Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries

Chen, Ji; Fan, Xiulin; Ji, Xiao; Gao, Tao; Hou, Singyuk; Zhou, Xiuquan; Wang, Luning; Wang, Fei; Yang, Chongyin; Chen, Long; Wang, Chunsheng

doi:10.1039/C7EE03016A

Title: Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries

Abstract

Bi@Graphite was synthesized as an ultra-fast and ultra-stable anode material for SIBs with 70% capacity retention at 300C with respect to 1C.

Authors:

^[1];

^[1]; Ji, Xiao ^[1]; Gao, Tao ^[1]; Hou, Singyuk ^[1];

^[2]; Wang, Luning ^[2];

^[1];

^[1]; Chen, Long ^[1];

^[1]

Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, USA
Department of Chemistry and Biochemistry, University of Maryland, College Park, USA

Publication Date:: Mon Jan 01 00:00:00 EST 2018

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1434117

Grant/Contract Number:: DESC0001160; DEAR0000389

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Energy & Environmental Science

Additional Journal Information:: Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 5; Journal ID: ISSN 1754-5692

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Chen, Ji, Fan, Xiulin, Ji, Xiao, Gao, Tao, Hou, Singyuk, Zhou, Xiuquan, Wang, Luning, Wang, Fei, Yang, Chongyin, Chen, Long, and Wang, Chunsheng. Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C7EE03016A.

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                    Chen, Ji, Fan, Xiulin, Ji, Xiao, Gao, Tao, Hou, Singyuk, Zhou, Xiuquan, Wang, Luning, Wang, Fei, Yang, Chongyin, Chen, Long, & Wang, Chunsheng. Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries.  United Kingdom.  https://doi.org/10.1039/C7EE03016A

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                    Chen, Ji, Fan, Xiulin, Ji, Xiao, Gao, Tao, Hou, Singyuk, Zhou, Xiuquan, Wang, Luning, Wang, Fei, Yang, Chongyin, Chen, Long, and Wang, Chunsheng. Mon .  
"Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries".  United Kingdom.  https://doi.org/10.1039/C7EE03016A.

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@article{osti_1434117,

  title        = {Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries},

  author       = {Chen, Ji and Fan, Xiulin and Ji, Xiao and Gao, Tao and Hou, Singyuk and Zhou, Xiuquan and Wang, Luning and Wang, Fei and Yang, Chongyin and Chen, Long and Wang, Chunsheng},

  abstractNote = {Bi@Graphite was synthesized as an ultra-fast and ultra-stable anode material for SIBs with 70% capacity retention at 300C with respect to 1C.},

  doi          = {10.1039/C7EE03016A},

  journal      = {Energy & Environmental Science},

  number       = 5,

  volume       = 11,

  place        = {United Kingdom},

  year         = {Mon Jan 01 00:00:00 EST 2018},

  month        = {Mon Jan 01 00:00:00 EST 2018}

}

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https://doi.org/10.1039/C7EE03016A

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Title: Intercalation of Bi nanoparticles into graphite results in an ultra-fast and ultra-stable anode material for sodium-ion batteries

Abstract

Citation Formats

Raman spectroscopy of graphene and graphite: Disorder, electron–phonon coupling, doping and nonadiabatic effects journal, July 2007

Review—Hard Carbon Negative Electrode Materials for Sodium-Ion Batteries journal, January 2015

The First Report on Excellent Cycling Stability and Superior Rate Capability of Na 3 V 2 (PO 4 ) 3 for Sodium Ion Batteries journal, November 2012

Critical Insight into the Relentless Progression Toward Graphene and Graphene-Containing Materials for Lithium-Ion Battery Anodes journal, December 2016

Carbon-Coated Na 3 V 2 (PO 4 ) 3 Embedded in Porous Carbon Matrix: An Ultrafast Na-Storage Cathode with the Potential of Outperforming Li Cathodes journal, March 2014

Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies journal, July 2011

High-Performance P2-Phase Na 2/3 Mn 0.8 Fe 0.1 Ti 0.1 O 2 Cathode Material for Ambient-Temperature Sodium-Ion Batteries journal, December 2015

Phase selective synthesis of copper sulfides by non-hydrolytic sol–gel methods journal, January 2014

Alloy-Based Anode Materials toward Advanced Sodium-Ion Batteries journal, June 2017

Use of Graphite as a Highly Reversible Electrode with Superior Cycle Life for Sodium-Ion Batteries by Making Use of Co-Intercalation Phenomena journal, July 2014

A fundamental parameters approach to X-ray line-profile fitting journal, April 1992

Surface capacitive contributions: Towards high rate anode materials for sodium ion batteries journal, March 2015

The role of graphene for electrochemical energy storage journal, December 2014

An improved Hummers method for eco-friendly synthesis of graphene oxide journal, November 2013

Quantifying ion-induced defects and Raman relaxation length in graphene journal, April 2010

Monodisperse Antimony Nanocrystals for High-Rate Li-ion and Na-ion Battery Anodes: Nano versus Bulk journal, February 2014

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Layered SnS 2 -Reduced Graphene Oxide Composite - A High-Capacity, High-Rate, and Long-Cycle Life Sodium-Ion Battery Anode Material journal, March 2014

Expanded graphite as superior anode for sodium-ion batteries journal, June 2014

High capacity Na-storage and superior cyclability of nanocomposite Sb/C anode for Na-ion batteries journal, January 2012

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Etude de l'insertion dans le graphite des alliages binaires KBi, RbBi, et CsBi journal, January 1988

NiSe 2 Nanooctahedra as an Anode Material for High-Rate and Long-Life Sodium-Ion Battery journal, December 2016

Building better batteries journal, February 2008

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage journal, January 2013

Recent Progress in Electrode Materials for Sodium-Ion Batteries journal, July 2016

