Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica

Luz, Ignacio; Soukri, Mustapha; Lail, Marty

doi:10.1002/chem.201800612

Title: Synthesis of Fluidized CO ₂ Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica

Abstract

Abstract A general and efficient method for shaping MOFs into fluidized forms has been developed by direct conversion of metal oxides supported on fluidized mesoporous silica. The resulting fluidized MOF hybrid materials containing diamines coordinated at the open metal sites have been studied as CO ₂ solid sorbents from post‐combustion flue gas showing similar performance than their bulk counterparts. These new fluidized MOF hybrid materials can be used for other applications involving fluidized bed reactor configurations, in which MOFs have never been considered.

Authors:

^[1];

^[1]

RTI International Research Triangle Park NC 27709-2194 USA

Publication Date:: Fri Jun 29 00:00:00 EDT 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1457802

Grant/Contract Number:: FE0026432

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Chemistry - A European Journal

Additional Journal Information:: Journal Name: Chemistry - A European Journal Journal Volume: 24 Journal Issue: 42; Journal ID: ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Luz, Ignacio, Soukri, Mustapha, and Lail, Marty. Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica.  Germany: N. p., 2018. 
Web.  doi:10.1002/chem.201800612.

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                    Luz, Ignacio, Soukri, Mustapha, & Lail, Marty. Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica.  Germany.  https://doi.org/10.1002/chem.201800612

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                    Luz, Ignacio, Soukri, Mustapha, and Lail, Marty. Fri .  
"Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica".  Germany.  https://doi.org/10.1002/chem.201800612.

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@article{osti_1457802,

  title        = {Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica},

  author       = {Luz, Ignacio and Soukri, Mustapha and Lail, Marty},

  abstractNote = {Abstract A general and efficient method for shaping MOFs into fluidized forms has been developed by direct conversion of metal oxides supported on fluidized mesoporous silica. The resulting fluidized MOF hybrid materials containing diamines coordinated at the open metal sites have been studied as CO 2 solid sorbents from post‐combustion flue gas showing similar performance than their bulk counterparts. These new fluidized MOF hybrid materials can be used for other applications involving fluidized bed reactor configurations, in which MOFs have never been considered.},

  doi          = {10.1002/chem.201800612},

  journal      = {Chemistry - A European Journal},

  number       = 42,

  volume       = 24,

  place        = {Germany},

  year         = {Fri Jun 29 00:00:00 EDT 2018},

  month        = {Fri Jun 29 00:00:00 EDT 2018}

}

Copy to clipboard

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Title: Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica

Abstract

Citation Formats

Mesoscopic architectures of porous coordination polymers fabricated by pseudomorphic replication journal, June 2012

Integration of nanosized ZIF-8 particles onto mesoporous TiO 2 nanobeads for enhanced photocatalytic activity journal, January 2017

Platinum–nickel frame within metal-organic framework fabricated in situ for hydrogen enrichment and molecular sieving journal, September 2015

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Alternative synthetic approaches for metal–organic frameworks: transformation from solid matters journal, January 2017

Shaping of Metal–Organic Frameworks: From Fluid to Shaped Bodies and Robust Foams journal, August 2016

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Valuing Metal-Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbents journal, August 2017

MOF positioning technology and device fabrication journal, January 2014

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Scalable Room-Temperature Conversion of Copper(II) Hydroxide into HKUST-1 (Cu 3 (btc) 2 ) journal, November 2012

Understanding the Formation Mechanism of Metal Nanocrystal@MOF-74 Hybrids journal, May 2016

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Title: Synthesis of Fluidized CO ₂ Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica

Mesoscopic architectures of porous coordination polymers fabricated by pseudomorphic replication
journal, June 2012

Integration of nanosized ZIF-8 particles onto mesoporous TiO ₂ nanobeads for enhanced photocatalytic activity
journal, January 2017

