Oxygen octahedral tilt ordering in (Na1/2Bi1/2)TiO3 ferroelectric thin films

Pramanick, A.; Paterson, A. R.; Denis, L.; Abbas, W.; Niu, G.; Ren, W.; Zhao, J.; Dai, L.; Borkiewicz, O.; Ren, Y.; Ho, D.; Trolier-McKinstry, S.; Jones, J. L.

doi:10.1063/1.5127212

Title: Oxygen octahedral tilt ordering in (Na_1/2Bi_1/2)TiO₃ ferroelectric thin films

Journal Article · 12 January 2020 · Applied Physics Letters

DOI: https://doi.org/10.1063/1.5127212 · OSTI ID:1774246

^[1];

^[2];

^[3]; Abbas, W. ^[1]; Niu, G. ^[4]; Ren, W. ^[4];

^[4]; Dai, L. ^[4];

^[5]; Ren, Y. ^[5];

^[6];

^[3]; Jones, J. L. ^[2]

City Univ. of Hong Kong (Hong Kong)
North Carolina State Univ., Raleigh, NC (United States)
Pennsylvania State Univ., University Park, PA (United States)
Xi'an Jiaotong Univ., Shaanxi (China)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Hong Kong Univ. (Hong Kong)

Oxygen octahedra tilt (OOT) transition is the most common type of distortion in inorganic ABO₃ compounds with a perovskite crystal structure. The importance of OOT transitions is underlined by accompanying changes in the B-O and A-O bonding environments, which consequently affects the electronic states and hence influences electrical, magnetic, and superconducting properties of many perovskite compounds. In recent years, controlled manipulation of the OOT order in perovskite thin film ferroelectrics has been attempted through heteroepitaxial strain engineering. The current study demonstrates an alternative approach whereby OOT ordering in a 200 nm thick polycrystalline thin film of (Na_1/2Bi_1/2)TiO₃ (NBT) Pb-free ferroelectric is induced by applying electric-field along the 111 octahedral tilt axis, which is furthermore enabled by a strong (111) crystallographic texture normal to the film surface. In situ x-ray diffraction reveals that electric-field-induced OOT ordering proceeds through nucleation and rapid growth of domains with ordered a^⁻a^⁻a^⁻ tilting, followed by an increase in the tilt angle within the ordered domains.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1774246

Journal Information:: Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 2 Vol. 116; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (43)

