On Disrupting the Na+-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na+-Ion Batteries

Gutierrez, Arturo; Dose, Wesley M.; Borkiewicz, Olaf; Guo, Fangmin; Avdeev, Maxim; Kim, Soojeong; Fister, Timothy T.; Ren, Yang; Bareño, Javier; Johnson, Christopher S.

doi:10.1021/acs.jpcc.8b05537

Title: On Disrupting the Na⁺-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na⁺-Ion Batteries

Abstract

An investigation of the electrochemical and structural properties of layered P2-Na_0.62Mn_0.75Ni_0.25O₂ is presented. The effect of changing the Mn:Ni ratio (3:1) from what is found in Na_0.67Mn_0.67Ni_0.33O₂ (2:1) and consequently the introduction of a third metal center (Mn³⁺) was investigated. X-ray diffraction (in-situ and powder) revealed the lack of Na+-ion/vacancy ordering at the relevant sodium contents (x = 0.33, 0.5 and 0.67). The Mn³⁺ in Na_0.62Mn_0.75Ni_0.25O₂ introduces defects into the Ni-Mn inter-plane charge order that in turn disrupts the ordering within the Na-plane. The material underwent a P2-O2 and P2-P2’ phase transition at high (4.2 V) and low (~ 1.85 V) voltages, respectively. The material was tested at several different voltage ranges in order to understand the effect of the phase transitions on the capacity retention. Interestingly, the inclusion of both phase transitions demonstrated comparable cycling performance to when both phase transitions were excluded. As a result, excellent rate performance was demonstrated between 4.3 – 1.5 V with a specific capacity of 120 mAh/g delivered at 500 mA/g current density.

Authors:

^[1]; Dose, Wesley M. ^[1]; Borkiewicz, Olaf ^[1]; Guo, Fangmin ^[1]; Avdeev, Maxim ^[2]; Kim, Soojeong ^[1];

^[1]; Ren, Yang ^[1];

^[1];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)
Australian Nuclear Science and Technology Organization, Lucas Heights, NSW (Australia)

Publication Date:: 2018-09-06

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1487115

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physical Chemistry. C

Additional Journal Information:: Journal Volume: 122; Journal Issue: 41; Journal ID: ISSN 1932-7447

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; Sodium battery

Citation Formats


                    Gutierrez, Arturo, Dose, Wesley M., Borkiewicz, Olaf, Guo, Fangmin, Avdeev, Maxim, Kim, Soojeong, Fister, Timothy T., Ren, Yang, Bareño, Javier, and Johnson, Christopher S. On Disrupting the Na+-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na+-Ion Batteries.  United States: N. p., 2018. 
Web.  doi:10.1021/acs.jpcc.8b05537.

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                    Gutierrez, Arturo, Dose, Wesley M., Borkiewicz, Olaf, Guo, Fangmin, Avdeev, Maxim, Kim, Soojeong, Fister, Timothy T., Ren, Yang, Bareño, Javier, & Johnson, Christopher S. On Disrupting the Na+-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na+-Ion Batteries.  United States.  https://doi.org/10.1021/acs.jpcc.8b05537

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                    Gutierrez, Arturo, Dose, Wesley M., Borkiewicz, Olaf, Guo, Fangmin, Avdeev, Maxim, Kim, Soojeong, Fister, Timothy T., Ren, Yang, Bareño, Javier, and Johnson, Christopher S. Thu .  
"On Disrupting the Na+-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na+-Ion Batteries".  United States.  https://doi.org/10.1021/acs.jpcc.8b05537.  https://www.osti.gov/servlets/purl/1487115.

