Advanced Characterization Techniques for Sodium-Ion Battery Studies
Abstract
Abstract Sodium (Na)‐ion batteries (NIBs) are considered promising alternative candidates to the well‐commercialized lithium‐ion batteries, especially for applications in large‐scale energy storage systems. The electrochemical performance of NIBs such as the cyclability, rate capability, and voltage profiles are strongly dependent on the structural and morphological evolution, phase transformation, sodium‐ion diffusion, and electrode/electrolyte interface reconstruction during charge–discharge cycling. Therefore, in‐depth understanding of the structure and kinetics of electrode materials and the electrode/electrolyte interfaces is essential for optimizing current NIB systems and exploring new materials for NIBs. Recently, rapid progress and development in spectroscopic, microscopic, and scattering techniques have provided extensive insight into the nature of structural evolution, morphological changes of electrode materials, and electrode/electrolyte interface in NIBs. In this review, a comprehensive overview of both static (ex situ) and real‐time (in situ or in operando) techniques for studying the NIBs is provided. Special focus is placed on how these techniques are applied to the fundamental investigation of NIB systems and what important results are obtained.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
- Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics, Inst. of Physics
- Fudan Univ., Shanghai (China). Dept. of Materials Science
- Xiamen Univ., Xiamen (China). State Key Lab. for Physical Chemistry of Solid Surfaces, and Dept. of Chemistry
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
- OSTI Identifier:
- 1425180
- Alternate Identifier(s):
- OSTI ID: 1422010
- Report Number(s):
- BNL-203321-2018-JAAM
Journal ID: ISSN 1614-6832; TRN: US1802059
- Grant/Contract Number:
- SC0012704; DE‐SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 17; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; characterization techniques; ex situ; in situ; sodium-ion batteries
Citation Formats
Shadike, Zulipiya, Zhao, Enyue, Zhou, Yong-Ning, Yu, Xiqian, Yang, Yong, Hu, Enyuan, Bak, Seongmin, Gu, Lin, and Yang, Xiao-Qing. Advanced Characterization Techniques for Sodium-Ion Battery Studies. United States: N. p., 2018.
Web. doi:10.1002/aenm.201702588.
Shadike, Zulipiya, Zhao, Enyue, Zhou, Yong-Ning, Yu, Xiqian, Yang, Yong, Hu, Enyuan, Bak, Seongmin, Gu, Lin, & Yang, Xiao-Qing. Advanced Characterization Techniques for Sodium-Ion Battery Studies. United States. https://doi.org/10.1002/aenm.201702588
Shadike, Zulipiya, Zhao, Enyue, Zhou, Yong-Ning, Yu, Xiqian, Yang, Yong, Hu, Enyuan, Bak, Seongmin, Gu, Lin, and Yang, Xiao-Qing. Mon .
"Advanced Characterization Techniques for Sodium-Ion Battery Studies". United States. https://doi.org/10.1002/aenm.201702588. https://www.osti.gov/servlets/purl/1425180.
@article{osti_1425180,
title = {Advanced Characterization Techniques for Sodium-Ion Battery Studies},
author = {Shadike, Zulipiya and Zhao, Enyue and Zhou, Yong-Ning and Yu, Xiqian and Yang, Yong and Hu, Enyuan and Bak, Seongmin and Gu, Lin and Yang, Xiao-Qing},
abstractNote = {Abstract Sodium (Na)‐ion batteries (NIBs) are considered promising alternative candidates to the well‐commercialized lithium‐ion batteries, especially for applications in large‐scale energy storage systems. The electrochemical performance of NIBs such as the cyclability, rate capability, and voltage profiles are strongly dependent on the structural and morphological evolution, phase transformation, sodium‐ion diffusion, and electrode/electrolyte interface reconstruction during charge–discharge cycling. Therefore, in‐depth understanding of the structure and kinetics of electrode materials and the electrode/electrolyte interfaces is essential for optimizing current NIB systems and exploring new materials for NIBs. Recently, rapid progress and development in spectroscopic, microscopic, and scattering techniques have provided extensive insight into the nature of structural evolution, morphological changes of electrode materials, and electrode/electrolyte interface in NIBs. In this review, a comprehensive overview of both static (ex situ) and real‐time (in situ or in operando) techniques for studying the NIBs is provided. Special focus is placed on how these techniques are applied to the fundamental investigation of NIB systems and what important results are obtained.},
doi = {10.1002/aenm.201702588},
journal = {Advanced Energy Materials},
number = 17,
volume = 8,
place = {United States},
year = {Mon Feb 19 00:00:00 EST 2018},
month = {Mon Feb 19 00:00:00 EST 2018}
}
Web of Science
Works referenced in this record:
Insights into the structural effects of layered cathode materials for high voltage sodium-ion batteries
journal, January 2017
- Xu, Gui-Liang; Amine, Rachid; Xu, Yue-Feng
- Energy & Environmental Science, Vol. 10, Issue 7
Probing three-dimensional sodiation–desodiation equilibrium in sodium-ion batteries by in situ hard X-ray nanotomography
journal, June 2015
- Wang, Jiajun; Eng, Christopher; Chen-Wiegart, Yu-chen Karen
- Nature Communications, Vol. 6, Issue 1
Automatic Tuning Matching Cycler (ATMC) in situ NMR spectroscopy as a novel approach for real-time investigations of Li- and Na-ion batteries
journal, April 2016
- Pecher, Oliver; Bayley, Paul M.; Liu, Hao
- Journal of Magnetic Resonance, Vol. 265
In Operando XRD and TXM Study on the Metastable Structure Change of NaNi 1/3 Fe 1/3 Mn 1/3 O 2 under Electrochemical Sodium-Ion Intercalation
journal, September 2016
- Xie, Yingying; Wang, Hong; Xu, Guiliang
- Advanced Energy Materials, Vol. 6, Issue 24
Behavior of Graphite Electrodes in Solutions Based on Ionic Liquids in In Situ Raman Studies
journal, January 2008
- Markevich, E.; Baranchugov, V.; Salitra, G.
