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Title: Correlation between Geometrically Induced Oxygen Octahedral Tilts and Multiferroic Behaviors in BiFeO3 Films

Abstract

Abstract The equilibrium position of atoms in a unit cell is directly connected to crystal functionalities, e.g., ferroelectricity, ferromagnetism, and piezoelectricity. The artificial tuning of the energy landscape can involve repositioning atoms as well as manipulating the functionalities of perovskites (ABO 3 ), which are good model systems to test this legacy. Mechanical energy from external sources accommodating various clamping substrates is utilized to perturb the energy state of perovskite materials fabricated on the substrates and consequently change their functionalities; however, this approach yields undesired complex behaviors of perovskite crystals, such as lattice distortion, displacement of B atoms, and/or tilting of oxygen octahedra. Owing to complimentary collaborations between experimental and theoretical studies, the effects of both lattice distortion and displacement of B atoms are well understood so far, which leaves us a simple question: Can we exclusively control the positions of oxygen atoms in perovskites for functionality manipulation? Here the artificial manipulation of oxygen octahedral tilt angles within multiferroic BiFeO 3 thin films using strong oxygen octahedral coupling with bottom SrRuO 3 layers is reported, which opens up new possibilities of oxygen octahedral engineering.

Authors:
 [1];  [2];  [3];  [4];  [5];  [6];  [7];  [1];  [8];  [8];  [8];  [9];  [10];  [11];  [4];  [12];  [12]; ORCiD logo [4]
+ Show Author Affiliations
  1. School of Materials Science and Engineering, Gwangju Institute of Science and Technology, Gwangju (South Korea)
  2. Sungkyunkwan University (SKKU), Suwon (South Korea); Institute for Basic Science (IBS), Suwon (South Korea). Center for Integrated Nanostructure Physics
  3. Ulsan National Institute of Science and Technology, Ulsan (South Korea). School of Energy and Chemical Engineering
  4. Gwangju Institute of Science and Technology (South Korea). School of Materials Science and Engineering
  5. Ulsan National Institute of Science and Technology (South Korea). UNIST Central Research Facilities (UCRF)
  6. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Cardiff University (United Kingdom). Cardiff Catalyst Institute, School of Chemistry
  7. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
  8. School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon (South Korea)
  9. Pohang Accelerator Laboratory (South Korea)
  10. Kyung Hee University, Yongin (South Korea). Department of Applied Physics and Institute of Natural Sciences
  11. Gwangju Institute of Science and Technology (South Korea). Department of Physics and Photon Science
  12. Ulsan National Institute of Science and Technology (South Korea). School of Energy and Chemical Engineering
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE
OSTI Identifier:
1435173
Alternate Identifier(s):
OSTI ID: 1429549
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Volume: 28; Journal Issue: 19; Journal ID: ISSN 1616-301X
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; BiFeO3; ferroelectrics; multiferroics; oxygen octahedral tilting; weak-ferromagnetics

