One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks
Abstract
Abstract Epitaxial growth of MOF‐on‐MOF composite is an evolving research topic in the quest for multifunctional materials. In previously reported methods, the core–shell MOFs were synthesized via a stepwise strategy that involved growing the shell‐MOFs on top of the preformed core‐MOFs with matched lattice parameters. However, the inconvenient stepwise synthesis and the strict lattice‐matching requirement have limited the preparation of core–shell MOFs. Herein, we demonstrate that hybrid core–shell MOFs with mismatching lattices can be synthesized under the guidance of nucleation kinetic analysis. A series of MOF composites with mesoporous core and microporous shell were constructed and characterized by optical microscopy, powder X‐ray diffraction, gas sorption measurement, and scanning electron microscopy. Isoreticular expansion of microporous shells and orthogonal modification of the core was realized to produce multifunctional MOF composites, which acted as size selective catalysts for olefin epoxidation with high activity and selectivity.
- Authors:
-
- Texas A & M Univ., College Station, TX (United States)
- King Saud Univ., Riyadh (Saudi Arabia)
- Publication Date:
- Research Org.:
- Univ. of California, Berkeley (United States). Energy Frontier Research Center (EFRC) (United States) Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO); USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1470334
- Alternate Identifier(s):
- OSTI ID: 1432067
- Grant/Contract Number:
- SC0001015; EE0007049; FE0026472
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 57; Journal Issue: 15; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; core–shell MOFs; nucleation kinetics; olefin epoxidation; size-selective catalyst
Citation Formats
Yang, Xinyu, Yuan, Shuai, Zou, Lanfang, Drake, Hannah, Zhang, Yingmu, Qin, Junsheng, Alsalme, Ali, and Zhou, Hong-Cai. One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks. United States: N. p., 2018.
Web. doi:10.1002/anie.201710019.
Yang, Xinyu, Yuan, Shuai, Zou, Lanfang, Drake, Hannah, Zhang, Yingmu, Qin, Junsheng, Alsalme, Ali, & Zhou, Hong-Cai. One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks. United States. https://doi.org/10.1002/anie.201710019
Yang, Xinyu, Yuan, Shuai, Zou, Lanfang, Drake, Hannah, Zhang, Yingmu, Qin, Junsheng, Alsalme, Ali, and Zhou, Hong-Cai. Fri .
"One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks". United States. https://doi.org/10.1002/anie.201710019. https://www.osti.gov/servlets/purl/1470334.
@article{osti_1470334,
title = {One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks},
author = {Yang, Xinyu and Yuan, Shuai and Zou, Lanfang and Drake, Hannah and Zhang, Yingmu and Qin, Junsheng and Alsalme, Ali and Zhou, Hong-Cai},
abstractNote = {Abstract Epitaxial growth of MOF‐on‐MOF composite is an evolving research topic in the quest for multifunctional materials. In previously reported methods, the core–shell MOFs were synthesized via a stepwise strategy that involved growing the shell‐MOFs on top of the preformed core‐MOFs with matched lattice parameters. However, the inconvenient stepwise synthesis and the strict lattice‐matching requirement have limited the preparation of core–shell MOFs. Herein, we demonstrate that hybrid core–shell MOFs with mismatching lattices can be synthesized under the guidance of nucleation kinetic analysis. A series of MOF composites with mesoporous core and microporous shell were constructed and characterized by optical microscopy, powder X‐ray diffraction, gas sorption measurement, and scanning electron microscopy. Isoreticular expansion of microporous shells and orthogonal modification of the core was realized to produce multifunctional MOF composites, which acted as size selective catalysts for olefin epoxidation with high activity and selectivity.},
doi = {10.1002/anie.201710019},
journal = {Angewandte Chemie (International Edition)},
number = 15,
volume = 57,
place = {United States},
year = {Fri Feb 16 00:00:00 EST 2018},
month = {Fri Feb 16 00:00:00 EST 2018}
}
Web of Science
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