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Title: Additive manufacturing of complex micro-architected graphene aerogels

Abstract

3D graphene foams exhibit immense degradation of mechanical properties. Micro-architecture can alleviate this problem, but no current technique meets the manufacturing requirements. In this work, we developed a light-based 3D printing process to create hierarchical graphene structures with arbitrary complexity and order-of-magnitude finer features, showing enhanced mechanical properties at decreasing density.

Authors:
ORCiD logo [1];  [1];  [2];  [2];  [2];  [2]; ORCiD logo [2];  [1];  [2]
  1. Virginia Polytechnic Institute and State University, Blacksburg, USA
  2. Lawrence Livermore National Laboratory, Livermore, USA
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1464295
Alternate Identifier(s):
OSTI ID: 1542750
Report Number(s):
LLNL-JRNL-749080
Journal ID: ISSN 2051-6347; MHAOAL
Grant/Contract Number:  
16-ERD-051 (LLNL-JRNL-749080); AC52-07NA27344
Resource Type:
Published Article
Journal Name:
Materials Horizons
Additional Journal Information:
Journal Name: Materials Horizons Journal Volume: 5 Journal Issue: 6; Journal ID: ISSN 2051-6347
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Hensleigh, Ryan M., Cui, Huachen, Oakdale, James S., Ye, Jianchao C., Campbell, Patrick G., Duoss, Eric B., Spadaccini, Christopher M., Zheng, Xiaoyu, and Worsley, Marcus A. Additive manufacturing of complex micro-architected graphene aerogels. United Kingdom: N. p., 2018. Web. doi:10.1039/C8MH00668G.
Hensleigh, Ryan M., Cui, Huachen, Oakdale, James S., Ye, Jianchao C., Campbell, Patrick G., Duoss, Eric B., Spadaccini, Christopher M., Zheng, Xiaoyu, & Worsley, Marcus A. Additive manufacturing of complex micro-architected graphene aerogels. United Kingdom. doi:10.1039/C8MH00668G.
Hensleigh, Ryan M., Cui, Huachen, Oakdale, James S., Ye, Jianchao C., Campbell, Patrick G., Duoss, Eric B., Spadaccini, Christopher M., Zheng, Xiaoyu, and Worsley, Marcus A. Mon . "Additive manufacturing of complex micro-architected graphene aerogels". United Kingdom. doi:10.1039/C8MH00668G.
@article{osti_1464295,
title = {Additive manufacturing of complex micro-architected graphene aerogels},
author = {Hensleigh, Ryan M. and Cui, Huachen and Oakdale, James S. and Ye, Jianchao C. and Campbell, Patrick G. and Duoss, Eric B. and Spadaccini, Christopher M. and Zheng, Xiaoyu and Worsley, Marcus A.},
abstractNote = {3D graphene foams exhibit immense degradation of mechanical properties. Micro-architecture can alleviate this problem, but no current technique meets the manufacturing requirements. In this work, we developed a light-based 3D printing process to create hierarchical graphene structures with arbitrary complexity and order-of-magnitude finer features, showing enhanced mechanical properties at decreasing density.},
doi = {10.1039/C8MH00668G},
journal = {Materials Horizons},
number = 6,
volume = 5,
place = {United Kingdom},
year = {2018},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8MH00668G

Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science

Figures / Tables:

Figure 1 Figure 1: A) Four "Green" MAG parts of differing unit-cell structures before pyrolysis from left to right octet-truss, gyroid, cubo-octahedron, and Kelvin foam; B Optical image of pyrolyzed gyroid; C) SEM image of pyrolyzed gyroid with intricate overhang structures D) Zoomed image of pyrolyzed gyroid in "C"; E) Optical imagemore » of pyrolyzed MAG octet-truss, of a different design than shown in "A" supported by a single strawberry blossom filament; F) SEM image of pyrolyzed octet-truss MAG; G) Zoomed image of octet-truss in "E" showing the very high 10 micron resolution achievable in our process« less

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    Works referencing / citing this record:

    3D Printing of Ultralight Biomimetic Hierarchical Graphene Materials with Exceptional Stiffness and Resilience
    journal, July 2019


    3D Printing of Ultralight Biomimetic Hierarchical Graphene Materials with Exceptional Stiffness and Resilience
    journal, July 2019


      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.