On Disrupting the Na+-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na+-Ion Batteries

Gutierrez, Arturo; Dose, Wesley M.; Borkiewicz, Olaf; Guo, Fangmin; Avdeev, Maxim; Kim, Soojeong; Fister, Timothy T.; Ren, Yang; Bareño, Javier; Johnson, Christopher S.

doi:10.1021/acs.jpcc.8b05537

Title: On Disrupting the Na⁺-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na⁺-Ion Batteries

Journal Article · Thu Sep 06 00:00:00 UTC 2018 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.8b05537 · OSTI ID:1487115

^[1]; Dose, Wesley M. ^[1]; Borkiewicz, Olaf ^[1]; Guo, Fangmin ^[1]; Avdeev, Maxim ^[2]; Kim, Soojeong ^[1];

^[1]; Ren, Yang ^[1];

^[1];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)
Australian Nuclear Science and Technology Organization, Lucas Heights, NSW (Australia)

An investigation of the electrochemical and structural properties of layered P2-Na_0.62Mn_0.75Ni_0.25O₂ is presented. The effect of changing the Mn:Ni ratio (3:1) from what is found in Na_0.67Mn_0.67Ni_0.33O₂ (2:1) and consequently the introduction of a third metal center (Mn³⁺) was investigated. X-ray diffraction (in-situ and powder) revealed the lack of Na+-ion/vacancy ordering at the relevant sodium contents (x = 0.33, 0.5 and 0.67). The Mn³⁺ in Na_0.62Mn_0.75Ni_0.25O₂ introduces defects into the Ni-Mn inter-plane charge order that in turn disrupts the ordering within the Na-plane. The material underwent a P2-O2 and P2-P2’ phase transition at high (4.2 V) and low (~ 1.85 V) voltages, respectively. The material was tested at several different voltage ranges in order to understand the effect of the phase transitions on the capacity retention. Interestingly, the inclusion of both phase transitions demonstrated comparable cycling performance to when both phase transitions were excluded. As a result, excellent rate performance was demonstrated between 4.3 – 1.5 V with a specific capacity of 120 mAh/g delivered at 500 mA/g current density.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1487115

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 41 Vol. 122; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: On Disrupting the Na+-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na+-Ion Batteries

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Title: On Disrupting the Na⁺-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na⁺-Ion Batteries