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Title: Controlling octahedral rotations in a perovskite via strain doping

Abstract

The perovskite unit cell is the fundamental building block of many functional materials. The manipulation of this crystal structure is known to be of central importance to controlling many technologically promising phenomena related to superconductivity, multiferroicity, mangetoresistivity, and photovoltaics. The broad range of properties that this structure can exhibit is in part due to the centrally coordinated octahedra bond flexibility, which allows for a multitude of distortions from the ideal highly symmetric structure. However, continuous and fine manipulation of these distortions has never been possible. Here, we show that controlled insertion of He atoms into an epitaxial perovskite film can be used to finely tune the lattice symmetry by modifying the local distortions, i.e., octahedral bonding angle and length. Orthorhombic SrRuO3 films coherently grown on SrTiO3 substrates are used as a model system. Implanted He atoms are confirmed to induce out-of-plane strain, which provides the ability to controllably shift the bulk-like orthorhombically distorted phase to a tetragonal structure by shifting the oxygen octahedra rotation pattern. Lastly, these results demonstrate that He implantation offers an entirely new pathway to strain engineering of perovskite-based complex oxide thin films, useful for creating new functionalities or properties in perovskite materials.

Authors:
 [1];  [1];  [1];  [1];  [2];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1255673
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 6; Journal Issue: 6; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; design, synthesis and processing; phase transitions and critical phenomena; structure of solids and liquids; surfaces, interfaces and thin films

Citation Formats

Herklotz, Andreas, Biegalski, Michael D., Lee, Ho Nyung, Ward, Thomas Zac, Wong, A. T., and Meyer, T. Controlling octahedral rotations in a perovskite via strain doping. United States: N. p., 2016. Web. doi:10.1038/srep26491.
Herklotz, Andreas, Biegalski, Michael D., Lee, Ho Nyung, Ward, Thomas Zac, Wong, A. T., & Meyer, T. Controlling octahedral rotations in a perovskite via strain doping. United States. doi:10.1038/srep26491.
Herklotz, Andreas, Biegalski, Michael D., Lee, Ho Nyung, Ward, Thomas Zac, Wong, A. T., and Meyer, T. Tue . "Controlling octahedral rotations in a perovskite via strain doping". United States. doi:10.1038/srep26491. https://www.osti.gov/servlets/purl/1255673.
@article{osti_1255673,
title = {Controlling octahedral rotations in a perovskite via strain doping},
author = {Herklotz, Andreas and Biegalski, Michael D. and Lee, Ho Nyung and Ward, Thomas Zac and Wong, A. T. and Meyer, T.},
abstractNote = {The perovskite unit cell is the fundamental building block of many functional materials. The manipulation of this crystal structure is known to be of central importance to controlling many technologically promising phenomena related to superconductivity, multiferroicity, mangetoresistivity, and photovoltaics. The broad range of properties that this structure can exhibit is in part due to the centrally coordinated octahedra bond flexibility, which allows for a multitude of distortions from the ideal highly symmetric structure. However, continuous and fine manipulation of these distortions has never been possible. Here, we show that controlled insertion of He atoms into an epitaxial perovskite film can be used to finely tune the lattice symmetry by modifying the local distortions, i.e., octahedral bonding angle and length. Orthorhombic SrRuO3 films coherently grown on SrTiO3 substrates are used as a model system. Implanted He atoms are confirmed to induce out-of-plane strain, which provides the ability to controllably shift the bulk-like orthorhombically distorted phase to a tetragonal structure by shifting the oxygen octahedra rotation pattern. Lastly, these results demonstrate that He implantation offers an entirely new pathway to strain engineering of perovskite-based complex oxide thin films, useful for creating new functionalities or properties in perovskite materials.},
doi = {10.1038/srep26491},
journal = {Scientific Reports},
number = 6,
volume = 6,
place = {United States},
year = {2016},
month = {5}
}

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Cited by: 8 works
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