Solid-state crystallization of metal organic frameworks within mesoporous materials methods and hybrid materials thereof

Minguez, Ignacio Luz; Soukri, Mustapha; Lail, Marty

Title: Solid-state crystallization of metal organic frameworks within mesoporous materials methods and hybrid materials thereof

Patent · Tue Sep 26 00:00:00 EDT 2023

OSTI ID:2222359

Minguez, Ignacio Luz; Soukri, Mustapha; Lail, Marty

A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula A_X(L^−X) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula A_X(L^−X)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula H_X(L^−X)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M^+y(B)y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M^+y(B)_y][H_x(L^−x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M^+yL^−x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.

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Research Organization:: RTI International, Research Triangle Park, NC (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FE0026432

Assignee:: Research Triangle Institute (Research Triangle Park, NC)

Patent Number(s):: 11,767,225

Application Number:: 16/324,296

OSTI ID:: 2222359

Resource Relation:: Patent File Date: 08/10/2017

Country of Publication:: United States

Language:: English

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