Mechanically Robust, Ultraelastic Hierarchical Foam with Tunable Properties via 3D Printing
Abstract
Abstract A mechanically robust, ultraelastic foam with controlled multiscale architectures and tunable mechanical/conductive performance is fabricated via 3D printing. Hierarchical porosity, including both macro‐ and microscaled pores, are produced by the combination of direct ink writing (DIW), acid etching, and phase inversion. The thixotropic inks in DIW are formulated by a simple one‐pot process to disperse duo nanoparticles (nanoclay and silica nanoparticles) in a polyurethane suspension. The resulting lightweight foam exhibits tailorable mechanical strength, unprecedented elasticity (standing over 1000 compression cycles), and remarkable robustness (rapidly and fully recover after a load more than 20 000 times of its own weight). Surface coating of carbon nanotubes yields a conductive elastic foam that can be used as piezoresistivity sensor with high sensitivity. For the first time, this strategy achieves 3D printing of elastic foam with controlled multilevel 3D structures and mechanical/conductive properties. Moreover, the facile ink preparation method can be utilized to fabricate foams of various materials with desirable performance via 3D printing.
- Authors:
-
[2];
[1]
- Case Western Reserve Univ., Cleveland, OH (United States). Department of Macromolecular Science and Engineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE
- OSTI Identifier:
- 1435182
- Alternate Identifier(s):
- OSTI ID: 1432731
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 28; Journal Issue: 21; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 42 ENGINEERING; controllable performance; direct ink writing; hierarchical porosity; stress sensing; ultraelastic foams
Citation Formats
Chen, Qiyi, Cao, Peng-Fei, and Advincula, Rigoberto C. Mechanically Robust, Ultraelastic Hierarchical Foam with Tunable Properties via 3D Printing. United States: N. p., 2018.
Web. doi:10.1002/adfm.201800631.
Chen, Qiyi, Cao, Peng-Fei, & Advincula, Rigoberto C. Mechanically Robust, Ultraelastic Hierarchical Foam with Tunable Properties via 3D Printing. United States. https://doi.org/10.1002/adfm.201800631
Chen, Qiyi, Cao, Peng-Fei, and Advincula, Rigoberto C. Wed .
"Mechanically Robust, Ultraelastic Hierarchical Foam with Tunable Properties via 3D Printing". United States. https://doi.org/10.1002/adfm.201800631. https://www.osti.gov/servlets/purl/1435182.
@article{osti_1435182,
title = {Mechanically Robust, Ultraelastic Hierarchical Foam with Tunable Properties via 3D Printing},
author = {Chen, Qiyi and Cao, Peng-Fei and Advincula, Rigoberto C.},
abstractNote = {Abstract A mechanically robust, ultraelastic foam with controlled multiscale architectures and tunable mechanical/conductive performance is fabricated via 3D printing. Hierarchical porosity, including both macro‐ and microscaled pores, are produced by the combination of direct ink writing (DIW), acid etching, and phase inversion. The thixotropic inks in DIW are formulated by a simple one‐pot process to disperse duo nanoparticles (nanoclay and silica nanoparticles) in a polyurethane suspension. The resulting lightweight foam exhibits tailorable mechanical strength, unprecedented elasticity (standing over 1000 compression cycles), and remarkable robustness (rapidly and fully recover after a load more than 20 000 times of its own weight). Surface coating of carbon nanotubes yields a conductive elastic foam that can be used as piezoresistivity sensor with high sensitivity. For the first time, this strategy achieves 3D printing of elastic foam with controlled multilevel 3D structures and mechanical/conductive properties. Moreover, the facile ink preparation method can be utilized to fabricate foams of various materials with desirable performance via 3D printing.},
doi = {10.1002/adfm.201800631},
journal = {Advanced Functional Materials},
number = 21,
volume = 28,
place = {United States},
year = {Wed Apr 11 00:00:00 EDT 2018},
month = {Wed Apr 11 00:00:00 EDT 2018}
}
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Works referenced in this record:
Electrically conductive thermoplastic elastomer nanocomposites at ultralow graphene loading levels for strain sensor applications
journal, January 2016
- Liu, Hu; Li, Yilong; Dai, Kun
- Journal of Materials Chemistry C, Vol. 4, Issue 1
Multimaterial magnetically assisted 3D printing of composite materials
journal, October 2015
- Kokkinis, Dimitri; Schaffner, Manuel; Studart, André R.
- Nature Communications, Vol. 6, Issue 1
Graphene–sponges as high-performance low-cost anodes for microbial fuel cells
journal, January 2012
- Xie, Xing; Yu, Guihua; Liu, Nian
- Energy & Environmental Science, Vol. 5, Issue 5
A review of biodegradation of synthetic plastic and foams
journal, April 2007
- Gautam, R.; Bassi, A. S.; Yanful, E. K.
- Applied Biochemistry and Biotechnology, Vol. 141, Issue 1
Auxetic compliant flexible PU foams: static and dynamic properties
journal, March 2005
- Scarpa, F.; Pastorino, P.; Garelli, A.