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@article{osti_1487115,

  title        = {On Disrupting the Na+-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na+-Ion Batteries},

  author       = {Gutierrez, Arturo and Dose, Wesley M. and Borkiewicz, Olaf and Guo, Fangmin and Avdeev, Maxim and Kim, Soojeong and Fister, Timothy T. and Ren, Yang and Bareño, Javier and Johnson, Christopher S.},

  abstractNote = {An investigation of the electrochemical and structural properties of layered P2-Na0.62Mn0.75Ni0.25O2 is presented. The effect of changing the Mn:Ni ratio (3:1) from what is found in Na0.67Mn0.67Ni0.33O2 (2:1) and consequently the introduction of a third metal center (Mn3+) was investigated. X-ray diffraction (in-situ and powder) revealed the lack of Na+-ion/vacancy ordering at the relevant sodium contents (x = 0.33, 0.5 and 0.67). The Mn3+ in Na0.62Mn0.75Ni0.25O2 introduces defects into the Ni-Mn inter-plane charge order that in turn disrupts the ordering within the Na-plane. The material underwent a P2-O2 and P2-P2’ phase transition at high (4.2 V) and low (~ 1.85 V) voltages, respectively. The material was tested at several different voltage ranges in order to understand the effect of the phase transitions on the capacity retention. Interestingly, the inclusion of both phase transitions demonstrated comparable cycling performance to when both phase transitions were excluded. As a result, excellent rate performance was demonstrated between 4.3 – 1.5 V with a specific capacity of 120 mAh/g delivered at 500 mA/g current density.},

  doi          = {10.1021/acs.jpcc.8b05537},

  journal      = {Journal of Physical Chemistry. C},

  number       = 41,

  volume       = 122,

  place        = {United States},

  year         = {2018},

  month        = {9}

}

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Works referenced in this record:

Sodium-Ion Batteries
journal, May 2012

Slater, Michael D.; Kim, Donghan; Lee, Eungje
Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
DOI: 10.1002/adfm.201200691

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012

Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
DOI: 10.1002/aenm.201200026

Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries
journal, August 2014

Yabuuchi, Naoaki; Komaba, Shinichi
Science and Technology of Advanced Materials, Vol. 15, Issue 4
DOI: 10.1088/1468-6996/15/4/043501

Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007

Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125
DOI: 10.1039/b702425h

Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005

Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267
DOI: 10.1039/b417616m

High-energy and high-power Li-rich nickel manganese oxide electrode materials
journal, November 2010

Kim, Donghan; Kang, Sun-Ho; Balasubramanian, Mahalingam
Electrochemistry Communications, Vol. 12, Issue 11, p. 1618-1621
DOI: 10.1016/j.elecom.2010.09.009

Lithium–manganese oxide electrodes with layered–spinel composite structures xLi₂MnO₃·(1−x)Li_1+yMn_2−yO₄ (0<x<1, 0⩽y⩽0.33) for lithium batteries
journal, May 2005

Johnson, C. S.; Li, N.; Vaughey, J. T.
Electrochemistry Communications, Vol. 7, Issue 5, p. 528-536
DOI: 10.1016/j.elecom.2005.02.027

Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries
journal, February 2007

Park, S.; Kang, S.; Johnson, C.
Electrochemistry Communications, Vol. 9, Issue 2, p. 262-268
DOI: 10.1016/j.elecom.2006.09.014

Structural Characterization of Layered Li _x Ni _0.5 Mn _0.5 O ₂ (0 < x ≤ 2) Oxide Electrodes for Li Batteries
journal, June 2003

Johnson, Christopher S.; Kim, Jeom-Soo; Kropf, A. Jeremy
Chemistry of Materials, Vol. 15, Issue 12
DOI: 10.1021/cm0204728

Development of Li-Ion Rechargeable Battery Using SnC ₂ O ₄ -Coated Si Anode Material and Its Safety Evaluation
journal, January 2013

Kataoka, Riki; Mukai, Takashi; Yoshizawa, Akihiro
Journal of The Electrochemical Society, Vol. 160, Issue 10
DOI: 10.1149/2.034310jes

