Transforming from planar to three-dimensional lithium with flowable interphase for solid lithium metal batteries
Abstract
Solid-state lithium (Li) metal batteries are prominent among next-generation energy storage technologies due to their significantly high energy density and reduced safety risks. Previously, solid electrolytes have been intensively studied and several materials with high ionic conductivity have been identified. However, there are still at least three obstacles before making the Li metal foil-based solid-state systems viable, namely, high interfacial resistance at the Li/electrolyte interface, low areal capacity, and poor power output. The problems are addressed by incorporating a flowable interfacial layer and three-dimensional Li into the system. The flowable interfacial layer can accommodate the interfacial fluctuation and guarantee excellent adhesion at all time, whereas the three-dimensional Li significantly reduces the interfacial fluctuation from the whole electrode level (tens of micrometers) to local scale (submicrometer) and also decreases the effective current density for high-capacity and high-power operations. As a consequence, both symmetric and full-cell configurations can achieve greatly improved electrochemical performances in comparison to the conventional Li foil, which are among the best reported values in the literature. Noticeably, solid-state full cells paired with high–mass loading LiFePO4 exhibited, at 80°C, a satisfactory specific capacity even at a rate of 5 C (110 mA·hour g-1) and a capacity retention of 93.6%more »
- Authors:
-
- Stanford Univ., CA (United States)
- Stanford Univ., CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1419638
- Grant/Contract Number:
- AC02-76SF00515; award351198; Battery Materials Research (BMR) program; award351199; Battery 500 Consortium program
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 10; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Liu, Yayuan, Lin, Dingchang, Jin, Yang, Liu, Kai, Tao, Xinyong, Zhang, Qiuhong, Zhang, Xiaokun, and Cui, Yi. Transforming from planar to three-dimensional lithium with flowable interphase for solid lithium metal batteries. United States: N. p., 2017.
Web. doi:10.1126/sciadv.aao0713.
Liu, Yayuan, Lin, Dingchang, Jin, Yang, Liu, Kai, Tao, Xinyong, Zhang, Qiuhong, Zhang, Xiaokun, & Cui, Yi. Transforming from planar to three-dimensional lithium with flowable interphase for solid lithium metal batteries. United States. https://doi.org/10.1126/sciadv.aao0713
Liu, Yayuan, Lin, Dingchang, Jin, Yang, Liu, Kai, Tao, Xinyong, Zhang, Qiuhong, Zhang, Xiaokun, and Cui, Yi. Sun .
"Transforming from planar to three-dimensional lithium with flowable interphase for solid lithium metal batteries". United States. https://doi.org/10.1126/sciadv.aao0713. https://www.osti.gov/servlets/purl/1419638.
@article{osti_1419638,
title = {Transforming from planar to three-dimensional lithium with flowable interphase for solid lithium metal batteries},
author = {Liu, Yayuan and Lin, Dingchang and Jin, Yang and Liu, Kai and Tao, Xinyong and Zhang, Qiuhong and Zhang, Xiaokun and Cui, Yi},
abstractNote = {Solid-state lithium (Li) metal batteries are prominent among next-generation energy storage technologies due to their significantly high energy density and reduced safety risks. Previously, solid electrolytes have been intensively studied and several materials with high ionic conductivity have been identified. However, there are still at least three obstacles before making the Li metal foil-based solid-state systems viable, namely, high interfacial resistance at the Li/electrolyte interface, low areal capacity, and poor power output. The problems are addressed by incorporating a flowable interfacial layer and three-dimensional Li into the system. The flowable interfacial layer can accommodate the interfacial fluctuation and guarantee excellent adhesion at all time, whereas the three-dimensional Li significantly reduces the interfacial fluctuation from the whole electrode level (tens of micrometers) to local scale (submicrometer) and also decreases the effective current density for high-capacity and high-power operations. As a consequence, both symmetric and full-cell configurations can achieve greatly improved electrochemical performances in comparison to the conventional Li foil, which are among the best reported values in the literature. Noticeably, solid-state full cells paired with high–mass loading LiFePO4 exhibited, at 80°C, a satisfactory specific capacity even at a rate of 5 C (110 mA·hour g-1) and a capacity retention of 93.6% after 300 cycles at a current density of 3 mA cm-2 using a composite solid electrolyte middle layer. In addition, when a ceramic electrolyte middle layer was adopted, stable cycling with greatly improved capacity could even be realized at room temperature.},
doi = {10.1126/sciadv.aao0713},
journal = {Science Advances},
number = 10,
volume = 3,
place = {United States},
year = {Sun Oct 01 00:00:00 EDT 2017},
month = {Sun Oct 01 00:00:00 EDT 2017}
}
Web of Science
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