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Title: Review of Recent Development of in situ/operando Characterization Techniques for Lithium Battery Research

Abstract

The increasing demands on energy storage requires significant improvement of current Li-ion battery electrode materials and development of advanced electrode materials. This necessitates in-depth understanding of the reaction processes, degradation mechanism, and thermal decomposition mechanisms of electrode materials under realistic operation conditions. This can be achieved by in situ/operando characterization techniques that provide information of the structure evolution, redox mechanism, solid-electrolyte interphase (SEI) formation, side reactions and Li-ion transport properties under operating conditions. In this review, recent progress of in situ/operando techniques employed for the investigation of the structural stability, dynamic properties, chemical environment changes and morphological evolution during electrochemical processes are described and summarized in detail. The experimental approaches reviewed in this paper include X-ray, Electron, Neutron, Optical, and Scanning probes. Each advanced technique has unique capabilities to study specific properties of electrode materials within specific limitations. The experimental methods and operating principles, and especially the in situ cell designs are described in detail. To illustrate the possibilities of each technique representative studies making use of these in situ/operando techniques are discussed and summarized. Finally, the major current challenges and future opportunities of the in situ/operando techniques are outlined. Several important battery challenges are anticipated to profit from thesemore » in situ/operando techniques, including the inhomogeneous reactions of high energy density cathodes, the development of safe and reversible Li metal plating and the development of stable SEI on electrodes.« less

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [1]; ORCiD logo [3];  [3];  [3];  [4];  [5];  [5];  [5];  [6]
+ Show Author Affiliations
  1. Tsinghua Univ., Shenzhen (China). Engineering Lab. for the Next Generation Power and Energy Storage Batteries, Graduate School at Shenzhen
  2. Tsinghua Univ., Shenzhen (China). Engineering Lab. for the Next Generation Power and Energy Storage Batteries, Graduate School at Shenzhen; Tsinghua Univ., Shenzhen (China). Nano Energy Materials Lab. (NEM), Tsinghua-Berkeley Shenzhen Inst. (TBSI)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
  4. Tsinghua Univ., Shenzhen (China). Nano Energy Materials Lab. (NEM), Tsinghua-Berkeley Shenzhen Inst. (TBSI)
  5. Delft Univ. of Technology (Netherlands). Dept. of Radiation Science and Technology
  6. Hong Kong Polytechnic Univ. (Hong Kong)
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Nature Science Foundation of China (NNSFC); USDOE
OSTI Identifier:
1507700
Alternate Identifier(s):
OSTI ID: 1513307
Report Number(s):
BNL-211557-2019-JAAM
Journal ID: ISSN 0935-9648
Grant/Contract Number:  
SC0012704; DE‐SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 31; Journal Issue: 28; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; characterization techniques; in situ-operando; lithium battery