A Comparative Study of Layered Transition Metal Oxide Cathodes for Application in Sodium-Ion Battery
journal, February 2015

Hasa, Ivana; Buchholz, Daniel; Passerini, Stefano
ACS Applied Materials & Interfaces, Vol. 7, Issue 9
DOI: 10.1021/am5080437

Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes
journal, February 2011

Kim, Donghan; Kang, Sun-Ho; Slater, Michael
Advanced Energy Materials, Vol. 1, Issue 3, p. 333-336
DOI: 10.1002/aenm.201000061

Superlattice Ordering of Mn, Ni, and Co in Layered Alkali Transition Metal Oxides with P2, P3, and O3 Structures
journal, December 2000

Lu, Zhonghua; Donaberger, R. A.; Dahn, J. R.
Chemistry of Materials, Vol. 12, Issue 12, p. 3583-3590
DOI: 10.1021/cm000359m

Study of the Transition Metal Ordering in Layered Na _x Ni _{x /2} Mn _{1– x /2} O ₂ (2/3 ≤ x ≤ 1) and Consequences of Na/Li Exchange
journal, July 2013

Cabana, Jordi; Chernova, Natasha A.; Xiao, Jie
Inorganic Chemistry, Vol. 52, Issue 15
DOI: 10.1021/ic400579w

Structural classification and properties of the layered oxides
journal, January 1980

Delmas, C.; Fouassier, C.; Hagenmuller, P.
Physica B+C, Vol. 99, Issue 1-4
DOI: 10.1016/0378-4363(80)90214-4

In Situ X-Ray Diffraction Study of P2-Na[sub 2/3][Ni[sub 1/3]Mn[sub 2/3]]O[sub 2]
journal, January 2001

Lu, Zhonghua; Dahn, J. R.
Journal of The Electrochemical Society, Vol. 148, Issue 11
DOI: 10.1149/1.1407247

An advanced cathode for Na-ion batteries with high rate and excellent structural stability
journal, January 2013

Lee, Dae Hoe; Xu, Jing; Meng, Ying Shirley
Physical Chemistry Chemical Physics, Vol. 15, Issue 9
DOI: 10.1039/c2cp44467d

P2-type Na _2/3 Ni _1/3 Mn _2/3−x Ti _x O ₂ as a new positive electrode for higher energy Na-ion batteries
journal, January 2014

Yoshida, Hiroaki; Yabuuchi, Naoaki; Kubota, Kei
Chem. Commun., Vol. 50, Issue 28
DOI: 10.1039/c3cc49856e

P2-Type Na _x Cu _0.15 Ni _0.20 Mn _0.65 O ₂ Cathodes with High Voltage for High-Power and Long-Life Sodium-Ion Batteries
journal, November 2016

Kang, Wenpei; Yu, Denis Y. W.; Lee, Pui-Kit
ACS Applied Materials & Interfaces, Vol. 8, Issue 46
DOI: 10.1021/acsami.6b10841

Origin of Enhanced Capacity Retention of P2-Type Na _2/3 Ni _1/3- _x Mn _2/3 Cu _x O ₂ for Na-Ion Batteries
journal, January 2017

Kubota, Kei; Yoda, Yusuke; Komaba, Shinichi
Journal of The Electrochemical Society, Vol. 164, Issue 12
DOI: 10.1149/2.0311712jes

Crystal Structures and Electrochemical Performance of Air-Stable Na _2/3 Ni _{1/3– x} Cu _x Mn _2/3 O ₂ in Sodium Cells
journal, February 2017

Zheng, Lituo; Li, Jierui; Obrovac, M. N.
Chemistry of Materials, Vol. 29, Issue 4
DOI: 10.1021/acs.chemmater.6b04769

High Voltage Mg-Doped Na _0.67 Ni _{0.3– x} Mg _x Mn _0.7 O ₂ ( x = 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability
journal, July 2016

