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Title: Sinter‐Resistant Platinum Catalyst Supported by Metal–Organic Framework

Abstract

Abstract Single atoms and few‐atom clusters of platinum are uniformly installed on the zirconia nodes of a metal‐organic framework (MOF) NU‐1000 via targeted vapor‐phase synthesis. The catalytic Pt clusters, site‐isolated by organic linkers, are shown to exhibit high catalytic activity for ethylene hydrogenation while exhibiting resistance to sintering up to 200 °C. In situ IR spectroscopy reveals the presence of both single atoms and few‐atom clusters that depend upon synthesis conditions. Operando X‐ray absorption spectroscopy and X‐ray pair distribution analyses reveal unique changes in chemical bonding environment and cluster size stability while on stream. Density functional theory calculations elucidate a favorable reaction pathway for ethylene hydrogenation with the novel catalyst. These results provide evidence that atomic layer deposition (ALD) in MOFs is a versatile approach to the rational synthesis of size‐selected clusters, including noble metals, on a high surface area support.

Authors:
 [1];  [2];  [3];  [4]; ORCiD logo [5];  [6];  [7];  [3];  [4];  [5];  [2];  [5];  [6];  [5];  [4];  [3];  [3];  [8];  [2];  [9] more »; ORCiD logo [10] « less
+ Show Author Affiliations
  1. Materials Science Division Argonne National Lab 9700 S Cass Ave. Argonne IL 60439 USA, Nanophotonics Center Korea Institute of Science and Technology Seoul 02792 South Korea
  2. Department of Chemistry Northwestern University 2145 Sheridan Rd. Evanston IL 60208 USA
  3. Institute for Integrated Catalysis Pacific Northwest National Lab P.O. Box 999 Richland WA 99352 USA
  4. X-ray Science Division Argonne National Lab 9700 S Cass Ave. Argonne IL 60439 USA
  5. Department of Chemistry University of Minnesota 207 Pleasant St. SE Minneapolis MN 55455 USA
  6. Chemical and Biomolecular Engineering Clemson University 205 Earle Hall Clemson SC 29634 USA
  7. Chemical Sciences and Engineering Division Argonne National Lab 9700 S. Cass Ave. Argonne IL 60439 USA
  8. Institute for Integrated Catalysis Pacific Northwest National Lab P.O. Box 999 Richland WA 99352 USA, Department of Chemistry and Catalysis Research Institute Technische Universität München Lichtenbergstrasse 4 85748 Garching Germany
  9. Materials Science Division Argonne National Lab 9700 S Cass Ave. Argonne IL 60439 USA, Department of Chemistry Northwestern University 2145 Sheridan Rd. Evanston IL 60208 USA
  10. Materials Science Division Argonne National Lab 9700 S Cass Ave. Argonne IL 60439 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1415320
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 4; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Kim, In Soo, Li, Zhanyong, Zheng, Jian, Platero‐Prats, Ana E., Mavrandonakis, Andreas, Pellizzeri, Steven, Ferrandon, Magali, Vjunov, Aleksei, Gallington, Leighanne C., Webber, Thomas E., Vermeulen, Nicolaas A., Penn, R. Lee, Getman, Rachel B., Cramer, Christopher J., Chapman, Karena W., Camaioni, Donald M., Fulton, John L., Lercher, Johannes A., Farha, Omar K., Hupp, Joseph T., and Martinson, Alex B. F. Sinter‐Resistant Platinum Catalyst Supported by Metal–Organic Framework. Germany: N. p., 2018. Web. doi:10.1002/ange.201708092.
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Kim, In Soo, Li, Zhanyong, Zheng, Jian, Platero‐Prats, Ana E., Mavrandonakis, Andreas, Pellizzeri, Steven, Ferrandon, Magali, Vjunov, Aleksei, Gallington, Leighanne C., Webber, Thomas E., Vermeulen, Nicolaas A., Penn, R. Lee, Getman, Rachel B., Cramer, Christopher J., Chapman, Karena W., Camaioni, Donald M., Fulton, John L., Lercher, Johannes A., Farha, Omar K., Hupp, Joseph T., & Martinson, Alex B. F. Sinter‐Resistant Platinum Catalyst Supported by Metal–Organic Framework. Germany. https://doi.org/10.1002/ange.201708092
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Kim, In Soo, Li, Zhanyong, Zheng, Jian, Platero‐Prats, Ana E., Mavrandonakis, Andreas, Pellizzeri, Steven, Ferrandon, Magali, Vjunov, Aleksei, Gallington, Leighanne C., Webber, Thomas E., Vermeulen, Nicolaas A., Penn, R. Lee, Getman, Rachel B., Cramer, Christopher J., Chapman, Karena W., Camaioni, Donald M., Fulton, John L., Lercher, Johannes A., Farha, Omar K., Hupp, Joseph T., and Martinson, Alex B. F. Tue . "Sinter‐Resistant Platinum Catalyst Supported by Metal–Organic Framework". Germany. https://doi.org/10.1002/ange.201708092.
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@article{osti_1415320,
title = {Sinter‐Resistant Platinum Catalyst Supported by Metal–Organic Framework},
author = {Kim, In Soo and Li, Zhanyong and Zheng, Jian and Platero‐Prats, Ana E. and Mavrandonakis, Andreas and Pellizzeri, Steven and Ferrandon, Magali and Vjunov, Aleksei and Gallington, Leighanne C. and Webber, Thomas E. and Vermeulen, Nicolaas A. and Penn, R. Lee and Getman, Rachel B. and Cramer, Christopher J. and Chapman, Karena W. and Camaioni, Donald M. and Fulton, John L. and Lercher, Johannes A. and Farha, Omar K. and Hupp, Joseph T. and Martinson, Alex B. F.},
abstractNote = {Abstract Single atoms and few‐atom clusters of platinum are uniformly installed on the zirconia nodes of a metal‐organic framework (MOF) NU‐1000 via targeted vapor‐phase synthesis. The catalytic Pt clusters, site‐isolated by organic linkers, are shown to exhibit high catalytic activity for ethylene hydrogenation while exhibiting resistance to sintering up to 200 °C. In situ IR spectroscopy reveals the presence of both single atoms and few‐atom clusters that depend upon synthesis conditions. Operando X‐ray absorption spectroscopy and X‐ray pair distribution analyses reveal unique changes in chemical bonding environment and cluster size stability while on stream. Density functional theory calculations elucidate a favorable reaction pathway for ethylene hydrogenation with the novel catalyst. These results provide evidence that atomic layer deposition (ALD) in MOFs is a versatile approach to the rational synthesis of size‐selected clusters, including noble metals, on a high surface area support.},
doi = {10.1002/ange.201708092},
journal = {Angewandte Chemie},
number = 4,
volume = 130,
place = {Germany},
year = {Tue Jan 02 00:00:00 EST 2018},
month = {Tue Jan 02 00:00:00 EST 2018}
}
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Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1002/ange.201708092
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