- Journal of The Electrochemical Society, Vol. 155, Issue 2
Revealing Chemical Processes Involved in Electrochemical (De)Lithiation of Al with in Situ Neutron Depth Profiling and X-ray Diffraction
journal, December 2015
- Liu, Danny X.; Co, Anne C.
- Journal of the American Chemical Society, Vol. 138, Issue 1
Phase transition behavior of NaCrO2 during sodium extraction studied by synchrotron-based X-ray diffraction and absorption spectroscopy
journal, January 2013
- Zhou, Yong-Ning; Ding, Jing-Jing; Nam, Kyung-Wan
- Journal of Materials Chemistry A, Vol. 1, Issue 37
Detailed investigation of Na2.24FePO4CO3 as a cathode material for Na-ion batteries
journal, March 2014
- Huang, Weifeng; Zhou, Jing; Li, Biao
- Scientific Reports, Vol. 4, Issue 1
PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions
journal, March 2013
- Juhás, P.; Davis, T.; Farrow, C. L.
- Journal of Applied Crystallography, Vol. 46, Issue 2
In operando neutron diffraction study of a commercial graphite/(Ni, Mn, Co) oxide-based multi-component lithium ion battery
journal, September 2016
- Nazer, N. S.; Yartys, V. A.; Azib, T.
- Journal of Power Sources, Vol. 326
P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries
journal, April 2015
- Wang, Yuesheng; Xiao, Ruijuan; Hu, Yong-Sheng
- Nature Communications, Vol. 6, Issue 1
Suppressing the chromium disproportionation reaction in O3-type layered cathode materials for high capacity sodium-ion batteries
journal, January 2017
- Cao, Ming-Hui; Wang, Yong; Shadike, Zulipiya
- Journal of Materials Chemistry A, Vol. 5, Issue 11
Mechanistic insights into sodium storage in hard carbon anodes using local structure probes
journal, January 2016
- Stratford, Joshua M.; Allan, Phoebe K.; Pecher, Oliver
- Chemical Communications, Vol. 52, Issue 84
Raman spectroscopic study of the phase transitions sequence in Li3Fe2(PO4)3 and Na3Fe2(PO4)3 at high temperature
journal, November 2009
- Bih, H.; Bih, L.; Manoun, B.
- Journal of Molecular Structure, Vol. 936, Issue 1-3
Anti-P2 structured Na 0.5 NbO 2 and its negative strain effect
journal, January 2015
- Wang, Xuefeng; Gao, Yurui; Shen, Xi
- Energy & Environmental Science, Vol. 8, Issue 9
Surface film formation on a graphite electrode in Li-ion batteries: AFM and XPS study
journal, January 2005
- Leroy, S.; Blanchard, F.; Dedryvère, R.
- Surface and Interface Analysis, Vol. 37, Issue 10
Where Do Batteries End and Supercapacitors Begin?
journal, March 2014
- Simon, P.; Gogotsi, Y.; Dunn, B.
- Science, Vol. 343, Issue 6176
Na-ion dynamics in tetragonal and cubic Na 3 PS 4 , a Na-ion conductor for solid state Na-ion batteries
journal, January 2016
- Yu, Chuang; Ganapathy, Swapna; de Klerk, Niek J. J.
- Journal of Materials Chemistry A, Vol. 4, Issue 39
A rechargeable room-temperature sodium superoxide (NaO2) battery
journal, December 2012
- Hartmann, Pascal; Bender, Conrad L.; Vračar, Miloš
- Nature Materials, Vol. 12, Issue 3, p. 228-232
Unfolding the Mechanism of Sodium Insertion in Anatase TiO 2 Nanoparticles
journal, August 2014
- Wu, Liming; Bresser, Dominic; Buchholz, Daniel
- Advanced Energy Materials, Vol. 5, Issue 2
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Underneath the Bragg Peaks
journal, June 2003
- Egami, T.; Billinge, S. J. L.
- Materials Today, Vol. 6, Issue 6
“Electron/Ion Sponge”-Like V-Based Polyoxometalate: Toward High-Performance Cathode for Rechargeable Sodium Ion Batteries
journal, May 2017
- Liu, Jilei; Chen, Zhen; Chen, Shi
- ACS Nano, Vol. 11, Issue 7
Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011
- Dunn, B.; Kamath, H.; Tarascon, J. -M.
- Science, Vol. 334, Issue 6058
Facile Method To Synthesize Na-Enriched Na 1+ x FeFe(CN) 6 Frameworks as Cathode with Superior Electrochemical Performance for Sodium-Ion Batteries
journal, March 2015
- Li, Wei-Jie; Chou, Shu-Lei; Wang, Jia-Zhao
- Chemistry of Materials, Vol. 27, Issue 6
1D to 2D Ion Diffusion Inherently Linked to Structural Transitions in
journal, June 2013
- Medarde, M.; Mena, M.; Gavilano, J. L.