Singh, Gurpreet; Tapia-Ruiz, Nuria; Lopez del Amo, Juan Miguel
Chemistry of Materials, Vol. 28, Issue 14
DOI: 10.1021/acs.chemmater.6b01935

Suppressing the P2-O2 Phase Transition of Na _0.67 Mn _0.67 Ni _0.33 O ₂ by Magnesium Substitution for Improved Sodium-Ion Batteries
journal, May 2016

Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
Angewandte Chemie International Edition, Vol. 55, Issue 26
DOI: 10.1002/anie.201602202

Synthesis of Lithium and Manganese-Rich Cathode Materials via an Oxalate Co-Precipitation Method
journal, January 2013

Wang, Dapeng; Belharouak, Ilias; Zhou, Guangwen
Journal of The Electrochemical Society, Vol. 160, Issue 5
DOI: 10.1149/2.016305jes

Surface Characterization of Electrodes from High Power Lithium-Ion Batteries
journal, January 2002

Andersson, A. M.; Abraham, D. P.; Haasch, R.
Journal of The Electrochemical Society, Vol. 149, Issue 10
DOI: 10.1149/1.1505636

IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001

Newville, Matthew
Journal of Synchrotron Radiation, Vol. 8, Issue 2
DOI: 10.1107/s0909049500016964

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Ravel, B.; Newville, M.
Journal of Synchrotron Radiation, Vol. 12, Issue 4
DOI: 10.1107/s0909049505012719

The P2-Na2/3Co2/3Mn1/3O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery
journal, January 2011

Carlier, D.; Cheng, J. H.; Berthelot, R.
Dalton Transactions, Vol. 40, Issue 36
DOI: 10.1039/c1dt10798d

Sodium Trimer Ordering on a ${Na}_{x} {CoO}_{2}$ Surface
journal, May 2008

Pai, Woei Wu; Huang, S. H.; Meng, Ying S.
Physical Review Letters, Vol. 100, Issue 20
DOI: 10.1103/physrevlett.100.206404

Beyond Divalent Copper: A Redox Couple for Sodium Ion Battery Cathode Materials
journal, January 2015

Mason, C. W.; Lange, F.; Saravanan, K.
ECS Electrochemistry Letters, Vol. 4, Issue 5
DOI: 10.1149/2.0041505eel

P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries
journal, April 2015

Wang, Yuesheng; Xiao, Ruijuan; Hu, Yong-Sheng
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms7954

Structural study of two layered phases in the NaxMnyO2 system. Electrochemical behavior of their lithium substituted derivatives
journal, January 2000

Bordet-Le Guenne, Laure; Deniard, Philippe; Biensan, Philippe
Journal of Materials Chemistry, Vol. 10, Issue 9
DOI: 10.1039/b004598p

P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012

Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
Nature Materials, Vol. 11, Issue 6
DOI: 10.1038/nmat3309

Electrochemical stability of non-aqueous electrolytes for sodium-ion batteries and their compatibility with Na _0.7 CoO ₂
journal, January 2014

Bhide, Amrtha; Hofmann, Jonas; Katharina Dürr, Anna
Phys. Chem. Chem. Phys., Vol. 16, Issue 5
DOI: 10.1039/c3cp53077a

Na _0.67 Mn _1−x Mg _x O ₂ (0 ≤ x ≤ 0.2): a high capacity cathode for sodium-ion batteries
journal, January 2014

Billaud, Juliette; Singh, Gurpreet; Armstrong, A. Robert
Energy Environ. Sci., Vol. 7, Issue 4
DOI: 10.1039/c4ee00465e

P′2-Na _2/3 Mn _0.9 Me _0.1 O ₂ (Me = Mg, Ti, Co, Ni, Cu, and Zn): Correlation between Orthorhombic Distortion and Electrochemical Property
journal, October 2017

Kumakura, Shinichi; Tahara, Yoshiyuki; Sato, Syuhei
Chemistry of Materials, Vol. 29, Issue 21
DOI: 10.1021/acs.chemmater.7b02772