Nano- and Mesoscale Structure of Na$_{1 \over 2}$Bi$_{1 \over 2}$TiO3: A TEM Perspective Levin, Igor; Reaney, Ian M. Advanced Functional Materials, Vol. 22, Issue 16 https://doi.org/10.1002/adfm.201200282	journal	May 2012
Bifurcated Polarization Rotation in Bismuth-Based Piezoelectrics Keeble, Dean S.; Barney, Emma R.; Keen, David A. Advanced Functional Materials, Vol. 23, Issue 2 https://doi.org/10.1002/adfm.201201564	journal	August 2012
Nanofragmentation of Ferroelectric Domains During Polarization Fatigue Guo, Hanzheng; Liu, Xiaoming; Rödel, Jürgen Advanced Functional Materials, Vol. 25, Issue 2 https://doi.org/10.1002/adfm.201402740	journal	November 2014
Structure and Properties of Functional Oxide Thin Films: Insights From Electronic-Structure Calculations Rondinelli, James M.; Spaldin, Nicola A. Advanced Materials, Vol. 23, Issue 30 https://doi.org/10.1002/adma.201101152	journal	July 2011
Atomic structures of two rhombohedral ferroelectric phases in the Pb(Zr, Ti)O3 solid solution series Michel, Christian; Moreau, Jean-Michel; Achenbach, Gary D. Solid State Communications, Vol. 7, Issue 12 https://doi.org/10.1016/0038-1098(69)90429-3	journal	June 1969
A transmission electron microscopy study of the A-site disordered perovskite Na0.5Bi0.5TiO3 Dorcet, V.; Trolliard, G. Acta Materialia, Vol. 56, Issue 8 https://doi.org/10.1016/j.actamat.2007.12.027	journal	May 2008
Transferring lead-free piezoelectric ceramics into application Rödel, Jürgen; Webber, Kyle G.; Dittmer, Robert Journal of the European Ceramic Society, Vol. 35, Issue 6 https://doi.org/10.1016/j.jeurceramsoc.2014.12.013	journal	June 2015
Life cycle assessment and environmental profile evaluation of lead-free piezoelectrics in comparison with lead zirconate titanate Ibn-Mohammed, T.; Reaney, I. M.; Koh, S. C. L. Journal of the European Ceramic Society, Vol. 38, Issue 15 https://doi.org/10.1016/j.jeurceramsoc.2018.06.044	journal	December 2018
Response of intergrown microstructure to an electric field and its consequences in the lead-free piezoelectric bismuth sodium titanate Liu, Yun; Norén, Lasse; Studer, Andrew J. Journal of Solid State Chemistry, Vol. 187 https://doi.org/10.1016/j.jssc.2012.01.027	journal	March 2012
Diffuse X-ray scattering in the lead-free piezoelectric crystals Na1/2Bi1/2TiO3 and Ba-doped Na1/2Bi1/2TiO3 Thomas, P. A.; Trujillo, S.; Boudard, M. Solid State Sciences, Vol. 12, Issue 3 https://doi.org/10.1016/j.solidstatesciences.2009.06.008	journal	March 2010
Recoverable Self-Polarization in Lead-Free Bismuth Sodium Titanate Piezoelectric Thin Films Zhao, Jinyan; Ren, Wei; Niu, Gang ACS Applied Materials & Interfaces, Vol. 9, Issue 34 https://doi.org/10.1021/acsami.7b04033	journal	August 2017
Reinvestigation of Phase Transitions in Na _0.5 Bi _0.5 TiO ₃ by TEM. Part I: First Order Rhombohedral to Orthorhombic Phase Transition Dorcet, V.; Trolliard, G.; Boullay, P. Chemistry of Materials, Vol. 20, Issue 15 https://doi.org/10.1021/cm8004634	journal	August 2008
Origin of ferroelectricity in perovskite oxides Cohen, Ronald E. Nature, Vol. 358, Issue 6382 https://doi.org/10.1038/358136a0	journal	July 1992
The origin of ferroelectricity in magnetoelectric YMnO3 Van Aken, Bas B.; Palstra, Thomas T. M.; Filippetti, Alessio Nature Materials, Vol. 3, Issue 3 https://doi.org/10.1038/nmat1080	journal	February 2004
Electric-field-induced local and mesoscale structural changes in polycrystalline dielectrics and ferroelectrics Usher, Tedi-Marie; Levin, Igor; Daniels, John E. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep14678	journal	October 2015
Reconciling Local Structure Disorder and the Relaxor State in (Bi1/2Na1/2)TiO3-BaTiO3 Groszewicz, Pedro B.; Gröting, Melanie; Breitzke, Hergen Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep31739	journal	August 2016
Electric field effect on the rhombohedral–rhombohedral phase transformation in tin modified lead zirconate titanate ceramics Yang, Pin; Rodriguez, Mark A.; Burns, George R. Journal of Applied Physics, Vol. 95, Issue 7 https://doi.org/10.1063/1.1650893	journal	April 2004
Octahedral tilt transitions in relaxed epitaxial Pb(Zr ₁₋ _x Ti _x )O ₃ films Tinberg, Daniel S.; Johnson-Wilke, Raegan L.; Fong, Dillon D. Journal of Applied Physics, Vol. 109, Issue 9 https://doi.org/10.1063/1.3580328	journal	May 2011
Structural origins of relaxor behavior in a 0.96(Bi1/2Na1/2)TiO3–0.04BaTiO3 single crystal under electric field Daniels, John E.; Jo, Wook; Rödel, Jürgen Applied Physics Letters, Vol. 98, Issue 25 https://doi.org/10.1063/1.3602316	journal	June 2011
Phase transition sequence in sodium bismuth titanate observed using high-resolution x-ray diffraction Aksel, Elena; Forrester, Jennifer S.; Kowalski, Benjamin Applied Physics Letters, Vol. 99, Issue 22 https://doi.org/10.1063/1.3664393	journal	November 2011
Origin of large recoverable strain in 0.94(Bi 0.5 Na 0.5 )TiO 3 -0.06BaTiO 3 near the ferroelectric-relaxor transition Simons, Hugh; Daniels, John E.; Glaum, Julia Applied Physics Letters, Vol. 102, Issue 6 https://doi.org/10.1063/1.4790285	journal	February 2013
A covalency model of ferroic phase transitions in perovskites Thomann, H. Ferroelectrics, Vol. 73, Issue 1 https://doi.org/10.1080/00150198708227917	journal	June 1987