- Physical Review Letters, Vol. 110, Issue 26
Local Structure and Dynamics in the Na Ion Battery Positive Electrode Material Na 3 V 2 (PO 4 ) 2 F 3
journal, April 2014
- Liu, Zigeng; Hu, Yan-Yan; Dunstan, Matthew T.
- Chemistry of Materials, Vol. 26, Issue 8
Sodium Intercalation Mechanism of 3.8 V Class Alluaudite Sodium Iron Sulfate
journal, July 2016
- Oyama, Gosuke; Pecher, Oliver; Griffith, Kent J.
- Chemistry of Materials, Vol. 28, Issue 15
From kröhnkite- to alluaudite-type of structure: novel method of synthesis of sodium manganese sulfates with electrochemical properties in alkali-metal ion batteries
journal, January 2015
- Marinova, D.; Kostov, V.; Nikolova, R.
- Journal of Materials Chemistry A, Vol. 3, Issue 44
Tracking Sodium-Antimonide Phase Transformations in Sodium-Ion Anodes: Insights from Operando Pair Distribution Function Analysis and Solid-State NMR Spectroscopy
journal, February 2016
- Allan, Phoebe K.; Griffin, John M.; Darwiche, Ali
- Journal of the American Chemical Society, Vol. 138, Issue 7
Spectroelectrochemical studies of magnesium deposition by in situ FTIR spectroscopy
journal, May 2001
- Aurbach, D.; Turgeman, R.; Chusid, O.
- Electrochemistry Communications, Vol. 3, Issue 5
FeO 0.7 F 1.3 /C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries
journal, November 2014
- Zhou, Yong-Ning; Sina, Mahsa; Pereira, Nathalie
- Advanced Functional Materials, Vol. 25, Issue 5
New Insights into the Performance Degradation of Fe-Based Layered Oxides in Sodium-Ion Batteries: Instability of Fe 3+ /Fe 4+ Redox in α-NaFeO 2
journal, September 2015
- Lee, Eungje; Brown, Dennis E.; Alp, Esen E.
- Chemistry of Materials, Vol. 27, Issue 19
Exploring reversible oxidation of oxygen in a manganese oxide
journal, January 2016
- Du, Ke; Zhu, Jinyou; Hu, Guorong
- Energy & Environmental Science, Vol. 9, Issue 8
New Insight into Structural Evolution in Layered NaCrO 2 during Electrochemical Sodium Extraction
journal, December 2014
- Kubota, Kei; Ikeuchi, Issei; Nakayama, Tetsuri
- The Journal of Physical Chemistry C, Vol. 119, Issue 1
Structure of the high voltage phase of layered P2-Na 2/3−z [Mn 1/2 Fe 1/2 ]O 2 and the positive effect of Ni substitution on its stability
journal, January 2015
- Talaie, Elahe; Duffort, Victor; Smith, Hillary L.
- Energy & Environmental Science, Vol. 8, Issue 8
FTIR spectral analysis and mechanical properties of sodium phosphate glass–ceramics
journal, March 2015
- Jha, Paramjyot Kumar; Pandey, O. P.; Singh, K.
- Journal of Molecular Structure, Vol. 1083
Single Nanowire Electrochemical Devices
journal, October 2010
- Mai, Liqiang; Dong, Yajie; Xu, Lin
- Nano Letters, Vol. 10, Issue 10
Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries
journal, February 2015
- Wang, Long; Song, Jie; Qiao, Ruimin
- Journal of the American Chemical Society, Vol. 137, Issue 7
Redox Potential Paradox in Na x MO 2 for Sodium-Ion Battery Cathodes
journal, February 2016
- Nanba, Yusuke; Iwao, Tatsumi; Boisse, Benoit Mortemard de
- Chemistry of Materials, Vol. 28, Issue 4
Electrochemical Properties of Monoclinic NaMnO2
journal, January 2011
- Ma, Xiaohua; Chen, Hailong; Ceder, Gerbrand
- Journal of The Electrochemical Society, Vol. 158, Issue 12
Towards high energy density sodium ion batteries through electrolyte optimization
journal, January 2013
- Ponrouch, Alexandre; Dedryvère, Rémi; Monti, Damien
- Energy & Environmental Science, Vol. 6, Issue 8
The Na x MoO 2 Phase Diagram ( 1 / 2 ≤ x < 1): An Electrochemical Devil’s Staircase
journal, August 2017
- Vitoux, Laura; Guignard, Marie; Suchomel, Matthew R.
- Chemistry of Materials, Vol. 29, Issue 17
Comprehensive Investigation of the Na 3 V 2 (PO 4 ) 2 F 3 –NaV 2 (PO 4 ) 2 F 3 System by Operando High Resolution Synchrotron X-ray Diffraction
journal, April 2015
- Bianchini, M.; Fauth, F.; Brisset, N.