Precision Measurements of the Coulombic Efficiency of Lithium-Ion Batteries and of Electrode Materials for Lithium-Ion Batteries
journal, January 2010

Smith, A. J.; Burns, J. C.; Trussler, S.
Journal of The Electrochemical Society, Vol. 157, Issue 2
DOI: 10.1149/1.3268129

Works referencing / citing this record:

Ni-based cathode materials for Na-ion batteries
journal, June 2019

Zhao, Chenglong; Lu, Yaxiang; Chen, Liquan
Nano Research, Vol. 12, Issue 9
DOI: 10.1007/s12274-019-2451-3

High performance P2 sodium layered oxides: an in-depth study into the effect of rationally selected stoichiometry
journal, January 2019

Ortiz-Vitoriano, Nagore; Drewett, Nicholas E.; Gonzalo, Elena
Journal of Materials Chemistry A, Vol. 7, Issue 38
DOI: 10.1039/c9ta07346a

Layered P2‐Type K _0.44 Ni _0.22 Mn _0.78 O ₂ as a High‐Performance Cathode for Potassium‐Ion Batteries
journal, October 2019

Zhang, Xinyuan; Yang, Yubo; Qu, Xianlin
Advanced Functional Materials, Vol. 29, Issue 49
DOI: 10.1002/adfm.201905679

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Title: On Disrupting the Na+-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na+-Ion Batteries

Abstract

Citation Formats

Sodium-Ion Batteries journal, May 2012

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries journal, May 2012

Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries journal, August 2014

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Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries journal, March 2005

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Lithium–manganese oxide electrodes with layered–spinel composite structures xLi2MnO3·(1−x)Li1+yMn2−yO4 (0<x<1, 0⩽y⩽0.33) for lithium batteries journal, May 2005

Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries journal, February 2007

Structural Characterization of Layered Li x Ni 0.5 Mn 0.5 O 2 (0 < x ≤ 2) Oxide Electrodes for Li Batteries journal, June 2003

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A Comparative Study of Layered Transition Metal Oxide Cathodes for Application in Sodium-Ion Battery journal, February 2015

Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes journal, February 2011

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High Voltage Mg-Doped Na 0.67 Ni 0.3– x Mg x Mn 0.7 O 2 ( x = 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability journal, July 2016

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Synthesis of Lithium and Manganese-Rich Cathode Materials via an Oxalate Co-Precipitation Method journal, January 2013

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IFEFFIT : interactive XAFS analysis and FEFF fitting journal, March 2001

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Ni-based cathode materials for Na-ion batteries journal, June 2019

High performance P2 sodium layered oxides: an in-depth study into the effect of rationally selected stoichiometry journal, January 2019

Layered P2‐Type K 0.44 Ni 0.22 Mn 0.78 O 2 as a High‐Performance Cathode for Potassium‐Ion Batteries journal, October 2019

Title: On Disrupting the Na⁺-Ion/Vacancy Ordering in P2-Type Sodium–Manganese–Nickel Oxide Cathodes for Na⁺-Ion Batteries

Sodium-Ion Batteries
journal, May 2012

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012

Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries
journal, August 2014

Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007

Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005

High-energy and high-power Li-rich nickel manganese oxide electrode materials
journal, November 2010

Lithium–manganese oxide electrodes with layered–spinel composite structures xLi₂MnO₃·(1−x)Li_1+yMn_2−yO₄ (0<x<1, 0⩽y⩽0.33) for lithium batteries
journal, May 2005

Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries
journal, February 2007

Structural Characterization of Layered Li _x Ni _0.5 Mn _0.5 O ₂ (0 < x ≤ 2) Oxide Electrodes for Li Batteries
journal, June 2003

Development of Li-Ion Rechargeable Battery Using SnC ₂ O ₄ -Coated Si Anode Material and Its Safety Evaluation
journal, January 2013