- physica status solidi (b), Vol. 242, Issue 3
Macroscale Elastomeric Conductors Generated from Hydrothermally Synthesized Metal-Polymer Hybrid Nanocable Sponges
journal, July 2011
- Yao, Hong-Bin; Huang, Gang; Cui, Chun-Hua
- Advanced Materials, Vol. 23, Issue 32
Carbon nanotube-coated macroporous sponge for microbial fuel cell electrodes
journal, January 2012
- Xie, Xing; Ye, Meng; Hu, Liangbing
- Energy Environ. Sci., Vol. 5, Issue 1
Integrated 3D-printed reactionware for chemical synthesis and analysis
journal, April 2012
- Symes, Mark D.; Kitson, Philip J.; Yan, Jun
- Nature Chemistry, Vol. 4, Issue 5
3D Printing of Emulsions and Foams into Hierarchical Porous Ceramics
journal, September 2016
- Minas, Clara; Carnelli, Davide; Tervoort, Elena
- Advanced Materials, Vol. 28, Issue 45
Direct Ink Writing of Three-Dimensional Ceramic Structures
journal, December 2006
- Lewis, Jennifer A.; Smay, James E.; Stuecker, John
- Journal of the American Ceramic Society, Vol. 89, Issue 12, p. 3599-3609
Metallic Architectures from 3D-Printed Powder-Based Liquid Inks
journal, November 2015
- Jakus, Adam E.; Taylor, Shannon L.; Geisendorfer, Nicholas R.
- Advanced Functional Materials, Vol. 25, Issue 45
Lightweight, Superelastic, and Mechanically Flexible Graphene/Polyimide Nanocomposite Foam for Strain Sensor Application
journal, August 2015
- Qin, Yuyang; Peng, Qingyu; Ding, Yujie
- ACS Nano, Vol. 9, Issue 9
High performance polymer nanocomposites for additive manufacturing applications
journal, June 2016
- de Leon, Al C.; Chen, Qiyi; Palaganas, Napolabel B.
- Reactive and Functional Polymers, Vol. 103
Development of water-blown bio-based thermoplastic polyurethane foams using bio-derived chain extender
journal, June 2012
- Rashmi, Baralu Jagannatha; Rusu, Daniela; Prashantha, Kalappa
- Journal of Applied Polymer Science, Vol. 128, Issue 1
Porous alumina ceramic scaffolds with biomimetic macro/micro-porous structure using three-dimensional (3-D) ceramic/camphene-based extrusion
journal, November 2015
- Moon, Young-Wook; Choi, Ik-Jun; Koh, Young-Hag
- Ceramics International, Vol. 41, Issue 9
Effect of ethanol composition in water coagulation bath on morphology of PVDF hollow fibre membranes
journal, November 1998
- Deshmukh, S. P.; Li, K.
- Journal of Membrane Science, Vol. 150, Issue 1
3D-Printed Transparent Glass
journal, April 2017
- Nguyen, Du T.; Meyers, Cameron; Yee, Timothy D.
- Advanced Materials, Vol. 29, Issue 26
Materials with structural hierarchy
journal, February 1993
- Lakes, Roderic
- Nature, Vol. 361, Issue 6412
3D Printing Biocompatible Polyurethane/Poly(lactic acid)/Graphene Oxide Nanocomposites: Anisotropic Properties
journal, January 2017
- Chen, Qiyi; Mangadlao, Joey Dacula; Wallat, Jaqueline
- ACS Applied Materials & Interfaces, Vol. 9, Issue 4
Structuring adsorbents and catalysts by processing of porous powders
journal, July 2014
- Akhtar, Farid; Andersson, Linnéa; Ogunwumi, Steven
- Journal of the European Ceramic Society, Vol. 34, Issue 7
Highly Stretchable and UV Curable Elastomers for Digital Light Processing Based 3D Printing
journal, February 2017
- Patel, Dinesh K.; Sakhaei, Amir Hosein; Layani, Michael
- Advanced Materials, Vol. 29, Issue 15
The formation of microporous polyvinylidene difluoride membranes by phase separation
journal, April 1991
- Bottino, A.; Camera-Roda, G.; Capannelli, G.
- Journal of Membrane Science, Vol. 57, Issue 1
Highly Compressible Macroporous Graphene Monoliths via an Improved Hydrothermal Process
journal, May 2014
- Li, Yingru; Chen, Ji; Huang, Liang
- Advanced Materials, Vol. 26, Issue 28
3D-Printing of Lightweight Cellular Composites
journal, June 2014
- Compton, Brett G.; Lewis, Jennifer A.
- Advanced Materials, Vol. 26, Issue 34, p. 5930-5935
New Materials for Rapid Prototyping Applications
journal, July 2005
- Stampfl, Jürgen; Liska, Robert
- Macromolecular Chemistry and Physics, Vol. 206, Issue 13
The formation mechanism of phase inversion membranes
journal, September 1977
- Strathmann, H.; Kock, K.