- Chemistry of Materials, Vol. 27, Issue 8
Direct imaging of layered O3- and P2-Na x Fe 1/2 Mn 1/2 O 2 structures at the atomic scale
journal, January 2014
- Lu, Xia; Wang, Yuesheng; Liu, Pin
- Phys. Chem. Chem. Phys., Vol. 16, Issue 40
Na-Ion Intercalation and Charge Storage Mechanism in 2D Vanadium Carbide
journal, July 2017
- Bak, Seong-Min; Qiao, Ruimin; Yang, Wanli
- Advanced Energy Materials, Vol. 7, Issue 20
Direct Observation of the Redistribution of Sulfur and Polysufides in Li-S Batteries During the First Cycle by In Situ X-Ray Fluorescence Microscopy
journal, March 2015
- Yu, Xiqian; Pan, Huilin; Zhou, Yongning
- Advanced Energy Materials, Vol. 5, Issue 16
Pseudocapacitive Na-Ion Storage Boosts High Rate and Areal Capacity of Self-Branched 2D Layered Metal Chalcogenide Nanoarrays
journal, October 2016
- Chao, Dongliang; Liang, Pei; Chen, Zhen
- ACS Nano, Vol. 10, Issue 11
Expanded graphite as superior anode for sodium-ion batteries
journal, June 2014
- Wen, Yang; He, Kai; Zhu, Yujie
- Nature Communications, Vol. 5, Issue 1
Recent advances in the characterization of amorphous pharmaceuticals by X-ray diffractometry
journal, May 2016
- Thakral, Seema; Terban, Maxwell W.; Thakral, Naveen K.
- Advanced Drug Delivery Reviews, Vol. 100
Structurally stable Mg-doped P2-Na 2/3 Mn 1−y Mg y O 2 sodium-ion battery cathodes with high rate performance: insights from electrochemical, NMR and diffraction studies
journal, January 2016
- Clément, Raphaële J.; Billaud, Juliette; Robert Armstrong, A.
- Energy & Environmental Science, Vol. 9, Issue 10
Solid-state polymer nanocomposite electrolyte of TiO2/PEO/NaClO4 for sodium ion batteries
journal, March 2015
- Ni'mah, Yatim Lailun; Cheng, Ming-Yao; Cheng, Ju Hsiang
- Journal of Power Sources, Vol. 278
P2–Na x Co y Mn 1– y O 2 ( y = 0, 0.1) as Cathode Materials in Sodium-Ion Batteries—Effects of Doping and Morphology To Enhance Cycling Stability
journal, March 2016
- Bucher, Nicolas; Hartung, Steffen; Franklin, Joseph B.
- Chemistry of Materials, Vol. 28, Issue 7
Environmentally stable interface of layered oxide cathodes for sodium-ion batteries
journal, July 2017
- Guo, Shaohua; Li, Qi; Liu, Pan
- Nature Communications, Vol. 8, Issue 1
Polaron Mobility and Disordering of the Sodium Sublattice in Triphylite-Na x FePO 4
journal, April 2016
- Tracy, S. J.; Mauger, L.; Smith, H. L.
- Chemistry of Materials, Vol. 28, Issue 9
Sodium-Ion Intercalation Mechanism in MXene Nanosheets
journal, February 2016
- Kajiyama, Satoshi; Szabova, Lucie; Sodeyama, Keitaro
- ACS Nano, Vol. 10, Issue 3
In Situ Investigation of Li and Na Ion Transport with Single Nanowire Electrochemical Devices
journal, May 2015
- Xu, Xu; Yan, Mengyu; Tian, Xiaocong
- Nano Letters, Vol. 15, Issue 6
Three-dimensional microstructural imaging methods for energy materials
journal, January 2013
- Cocco, Alex P.; Nelson, George J.; Harris, William M.
- Physical Chemistry Chemical Physics, Vol. 15, Issue 39
Operando X-ray Diffraction Characterization for Understanding the Intrinsic Electrochemical Mechanism in Rechargeable Battery Materials
journal, April 2017
- Wei, Xiujuan; Wang, Xuanpeng; An, Qinyou
- Small Methods, Vol. 1, Issue 5
Robust atomic resolution imaging of light elements using scanning transmission electron microscopy
journal, November 2009
- Findlay, S. D.; Shibata, N.; Sawada, H.
- Applied Physics Letters, Vol. 95, Issue 19
Atomic Force Microscopy Studies on Molybdenum Disulfide Flakes as Sodium-Ion Anodes
journal, January 2015
- Lacey, Steven D.; Wan, Jiayu; Cresce, Arthur von Wald
- Nano Letters, Vol. 15, Issue 2
Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi 1 / 3 Mn 1 / 3 Co 1 / 3 O 2
journal, April 2012
- Sathiya, M.; Hemalatha, K.; Ramesha, K.
- Chemistry of Materials, Vol. 24, Issue 10
The AMPIX electrochemical cell: a versatile apparatus for in situ X-ray scattering and spectroscopic measurements
journal, November 2012
- Borkiewicz, Olaf J.; Shyam, Badri; Wiaderek, Kamila M.
- Journal of Applied Crystallography, Vol. 45, Issue 6
Temperature Dependent Local Structure of Na x CoO 2 Cathode Material for Rechargeable Sodium-Ion Batteries
journal, February 2016
- Olszewski, Wojciech; Ávila Pérez, Marta; Marini, Carlo
- The Journal of Physical Chemistry C, Vol. 120, Issue 8
Exploring the working mechanism of Li + in O3-type NaLi 0.1 Ni 0.35 Mn 0.55 O 2 cathode materials for rechargeable Na-ion batteries
journal, January 2016
- Zheng, Shiyao; Zhong, Guiming; McDonald, Matthew J.