A Comparative Study of Layered Transition Metal Oxide Cathodes for Application in Sodium-Ion Battery
journal, February 2015

Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes
journal, February 2011

Superlattice Ordering of Mn, Ni, and Co in Layered Alkali Transition Metal Oxides with P2, P3, and O3 Structures
journal, December 2000

Study of the Transition Metal Ordering in Layered Na _x Ni _{x /2} Mn _{1– x /2} O ₂ (2/3 ≤ x ≤ 1) and Consequences of Na/Li Exchange
journal, July 2013

Structural classification and properties of the layered oxides
journal, January 1980

In Situ X-Ray Diffraction Study of P2-Na[sub 2/3][Ni[sub 1/3]Mn[sub 2/3]]O[sub 2]
journal, January 2001

An advanced cathode for Na-ion batteries with high rate and excellent structural stability
journal, January 2013

P2-type Na _2/3 Ni _1/3 Mn _2/3−x Ti _x O ₂ as a new positive electrode for higher energy Na-ion batteries
journal, January 2014

P2-Type Na _x Cu _0.15 Ni _0.20 Mn _0.65 O ₂ Cathodes with High Voltage for High-Power and Long-Life Sodium-Ion Batteries
journal, November 2016

Origin of Enhanced Capacity Retention of P2-Type Na _2/3 Ni _1/3- _x Mn _2/3 Cu _x O ₂ for Na-Ion Batteries
journal, January 2017

Crystal Structures and Electrochemical Performance of Air-Stable Na _2/3 Ni _{1/3– x} Cu _x Mn _2/3 O ₂ in Sodium Cells
journal, February 2017

High Voltage Mg-Doped Na _0.67 Ni _{0.3– x} Mg _x Mn _0.7 O ₂ ( x = 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability
journal, July 2016

Suppressing the P2-O2 Phase Transition of Na _0.67 Mn _0.67 Ni _0.33 O ₂ by Magnesium Substitution for Improved Sodium-Ion Batteries
journal, May 2016

Synthesis of Lithium and Manganese-Rich Cathode Materials via an Oxalate Co-Precipitation Method
journal, January 2013

Surface Characterization of Electrodes from High Power Lithium-Ion Batteries
journal, January 2002

IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

The P2-Na2/3Co2/3Mn1/3O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery
journal, January 2011

Sodium Trimer Ordering on a ${Na}_{x} {CoO}_{2}$ Surface
journal, May 2008

Beyond Divalent Copper: A Redox Couple for Sodium Ion Battery Cathode Materials
journal, January 2015

P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries
journal, April 2015

Structural study of two layered phases in the NaxMnyO2 system. Electrochemical behavior of their lithium substituted derivatives
journal, January 2000

P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012

Electrochemical stability of non-aqueous electrolytes for sodium-ion batteries and their compatibility with Na _0.7 CoO ₂
journal, January 2014

Na _0.67 Mn _1−x Mg _x O ₂ (0 ≤ x ≤ 0.2): a high capacity cathode for sodium-ion batteries
journal, January 2014

P′2-Na _2/3 Mn _0.9 Me _0.1 O ₂ (Me = Mg, Ti, Co, Ni, Cu, and Zn): Correlation between Orthorhombic Distortion and Electrochemical Property
journal, October 2017

Precision Measurements of the Coulombic Efficiency of Lithium-Ion Batteries and of Electrode Materials for Lithium-Ion Batteries
journal, January 2010

Ni-based cathode materials for Na-ion batteries
journal, June 2019

High performance P2 sodium layered oxides: an in-depth study into the effect of rationally selected stoichiometry
journal, January 2019

Layered P2‐Type K _0.44 Ni _0.22 Mn _0.78 O ₂ as a High‐Performance Cathode for Potassium‐Ion Batteries
journal, October 2019