Two-dimensional detector software: From real detector to idealised image or two-theta scan Hammersley, A. P.; Svensson, S. O.; Hanfland, M. High Pressure Research, Vol. 14, Issue 4-6, p. 235-248 https://doi.org/10.1080/08957959608201408	journal	January 1996
High-pressure x-ray scattering of oxides with a nanoscale local structure: Application to Na 1 / 2 Bi 1 / 2 TiO 3 Kreisel, J.; Bouvier, P.; Dkhil, B. Physical Review B, Vol. 68, Issue 1 https://doi.org/10.1103/PhysRevB.68.014113	journal	July 2003
Review of crystal and domain structures in the PbZr x Ti 1 − x O 3 solid solution Woodward, David I.; Knudsen, Jesper; Reaney, Ian M. Physical Review B, Vol. 72, Issue 10 https://doi.org/10.1103/PhysRevB.72.104110	journal	September 2005
Structure and properties of Fe-modified Na 0.5 Bi 0.5 TiO 3 at ambient and elevated temperature Aksel, Elena; Forrester, Jennifer S.; Kowalski, Benjamin Physical Review B, Vol. 85, Issue 2 https://doi.org/10.1103/PhysRevB.85.024121	journal	January 2012
Electric-field-driven monoclinic-to-rhombohedral transformation in Na 1 / 2 Bi 1 / 2 TiO 3 Rao, Badari Narayana; Ranjan, Rajeev Physical Review B, Vol. 86, Issue 13 https://doi.org/10.1103/PhysRevB.86.134103	journal	October 2012
Ferroelectric-ferroelectric phase coexistence in Na 1 / 2 Bi 1 / 2 TiO 3 Rao, Badari Narayana; Fitch, Andy N.; Ranjan, Rajeev Physical Review B, Vol. 87, Issue 6 https://doi.org/10.1103/PhysRevB.87.060102	journal	February 2013
Local structural disorder and its influence on the average global structure and polar properties in Na 0.5 Bi 0.5 TiO 3 Rao, Badari Narayana; Datta, Ranjan; Chandrashekaran, S. Selva Physical Review B, Vol. 88, Issue 22 https://doi.org/10.1103/PhysRevB.88.224103	journal	December 2013
Magnetoelectric effects via pentalinear interactions Zhao, Hong Jian; Grisolia, M. N.; Yang, Yurong Physical Review B, Vol. 92, Issue 23 https://doi.org/10.1103/PhysRevB.92.235133	journal	December 2015
Creation and Destruction of Morphotropic Phase Boundaries through Electrical Poling: A Case Study of Lead-Free ( Bi 1 / 2 Na 1 / 2 ) TiO 3 − BaTiO 3 Piezoelectrics Ma, Cheng; Guo, Hanzheng; Beckman, Scott P. Physical Review Letters, Vol. 109, Issue 10 https://doi.org/10.1103/PhysRevLett.109.107602	journal	September 2012
Prediction of a Novel Magnetoelectric Switching Mechanism in Multiferroics Yang, Yurong; Íñiguez, Jorge; Mao, Ai-Jie Physical Review Letters, Vol. 112, Issue 5 https://doi.org/10.1103/PhysRevLett.112.057202	journal	February 2014
Octahedral tilting instabilities in inorganic halide perovskites Bechtel, Jonathon S.; Van der Ven, Anton Physical Review Materials, Vol. 2, Issue 2 https://doi.org/10.1103/PhysRevMaterials.2.025401	journal	February 2018
Evidence for a non-rhombohedral average structure in the lead-free piezoelectric material Na _0.5 Bi _0.5 TiO ₃ Gorfman, S.; Thomas, P. A. Journal of Applied Crystallography, Vol. 43, Issue 6 https://doi.org/10.1107/S002188981003342X	journal	October 2010
Field-induced phase transition in Bi _1/2 Na _1/2 TiO ₃ -based lead-free piezoelectric ceramics Hinterstein, Manuel; Knapp, Michael; Hölzel, Markus Journal of Applied Crystallography, Vol. 43, Issue 6 https://doi.org/10.1107/S0021889810038264	journal	October 2010
The tetragonal phase of Na 0.5 Bi 0.5 TiO 3 – a new variant of the perovskite structure Jones, G. O.; Thomas, P. A. Acta Crystallographica Section B Structural Science, Vol. 56, Issue 3 https://doi.org/10.1107/S0108768100001166	journal	June 2000
Investigation of the structure and phase transitions in the novel A-site substituted distorted perovskite compound Na _0.5 Bi _0.5 TiO ₃ Jones, G. O.; Thomas, P. A. Acta Crystallographica Section B Structural Science, Vol. 58, Issue 2 https://doi.org/10.1107/S0108768101020845	journal	March 2002
Octahedral Tilting in Perovskites. I. Geometrical Considerations Woodward, P. M. Acta Crystallographica Section B Structural Science, Vol. 53, Issue 1 https://doi.org/10.1107/S0108768196010713	journal	February 1997
Simple ways of determining perovskite structures Glazer, A. M. Acta Crystallographica Section A, Vol. 31, Issue 6 https://doi.org/10.1107/S0567739475001635	journal	November 1975
The classification of tilted octahedra in perovskites Glazer, A. M. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 11 https://doi.org/10.1107/S0567740872007976	journal	November 1972
Topology and temperature dependence of the diffuse X-ray scattering in Na 0.5 Bi 0.5 TiO 3 ferroelectric single crystals Gorfman, Semën; Keeble, Dean S.; Bombardi, Alessandro Journal of Applied Crystallography, Vol. 48, Issue 5 https://doi.org/10.1107/S160057671501571X	journal	September 2015
Structure and electrical properties of Na 0.5 Bi 0.5 TiO 3 ferroelectric thick films derived from a polymer modified sol-gel method IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 58, Issue 10 https://doi.org/10.1109/TUFFC.2011.2054	journal	October 2011
Relaxor-ferroelectric transitions: Sodium bismuth titanate derivatives Paterson, Alisa R.; Nagata, Hajime; Tan, Xiaoli MRS Bulletin, Vol. 43, Issue 8 https://doi.org/10.1557/mrs.2018.156	journal	August 2018

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Title: Oxygen octahedral tilt ordering in (Na_1/2Bi_1/2)TiO₃ ferroelectric thin films