- Journal of Materials Chemistry A, Vol. 4, Issue 23
Neutron Diffraction and Electrochemical Studies of Na 0.79 CoO 2 and Na 0.79 Co 0.7 Mn 0.3 O 2 Cathodes for Sodium-Ion Batteries
journal, January 2014
- Beck, Faith R.; Cheng, Y. Q.; Bi, Zhonghe
- Journal of The Electrochemical Society, Vol. 161, Issue 6
Ex Situ 23 Na Solid-State NMR Reveals the Local Na-Ion Distribution in Carbon-Coated Na 2 FePO 4 F during Electrochemical Cycling
journal, October 2016
- Smiley, Danielle L.; Goward, Gillian R.
- Chemistry of Materials, Vol. 28, Issue 21
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
β-NaMnO 2 : A High-Performance Cathode for Sodium-Ion Batteries
journal, November 2014
- Billaud, Juliette; Clément, Raphaële J.; Armstrong, A. Robert
- Journal of the American Chemical Society, Vol. 136, Issue 49
Neutron scattering for analysis of processes in lithium-ion batteries
journal, December 2014
- Balagurov, A. M.; Bobrikov, I. A.; Samoylova, N. Yu
- Russian Chemical Reviews, Vol. 83, Issue 12
Utilizing Co 2+ /Co 3+ Redox Couple in P2-Layered Na 0.66 Co 0.22 Mn 0.44 Ti 0.34 O 2 Cathode for Sodium-Ion Batteries
journal, July 2017
- Wang, Qin-Chao; Hu, Enyuan; Pan, Yang
- Advanced Science, Vol. 4, Issue 11
In situ FTIR study of the decomposition of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)amide ionic liquid during cathodic polarization of lithium and graphite electrodes
journal, March 2010
- Markevich, E.; Sharabi, R.; Borgel, V.
- Electrochimica Acta, Vol. 55, Issue 8
Crystal Structures and Electrode Performance of Alpha-NaFeO2 for Rechargeable Sodium Batteries
journal, January 2012
- Yabuuchi, Naoaki; Yoshida, Hiroaki; Komaba, Shinichi
- Electrochemistry, Vol. 80, Issue 10
Enhanced Sodium-Ion Battery Performance by Structural Phase Transition from Two-Dimensional Hexagonal-SnS 2 to Orthorhombic-SnS
journal, July 2014
- Zhou, Tengfei; Pang, Wei Kong; Zhang, Chaofeng
- ACS Nano, Vol. 8, Issue 8
Accommodating High Transformation Strains in Battery Electrodes via the Formation of Nanoscale Intermediate Phases: Operando Investigation of Olivine NaFePO 4
journal, February 2017
- Xiang, Kai; Xing, Wenting; Ravnsbæk, Dorthe B.
- Nano Letters, Vol. 17, Issue 3
Recent Progress on Synchrotron-Based In-Situ Soft X-ray Spectroscopy for Energy Materials
journal, May 2014
- Liu, Xiaosong; Yang, Wanli; Liu, Zhi
- Advanced Materials, Vol. 26, Issue 46
Phase Diagram of Olivine Na x FePO 4 (0 < x < 1)
journal, October 2013
- Lu, Jiechen; Chung, Sai Cheong; Nishimura, Shin-ichi
- Chemistry of Materials, Vol. 25, Issue 22
Direct Observation of Li-Ion Transport in Electrodes under Nonequilibrium Conditions Using Neutron Depth Profiling
journal, June 2015
- Zhang, Xiaoyu; Verhallen, Tomas W.; Labohm, Freek
- Advanced Energy Materials, Vol. 5, Issue 15
In situ Raman spectroscopic–electrochemical studies of lithium-ion battery materials: a historical overview
journal, October 2013
- Stancovski, Victor; Badilescu, Simona
- Journal of Applied Electrochemistry, Vol. 44, Issue 1
In operando tracking phase transformation evolution of lithium iron phosphate with hard X-ray microscopy
journal, August 2014
- Wang, Jiajun; Chen-Wiegart, Yu-chen Karen; Wang, Jun
- Nature Communications, Vol. 5, Issue 1
Simultaneous Reduction of Co 3+ and Mn 4+ in P2-Na 2/3 Co 2/3 Mn 1/3 O 2 As Evidenced by X-ray Absorption Spectroscopy during Electrochemical Sodium Intercalation
journal, December 2013
- Cheng, Ju-Hsiang; Pan, Chun-Jern; Lee, Jyh-Fu
- Chemistry of Materials, Vol. 26, Issue 2
Layered P 3-Na x Co 1/3 Ni 1/3 Mn 1/3 O 2 versus Spinel Li 4 Ti 5 O 12 as a Positive and a Negative Electrode in a Full Sodium–Lithium Cell
journal, June 2016
- Ivanova, Svetlana; Zhecheva, Ekaterina; Kukeva, Rositsa
- ACS Applied Materials & Interfaces, Vol. 8, Issue 27
Direct visualization of the Jahn–Teller effect coupled to Na ordering in Na5/8MnO2
journal, May 2014
- Li, Xin; Ma, Xiaohua; Su, Dong
- Nature Materials, Vol. 13, Issue 6
Investigating the Energy Storage Mechanism of SnS 2 -rGO Composite Anode for Advanced Na-Ion Batteries
journal, August 2015
- Ma, Chuze; Xu, Jing; Alvarado, Judith
- Chemistry of Materials, Vol. 27, Issue 16
Electrochemical Na Extraction/Insertion of Na 3 V 2 O 2 x (PO 4 ) 2 F 3–2 x
journal, December 2013
- Serras, Paula; Palomares, Verónica; Alonso, Javier
- Chemistry of Materials, Vol. 25, Issue 24
Elucidating the Irreversible Mechanism and Voltage Hysteresis in Conversion Reaction for High-Energy Sodium-Metal Sulfide Batteries
journal, March 2017
- Wang, Jiajun; Wang, Liguang; Eng, Christopher
- Advanced Energy Materials, Vol. 7, Issue 14
Sol-gel synthesis of Na4Fe3(PO4)2(P2O7)/C nanocomposite for sodium ion batteries and new insights into microstructural evolution during sodium extraction
journal, September 2016
- Wu, Xuehang; Zhong, Guiming; Yang, Yong
- Journal of Power Sources, Vol. 327
Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode
journal, January 2018
- Rong, Xiaohui; Liu, Jue; Hu, Enyuan
- Joule, Vol. 2, Issue 1
Investigating Sodium Storage Mechanisms in Tin Anodes: A Combined Pair Distribution Function Analysis, Density Functional Theory, and Solid-State NMR Approach
journal, May 2017
- Stratford, Joshua M.; Mayo, Martin; Allan, Phoebe K.