Citation Formats

Liu, Dongqing, Qian, K., Li, H., Wang, S.W., Yu, Q. P., Qin, X.Y., Yang, Q.-H., Kang, F.Y., Li, B. H., Shadike, Zulipiya, Lin, R. Q., Yang, X.-Q., Qian, K., Liu, M., Ganapathy, S., Wagemaker, M., and Li, K. K. Review of Recent Development of in situ/operando Characterization Techniques for Lithium Battery Research. United States: N. p., 2019. Web. doi:10.1002/adma.201806620.
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Liu, Dongqing, Qian, K., Li, H., Wang, S.W., Yu, Q. P., Qin, X.Y., Yang, Q.-H., Kang, F.Y., Li, B. H., Shadike, Zulipiya, Lin, R. Q., Yang, X.-Q., Qian, K., Liu, M., Ganapathy, S., Wagemaker, M., & Li, K. K. Review of Recent Development of in situ/operando Characterization Techniques for Lithium Battery Research. United States. https://doi.org/10.1002/adma.201806620
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Liu, Dongqing, Qian, K., Li, H., Wang, S.W., Yu, Q. P., Qin, X.Y., Yang, Q.-H., Kang, F.Y., Li, B. H., Shadike, Zulipiya, Lin, R. Q., Yang, X.-Q., Qian, K., Liu, M., Ganapathy, S., Wagemaker, M., and Li, K. K. Tue . "Review of Recent Development of in situ/operando Characterization Techniques for Lithium Battery Research". United States. https://doi.org/10.1002/adma.201806620. https://www.osti.gov/servlets/purl/1507700.
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@article{osti_1507700,
title = {Review of Recent Development of in situ/operando Characterization Techniques for Lithium Battery Research},
author = {Liu, Dongqing and Qian, K. and Li, H. and Wang, S.W. and Yu, Q. P. and Qin, X.Y. and Yang, Q.-H. and Kang, F.Y. and Li, B. H. and Shadike, Zulipiya and Lin, R. Q. and Yang, X.-Q. and Qian, K. and Liu, M. and Ganapathy, S. and Wagemaker, M. and Li, K. K.},
abstractNote = {The increasing demands on energy storage requires significant improvement of current Li-ion battery electrode materials and development of advanced electrode materials. This necessitates in-depth understanding of the reaction processes, degradation mechanism, and thermal decomposition mechanisms of electrode materials under realistic operation conditions. This can be achieved by in situ/operando characterization techniques that provide information of the structure evolution, redox mechanism, solid-electrolyte interphase (SEI) formation, side reactions and Li-ion transport properties under operating conditions. In this review, recent progress of in situ/operando techniques employed for the investigation of the structural stability, dynamic properties, chemical environment changes and morphological evolution during electrochemical processes are described and summarized in detail. The experimental approaches reviewed in this paper include X-ray, Electron, Neutron, Optical, and Scanning probes. Each advanced technique has unique capabilities to study specific properties of electrode materials within specific limitations. The experimental methods and operating principles, and especially the in situ cell designs are described in detail. To illustrate the possibilities of each technique representative studies making use of these in situ/operando techniques are discussed and summarized. Finally, the major current challenges and future opportunities of the in situ/operando techniques are outlined. Several important battery challenges are anticipated to profit from these in situ/operando techniques, including the inhomogeneous reactions of high energy density cathodes, the development of safe and reversible Li metal plating and the development of stable SEI on electrodes.},
doi = {10.1002/adma.201806620},
journal = {Advanced Materials},
number = 28,
volume = 31,
place = {United States},
year = {Tue Apr 30 00:00:00 EDT 2019},
month = {Tue Apr 30 00:00:00 EDT 2019}
}
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Leapfrog Cracking and Nanoamorphization of ZnO Nanowires during In Situ Electrochemical Lithiation
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Revealing the conversion mechanism of CuO nanowires during lithiation–delithiation by in situ transmission electron microscopy
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In Situ Transmission Electron Microscopy Study of Electrochemical Lithiation and Delithiation Cycling of the Conversion Anode RuO 2
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Real-time Observation of Deep Lithiation of Tungsten Oxide Nanowires by In Situ Electron Microscopy
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Strain Coupling of Conversion-type Fe 3 O 4 Thin Films for Lithium Ion Batteries
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Study on the Electrochemical Reaction Mechanism of ZnFe2O4 by In Situ Transmission Electron Microscopy
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In Situ Transmission Electron Microscopy Observation of Electrochemical Behavior of CoS 2 in Lithium-Ion Battery
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High-Resolution Tracking Asymmetric Lithium Insertion and Extraction and Local Structure Ordering in SnS 2
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In Situ TEM Observation of Local Phase Transformation in a Rechargeable LiMn 2 O 4 Nanowire Battery
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In Situ Atomic-Scale Imaging of Phase Boundary Migration in FePO 4 Microparticles During Electrochemical Lithiation
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In Situ Observation of Random Solid Solution Zone in LiFePO 4 Electrode
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Direct characterization of the Li intercalation mechanism into α-V 2 O 5 nanowires using in-situ transmission electron microscopy
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Controlling the Lithiation-Induced Strain and Charging Rate in Nanowire Electrodes by Coating
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Sandwich-Lithiation and Longitudinal Crack in Amorphous Silicon Coated on Carbon Nanofibers
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Lithiation of SiO 2 in Li-Ion Batteries: In Situ Transmission Electron Microscopy Experiments and Theoretical Studies
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Dynamics of Electrochemical Lithiation/Delithiation of Graphene-Encapsulated Silicon Nanoparticles Studied by In-situ TEM
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Tailoring Lithiation Behavior by Interface and Bandgap Engineering at the Nanoscale
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A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
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In Situ TEM Study of Lithiation Behavior of Silicon Nanoparticles Attached to and Embedded in a Carbon Matrix
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Engineering Heteromaterials to Control Lithium Ion Transport Pathways
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Lithium Electrodeposition Dynamics in Aprotic Electrolyte Observed in Situ via Transmission Electron Microscopy
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Observation and Quantification of Nanoscale Processes in Lithium Batteries by Operando Electrochemical (S)TEM
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Direct Observation of Li-Ion Transport in Electrodes under Nonequilibrium Conditions Using Neutron Depth Profiling
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In Situ Neutron Depth Profiling: A Powerful Method to Probe Lithium Transport in Micro-Batteries
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Operando Neutron Depth Profiling to Determine the Spatial Distribution of Li in Li-ion Batteries
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Probing Multiscale Transport and Inhomogeneity in a Lithium-Ion Pouch Cell Using In Situ Neutron Methods
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