Chemical Synthesis of 3D Graphene‐Like Cages for Sodium‐Ion Batteries Applications
Abstract
Abstract Sodium (Na) super ion conductor structured Na 3 V 2 (PO 4 ) 3 (NVP) is extensively explored as cathode material for sodium‐ion batteries (SIBs) due to its large interstitial channels for Na + migration. The synthesis of 3D graphene‐like structure coated on NVP nanoflakes arrays via a one‐pot, solid‐state reaction in molten hydrocarbon is reported. The NVP nanoflakes are uniformly coated by the in situ generated 3D graphene‐like layers with the thickness of 3 nm. As a cathode material, graphene covered NVP nanoflakes exhibit excellent electrochemical performances, including close to theoretical reversible capacity (115.2 mA h g −1 at 1 C), superior rate capability (75.9 mA h g −1 at 200 C), and excellent cyclic stability (62.5% of capacity retention over 30000 cycles at 50 C). Furthermore, the 3D graphene‐like cages after removing NVP also serve as a good anode material and deliver a specific capacity of 242.5 mA h g −1 at 0.1 A g −1 . The full SIB using these two cathode and anode materials delivers a high specific capacity (109.2 mA h g −1 at 0.1 A g −1 ) and good cycling stability (77.1% capacity retention over 200 cycles at 0.1 A gmore »
- Authors:
-
- School of Material Science and Engineering Central South University Changsha 410083 P. R. China
- Department of Materials Science &, Engineering University of Washington Seattle WA 98195 USA
- Pacific Northwest National Laboratory Richland WA 99352 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401552
- Grant/Contract Number:
- KC020105‐FWP12152
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Name: Advanced Energy Materials Journal Volume: 7 Journal Issue: 20; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Cao, Xinxin, Pan, Anqiang, Liu, Sainan, Zhou, Jiang, Li, Site, Cao, Guozhong, Liu, Jun, and Liang, Shuquan. Chemical Synthesis of 3D Graphene‐Like Cages for Sodium‐Ion Batteries Applications. Germany: N. p., 2017.
Web. doi:10.1002/aenm.201700797.
Cao, Xinxin, Pan, Anqiang, Liu, Sainan, Zhou, Jiang, Li, Site, Cao, Guozhong, Liu, Jun, & Liang, Shuquan. Chemical Synthesis of 3D Graphene‐Like Cages for Sodium‐Ion Batteries Applications. Germany. https://doi.org/10.1002/aenm.201700797
Cao, Xinxin, Pan, Anqiang, Liu, Sainan, Zhou, Jiang, Li, Site, Cao, Guozhong, Liu, Jun, and Liang, Shuquan. Fri .
"Chemical Synthesis of 3D Graphene‐Like Cages for Sodium‐Ion Batteries Applications". Germany. https://doi.org/10.1002/aenm.201700797.
@article{osti_1401552,
title = {Chemical Synthesis of 3D Graphene‐Like Cages for Sodium‐Ion Batteries Applications},
author = {Cao, Xinxin and Pan, Anqiang and Liu, Sainan and Zhou, Jiang and Li, Site and Cao, Guozhong and Liu, Jun and Liang, Shuquan},
abstractNote = {Abstract Sodium (Na) super ion conductor structured Na 3 V 2 (PO 4 ) 3 (NVP) is extensively explored as cathode material for sodium‐ion batteries (SIBs) due to its large interstitial channels for Na + migration. The synthesis of 3D graphene‐like structure coated on NVP nanoflakes arrays via a one‐pot, solid‐state reaction in molten hydrocarbon is reported. The NVP nanoflakes are uniformly coated by the in situ generated 3D graphene‐like layers with the thickness of 3 nm. As a cathode material, graphene covered NVP nanoflakes exhibit excellent electrochemical performances, including close to theoretical reversible capacity (115.2 mA h g −1 at 1 C), superior rate capability (75.9 mA h g −1 at 200 C), and excellent cyclic stability (62.5% of capacity retention over 30000 cycles at 50 C). Furthermore, the 3D graphene‐like cages after removing NVP also serve as a good anode material and deliver a specific capacity of 242.5 mA h g −1 at 0.1 A g −1 . The full SIB using these two cathode and anode materials delivers a high specific capacity (109.2 mA h g −1 at 0.1 A g −1 ) and good cycling stability (77.1% capacity retention over 200 cycles at 0.1 A g −1 ).},
doi = {10.1002/aenm.201700797},
journal = {Advanced Energy Materials},
number = 20,
volume = 7,
place = {Germany},
year = {Fri Jul 14 00:00:00 EDT 2017},
month = {Fri Jul 14 00:00:00 EDT 2017}
}
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