- Journal of the American Chemical Society, Vol. 139, Issue 21
Insights into Electrochemical Sodium Metal Deposition as Probed with in Situ 23 Na NMR
journal, February 2016
- Bayley, Paul M.; Trease, Nicole M.; Grey, Clare P.
- Journal of the American Chemical Society, Vol. 138, Issue 6
NMR study for electrochemically inserted Na in hard carbon electrode of sodium ion battery
journal, March 2013
- Gotoh, Kazuma; Ishikawa, Toru; Shimadzu, Saori
- Journal of Power Sources, Vol. 225
Nanoscale Clarification of the Electronic Structure and Optical Properties of TiO 2 Nanowire with an Impurity Phase upon Sodium Intercalation
journal, July 2015
- Li, Jun; Wang, Zhiqiang; Zhao, Ankang
- The Journal of Physical Chemistry C, Vol. 119, Issue 31
A phosphorene–graphene hybrid material as a high-capacity anode for sodium-ion batteries
journal, September 2015
- Sun, Jie; Lee, Hyun-Wook; Pasta, Mauro
- Nature Nanotechnology, Vol. 10, Issue 11
Elucidation of the Na 2/3 FePO 4 and Li 2/3 FePO 4 Intermediate Superstructure Revealing a Pseudouniform Ordering in 2D
journal, June 2014
- Boucher, Florent; Gaubicher, Joël; Cuisinier, Marine
- Journal of the American Chemical Society, Vol. 136, Issue 25
Electrochemical Interaction of Few-Layer Molybdenum Disulfide Composites vs Sodium: New Insights on the Reaction Mechanism
journal, July 2017
- González, José R.; Alcántara, Ricardo; Tirado, José L.
- Chemistry of Materials, Vol. 29, Issue 14
An O3-type NaNi 0.5 Mn 0.5 O 2 cathode for sodium-ion batteries with improved rate performance and cycling stability
journal, January 2016
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Journal of Materials Chemistry A, Vol. 4, Issue 45
Improved Electrochemical Performance of Fe-Substituted NaNi 0.5 Mn 0.5 O 2 Cathode Materials for Sodium-Ion Batteries
journal, April 2015
- Yuan, Ding D.; Wang, Yan X.; Cao, Yu L.
- ACS Applied Materials & Interfaces, Vol. 7, Issue 16
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Vanadium Clustering/Declustering in P2–Na 1/2 VO 2 Layered Oxide
journal, February 2014
- Guignard, Marie; Carlier, Dany; Didier, Christophe
- Chemistry of Materials, Vol. 26, Issue 4
An Iodine Quantum Dots Based Rechargeable Sodium-Iodine Battery
journal, October 2016
- Gong, Decai; Wang, Bin; Zhu, Jingyi
- Advanced Energy Materials, Vol. 7, Issue 3
Three-dimensional graphene frameworks wrapped Li3V2(PO4)3 with reversible topotactic sodium-ion storage
journal, February 2017
- Xiong, Fangyu; Tan, Shuangshuang; Wei, Qiulong
- Nano Energy, Vol. 32
Thermally and Electrochemically Driven Topotactical Transformations in Sodium Layered Oxides Na x VO 2
journal, February 2016
- Didier, Christophe; Guignard, Marie; Suchomel, Matthew R.
