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Title: A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

Authors:
; ; ; ; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1419590
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Magnetochemistry
Additional Journal Information:
Journal Name: Magnetochemistry Journal Volume: 2 Journal Issue: 4; Journal ID: ISSN 2312-7481
Publisher:
MDPI AG
Country of Publication:
Country unknown/Code not available
Language:
English

Citation Formats

Shepherd, Helena, Tonge, George, Hatcher, Lauren, Bryant, Mathew, Knichal, Jane, Raithby, Paul, Halcrow, Malcolm, Kulmaczewski, Rafal, Gagnon, Kevin, and Teat, Simon. A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Country unknown/Code not available: N. p., 2016. Web. doi:10.3390/magnetochemistry2010009.
Shepherd, Helena, Tonge, George, Hatcher, Lauren, Bryant, Mathew, Knichal, Jane, Raithby, Paul, Halcrow, Malcolm, Kulmaczewski, Rafal, Gagnon, Kevin, & Teat, Simon. A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Country unknown/Code not available. https://doi.org/10.3390/magnetochemistry2010009
Shepherd, Helena, Tonge, George, Hatcher, Lauren, Bryant, Mathew, Knichal, Jane, Raithby, Paul, Halcrow, Malcolm, Kulmaczewski, Rafal, Gagnon, Kevin, and Teat, Simon. Wed . "A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)". Country unknown/Code not available. https://doi.org/10.3390/magnetochemistry2010009.
@article{osti_1419590,
title = {A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)},
author = {Shepherd, Helena and Tonge, George and Hatcher, Lauren and Bryant, Mathew and Knichal, Jane and Raithby, Paul and Halcrow, Malcolm and Kulmaczewski, Rafal and Gagnon, Kevin and Teat, Simon},
abstractNote = {},
doi = {10.3390/magnetochemistry2010009},
journal = {Magnetochemistry},
number = 4,
volume = 2,
place = {Country unknown/Code not available},
year = {Wed Feb 17 00:00:00 EST 2016},
month = {Wed Feb 17 00:00:00 EST 2016}
}

Works referenced in this record:

Coupled Crystallographic Order–Disorder and Spin State in a Bistable Molecule: Multiple Transition Dynamics
journal, February 2011

  • Craig, Gavin A.; Sánchez Costa, José; Roubeau, Olivier
  • Chemistry – A European Journal, Vol. 17, Issue 11
  • DOI: 10.1002/chem.201003197

Synthesis of 4-Hydroxy-2,6-di(pyrazol-1-yl)pyridine, and the Spin State Behaviour of Its Iron(II) Complex Salts
journal, October 2015


Polymorphism in spin-crossover systems
journal, January 2012

  • Tao, Jun; Wei, Rong-Jia; Huang, Rong-Bin
  • Chem. Soc. Rev., Vol. 41, Issue 2
  • DOI: 10.1039/C1CS15136C

Tunable Trimers: Using Temperature and Pressure to Control Luminescent Emission in Gold(I) Pyrazolate-Based Trimers
journal, October 2014

  • Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M.
  • Chemistry - A European Journal, Vol. 20, Issue 51
  • DOI: 10.1002/chem.201404058

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009

  • Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J.
  • Journal of Applied Crystallography, Vol. 42, Issue 2
  • DOI: 10.1107/S0021889808042726

Calibration of the pressure dependence of the R 1 ruby fluorescence line to 195 kbar
journal, June 1975

  • Piermarini, G. J.; Block, S.; Barnett, J. D.
  • Journal of Applied Physics, Vol. 46, Issue 6
  • DOI: 10.1063/1.321957

A study of the thermal and light induced spin transition in [FeL 2 ](BF 4 ) 2 and [FeL 2 ](ClO 4 ) 2 L = 2,6-di(3-methylpyrazol-1-yl)pyrazine
journal, January 2004

  • Money, Victoria A.; Elhaïk, Jerome; Radosavljevic Evans, Ivana
  • Dalton Trans., Issue 1
  • DOI: 10.1039/b311262b

The spin-states and spin-crossover behaviour of iron( ii ) complexes of 2,6-dipyrazol-1-ylpyrazine derivatives
journal, January 2003

  • Elhaïk, Jérôme; Money, Victoria A.; Barrett, Simon A.
  • Dalton Trans., Issue 10
  • DOI: 10.1039/B210368K

Structure:function relationships in molecular spin-crossover complexes
journal, January 2011


Simple Two-Dimensional Model for the Elastic Origin of Cooperativity among Spin States of Spin-Crossover Complexes
journal, June 2007


Magnetostructural Relationship in the Spin-Crossover Complex t-{Fe(abpt) 2 [N(CN) 2 ] 2 }: Polymorphism and Disorder Phenomenon
journal, December 2008

  • Sheu, Chou-Fu; Pillet, Sébastien; Lin, Yen-Chen
  • Inorganic Chemistry, Vol. 47, Issue 23
  • DOI: 10.1021/ic800879c

Use of a CCD diffractometer in crystal structure determinations at high pressure
journal, May 2004

  • Dawson, Alice; Allan, David R.; Parsons, Simon
  • Journal of Applied Crystallography, Vol. 37, Issue 3
  • DOI: 10.1107/S0021889804007149

Coupling between spin conversion and solvent disorder in spin crossover solids
journal, July 2007


Antagonism between Extreme Negative Linear Compression and Spin Crossover in [Fe(dpp)2(NCS)2]⋅py
journal, March 2012

  • Shepherd, Helena J.; Palamarciuc, Tatiana; Rosa, Patrick
  • Angewandte Chemie International Edition, Vol. 51, Issue 16
  • DOI: 10.1002/anie.201108919