Citation Formats

Lee, Sung Su, Kim, Young-Min, Lee, Hyun-Jae, Seo, Okkyun, Jeong, Hu Young, He, Qian, Borisevich, Albina Y., Kang, Boyoun, Kwon, Owoong, Kang, Seunghun, Kim, Yunseok, Koo, Tae Yeong, Rhyee, Jong-Soo, Noh, Do Young, Cho, Beongki, Seo, Ji Hui, Lee, Jun Hee, and Jo, Ji Young. Correlation between Geometrically Induced Oxygen Octahedral Tilts and Multiferroic Behaviors in BiFeO3 Films. United States: N. p., 2018. Web. doi:10.1002/adfm.201800839.
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Lee, Sung Su, Kim, Young-Min, Lee, Hyun-Jae, Seo, Okkyun, Jeong, Hu Young, He, Qian, Borisevich, Albina Y., Kang, Boyoun, Kwon, Owoong, Kang, Seunghun, Kim, Yunseok, Koo, Tae Yeong, Rhyee, Jong-Soo, Noh, Do Young, Cho, Beongki, Seo, Ji Hui, Lee, Jun Hee, & Jo, Ji Young. Correlation between Geometrically Induced Oxygen Octahedral Tilts and Multiferroic Behaviors in BiFeO3 Films. United States. https://doi.org/10.1002/adfm.201800839
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Lee, Sung Su, Kim, Young-Min, Lee, Hyun-Jae, Seo, Okkyun, Jeong, Hu Young, He, Qian, Borisevich, Albina Y., Kang, Boyoun, Kwon, Owoong, Kang, Seunghun, Kim, Yunseok, Koo, Tae Yeong, Rhyee, Jong-Soo, Noh, Do Young, Cho, Beongki, Seo, Ji Hui, Lee, Jun Hee, and Jo, Ji Young. Mon . "Correlation between Geometrically Induced Oxygen Octahedral Tilts and Multiferroic Behaviors in BiFeO3 Films". United States. https://doi.org/10.1002/adfm.201800839. https://www.osti.gov/servlets/purl/1435173.
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@article{osti_1435173,
title = {Correlation between Geometrically Induced Oxygen Octahedral Tilts and Multiferroic Behaviors in BiFeO3 Films},
author = {Lee, Sung Su and Kim, Young-Min and Lee, Hyun-Jae and Seo, Okkyun and Jeong, Hu Young and He, Qian and Borisevich, Albina Y. and Kang, Boyoun and Kwon, Owoong and Kang, Seunghun and Kim, Yunseok and Koo, Tae Yeong and Rhyee, Jong-Soo and Noh, Do Young and Cho, Beongki and Seo, Ji Hui and Lee, Jun Hee and Jo, Ji Young},
abstractNote = {Abstract The equilibrium position of atoms in a unit cell is directly connected to crystal functionalities, e.g., ferroelectricity, ferromagnetism, and piezoelectricity. The artificial tuning of the energy landscape can involve repositioning atoms as well as manipulating the functionalities of perovskites (ABO 3 ), which are good model systems to test this legacy. Mechanical energy from external sources accommodating various clamping substrates is utilized to perturb the energy state of perovskite materials fabricated on the substrates and consequently change their functionalities; however, this approach yields undesired complex behaviors of perovskite crystals, such as lattice distortion, displacement of B atoms, and/or tilting of oxygen octahedra. Owing to complimentary collaborations between experimental and theoretical studies, the effects of both lattice distortion and displacement of B atoms are well understood so far, which leaves us a simple question: Can we exclusively control the positions of oxygen atoms in perovskites for functionality manipulation? Here the artificial manipulation of oxygen octahedral tilt angles within multiferroic BiFeO 3 thin films using strong oxygen octahedral coupling with bottom SrRuO 3 layers is reported, which opens up new possibilities of oxygen octahedral engineering.},
doi = {10.1002/adfm.201800839},
journal = {Advanced Functional Materials},
number = 19,
volume = 28,
place = {United States},
year = {Mon Mar 26 00:00:00 EDT 2018},
month = {Mon Mar 26 00:00:00 EDT 2018}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adfm.201800839
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Cited by: 18 works
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Figures / Tables:

Figure 1 Figure 1: Crystal structure and oxygen octahedral pattern of BFO/M-SRO and BFO/T-SRO films. a) Reciprocal space (00L) scans of M-BFO/M-SRO/ STO(001) (red) and T-BFO/T-SRO/STO(001) films (blue). b) Schematic of tilt axes and angles of oxygen octahedra. c) Schematic models of oxygen octahedral patterns for BFO/M-SRO and BFO/T-SRO. We defined themore » out-of-plane direction as [001]pc axes, which is the direction of film growth. d) (from top to bottom) Reciprocal space L-scans around half-integer reflections along (0.5 0 L), (0 0.5 L), (1.5 0.5 L), (0.5 1.5 L), and (0.5 0.5 L).  and * marks indicate the diffraction peaks originated from BFO and SRO films.« less
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    Works referencing / citing this record:

    Oxygen octahedral distortions in compressively strained SrRuO 3 epitaxial thin films
    journal, June 2018

    • Kan, Daisuke; Anada, Masato; Wakabayashi, Yusuke
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    Ferroelectricity and magnetoelectric coupling in hexagonal Lu 0.5 In 0.5 FeO 3 ceramics
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    • Liu, Mei Ying; Gao, Ting Ting; Zhu, Xiao Li
    • Journal of Applied Physics, Vol. 126, Issue 16
    • DOI: 10.1063/1.5117344
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