skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High‐Fluorinated Electrolytes for Li–S Batteries

Authors:
 [1];  [2];  [3];  [3];  [3];  [3];  [3];  [4];  [3]; ORCiD logo [3]
  1. Department of Chemical and Biomolecular Engineering University of Maryland College Park MD 20742 USA, College of Materials Science and Technology Nanjing University of Aeronautics and Astronautics Nanjing 210016 P. R. China
  2. College of Materials Science and Technology Nanjing University of Aeronautics and Astronautics Nanjing 210016 P. R. China
  3. Department of Chemical and Biomolecular Engineering University of Maryland College Park MD 20742 USA
  4. Department of Chemistry and Biochemistry University of Maryland College Park MD 20742 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1497239
Grant/Contract Number:  
DEEE0008202; DEEE0008200
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 9 Journal Issue: 16; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zheng, Jing, Ji, Guangbin, Fan, Xiulin, Chen, Ji, Li, Qin, Wang, Haiyang, Yang, Yong, DeMella, Kerry C., Raghavan, Srinivasa R., and Wang, Chunsheng. High‐Fluorinated Electrolytes for Li–S Batteries. Germany: N. p., 2019. Web. https://doi.org/10.1002/aenm.201803774.
Zheng, Jing, Ji, Guangbin, Fan, Xiulin, Chen, Ji, Li, Qin, Wang, Haiyang, Yang, Yong, DeMella, Kerry C., Raghavan, Srinivasa R., & Wang, Chunsheng. High‐Fluorinated Electrolytes for Li–S Batteries. Germany. https://doi.org/10.1002/aenm.201803774
Zheng, Jing, Ji, Guangbin, Fan, Xiulin, Chen, Ji, Li, Qin, Wang, Haiyang, Yang, Yong, DeMella, Kerry C., Raghavan, Srinivasa R., and Wang, Chunsheng. Wed . "High‐Fluorinated Electrolytes for Li–S Batteries". Germany. https://doi.org/10.1002/aenm.201803774.
@article{osti_1497239,
title = {High‐Fluorinated Electrolytes for Li–S Batteries},
author = {Zheng, Jing and Ji, Guangbin and Fan, Xiulin and Chen, Ji and Li, Qin and Wang, Haiyang and Yang, Yong and DeMella, Kerry C. and Raghavan, Srinivasa R. and Wang, Chunsheng},
abstractNote = {},
doi = {10.1002/aenm.201803774},
journal = {Advanced Energy Materials},
number = 16,
volume = 9,
place = {Germany},
year = {2019},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/aenm.201803774

Citation Metrics:
Cited by: 27 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

A Soft Approach to Encapsulate Sulfur: Polyaniline Nanotubes for Lithium-Sulfur Batteries with Long Cycle Life
journal, January 2012

  • Xiao, Lifen; Cao, Yuliang; Xiao, Jie
  • Advanced Materials, Vol. 24, Issue 9, p. 1176-1181
  • DOI: 10.1002/adma.201103392

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018

  • Chen, Shuru; Zheng, Jianming; Mei, Donghai
  • Advanced Materials, Vol. 30, Issue 21
  • DOI: 10.1002/adma.201706102

Dilution of Highly Concentrated LiBF 4 /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi 0.5 Mn 1.5 O 4 Positive Electrodes
journal, January 2017

  • Doi, Takayuki; Shimizu, Yusuke; Hashinokuchi, Michihiro
  • Journal of The Electrochemical Society, Vol. 164, Issue 1
  • DOI: 10.1149/2.0611701jes

Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode
journal, January 2015

  • Bieker, Georg; Winter, Martin; Bieker, Peter
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 14
  • DOI: 10.1039/C4CP05865H

Encapsulated Monoclinic Sulfur for Stable Cycling of Li-S Rechargeable Batteries
journal, September 2013


Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015

  • Yamada, Yuki; Yamada, Atsuo
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0041514jes

Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors
journal, September 2012

  • Choi, Nam-Soon; Chen, Zonghai; Freunberger, Stefan A.
  • Angewandte Chemie International Edition, Vol. 51, Issue 40
  • DOI: 10.1002/anie.201201429

Liquid Structure with Nano-Heterogeneity Promotes Cationic Transport in Concentrated Electrolytes
journal, October 2017


Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification
journal, April 2012

  • Barchasz, Céline; Molton, Florian; Duboc, Carole
  • Analytical Chemistry, Vol. 84, Issue 9
  • DOI: 10.1021/ac2032244

An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes
journal, December 2015


Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells
journal, November 2011

  • Ji, Liwen; Rao, Mumin; Zheng, Haimei
  • Journal of the American Chemical Society, Vol. 133, Issue 46, p. 18522-18525
  • DOI: 10.1021/ja206955k

