skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries

Abstract

Bi@Graphite was synthesized as an ultra-fast and ultra-stable anode material for SIBs with 70% capacity retention at 300C with respect to 1C.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1];  [1]; ORCiD logo [2];  [2]; ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, USA
  2. Department of Chemistry and Biochemistry, University of Maryland, College Park, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1434117
Grant/Contract Number:  
DESC0001160; DEAR0000389
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 5; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Chen, Ji, Fan, Xiulin, Ji, Xiao, Gao, Tao, Hou, Singyuk, Zhou, Xiuquan, Wang, Luning, Wang, Fei, Yang, Chongyin, Chen, Long, and Wang, Chunsheng. Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries. United Kingdom: N. p., 2018. Web. doi:10.1039/C7EE03016A.
Chen, Ji, Fan, Xiulin, Ji, Xiao, Gao, Tao, Hou, Singyuk, Zhou, Xiuquan, Wang, Luning, Wang, Fei, Yang, Chongyin, Chen, Long, & Wang, Chunsheng. Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries. United Kingdom. doi:10.1039/C7EE03016A.
Chen, Ji, Fan, Xiulin, Ji, Xiao, Gao, Tao, Hou, Singyuk, Zhou, Xiuquan, Wang, Luning, Wang, Fei, Yang, Chongyin, Chen, Long, and Wang, Chunsheng. Mon . "Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries". United Kingdom. doi:10.1039/C7EE03016A.
@article{osti_1434117,
title = {Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries},
author = {Chen, Ji and Fan, Xiulin and Ji, Xiao and Gao, Tao and Hou, Singyuk and Zhou, Xiuquan and Wang, Luning and Wang, Fei and Yang, Chongyin and Chen, Long and Wang, Chunsheng},
abstractNote = {Bi@Graphite was synthesized as an ultra-fast and ultra-stable anode material for SIBs with 70% capacity retention at 300C with respect to 1C.},
doi = {10.1039/C7EE03016A},
journal = {Energy & Environmental Science},
number = 5,
volume = 11,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C7EE03016A

Citation Metrics:
Cited by: 30 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Raman spectroscopy of graphene and graphite: Disorder, electron–phonon coupling, doping and nonadiabatic effects
journal, July 2007


Review—Hard Carbon Negative Electrode Materials for Sodium-Ion Batteries
journal, January 2015

  • Irisarri, E.; Ponrouch, A.; Palacin, M. R.
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0091514jes

The First Report on Excellent Cycling Stability and Superior Rate Capability of Na 3 V 2 (PO 4 ) 3 for Sodium Ion Batteries
journal, November 2012

  • Saravanan, Kuppan; Mason, Chad W.; Rudola, Ashish
  • Advanced Energy Materials, Vol. 3, Issue 4
  • DOI: 10.1002/aenm.201200803

Critical Insight into the Relentless Progression Toward Graphene and Graphene-Containing Materials for Lithium-Ion Battery Anodes
journal, December 2016

  • Raccichini, Rinaldo; Varzi, Alberto; Wei, Di
  • Advanced Materials, Vol. 29, Issue 11
  • DOI: 10.1002/adma.201603421

Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies
journal, July 2011

  • Cançado, L. G.; Jorio, A.; Ferreira, E. H. Martins
  • Nano Letters, Vol. 11, Issue 8, p. 3190-3196
  • DOI: 10.1021/nl201432g

High-Performance P2-Phase Na 2/3 Mn 0.8 Fe 0.1 Ti 0.1 O 2 Cathode Material for Ambient-Temperature Sodium-Ion Batteries
journal, December 2015


Phase selective synthesis of copper sulfides by non-hydrolytic sol–gel methods
journal, January 2014

  • Zhou, Xiuquan; Soldat, Anne Christine; Lind, Cora
  • RSC Adv., Vol. 4, Issue 2
  • DOI: 10.1039/C3RA45053H

Alloy-Based Anode Materials toward Advanced Sodium-Ion Batteries
journal, June 2017


Use of Graphite as a Highly Reversible Electrode with Superior Cycle Life for Sodium-Ion Batteries by Making Use of Co-Intercalation Phenomena
journal, July 2014

  • Jache, Birte; Adelhelm, Philipp
  • Angewandte Chemie International Edition, Vol. 53, Issue 38
  • DOI: 10.1002/anie.201403734

A fundamental parameters approach to X-ray line-profile fitting
journal, April 1992


Surface capacitive contributions: Towards high rate anode materials for sodium ion batteries
journal, March 2015


