Chemical Synthesis of 3D Graphene-Like Cages for Sodium-Ion Batteries Applications

Cao, Xinxin; Pan, Anqiang; Liu, Sainin; Zhou, Jiang; Li, Site; Cao, Guozhong; Liu, Jun; Liang, Shuquan

doi:10.1002/aenm.201700797

Title: Chemical Synthesis of 3D Graphene-Like Cages for Sodium-Ion Batteries Applications

Journal Article · Wed Oct 25 00:00:00 EDT 2017 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201700797· OSTI ID:1510981

Cao, Xinxin ^[1]; Pan, Anqiang ^[1]; Liu, Sainin ^[1]; Zhou, Jiang ^[1]; Li, Site ^[1]; Cao, Guozhong ^[2]; Liu, Jun ^[3]; Liang, Shuquan ^[1]

Central South University
University of Washington
BATTELLE (PACIFIC NW LAB)

Sodium (Na) super ion conductor structured Na3V2(PO4)3 (NVP) is extensively explored as cathode material for sodium-ion batteries (SIBs) due to its large interstitial channels for Na+ migration. The synthesis of 3D graphene-like structure coated on NVP nanoflakes arrays via a one-pot, solid-state reaction in molten hydrocarbon is reported. The NVP nanoflakes are uniformly coated by the in situ generated 3D graphene-like layers with the thickness of 3 nm. As a cathode material, graphene covered NVP nanoflakes exhibit excellent electrochemical performances, including close to theoretical reversible capacity (115.2 mA h g-1 at 1 C), superior rate capability (75.9 mA h g-1 at 200 C), and excellent cyclic stability (62.5% of capacity retention over 30000 cycles at 50 C). Furthermore, the 3D graphene-like cages after removing NVP also serve as a good anode material and deliver a specific capacity of 242.5 mA h g-1 at 0.1 A g-1. The full SIB using these two cathode and anode materials delivers a high specific capacity (109.2 mA h g-1 at 0.1 A g-1) and good cycling stability (77.1% capacity retention over 200 cycles at 0.1 A g-1).

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1510981

Report Number(s):: PNNL-SA-136333

Journal Information:: Advanced Energy Materials, Vol. 7, Issue 20

Country of Publication:: United States

Language:: English

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