- Desalination, Vol. 21, Issue 3
Fabrication of stretchable, flexible conductive thermoplastic polyurethane/graphene composites via foaming
journal, January 2015
- Chen, Yuejuan; Li, Yang; Xu, Donghua
- RSC Advances, Vol. 5, Issue 100
Biomimetic superelastic graphene-based cellular monoliths
journal, January 2012
- Qiu, Ling; Liu, Jeffery Z.; Chang, Shery L. Y.
- Nature Communications, Vol. 3, Issue 1
Highly compressible 3D periodic graphene aerogel microlattices
journal, April 2015
- Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.
- Nature Communications, Vol. 6, Issue 1
Metal Additive Manufacturing: A Review
journal, April 2014
- Frazier, William E.
- Journal of Materials Engineering and Performance, Vol. 23, Issue 6
Fabrication of thermoplastic polyurethane tissue engineering scaffold by combining microcellular injection molding and particle leaching
journal, April 2014
- Mi, Hao-Yang; Jing, Xin; Salick, Max R.
- Journal of Materials Research, Vol. 29, Issue 8
3D Printing of Polymer Nanocomposites via Stereolithography
journal, May 2017
- Manapat, Jill Z.; Chen, Qiyi; Ye, Piaoran
- Macromolecular Materials and Engineering, Vol. 302, Issue 9
Mechanically Flexible and Multifunctional Polymer-Based Graphene Foams for Elastic Conductors and Oil-Water Separators
journal, August 2013
- Wu, Chao; Huang, Xingyi; Wu, Xinfeng
- Advanced Materials, Vol. 25, Issue 39
Fabrication of highly expanded thermoplastic polyurethane foams using microcellular injection molding and gas-laden pellets
journal, August 2015
- Sun, Xiaofei; Kharbas, Hrishikesh; Turng, Lih-Sheng
- Polymer Engineering & Science, Vol. 55, Issue 11
Multimaterial magnetically assisted 3D printing of composite materials
text, January 2015
- Dimitri, Kokkinis,; Manuel, Schaffner,; R., Studart, André
- ETH Zurich
Works referencing / citing this record:
Emerging Technologies of Flexible Pressure Sensors: Materials, Modeling, Devices, and Manufacturing
journal, January 2019
- Huang, Yan; Fan, Xiangyu; Chen, Shih‐Chi
- Advanced Functional Materials, Vol. 29, Issue 12
3D Printed Multifunctional, Hyperelastic Silicone Rubber Foam
journal, April 2019
- Chen, Qiyi; Zhao, Jiayu; Ren, Jingbo
- Advanced Functional Materials, Vol. 29, Issue 23
3D Printing of Textiles: Potential Roadmap to Printing with Fibers
journal, December 2019
- Chatterjee, Kony; Ghosh, Tushar K.
- Advanced Materials, Vol. 32, Issue 4
Architected Polymer Foams via Direct Bubble Writing
journal, September 2019
- Visser, Claas Willem; Amato, Dahlia N.; Mueller, Jochen
- Advanced Materials, Vol. 31, Issue 46
3D Printing of a Robust Polyamide‐12‐Carbon Black Composite via Selective Laser Sintering: Thermal and Electrical Conductivity
journal, February 2019
- Espera, Alejandro H.; Valino, Arnaldo D.; Palaganas, Jerome O.
- Macromolecular Materials and Engineering, Vol. 304, Issue 4
Bone Defect Model Dependent Optimal Pore Sizes of 3D‐Plotted Beta‐Tricalcium Phosphate Scaffolds for Bone Regeneration
journal, May 2019
- Diao, Jingjing; Ding, Huanwen; Huang, Minqiang
- Small Methods, Vol. 3, Issue 11
Carbonized cotton fabric-based multilayer piezoresistive pressure sensors
journal, April 2019
- Zhang, Lin; Li, Hongqiang; Lai, Xuejun
- Cellulose, Vol. 26, Issue 8
3D-printing and advanced manufacturing for electronics
journal, February 2019
- Espera, Alejandro H.; Dizon, John Ryan C.; Chen, Qiyi
- Progress in Additive Manufacturing, Vol. 4, Issue 3
Digitally printed stretchable electronics: a review
journal, January 2019
- Fernandes, Daniel Félix; Majidi, Carmel; Tavakoli, Mahmoud
- Journal of Materials Chemistry C, Vol. 7, Issue 45
Recent advances in lithographic fabrication of micro-/nanostructured polydimethylsiloxanes and their soft electronic applications
journal, November 2019
- Cho, Donghwi; Park, Junyong; Kim, Taehoon
- Journal of Semiconductors, Vol. 40, Issue 11
Machine learning for composite materials
journal, March 2019
- Chen, Chun-Teh; Gu, Grace X.
- MRS Communications, Vol. 9, Issue 02