Platinum–nickel frame within metal-organic framework fabricated in situ for hydrogen enrichment and molecular sieving
journal, September 2015

Silica-MOF Composites as a Stationary Phase in Liquid Chromatography
journal, June 2010

A Facile and General Coating Approach to Moisture/Water-Resistant Metal–Organic Frameworks with Intact Porosity
journal, November 2014

Manufacturing of metal-organic framework monoliths and their application in CO 2 adsorption
journal, September 2015

Chemical vapour deposition of zeolitic imidazolate framework thin films
journal, December 2015

Boosting the Catalytic Performance of Metal-Organic Frameworks for Steroid Transformations by Confinement within a Mesoporous Scaffold
journal, September 2017

Incorporation of Alkylamine into Metal-Organic Frameworks through a Brønsted Acid-Base Reaction for CO ₂ Capture
journal, September 2016

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO ₂ , N ₂ , and H ₂ O
journal, April 2015

Metal-Organic Frameworks in Monolithic Structures: Rapid Communications of the American Ceramic Society
journal, April 2010

Minute-MOFs: Ultrafast Synthesis of M ₂ (dobpdc) Metal–Organic Frameworks from Divalent Metal Oxide Colloidal Nanocrystals
journal, February 2016

Confining Metal–Organic Framework Nanocrystals within Mesoporous Materials: A General Approach via “Solid-State” Synthesis
journal, August 2017

Flying MOFs: polyamine-containing fluidized MOF/SiO ₂ hybrid materials for CO ₂ capture from post-combustion flue gas
journal, January 2018

A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO ₂ Removal and Air Capture Using Physisorption
journal, July 2016

Controlling Cooperative CO ₂ Adsorption in Diamine-Appended Mg ₂ (dobpdc) Metal–Organic Frameworks
journal, July 2017

Metal–organic framework nanosheets in polymer composite materials for gas separation
journal, November 2014

Vapor-Phase Deposition and Modification of Metal-Organic Frameworks: State-of-the-Art and Future Directions
journal, August 2016

Transformation of Metal–Organic Frameworks/Coordination Polymers into Functional Nanostructured Materials: Experimental Approaches Based on Mechanistic Insights
journal, October 2017

A Diaminopropane-Appended Metal–Organic Framework Enabling Efficient CO ₂ Capture from Coal Flue Gas via a Mixed Adsorption Mechanism
journal, September 2017

New synthetic routes towards MOF production at scale
journal, January 2017

Composites of metal–organic frameworks: Preparation and application in adsorption
journal, April 2014

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015

Alternative synthetic approaches for metal–organic frameworks: transformation from solid matters
journal, January 2017

Shaping of Metal–Organic Frameworks: From Fluid to Shaped Bodies and Robust Foams
journal, August 2016

MOF thin films: existing and future applications
journal, January 2011

Valuing Metal-Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbents
journal, August 2017

MOF positioning technology and device fabrication
journal, January 2014

Calcination temperature-dependent surface structure and physicochemical properties of magnesium oxide
journal, January 2015

Grand Challenges and Future Opportunities for Metal–Organic Frameworks
journal, June 2017

Boosting the Catalytic Performance of Metal-Organic Frameworks for Steroid Transformations by Confinement within a Mesoporous Scaffold
journal, September 2017

Scalable Room-Temperature Conversion of Copper(II) Hydroxide into HKUST-1 (Cu ₃ (btc) ₂ )
journal, November 2012

Understanding the Formation Mechanism of Metal Nanocrystal@MOF-74 Hybrids
journal, May 2016

Engineering structured MOF at nano and macroscales for catalysis and separation
journal, January 2011

Metal–organic framework composites: from fundamentals to applications
journal, January 2015

An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors
journal, January 2017

Imparting surface hydrophobicity to metal–organic frameworks using a facile solution-immersion process to enhance water stability for CO ₂ capture
journal, January 2017

Metal–organic framework composites
journal, January 2014