Construction of Hierarchically Porous Nanoparticles@Metal-Organic Frameworks Composites by Inherent Defects for the Enhancement of Catalytic Efficiency
Abstract
Abstract Nanoparticles@metal–organic frameworks (MOFs) composites have attracted considerable attention in recent years due to the prominent selective catalytic activity. However, it is highly desirable to develop a simple and universal way to settle the trade‐off between the catalytic efficiency and selectivity. Herein, by employing the thermal instability of inherent defects, hierarchically porous Pt@UiO‐66‐NH 2 , Pt@UiO‐66, Pt@ZIF‐8, and Au@ZIF‐8 are successfully constructed after annealing at an appropriate temperature, respectively. The generated mesopores in the MOFs can be located around the external nanoparticle to retain the MOF shell for catalytic selectivity. Finally, when tested in olefin hydrogenation, Pt@UiO‐66‐NH 2 shows significantly improved catalytic rate and enhanced dynamic selectivity.
- Authors:
-
[3]
- Nanjing Tech Univ. (Nanjing Tech), Nanjing (People's Republic of China)
- Nanjing Tech Univ. (Nanjing Tech), Nanjing (People's Republic of China); Argonne National Lab. (ANL), Argonne, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Univ. of Waterloo, Waterloo, ON (Canada); Argonne National Lab. (ANL), Argonne, IL (United States)
- Nanjing Tech Univ., Nanjing (People's Republic of China)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NSFC); National Natural Science Foundation of Jiangsu Province; China Scholarship Council; USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China
- OSTI Identifier:
- 1504256
- Alternate Identifier(s):
- OSTI ID: 1479567
- Grant/Contract Number:
- AC02-06CH11357; DE‐AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 30; Journal Issue: 49; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY; composites; defects; hierarchical pores; metal-organic frameworks; selectivity
Citation Formats
Meng, Fanchen, Zhang, Suoying, Ma, Lu, Zhang, Weina, Li, Matthew, Wu, Tianpin, Li, Hang, Zhang, Tao, Lu, Xiaohua, Huo, Fengwei, and Lu, Jun. Construction of Hierarchically Porous Nanoparticles@Metal-Organic Frameworks Composites by Inherent Defects for the Enhancement of Catalytic Efficiency. United States: N. p., 2018.
Web. doi:10.1002/adma.201803263.
Meng, Fanchen, Zhang, Suoying, Ma, Lu, Zhang, Weina, Li, Matthew, Wu, Tianpin, Li, Hang, Zhang, Tao, Lu, Xiaohua, Huo, Fengwei, & Lu, Jun. Construction of Hierarchically Porous Nanoparticles@Metal-Organic Frameworks Composites by Inherent Defects for the Enhancement of Catalytic Efficiency. United States. https://doi.org/10.1002/adma.201803263
Meng, Fanchen, Zhang, Suoying, Ma, Lu, Zhang, Weina, Li, Matthew, Wu, Tianpin, Li, Hang, Zhang, Tao, Lu, Xiaohua, Huo, Fengwei, and Lu, Jun. Wed .
"Construction of Hierarchically Porous Nanoparticles@Metal-Organic Frameworks Composites by Inherent Defects for the Enhancement of Catalytic Efficiency". United States. https://doi.org/10.1002/adma.201803263. https://www.osti.gov/servlets/purl/1504256.
@article{osti_1504256,
title = {Construction of Hierarchically Porous Nanoparticles@Metal-Organic Frameworks Composites by Inherent Defects for the Enhancement of Catalytic Efficiency},
author = {Meng, Fanchen and Zhang, Suoying and Ma, Lu and Zhang, Weina and Li, Matthew and Wu, Tianpin and Li, Hang and Zhang, Tao and Lu, Xiaohua and Huo, Fengwei and Lu, Jun},
abstractNote = {Abstract Nanoparticles@metal–organic frameworks (MOFs) composites have attracted considerable attention in recent years due to the prominent selective catalytic activity. However, it is highly desirable to develop a simple and universal way to settle the trade‐off between the catalytic efficiency and selectivity. Herein, by employing the thermal instability of inherent defects, hierarchically porous Pt@UiO‐66‐NH 2 , Pt@UiO‐66, Pt@ZIF‐8, and Au@ZIF‐8 are successfully constructed after annealing at an appropriate temperature, respectively. The generated mesopores in the MOFs can be located around the external nanoparticle to retain the MOF shell for catalytic selectivity. Finally, when tested in olefin hydrogenation, Pt@UiO‐66‐NH 2 shows significantly improved catalytic rate and enhanced dynamic selectivity.},
doi = {10.1002/adma.201803263},
journal = {Advanced Materials},
number = 49,
volume = 30,
place = {United States},
year = {Wed Oct 10 00:00:00 EDT 2018},
month = {Wed Oct 10 00:00:00 EDT 2018}
}
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Scheme 1: Schematic illustration of hierarchically porous Pt@MOFs prepared by inherent defects for the high catalytic efficiency.
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