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Title: One‐Step Synthesis of Hybrid Core–Shell Metal–Organic Frameworks

Abstract

Abstract Epitaxial growth of MOF‐on‐MOF composite is an evolving research topic in the quest for multifunctional materials. In previously reported methods, the core–shell MOFs were synthesized via a stepwise strategy that involved growing the shell‐MOFs on top of the preformed core‐MOFs with matched lattice parameters. However, the inconvenient stepwise synthesis and the strict lattice‐matching requirement have limited the preparation of core–shell MOFs. Herein, we demonstrate that hybrid core–shell MOFs with mismatching lattices can be synthesized under the guidance of nucleation kinetic analysis. A series of MOF composites with mesoporous core and microporous shell were constructed and characterized by optical microscopy, powder X‐ray diffraction, gas sorption measurement, and scanning electron microscopy. Isoreticular expansion of microporous shells and orthogonal modification of the core was realized to produce multifunctional MOF composites, which acted as size selective catalysts for olefin epoxidation with high activity and selectivity.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [2]; ORCiD logo [3]
+ Show Author Affiliations
  1. Department of Chemistry Texas A&,M University USA
  2. Department of Chemistry College of Science King Saud University Saudi Arabia
  3. Department of Chemistry Texas A&,M University USA, Department of Materials Science and Engineering Texas A&,M University USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1426509
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 15; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Yang, Xinyu, Yuan, Shuai, Zou, Lanfang, Drake, Hannah, Zhang, Yingmu, Qin, Junsheng, Alsalme, Ali, and Zhou, Hong‐Cai. One‐Step Synthesis of Hybrid Core–Shell Metal–Organic Frameworks. Germany: N. p., 2018. Web. doi:10.1002/ange.201710019.
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Yang, Xinyu, Yuan, Shuai, Zou, Lanfang, Drake, Hannah, Zhang, Yingmu, Qin, Junsheng, Alsalme, Ali, & Zhou, Hong‐Cai. One‐Step Synthesis of Hybrid Core–Shell Metal–Organic Frameworks. Germany. https://doi.org/10.1002/ange.201710019
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Yang, Xinyu, Yuan, Shuai, Zou, Lanfang, Drake, Hannah, Zhang, Yingmu, Qin, Junsheng, Alsalme, Ali, and Zhou, Hong‐Cai. Mon . "One‐Step Synthesis of Hybrid Core–Shell Metal–Organic Frameworks". Germany. https://doi.org/10.1002/ange.201710019.
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@article{osti_1426509,
title = {One‐Step Synthesis of Hybrid Core–Shell Metal–Organic Frameworks},
author = {Yang, Xinyu and Yuan, Shuai and Zou, Lanfang and Drake, Hannah and Zhang, Yingmu and Qin, Junsheng and Alsalme, Ali and Zhou, Hong‐Cai},
abstractNote = {Abstract Epitaxial growth of MOF‐on‐MOF composite is an evolving research topic in the quest for multifunctional materials. In previously reported methods, the core–shell MOFs were synthesized via a stepwise strategy that involved growing the shell‐MOFs on top of the preformed core‐MOFs with matched lattice parameters. However, the inconvenient stepwise synthesis and the strict lattice‐matching requirement have limited the preparation of core–shell MOFs. Herein, we demonstrate that hybrid core–shell MOFs with mismatching lattices can be synthesized under the guidance of nucleation kinetic analysis. A series of MOF composites with mesoporous core and microporous shell were constructed and characterized by optical microscopy, powder X‐ray diffraction, gas sorption measurement, and scanning electron microscopy. Isoreticular expansion of microporous shells and orthogonal modification of the core was realized to produce multifunctional MOF composites, which acted as size selective catalysts for olefin epoxidation with high activity and selectivity.},
doi = {10.1002/ange.201710019},
journal = {Angewandte Chemie},
number = 15,
volume = 130,
place = {Germany},
year = {Mon Mar 12 00:00:00 EDT 2018},
month = {Mon Mar 12 00:00:00 EDT 2018}
}
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https://doi.org/10.1002/ange.201710019
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