Recent Advances in Electrolytes for Lithium-Sulfur Batteries
journal, April 2015

  • Zhang, Shiguo; Ueno, Kazuhide; Dokko, Kaoru
  • Advanced Energy Materials, Vol. 5, Issue 16
  • DOI: 10.1002/aenm.201500117

Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy
journal, September 2013

  • Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 19
  • DOI: 10.1021/jz401763d

Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications
journal, March 2017

  • Zheng, Jianming; Lochala, Joshua A.; Kwok, Alexander
  • Advanced Science, Vol. 4, Issue 8
  • DOI: 10.1002/advs.201700032

Prescribing Functional Additives for Treating the Poor Performances of High-Voltage (5 V-class) LiNi 0.5 Mn 1.5 O 4 /MCMB Li-Ion Batteries
journal, December 2017

  • Xu, Gaojie; Pang, Chunguang; Chen, Bingbing
  • Advanced Energy Materials, Vol. 8, Issue 9
  • DOI: 10.1002/aenm.201701398

Carbon–sulfur composites for Li–S batteries: status and prospects
journal, January 2013

  • Wang, Da-Wei; Zeng, Qingcong; Zhou, Guangmin
  • Journal of Materials Chemistry A, Vol. 1, Issue 33
  • DOI: 10.1039/c3ta11045a

Effect of the Hydrofluoroether Cosolvent Structure in Acetonitrile-Based Solvate Electrolytes on the Li + Solvation Structure and Li–S Battery Performance
journal, November 2017

  • Shin, Minjeong; Wu, Heng-Liang; Narayanan, Badri
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 45
  • DOI: 10.1021/acsami.7b11566

Solvent Effect of Room Temperature Ionic Liquids on Electrochemical Reactions in Lithium–Sulfur Batteries
journal, February 2013

  • Park, Jun-Woo; Yamauchi, Kento; Takashima, Eriko
  • The Journal of Physical Chemistry C, Vol. 117, Issue 9
  • DOI: 10.1021/jp400153m

A Highly Reversible Lithium Metal Anode
journal, January 2014

  • Park, Min Sik; Ma, Sang Bok; Lee, Dong Joon
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep03815

Solvent Activity in Electrolyte Solutions Controls Electrochemical Reactions in Li-Ion and Li-Sulfur Batteries
journal, February 2015

  • Moon, Heejoon; Mandai, Toshihiko; Tatara, Ryoichi
  • The Journal of Physical Chemistry C, Vol. 119, Issue 8
  • DOI: 10.1021/jp5128578

Scotch-tape-like exfoliation of graphite assisted with elemental sulfur and graphene–sulfur composites for high-performance lithium-sulfur batteries
journal, January 2013

  • Lin, Tianquan; Tang, Yufeng; Wang, Yaoming
  • Energy & Environmental Science, Vol. 6, Issue 4
  • DOI: 10.1039/c3ee24324a

Anodes for Rechargeable Lithium-Sulfur Batteries
journal, April 2015


Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries
journal, January 2014

  • Cuisinier, M.; Cabelguen, P. -E.; Adams, B. D.
  • Energy Environ. Sci., Vol. 7, Issue 8
  • DOI: 10.1039/C4EE00372A

Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth
journal, February 2016

  • Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook
  • Nature Energy, Vol. 1, Issue 3, Article No. 16010
  • DOI: 10.1038/nenergy.2016.10

Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions
journal, June 2013


Rechargeable Lithium–Sulfur Batteries
journal, July 2014

  • Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500062v

All solid-state polymer electrolytes for high-performance lithium ion batteries
journal, October 2016


Manipulating electrolyte and solid electrolyte interphase to enable safe and efficient Li-S batteries
journal, August 2018


Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, January 2018


Solvate Ionic Liquid Electrolyte for Li–S Batteries
journal, January 2013

  • Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento
  • Journal of The Electrochemical Society, Vol. 160, Issue 8
  • DOI: 10.1149/2.111308jes

A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013

  • Suo, Liumin; Hu, Yong-Sheng; Li, Hong
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2513

A stable graphite negative electrode for the lithium–sulfur battery
journal, January 2015

  • Jeschull, Fabian; Brandell, Daniel; Edström, Kristina
  • Chemical Communications, Vol. 51, Issue 96
  • DOI: 10.1039/C5CC06666B

Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes
journal, March 2016

  • Lin, Dingchang; Liu, Yayuan; Liang, Zheng
  • Nature Nanotechnology, Vol. 11, Issue 7
  • DOI: 10.1038/nnano.2016.32

A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009

  • Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
  • Nature Materials, Vol. 8, Issue 6, p. 500-506
  • DOI: 10.1038/nmat2460

Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014

  • Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng
  • Nature Nanotechnology, Vol. 9, Issue 8
  • DOI: 10.1038/nnano.2014.152

High rate and stable cycling of lithium metal anode
journal, February 2015

  • Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7362