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Title: Biomimetic composite architecture achieves ultrahigh rate capability and cycling life of sodium ion battery cathodes

Abstract

A biomimetic bone-inspired Na3V2(PO4)3-reduced graphene oxide (rGO) composite cathode "BI-NVP" achieves ultrahigh rate charging and ultralong cycling life in a sodium ion battery (SIB). At a charging rate of 1C, BI-NVP delivers 97% of its theoretical capacity (114 mA h g-1 vs. 117 mA h g-1), while at 100C and 200C, the capacities are 68 and 49 mA h g-1, respectively. It also shows long cycling life with capacity retention of 90.5% after 10000 cycles at 50C. SIB cells with a BI-NVP cathode and Na metal anode delivered maximum specific energy of 350 W h kg-1 and maximum specific power of 154 kW kg-1. The Ragone chart shows a uniquely flat specific energy profile to above 10 kW kg-1, yielding the most favorable high power characteristics reported for SIBs. Electroanalytical results indicate that the Na ion diffusivity of BI-NVP is 3.90 × 10-10 cm2 s-1, as compared to the 1.17 × 10-11 cm2 s-1 for the NVP baseline. The enhanced diffusivity in BI-NVP helps to explain its extremely fast redox kinetics, in turn being attributable to a combination of the ion-active rGO shell, the nanosizing of the NVP, and the interpenetrating mesoporosity. In-situ and post-mortem analyses of cycled BI-NVP, includingmore » by Raman and XRD spectra, HRTEM and STEM-EELS, indicate highly reversible dilation contraction, negligible electrode pulverization, and a stable NVP-rGO layer interface.« less

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [2];  [2]; ORCiD logo [3];  [1];  [2]; ORCiD logo [1]
  1. Sungkyunkwan Univ., Suwon (Republic of Korea)
  2. Univ. of Texas, Austin, TX (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Research Foundation of Korea (NRF); National Science Foundation (NSF)
OSTI Identifier:
1749906
Alternate Identifier(s):
OSTI ID: 1734801
Report Number(s):
BNL-220740-2020-JAAM
Journal ID: ISSN 1931-9401
Grant/Contract Number:  
SC0012704; NRF-2020R1A3B2079803; 1938833
Resource Type:
Accepted Manuscript
Journal Name:
Applied Physics Reviews
Additional Journal Information:
Journal Volume: 7; Journal Issue: 4; Journal ID: ISSN 1931-9401
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Shin, Kang Ho, Park, Sul Ki, Nakhanivej, Puritut, Wang, Yixian, Liu, Pengcheng, Bak, Seong-Min, Choi, Min Sung, Mitlin, David, and Park, Ho Seok. Biomimetic composite architecture achieves ultrahigh rate capability and cycling life of sodium ion battery cathodes. United States: N. p., 2020. Web. https://doi.org/10.1063/5.0020805.
Shin, Kang Ho, Park, Sul Ki, Nakhanivej, Puritut, Wang, Yixian, Liu, Pengcheng, Bak, Seong-Min, Choi, Min Sung, Mitlin, David, & Park, Ho Seok. Biomimetic composite architecture achieves ultrahigh rate capability and cycling life of sodium ion battery cathodes. United States. https://doi.org/10.1063/5.0020805
Shin, Kang Ho, Park, Sul Ki, Nakhanivej, Puritut, Wang, Yixian, Liu, Pengcheng, Bak, Seong-Min, Choi, Min Sung, Mitlin, David, and Park, Ho Seok. Tue . "Biomimetic composite architecture achieves ultrahigh rate capability and cycling life of sodium ion battery cathodes". United States. https://doi.org/10.1063/5.0020805. https://www.osti.gov/servlets/purl/1749906.
@article{osti_1749906,
title = {Biomimetic composite architecture achieves ultrahigh rate capability and cycling life of sodium ion battery cathodes},
author = {Shin, Kang Ho and Park, Sul Ki and Nakhanivej, Puritut and Wang, Yixian and Liu, Pengcheng and Bak, Seong-Min and Choi, Min Sung and Mitlin, David and Park, Ho Seok},
abstractNote = {A biomimetic bone-inspired Na3V2(PO4)3-reduced graphene oxide (rGO) composite cathode "BI-NVP" achieves ultrahigh rate charging and ultralong cycling life in a sodium ion battery (SIB). At a charging rate of 1C, BI-NVP delivers 97% of its theoretical capacity (114 mA h g-1 vs. 117 mA h g-1), while at 100C and 200C, the capacities are 68 and 49 mA h g-1, respectively. It also shows long cycling life with capacity retention of 90.5% after 10000 cycles at 50C. SIB cells with a BI-NVP cathode and Na metal anode delivered maximum specific energy of 350 W h kg-1 and maximum specific power of 154 kW kg-1. The Ragone chart shows a uniquely flat specific energy profile to above 10 kW kg-1, yielding the most favorable high power characteristics reported for SIBs. Electroanalytical results indicate that the Na ion diffusivity of BI-NVP is 3.90 × 10-10 cm2 s-1, as compared to the 1.17 × 10-11 cm2 s-1 for the NVP baseline. The enhanced diffusivity in BI-NVP helps to explain its extremely fast redox kinetics, in turn being attributable to a combination of the ion-active rGO shell, the nanosizing of the NVP, and the interpenetrating mesoporosity. In-situ and post-mortem analyses of cycled BI-NVP, including by Raman and XRD spectra, HRTEM and STEM-EELS, indicate highly reversible dilation contraction, negligible electrode pulverization, and a stable NVP-rGO layer interface.},
doi = {10.1063/5.0020805},
journal = {Applied Physics Reviews},
number = 4,
volume = 7,
place = {United States},
year = {2020},
month = {12}
}

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