The role of graphene for electrochemical energy storage
journal, December 2014

  • Raccichini, Rinaldo; Varzi, Alberto; Passerini, Stefano
  • Nature Materials, Vol. 14, Issue 3
  • DOI: 10.1038/nmat4170

An improved Hummers method for eco-friendly synthesis of graphene oxide
journal, November 2013


Quantifying ion-induced defects and Raman relaxation length in graphene
journal, April 2010


Monodisperse Antimony Nanocrystals for High-Rate Li-ion and Na-ion Battery Anodes: Nano versus Bulk
journal, February 2014

  • He, Meng; Kravchyk, Kostiantyn; Walter, Marc
  • Nano Letters, Vol. 14, Issue 3
  • DOI: 10.1021/nl404165c

Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life
journal, January 2016


Incorporation of Mercury into Graphitevia K/Hg Intercalation Compounds
journal, January 1983

  • Rabinovitz, Mordecai; Selig, Henry; Levy, Jaacov
  • Angewandte Chemie International Edition in English, Vol. 22, Issue 1
  • DOI: 10.1002/anie.198300531

Sodium Storage Behavior in Natural Graphite using Ether-based Electrolyte Systems
journal, November 2014

  • Kim, Haegyeom; Hong, Jihyun; Park, Young-Uk
  • Advanced Functional Materials, Vol. 25, Issue 4
  • DOI: 10.1002/adfm.201402984

Functional Composite Materials Based on Chemically Converted Graphene
journal, January 2011


P2–Na x Co y Mn 1– y O 2 ( y = 0, 0.1) as Cathode Materials in Sodium-Ion Batteries—Effects of Doping and Morphology To Enhance Cycling Stability
journal, March 2016


Etude de l'insertion dans le graphite des alliages binaires KBi, RbBi, et CsBi
journal, January 1988


NiSe 2 Nanooctahedra as an Anode Material for High-Rate and Long-Life Sodium-Ion Battery
journal, December 2016

  • Zhu, Shaohua; Li, Qidong; Wei, Qiulong
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 1
  • DOI: 10.1021/acsami.6b10143

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013

  • Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
  • Energy & Environmental Science, Vol. 6, Issue 8
  • DOI: 10.1039/c3ee40847g

Size–strain line-broadening analysis of the ceria round-robin sample
journal, November 2004

  • Balzar, D.; Audebrand, N.; Daymond, M. R.
  • Journal of Applied Crystallography, Vol. 37, Issue 6
  • DOI: 10.1107/S0021889804022551

Recent Progress in Electrode Materials for Sodium-Ion Batteries
journal, July 2016

  • Kim, Hyungsub; Kim, Haegyeom; Ding, Zhang
  • Advanced Energy Materials, Vol. 6, Issue 19
  • DOI: 10.1002/aenm.201600943

Hollow Carbon Nanospheres with Superior Rate Capability for Sodium-Based Batteries
journal, May 2012

  • Tang, Kun; Fu, Lijun; White, Robin J.
  • Advanced Energy Materials, Vol. 2, Issue 7
  • DOI: 10.1002/aenm.201100691

Bulk Bismuth as a High-Capacity and Ultralong Cycle-Life Anode for Sodium-Ion Batteries by Coupling with Glyme-Based Electrolytes
journal, July 2017


NaCrO 2 cathode for high-rate sodium-ion batteries
journal, January 2015

  • Yu, Chan-Yeop; Park, Jae-Sang; Jung, Hun-Gi
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C5EE00695C

Water-enhanced oxidation of graphite to graphene oxide with controlled species of oxygenated groups
journal, January 2016

  • Chen, Ji; Zhang, Yao; Zhang, Miao
  • Chemical Science, Vol. 7, Issue 3
  • DOI: 10.1039/C5SC03828F

Raman Spectrum of Graphene and Graphene Layers
journal, October 2006


Intercalation compounds of graphite
journal, April 1981


A review of carbon materials and their composites with alloy metals for sodium ion battery anodes
journal, March 2016


Tunnel-Structured K x TiO 2 Nanorods by in Situ Carbothermal Reduction as a Long Cycle and High Rate Anode for Sodium-Ion Batteries
journal, February 2017

  • Zhang, Qing; Wei, Yaqing; Yang, Haotian
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 8
  • DOI: 10.1021/acsami.6b13869

High Capacity of Hard Carbon Anode in Na-Ion Batteries Unlocked by PO x Doping
journal, July 2016