- Chemistry of Materials, Vol. 28, Issue 5
High-Performance P2-Phase Na 2/3 Mn 0.8 Fe 0.1 Ti 0.1 O 2 Cathode Material for Ambient-Temperature Sodium-Ion Batteries
journal, December 2015
- Han, Man Huon; Gonzalo, Elena; Sharma, Neeraj
- Chemistry of Materials, Vol. 28, Issue 1
Hydrated vanadium pentoxide with superior sodium storage capacity
journal, January 2015
- Wei, Qiulong; Liu, Jin; Feng, Wei
- Journal of Materials Chemistry A, Vol. 3, Issue 15
Two-dimensional lithium diffusion behavior and probable hybrid phase transformation kinetics in olivine lithium iron phosphate
journal, October 2017
- Hong, Liang; Li, Linsen; Chen-Wiegart, Yuchen-Karen
- Nature Communications, Vol. 8, Issue 1
Visualization of anisotropic-isotropic phase transformation dynamics in battery electrode particles
journal, August 2016
- Wang, Jiajun; Karen Chen-Wiegart, Yu-chen; Eng, Christopher
- Nature Communications, Vol. 7, Issue 1
Neutron diffraction studies of the Na-ion battery electrode materials NaCoCr2(PO4)3, NaNiCr2(PO4)3, and Na2Ni2Cr(PO4)3
journal, June 2016
- Yahia, H. Ben; Essehli, R.; Avdeev, M.
- Journal of Solid State Chemistry, Vol. 238
In situ atomic-scale observation of reversible sodium ions migration in layered metal dichalcogenide SnS2 nanostructures
journal, February 2017
- Gao, Peng; Zhang, Yu-Yang; Wang, Liping
- Nano Energy, Vol. 32
Structural evolution during sodium deintercalation/intercalation in Na 2/3 [Fe 1/2 Mn 1/2 ]O 2
journal, January 2015
- Singh, Gurpreet; López del Amo, Juan Miguel; Galceran, Montserrat
- Journal of Materials Chemistry A, Vol. 3, Issue 13
Distinct nanoscale reaction pathways in a sulfide material for sodium and lithium batteries
journal, January 2017
- Boebinger, Matthew G.; Xu, Michael; Ma, Xuetian
- Journal of Materials Chemistry A, Vol. 5, Issue 23
A Novel High Capacity Positive Electrode Material with Tunnel-Type Structure for Aqueous Sodium-Ion Batteries
journal, August 2015
- Wang, Yuesheng; Mu, Linqin; Liu, Jue
- Advanced Energy Materials, Vol. 5, Issue 22
O3-type layered transition metal oxide Na(NiCoFeTi) 1/4 O 2 as a high rate and long cycle life cathode material for sodium ion batteries
journal, January 2015
- Yue, Ji-Li; Zhou, Yong-Ning; Yu, Xiqian
- Journal of Materials Chemistry A, Vol. 3, Issue 46
Electrospun NaVPO 4 F/C Nanofibers as Self-Standing Cathode Material for Ultralong Cycle Life Na-Ion Batteries
journal, April 2017
- Jin, Ting; Liu, Yongchang; Li, Yang
- Advanced Energy Materials, Vol. 7, Issue 15
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Anomalous Jahn–Teller behavior in a manganese-based mixed-phosphate cathode for sodium ion batteries
journal, January 2015
- Kim, Hyungsub; Yoon, Gabin; Park, Inchul
- Energy & Environmental Science, Vol. 8, Issue 11
Origin of additional capacities in metal oxide lithium-ion battery electrodes
journal, November 2013
- Hu, Yan-Yan; Liu, Zigeng; Nam, Kyung-Wan
- Nature Materials, Vol. 12, Issue 12
Insights into the Effects of Zinc Doping on Structural Phase Transition of P2-Type Sodium Nickel Manganese Oxide Cathodes for High-Energy Sodium Ion Batteries
journal, August 2016
- Wu, Xuehang; Xu, Gui-Liang; Zhong, Guiming
- ACS Applied Materials & Interfaces, Vol. 8, Issue 34
Tuning the Solid Electrolyte Interphase for Selective Li- and Na-Ion Storage in Hard Carbon
journal, March 2017
- Soto, Fernando A.; Yan, Pengfei; Engelhard, Mark H.
- Advanced Materials, Vol. 29, Issue 18
Two-Dimensional Materials for Beyond-Lithium-Ion Batteries
journal, March 2016
- Peng, Lele; Zhu, Yue; Chen, Dahong
- Advanced Energy Materials, Vol. 6, Issue 11
A Size-Dependent Sodium Storage Mechanism in Li 4 Ti 5 O 12 Investigated by a Novel Characterization Technique Combining in Situ X-ray Diffraction and Chemical Sodiation
journal, September 2013
- Yu, Xiqian; Pan, Huilin; Wan, Wang
- Nano Letters, Vol. 13, Issue 10
Discharge/charge reaction mechanism of a pyrite-type FeS 2 cathode for sodium secondary batteries
journal, February 2014
- Kitajou, Ayuko; Yamaguchi, Junpei; Hara, Satoshi
- Journal of Power Sources, Vol. 247
A Reversible Phase Transition for Sodium Insertion in Anatase TiO 2
journal, February 2017
- Li, Wei; Fukunishi, Mika; Morgan, Benjamin. J.
- Chemistry of Materials, Vol. 29, Issue 4
Phase transformation mechanism in lithium manganese nickel oxide revealed by single-crystal hard X-ray microscopy
journal, February 2017
- Kuppan, Saravanan; Xu, Yahong; Liu, Yijin
- Nature Communications, Vol. 8, Issue 1
Direct atomic-scale confirmation of three-phase storage mechanism in Li4Ti5O12 anodes for room-temperature sodium-ion batteries
journal, May 2013
- Sun, Yang; Zhao, Liang; Pan, Huilin
- Nature Communications, Vol. 4, Issue 1
History, Evolution, and Future Status of Energy Storage
journal, May 2012
- Whittingham, M. S.
