Sn0.02O2 cathode exhibits high reversible capacities of 123 mAh g–1 (10 mA g–1), 110 mAh g–1 (200 mA g–1), and 100 mAh g–1 (500 mA g–1) and a high capacity retention of 80% (500 mA g–1, 500 cycles).
- Authors:
-
[3];
[3];
[3];
[3];
[7];
[1];
[5];
[1]
- Shanghai Jiao Tong Univ. (China)
- Nanjing Univ. of Information Science and Technology (China). Key Lab. for Soft Chemistry and Functional Materials
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Beijing Institute of Technology (China)
- Shanghai SodaEn New Energy Technology (China)
- City Univ. of Hong Kong, Kowloon (Hong Kong)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 2310287
- Grant/Contract Number:
- AC02-06CH11357; AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 23; Journal Issue: 5; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; P2-type cathode; solid-state synthesis; cosubstitution; reversible phase transition; sodium-ion batteries
Citation Formats
Yuan, Siqi, Yu, Lei, Qian, Guannan, Xie, Yingying, Guo, Penghui, Cui, Guijia, Ma, Jun, Ren, Xiangyu, Xu, Zhixin, Lee, Sang-Jun, Lee, Jun-Sik, Liu, Yijin, Ren, Yang, Li, Linsen, Tan, Guoqiang, and Liao, Xiaozhen. P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries. United States: N. p., 2023.
Web. doi:10.1021/acs.nanolett.2c04465.
Yuan, Siqi, Yu, Lei, Qian, Guannan, Xie, Yingying, Guo, Penghui, Cui, Guijia, Ma, Jun, Ren, Xiangyu, Xu, Zhixin, Lee, Sang-Jun, Lee, Jun-Sik, Liu, Yijin, Ren, Yang, Li, Linsen, Tan, Guoqiang, & Liao, Xiaozhen. P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries. United States. https://doi.org/10.1021/acs.nanolett.2c04465
Yuan, Siqi, Yu, Lei, Qian, Guannan, Xie, Yingying, Guo, Penghui, Cui, Guijia, Ma, Jun, Ren, Xiangyu, Xu, Zhixin, Lee, Sang-Jun, Lee, Jun-Sik, Liu, Yijin, Ren, Yang, Li, Linsen, Tan, Guoqiang, and Liao, Xiaozhen. Wed .
"P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries". United States. https://doi.org/10.1021/acs.nanolett.2c04465. https://www.osti.gov/servlets/purl/2310287.
@article{osti_2310287,
title = {P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries},
author = {Yuan, Siqi and Yu, Lei and Qian, Guannan and Xie, Yingying and Guo, Penghui and Cui, Guijia and Ma, Jun and Ren, Xiangyu and Xu, Zhixin and Lee, Sang-Jun and Lee, Jun-Sik and Liu, Yijin and Ren, Yang and Li, Linsen and Tan, Guoqiang and Liao, Xiaozhen},
abstractNote = {P2-Na0.67Ni0.33Mn0.67O2 represents a promising cathode for Na-ion batteries, but it suffers from severe structural degradation upon storing in a humid atmosphere and cycling at a high cutoff voltage. Here we propose an in situ construction to achieve simultaneous material synthesis and Mg/Sn cosubstitution of Na0.67Ni0.33Mn0.67O2 via one-pot solid-state sintering. Here, the materials exhibit superior structural reversibility and moisture insensitivity. In-operando XRD reveals an essential correlation between cycling stability and phase reversibility, whereas Mg substitution suppressed the P2–O2 phase transition by forming a new Z phase, and Mg/Sn cosubstitution enhanced the P2–Z transition reversibility benefiting from strong Sn–O bonds. DFT calculations disclosed high chemical tolerance to moisture, as the adsorption energy to H2O was lower than that of the pure Na0.67Ni0.33Mn0.67O2. A representative Na0.67Ni0.23Mg0.1Mn0.65Sn0.02O2 cathode exhibits high reversible capacities of 123 mAh g–1 (10 mA g–1), 110 mAh g–1 (200 mA g–1), and 100 mAh g–1 (500 mA g–1) and a high capacity retention of 80% (500 mA g–1, 500 cycles).},
doi = {10.1021/acs.nanolett.2c04465},
journal = {Nano Letters},
number = 5,
volume = 23,
place = {United States},
year = {Wed Feb 22 00:00:00 EST 2023},
month = {Wed Feb 22 00:00:00 EST 2023}
}
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