Hollow Carbon Nanospheres with Superior Rate Capability for Sodium-Based Batteries journal, May 2012

Bulk Bismuth as a High-Capacity and Ultralong Cycle-Life Anode for Sodium-Ion Batteries by Coupling with Glyme-Based Electrolytes journal, July 2017

NaCrO 2 cathode for high-rate sodium-ion batteries journal, January 2015

Sn 4+ x P 3 @ Amorphous Sn-P Composites as Anodes for Sodium-Ion Batteries with Low Cost, High Capacity, Long Life, and Superior Rate Capability journal, April 2014

Raman Spectrum of Graphene and Graphene Layers journal, October 2006

Intercalation compounds of graphite journal, April 1981

A review of carbon materials and their composites with alloy metals for sodium ion battery anodes journal, March 2016

Tunnel-Structured K x TiO 2 Nanorods by in Situ Carbothermal Reduction as a Long Cycle and High Rate Anode for Sodium-Ion Batteries journal, February 2017

High Capacity of Hard Carbon Anode in Na-Ion Batteries Unlocked by PO x Doping journal, July 2016

Raman spectroscopy of graphene and graphite: Disorder, electron–phonon coupling, doping and nonadiabatic effects
journal, July 2007

Review—Hard Carbon Negative Electrode Materials for Sodium-Ion Batteries
journal, January 2015

The First Report on Excellent Cycling Stability and Superior Rate Capability of Na ₃ V ₂ (PO ₄ ) ₃ for Sodium Ion Batteries
journal, November 2012

Critical Insight into the Relentless Progression Toward Graphene and Graphene-Containing Materials for Lithium-Ion Battery Anodes
journal, December 2016

Carbon-Coated Na ₃ V ₂ (PO ₄ ) ₃ Embedded in Porous Carbon Matrix: An Ultrafast Na-Storage Cathode with the Potential of Outperforming Li Cathodes
journal, March 2014

Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies
journal, July 2011

High-Performance P2-Phase Na _2/3 Mn _0.8 Fe _0.1 Ti _0.1 O ₂ Cathode Material for Ambient-Temperature Sodium-Ion Batteries
journal, December 2015

Phase selective synthesis of copper sulfides by non-hydrolytic sol–gel methods
journal, January 2014

Alloy-Based Anode Materials toward Advanced Sodium-Ion Batteries
journal, June 2017

Use of Graphite as a Highly Reversible Electrode with Superior Cycle Life for Sodium-Ion Batteries by Making Use of Co-Intercalation Phenomena
journal, July 2014

A fundamental parameters approach to X-ray line-profile fitting
journal, April 1992

Surface capacitive contributions: Towards high rate anode materials for sodium ion batteries
journal, March 2015

The role of graphene for electrochemical energy storage
journal, December 2014

An improved Hummers method for eco-friendly synthesis of graphene oxide
journal, November 2013

Quantifying ion-induced defects and Raman relaxation length in graphene
journal, April 2010

Monodisperse Antimony Nanocrystals for High-Rate Li-ion and Na-ion Battery Anodes: Nano versus Bulk
journal, February 2014

Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life
journal, January 2016

Incorporation of Mercury into Graphitevia K/Hg Intercalation Compounds
journal, January 1983

Layered SnS ₂ -Reduced Graphene Oxide Composite - A High-Capacity, High-Rate, and Long-Cycle Life Sodium-Ion Battery Anode Material
journal, March 2014

Expanded graphite as superior anode for sodium-ion batteries
journal, June 2014

High capacity Na-storage and superior cyclability of nanocomposite Sb/C anode for Na-ion batteries
journal, January 2012

Sodium Storage Behavior in Natural Graphite using Ether-based Electrolyte Systems
journal, November 2014

Functional Composite Materials Based on Chemically Converted Graphene
journal, January 2011

Differentiating Contributions to “Ion Transfer” Barrier from Interphasial Resistance and Li ⁺ Desolvation at Electrolyte/Graphite Interface
journal, July 2010

P2–Na _x Co _y Mn _{1– y} O ₂ ( y = 0, 0.1) as Cathode Materials in Sodium-Ion Batteries—Effects of Doping and Morphology To Enhance Cycling Stability
journal, March 2016

Etude de l'insertion dans le graphite des alliages binaires KBi, RbBi, et CsBi
journal, January 1988

NiSe ₂ Nanooctahedra as an Anode Material for High-Rate and Long-Life Sodium-Ion Battery
journal, December 2016

Building better batteries
journal, February 2008

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013

Recent Progress in Electrode Materials for Sodium-Ion Batteries
journal, July 2016

Hollow Carbon Nanospheres with Superior Rate Capability for Sodium-Based Batteries
journal, May 2012

Bulk Bismuth as a High-Capacity and Ultralong Cycle-Life Anode for Sodium-Ion Batteries by Coupling with Glyme-Based Electrolytes
journal, July 2017

NaCrO ₂ cathode for high-rate sodium-ion batteries
journal, January 2015

Sn _{4+ x} P ₃ @ Amorphous Sn-P Composites as Anodes for Sodium-Ion Batteries with Low Cost, High Capacity, Long Life, and Superior Rate Capability
journal, April 2014

Raman Spectrum of Graphene and Graphene Layers
journal, October 2006

Intercalation compounds of graphite
journal, April 1981

A review of carbon materials and their composites with alloy metals for sodium ion battery anodes
journal, March 2016

Tunnel-Structured K _x TiO ₂ Nanorods by in Situ Carbothermal Reduction as a Long Cycle and High Rate Anode for Sodium-Ion Batteries
journal, February 2017

High Capacity of Hard Carbon Anode in Na-Ion Batteries Unlocked by PO _x Doping
journal, July 2016