- Proceedings of the IEEE, Vol. 100, Issue Special Centennial Issue
Alkaline earth metal vanadates as sodium-ion battery anodes
journal, September 2017
- Xu, Xiaoming; Niu, Chaojiang; Duan, Manyi
- Nature Communications, Vol. 8, Issue 1
Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe2(MoO4)3
journal, March 2015
- Yue, Ji-Li; Zhou, Yong-Ning; Shi, Si-Qi
- Scientific Reports, Vol. 5, Issue 1
Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide
journal, September 2017
- Shadike, Zulipiya; Zhou, Yong-Ning; Chen, Lan-Li
- Nature Communications, Vol. 8, Issue 1
New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon
journal, August 2015
- Bommier, Clement; Surta, Todd Wesley; Dolgos, Michelle
- Nano Letters, Vol. 15, Issue 9
Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging
journal, April 2015
- Li, Linsen; Chen-Wiegart, Yu-chen Karen; Wang, Jiajun
- Nature Communications, Vol. 6, Issue 1
Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries
journal, October 2014
- You, Ya; Yu, Xiqian; Yin, Yaxia
- Nano Research, Vol. 8, Issue 1
A Layered P2- and O3-Type Composite as a High-Energy Cathode for Rechargeable Sodium-Ion Batteries
journal, April 2015
- Guo, Shaohua; Liu, Pan; Yu, Haijun
- Angewandte Chemie International Edition, Vol. 54, Issue 20
Identifying the Conversion Mechanism of NiCo 2 O 4 during Sodiation-Desodiation Cycling by In Situ TEM
journal, March 2017
- Zhu, Chongyang; Xu, Feng; Min, Huihua
- Advanced Functional Materials, Vol. 27, Issue 17
Works referencing / citing this record:
Bismuth Sulfide–Integrated Carbon Derived from Organic Ligands as a Superior Anode for Sodium Storage
journal, August 2019
- Chai, Wenwen; Yin, Weihao; Wang, Ke
- Energy Technology, Vol. 7, Issue 10
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy
journal, July 2019
- Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue
- Batteries & Supercaps, Vol. 2, Issue 10
Real-time monitoring of stress development during electrochemical cycling of electrode materials for Li-ion batteries: overview and perspectives
journal, January 2019
- Jangid, Manoj K.; Mukhopadhyay, Amartya
- Journal of Materials Chemistry A, Vol. 7, Issue 41
Enhanced Interfacial Kinetics of Carbon Monolith Boosting Ultrafast Na‐Storage
journal, December 2018
- Liu, Lei; Chen, Yu; Xie, Yihao
- Small, Vol. 15, Issue 5
Water-Processable P2-Na 0.67 Ni 0.22 Cu 0.11 Mn 0.56 Ti 0.11 O 2 Cathode Material for Sodium Ion Batteries
journal, January 2019
- Mu, Linqin; Hou, Qingping; Yang, Zhenzhong
- Journal of The Electrochemical Society, Vol. 166, Issue 2
Review of Recent Development of In Situ/Operando Characterization Techniques for Lithium Battery Research
journal, May 2019
- Liu, Dongqing; Shadike, Zulipiya; Lin, Ruoqian
- Advanced Materials, Vol. 31, Issue 28
Facile preparation of NaV 3 O 8 /polytriphenylamine composites as cathode materials towards high‐performance sodium storage
journal, December 2019
- Zhu, Limin; Ding, Guochun; Xie, Lingling
- International Journal of Energy Research, Vol. 44, Issue 4
The Advances of Metal Sulfides and In Situ Characterization Methods beyond Li Ion Batteries: Sodium, Potassium, and Aluminum Ion Batteries
journal, November 2019
- Chen, Jingwei; Chua, Daniel H. C.; Lee, Pooi See
- Small Methods, Vol. 4, Issue 1
Facile and scalable synthesis of low-cost FeS@C as long-cycle anodes for sodium-ion batteries
journal, January 2019
- Yang, Dan; Chen, Weihua; Zhang, Xixue
- Journal of Materials Chemistry A, Vol. 7, Issue 34
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode
journal, December 2019
- Xiao, Yao; Zhu, Yan‐Fang; Xiang, Wei
- Angewandte Chemie, Vol. 132, Issue 4
A Stable Layered Oxide Cathode Material for High‐Performance Sodium‐Ion Battery
journal, March 2019
- Xiao, Yao; Zhu, Yan‐Fang; Yao, Hu‐Rong
- Advanced Energy Materials, Vol. 9, Issue 19
High‐Abundance and Low‐Cost Metal‐Based Cathode Materials for Sodium‐Ion Batteries: Problems, Progress, and Key Technologies
journal, February 2019
- Chen, Mingzhe; Liu, Qiannan; Wang, Shi‐Wen
- Advanced Energy Materials, Vol. 9, Issue 14
Lab‐Scale In Situ X‐Ray Diffraction Technique for Different Battery Systems: Designs, Applications, and Perspectives
journal, May 2019
- Xia, Maoting; Liu, Tingting; Peng, Na
- Small Methods, Vol. 3, Issue 7
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode
journal, January 2020
- Xiao, Yao; Zhu, Yan‐Fang; Xiang, Wei
- Angewandte Chemie International Edition, Vol. 59, Issue 4